TiAl合金表面激光重熔等离子喷涂MCrAlY涂层研究

为了进一步提高TiAl合金表面等离子喷涂MCrAlY涂层的高温氧化性能,采用激光重熔工艺对涂层进行处理,研究了激光重熔对涂层微观组织及抗氧化性能的影响.用扫描电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)分析了涂层氧化前后的表面形貌、微观组织和相组成.结果表明:经过激光重熔处理后,涂层片层状组织得以消失,致密性提高,消除了喷涂层的大部分孔洞、夹杂等缺陷,同时使Al元素在涂层表面的重新分布,形成了Al的富集区;等离子喷涂MCrAlY层能显著提高TiAl合金的抗高温氧化性能,经过激光重熔后可进一步提高其抗高温氧化性能.     

铜合金表面热喷涂镍基合金层激光重熔后的显微组织及耐磨性能

为了满足工业领域铜合金传热、耐磨、耐腐蚀性能优异的要求,对铜合金表面先等离子喷涂NiCrFeWBC自熔合金层,再进行激光重熔.采用现代分析技术研究了重熔处理对涂层显微组织及耐磨性能的影响.结果表明:等离子喷涂NiCrFeWBC自熔合金涂层重熔后层状组织、孔洞等缺陷完全消失,激光熔覆层与铜基体为冶金结合,涂层致密、组织均匀;熔覆层由表及里依次呈等轴晶、树枝晶及胞状晶形貌,并有WC,W_2C,Ni_3B等颗粒析出;熔覆层磨损性能明显高于铜合金基体及热喷涂涂层,磨损机理为典型的磨粒磨损.     

WC基热喷涂金属陶瓷涂层的激光改性研究

本工作研究了CO2激光重熔处理对超音速火焰喷涂WC--Co和WC--NiCr涂层的组织结构和摩擦学行为的影响。结果表明：选定优化参数下,激光重熔可降低涂层气孔率,提高涂层显微硬度,涂层与基材之间实现冶金结合;干摩擦条件下,涂层经过激光重熔处理耐磨性能显著提高;但润滑条件下劣于未经重熔处理涂层,这可能与未重熔涂层含有较多的气孔,可存储润滑油较好地发挥润滑效果有关。     

Laser surface remelting of WC–12Co coating: finite element simulations and experimental analyses

A three-dimensional finite element model taking into account interfacial topography, porosity of plasma sprayed coatings, temperature dependent thermophysical parameters and phase change has been developed to simulate multipass laser remelting process. Temperature evolution, temperature gradient, melting pool shape and dimensions are simulated. The laser remelting experiments are carried out on the plasma sprayed WC–12Co coatings. The simulated results are in good agreement with the experimental measurements. After laser remelting, a denser and more homogenous coating is obtained. The microhardness of the coating is significantly enhanced owing to the dispersion strengthening, the fine grain strengthening and the solution strengthening, which is increased by three times compared with that of the plasma sprayed coatings.     

Development of wear resistant composite surface on mild steel by laser surface alloying with silicon and reactive melting

The present study concerns laser surface alloying with silicon of mild steel substrate using a high-power continuous wave CO₂ laser with an objective to improve wear resistance. The effect of surface remelting using nitrogen as shrouding environment (with and without graphite coating) on microhardness and wear resistance has also been evaluated. Laser surface alloying leads to formation of a defect free microstructure consisting of iron silicides in laser surface alloyed mild steel with silicon and a combination of silicides and nitrides when remelted in nitrogen. Carbon deposition prior to remelting leads to presence of a few martensite in the microstructure. A significant improvement in microhardness is achieved by laser surface alloying and remelting to a maximum of 800 VHN when silicon alloyed surface is melted using nitrogen shroud with carbon coating. A detailed wear study (against diamond) showed that a significant improvement in wear resistance is obtained with a maximum improvement when remelted in nitrogen atmosphere followed by carbon coating.     

激光重熔对NiCrBSi等离子喷涂层显微结构和性能的影响

1Crl8Ni9Ti不锈钢表面的NiCrBSi等离子喷涂层存在孔洞及与基体结合差等缺陷,为此进行了激光重熔处理.采用扫描电镜和显微硬度压痕仪分别对涂层的显微结构和力学性能进行了对比研究,采用SRV试验机评价了涂层激光重熔前后的滑动摩擦磨损性能,研究了激光重熔对NiCrBSi等离子喷涂层结构和性能的影响.结果表明:经过激...     

激光表面重熔等离子喷涂陶瓷涂层的研究与发展

总结了等离子喷涂陶瓷涂层的缺欠以及激光重熔等离子喷涂陶涂层所存在的问题,在分析问题产生原因的基础上,提出了防止激光重熔等离子喷涂陶瓷涂层裂纹,气孔和剥等问题的同时指出了激光了涂陶瓷涂层的发展趋势。     

铜基体低压等离子体钨喷涂层激光重熔后的结构与性能

在紫铜上直接喷涂的金属钨(W)层容易出现早期剥落。采用低压等离子体技术制备了Ni-Cu底层、Ni-W中间层和W层;利用大功率CO2激光束对W涂层重熔,研究了激光重熔处理对W涂层显微组织、致密度、结合强度及显微硬度的影响。结果表明:低压等离子喷涂的W层主要呈层状结构,W颗粒熔化不充分,涂层中存在大量的孔洞等缺陷;激光重熔后,W涂层表面的W颗粒已完全熔化,并在激光冷效应的作用下形成了一层厚度约为300μm的细晶组织,W涂层的致密度、结合强度得到了明显的提高。     

常规和纳米ZrO_2-7%Y_2O_3等离子喷涂热障层及其激光重熔后的抗热震性能

为了探讨激光重熔对等离子喷涂常规和纳米热障涂层(TBCs)的影响,采用等离子喷涂工艺在γ-TiAl合金表面制备了常规和纳米ZrO2-7%Y2O3TBCs,并对其进行激光重熔处理,研究了等离子喷涂常规TBCs、激光重熔-等离子喷涂常规TBCs、等离子喷涂纳米TBCs及激光重熔-等离子喷涂纳米TBCs 4种涂层在850℃下的抗热震性能。结果表明:4种TBCs热震失效次数依次为73,118,146,163次,相应的热震破坏形式分别为整体剥落、局部剥落、边角剥落和局部剥落;纳米结构有利于提高涂层的抗热震性能;激光重熔在一定程度上改善了等离子喷涂层的抗热震性能。     

Laser Surface Strengthening Process of Al-Si Base Alloy

With a laser beam, the surface remelting/resolidifying treatment of ZL108 alloy was studied. Test results showed that a compact remelting layer was obtained with appropriate laser processing conditions and a suitable surface coating for laser energy absorption. The eutectic silicon phase in the laser-treating zone changed from the shape of thick-plate (stripe) into the very small grains, the structure was extremely fined, the hardness and wear resistance were improved greatly compared with that of the base alloy. A laser -treating layer, which is 3.5 mm thick and 5 mm wide, could be obtained.     

激光表面重熔对等离子喷涂氧化铝陶瓷涂层耐腐蚀性的影响

通过采用激光表面重熔和在氧化铝涂层中加入稀土的工艺方法，封闭了表层中残存的孔隙，减少了微裂纹。不仅提高涂层的质量，而且使其耐蚀性得到明显提高。     

TiAl合金表面激光重熔热障涂层组织及抗高温氧化性能

为了进一步提高TiAl合金表面等离子喷涂ZrO2-7%(质量分数)Y203热障陶瓷涂层的性能,采用激光重熔工艺对涂层进行处理,研究了激光重熔对涂层微观组织和抗高温氧化性能的影响.用扫描电镜(SEM)分析了涂层形貌和微观结构,同时对其抗高温(850℃)氧化性能进行了考察.结果表明,等离子喷涂热障陶瓷涂层呈典型的层状堆积特征,有一定的孔隙且分布有微裂纹;经过激光重熔处理后,陶瓷涂层片层状组织得以消失,致密性提高,获得了基本没有裂纹等缺陷的重熔层;整个重熔层包括界面没有明显特征的平面晶和上部沿热流方向生长的柱状晶组织.等离子喷涂热障涂层具有较好的抗高温氧化性能,经过激光重熔后可进一步提高其抗高温氧化能力.     

氩弧重熔对20G钢渗硼层组织结构和耐磨性能的影响

为了降低渗硼层的脆性,提高其耐磨性,对20G钢渗硼层进行了氩弧重熔处理,研究了渗硼层重熔前后的形貌、相结构、显微硬度及耐磨性。结果表明：渗硼层由FeB和Fe2B两相组成,经氩弧重熔处理后FeB相消除,氩弧重熔渗硼层由Fe23（C,B）6和Fe2B相组成,包括氩弧重熔区和过渡区;氩弧重熔处理使渗硼层表层微观硬度降低,且使...     

Oxidation Behaviour of Laser Remelted Cr-containing Steels

Laser surface remelting of steels with different Cr contents has been performed by using a CO_2 laser.The results of oxidation tests showed that the effects of laser remelting on the oxidation resistance ofCr-containing steels have close relation to the Cr contents and microstructures of the steels. The re-sistance to high temperature oxidation of 18-8 and HK40 at 1273 K can be obviously improved bylaser remelting, whereas laser remelting showed little effect on the oxidation resistance of Fe-6Crand Cr30 at 1173-1273 K.     

Laser surface remelting of Cu–Cr–Fe contact material

Abstract

Laser surface remelting/resolidifying treatment on a powder metallurgically manufactured Cu–Cr–Fe contact material was studied. Test results showed that a compact remelting/resolidifying layer was obtained with appropriate laser treatment conditions and a suitable surface absorption coating. After such treatment, the Cu–Cr–Fe microstructure was greatly refined and the Cr phase was uniformly dispersed in the Cu rich matrix with fine spherical or near spherical form. Improved compactness and microstructure of the laser remelted Cu–Cr–Fe material yielded increased hardness (by ~80%), wear resistance, and a reduced friction coefficient compared with the base material. The mechanism of laser strengthening is discussed in relation to the microstructural features of the Cu–Cr–Fe material.     

Ni–TiC coating deposited on Ti–6Al–4V substrate by thermal spraying and laser remelting of Ni-clad graphite powder

A process of thermal spraying and laser remelting of a Ni-clad graphite powder to form a coating on Ti–6Al–4V substrate was carried out. A good coating without cracks and pores was obtained. The microstructure of the coating was examined using SEM and EDS. The coating mainly consists of austenitic nickel as matrix and TiC dendrite as reinforcement. During the laser remelting process, a reaction between C and Ti occurred, which lead to an in-situ synthesis of TiC reinforcement in the coating. The microhardness of the coating was measured using a Vickers hardness tester. The average microhardness of the composite coating is HV 1000 and it is two times greater than that of the Ti–6Al–4V substrate.     

铸铁激光表面重熔过程中表面涂层的作用

本文采用比较的方法研究了激光表面重熔过程中表面涂层、工艺参数与熔化深度、熔区化学成分、显微组织和显微硬度之间变化规律。发现表面涂层不但可提高金属对激光的吸收率,而且渗入熔化区,参与相变,改变强化效果。     

Homogenization of Carbides in Ni60/WC Composite Coatings Made by Fiber Laser Remelting

In the current study, the effect of laser remelting on homogenization of carbides in WC-reinforced Ni60 composite coatings was investigated. Ni60 + 50 wt% WC composite coatings were fabricated on the surface of Q550 steel by LDF4000-100 fiber laser device. First cladding layer was made by rectangle laser spot and then circular laser spot was utilized to remelt the coatings. Microstructure characteristics were investigated by optical microscope and scanning electron microscopy. Elemental distribution and phase constitution were analyzed by energy disperse spectroscopy and X-ray diffraction. The results showed that accumulation of residual WC particles was sufficiently eliminated under the effect of laser remelting. The irregularly shaped carbides in first cladding layer were transformed into well-distributed polygonal carbides by laser remelting. Statistical analysis indicated median size of reinforcement particles decreased from 35.40 to 5.62 µm. Microhardness of remelted region had a smooth profile and decreased by ?50 HV_0.1 than that of first cladding region. Homogenization of carbides in nickel composite coating was well realized by laser remelting.     

Microstructural characterisation and corrosion behaviour of laser cladded Al–12Si alloy onto magnesium AS41/carbon fibre composite

Abstract

The quality and properties of laser clad layers are dependent on the microstructure and properties of the interfaces with the substrate. The present paper reports, in details, on the characterisation of microstructure of the coating and interfacial layers evolved as a result of the CO₂ laser remelting of previously plasma sprayed Al–12Si alloy onto C short fibres reinforced AS41–Mg composite. Scanning electron microscopy (SEM), wavelength dispersive X-ray (WDX) analysis and X-ray diffraction (XRD) were employed to identify the phases arising in the interfacial layers. The latter are composed mainly of Mg₁₇Al₁₂ and Mg₂Si phases. XRD was conducted on the clad layers at different distances from the interface. At the same layers, the potentiodynamic polarisation in sodium chloride solution was measured and it was found that as the Mg content increases in the clad coating, the corrosion resistance decreases. However, the corrosion current of the clad coating is around two orders of magnitude lower than that of the C/Mg composite.     

Crack Formation in Gas-Thermal Coatings Depending on the Conditions of Their Laser Remelting

In the course of heating of Fe–Cr–B–Al electrometallized coatings on low-alloy steel by a scanning CO₂ laser beam, cracks, oriented mainly perpendicularly to the direction of scanning, can be initiated in the paths of the remelted coating. If the depth of the coating is small, the number of cracks and their width are greater. If the depth of remelting is comparable with the initial thickness of the coating, the number of cracks after its remelting decreases sharply.