共查询到17条相似文献,搜索用时 0 毫秒
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1电偶腐蚀的影响因素(1)面积效应(阴极和阳极之间的面积比)是电偶腐蚀的一个重要因素,对腐蚀速度有着重大的影响,随着阴极对阳极面积比的增大,阳极金属的腐蚀增大。(2)氯化钠浓度低于1%时,腐蚀速度随其增高而增大;等于1%时,腐蚀速度达到最大值;高于1... 相似文献
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对比了电偶对材料的自腐蚀电位和各自的极化曲线,以及同一阴阳极面积比下,偶接后的混合电位和电流密度,研究了09MnNiDR和不锈钢(316L、304冷轧板、304热轧板、201)电偶对在3.5%的Na Cl溶液中的电偶腐蚀特性。结果表明,09MnNiDR处于活化状态,4种不锈钢则比较稳定;不锈钢的自腐蚀电位高于09MnNiDR,偶接后不锈钢作为阴极被保护,而09MnNiDR作为阳极腐蚀加剧。电偶腐蚀效应的大小为:09MnNiDR/316L09MnNiDR/20109MnNiDR/304热轧板09MnNiDR/304冷轧板。 相似文献
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研究了温度对T700碳纤维复合材料(CFRP)与不锈钢和6061铝合金之间的电偶腐蚀的影响,以及电偶腐蚀电流及其腐蚀速率对材料表面形貌的影响。结果表明:CFRP与6061铝合金在氯化钠(NaCl)电解质溶液体系中会发生电偶腐蚀,而CFRP与不锈钢在NaCl电解质溶液体系中则会发生较小的电偶腐蚀;随着温度的增加,CFRP与6061铝合金发生的电偶腐蚀电流、平均电偶腐蚀速率相应增大,表面腐蚀现象更加严重;在NaCl电解质溶液体系中电偶腐蚀作用对CFRP影响不大,CFRP基本没有受到腐蚀。 相似文献
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《Desalination》1987
Galvanic currents and potentials have been measured for bimetallic couples involving carbon steel, three grades of stainless steel, 90 Cu/10 Ni and titanium when exposed to seawater in the laboratory at temperatures of 18C and 60C and varying oxygen content. The galvanic currents flowing between couples consisting of two of the corrosion-resistant materials were very small. The galvanic corrosion rate of carbon steel, when connected to one of the other materials, was dependent upon the cathodic-polarisation characteristics of the noble-material surface with indications that, at a given area ratio, the galvanic corrosion of carbon steel was greater when coupled to the 90 Cu/10 Ni alloy than when connected to stainless steel or titanium. The usual effects of increasing the anode/cathode area ratio were observed and data were obtained to demonstrate quantitatively the significant beneficial effect of coating the cathode in a bimetallic couple. Intermediate air exposures were not found to promote any large, long-term, effects on galvanic corrosion. There was evidence that galvanic corrosion rates were very small when the dissolved oxygen content was controlled at low levels and some interesting aspects of galvanic corrosion at the higher temperature were noted. 相似文献
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In this work, corrosion and localized corrosion behavior of X65 pipeline steel were studied in a simulated, CO2-saturated oilfield formation water by various electrochemical measurement techniques, including electrochemical impedance spectroscopy (EIS), potentiodynamic polarization curves, galvanic current and localized EIS (LEIS). The morphology and composition of the formed corrosion scale were characterized by scanning electron microscopy and energy-dispersive X-ray analysis. A conceptual model was developed to illustrate the occurrence of localized corrosion of the steel under scale. Both galvanic current and LEIS measurements showed that a galvanic effect existed between the bare steel and the scale-covered region. The scale-covered region served as cathode and the bare steel site as the anode. The big cathode vs. small anode geometry accelerated the local corrosion reaction. At an elevated temperature, a compact, crystalline scale was formed on the steel surface, enhancing the galvanic effect. Moreover, the stability of the scale was increased with time, and localized corrosion of the steel under scale experienced mechanistic changes with time. 相似文献
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The state in which a stainless steel (STS) exhibits a very low corrosion rate is known as passivity, which is self-healing
in a wide variety of environments. However, for those STS the corrosion includes pitting, crevice corrosion, galvanic corrosion,
hydrogen embrittlement and stress corrosion cracking etc. And the corrosion resistance of STS is affected by area ratio, solution
temperature and solution condition etc. Corrosion characteristics of STS 304, welding parts STS 316, STS 329 and STS 444 were
investigated with parameters such as corrosion potential, galvanic current measurements, cathodic and anodic polarization
behaviors as a function of area ratio and solution temperature in solution for hot water tank. It was found that galvanic
current is affected by the area ratio, temperature and a kind of STS for hot water tank. Corrosion potential of welding part
STS 316 was lower than that of STS 304, STS 329, STS 444 in solution for #1, #2 hot water tank. Therefore, it is suggested
that the welding part STS 316 acts as anode for the other STSs. The amplitude of galvanic current between welding parts STS
316 and STS 304, STS 329, STS 444 in #1 solution is smaller than that in #2 solution. This is the reason that chloride ion
quantity in #2 solution is more than that for #1 solution. And then welding part STS 316 corrodes easily by acting as anode
compared to the other STS. 相似文献
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The mechanisms of corrosion inhibition of AA2024-T3 by vanadates were studied in this work using the split cell technique and polarization curves. The electrochemical behavior of clear solutions containing metavanadates and orange solutions containing decavanadates was clearly distinctive. Injection of metavanadates to the cathode side of the different split cell setups greatly reduced the galvanic current, indicating a potent inhibition of the oxygen reduction kinetics. The galvanic current never exhibited a transient current peak, suggesting that metavanadates inhibit AA2024-T3 corrosion by a mechanism that does not involve electrochemical reduction. Injection of metavanadate to the anode side of the different split cells had no effect on the galvanic current. Injection of orange decavanadate to the cathode side of the AA2024-T3 split cell resulted in a large current peak, associated with the electrochemical reduction of decavanadate. However, decavanadates did not impart significant corrosion protection. 相似文献
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原位测定金属/溶液界面微区物化参数分布对研究金属局部腐蚀的发生、发展机理有重要意义。本研究应用扫描微参比电极(SMRE)技术对NaC l溶液中印刷电路板Cu-焊锡界面局部腐蚀早期表面微区电位分布进行测量。结果表明:在0.5mol/LNaC l溶液中焊锡电极电位基本稳定在-0.47V附近,纯铜电极的电位基本稳定在-0.19V附近,两者差别较大;Cu/焊锡浸入0.5mol/L NaC l溶液中前期局部腐蚀发生在Cu与焊锡相接触的界面上且腐蚀程度随时间逐渐达到最大。后期焊锡作为阳极腐蚀逐渐加剧而铜作为阴极受到保护,腐蚀程度逐渐减弱,直至焊锡最终全面腐蚀。 相似文献
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The corrosion mechanism of X80 steel in simulated solutions of acid red soil and product oil sediment under mechano-electrochemical interaction (MEI) was researched to build a new finite element model through multi-physical field coupling simulation technology. Based on the new model, the effect of external wall defect growth on the internal wall corrosion of oil pipelines was analyzed in detail. The results showed that the distributions of stress and corrosion of the internal wall were extremely affected by the external wall defect depth, and the corrosion rate of the internal wall was enlarged remarkably by the external wall defect growth. Moreover, attributing to the local galvanic cell effect under MEI, the growth rates of corrosion defects in the depth and length directions of the external defect were accelerated because these directions were associated with larger stress and equivalent to the anode, but the corrosion rate in the width direction of the external defect was inhibited because this direction was associated with smaller stress and equivalent to the cathode. 相似文献
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A new occluded corrosion cavity (OCC) simulation cell was designed to study the underscale corrosion behavior of carbon steel
(N80) in 0.2 mol L−1 NaCl solution. The chemical components of the solution in the OCC were measured and the electrochemical behavior of the occluded
anode and the bulk cathode were studied by electrochemical impedance spectroscopy (EIS). The newly designed OCC cell can easily
simulate the auto-catalyzing acidification process and may be used to study the mechanism of underscale corrosion. The corrosion
scale exacerbates the underscale corrosion and the area ratio of the bulk cathode to the occluded anode (R = Sc/Sa) determines the development of simulated localized corrosion in the OCC cell. When R was within a certain range, the corrosion rate in the OCC could be kept at a persistently high level. The pH of the solution
in the OCC decreased and the chloride ions (Cl−) concentrated as the local corrosion developed. The anodic process on the occluded anode was controlled by irreversible charge
transfer and the cathodic process on the bulk cathode was controlled mainly by oxygen diffusion. 相似文献