共查询到20条相似文献,搜索用时 56 毫秒
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Al4SiC4是一种极好的抗水化化合物,它作为含炭耐火材料的抗氧化剂,对其性能用作用进行了研究,并探讨了相应机理。Al4SiC4添加到含炭耐火材料中,起初与CO反应,生成Al2O3、SiC和Co反应后,如果温度在-1560℃以下,生成的SiC和Al2Oe将进一步与CO应生成莫来石(Al6SiC2O13)和Co。在耐火材料表面进行的上述反应形成了保护层,这就阻止了耐火材料的氧化。为此,Al4SiC4 相似文献
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C-B4C-SiC与Ti组分的原位反应及热压烧结 总被引:1,自引:0,他引:1
以炭黑、炭纤维、B4C、SiC、Si、TiO2和TiC为原料制备了不同TiO2和TiC含量的炭/陶复合材料,采用原位合成及热压技术研究了不同TiO2和TiC含量对多组分炭/陶复合材料的组成、结构和性能的影响。在烧结过程中TiO2和TiC与B4C反应原位生成TiB2,Si和TiO2分别与C反应生成SiC和TiC,这些陶瓷相的生成对提高炭/陶复合材料的力学性能有显著作用。加入TiO2能使炭/陶复合材料在较低的温度下实现致密化烧结,获得了抗弯强度达430MPa的炭/陶复合材料 相似文献
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Luen-Yuan Chao R. Lakshminarayanan Dinesh K. Shetty Raymond A. Cutler 《Journal of the American Ceramic Society》1995,78(9):2307-2313
The rolling-contact fatigue life and wear of CVD-SiC coatings with surface compression were studied using a three- ball-on-rod rolling-contact fatigue (RCF) tester. Two levels of surface compression in the coatings, approximately 190 μm thick, were introduced by using substrates of a liquid-phase sintered SiC and a SiC-30 vol% TiC to obtain desired thermal-expansion mismatches with the CVD-SiC. Residual surface compressions of 250 and 680 MPa were measured in the CVD-SiC coatings on SiC and SiC-30 vol% TiC substrates, respectively, by a strain-gage technique. In the RCF test, the fatigue life of the CVD-SiC coating with the moderate surface compression was limited by severe wear by a brittle fracture mechanism at a Hertzian contact stress of 5.5 GPa. The CVD-SiC coating on the SiC-30 vol% TiC composite, on the other hand, did not show measurable wear. A majority of the tests (11 out of 16) were suspended at 100 h or stopped due to failure of the steel balls. Five tests stopped due to spalling of the CVD-SiC coating at weak interfaces 10 to 15 μm below the contact surface. Examination of the microstructure of the CVD-SiC coating in cross sections revealed that the weak interfaces that led to the spalling were related to discontinuous growth of the CVD-SiC in the form of nodules or growth regions. Elimination of these defective structures is likely to enhance the tribological performance of surface-toughened CVD-SiC. 相似文献
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N. CoceraN. Remirez de Esparza I. OcañaJ.M. Sanchez 《Journal of the European Ceramic Society》2011,31(6):1155-1164
Oxidation tests have been carried out on highly porous ceramic matrix fiber composites consisting of Tyranno Lox M fibers coated with Pyro C and CVD-SiC thin layers. TGA experiments carried out at 900 °C confirm that mass loss rates are higher for materials with thicker Pyro C layers. At higher temperatures (i.e. 1250 °C) such differences are not significant likely due to the interaction between SiC oxidation and Pyro C burnout. These tests clearly show that the oxidation kinetics of Tyranno fibers are much faster than those of CVD-SiC coatings. Therefore, the CVD-SiC coatings protect the Tyranno fibers against oxidation, although this is less effective as the thickness of the Pyro C layer increases. Finally, it has been found that the oxidation kinetics of the CVD-SiC layers are faster as the coating thickness increases and are different for the inner and the outer coating surfaces. 相似文献
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A feed-forward, multilayer perceptron artificial neural network (ANN) model with eight hidden layers and 12 neurons was used to predict the corrosion behavior of Ni–SiC composite coatings deposited by ultrasonic electrodeposition. The effect of process parameters, namely, ultrasonic power, SiC particle concentration, and current density, on the weight losses of Ni–SiC composite coatings was investigated. The grain sizes of Ni and SiC were determined by using X-ray diffraction (XRD) and scanning probe microscopy (SPM). Results indicate that ultrasonic power, SiC particle concentration, and current density have significant effects on the weight losses of Ni–SiC composite coatings. The ANN model, which has a mean square error of approximately 3.35%, can effectively predict the corrosion behavior of Ni–SiC composite coatings. The following optimum conditions for depositing Ni–SiC composite coatings were determined on the basis of the lowest weight loss of Ni–SiC deposits: ultrasonic power of 250 W, SiC particle concentration of 8 g/l, and current density of 4 A/dm2. XRD and SPM results demonstrate that the average grain sizes of Ni and SiC in the Ni–SiC composite coating are 90 and 70 nm, respectively. 相似文献
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Coverage of artificial surfaces within seawater by fouling organisms is defined as biofouling. Although biofouling is a natural process, it has some disadvantages for shipping industry such as increased fuel consumption, and CO2 emission. Therefore, the ships' hull must be covered by antifouling (AF) or fouling release type coatings to overcome biofouling. In general, the so-called self-polishing AF paints contain biocides for preventing fouling organisms. Their concentrations and release rates from AF coatings are of great importance and they definitely affect both quality and cost of the coating. In the present study, we aimed at applying a new robust method. In this method, we used a model biocide, i.e., econea, to obtain its RP-HPLC optimization through artificial neural networks (ANN) and to see its antifouling performance. Column temperature, mobile phase ratio, flow rate, concentration and wavelength as input parameters and retention time as an output parameter were used in the ANN modeling. In conclusion, the R&D groups in AF paint industry may use RP-HPLC method supported with ANN modeling in further studies. 相似文献
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Ming-Der Jean Bor-Tsuen Lin Jyh-Horng Chou 《Journal of the American Ceramic Society》2008,91(5):1539-1547
This article presents the application of the artificial neural network (ANN) of a statistically designed experiment for developing a robust wear-resistant zirconia coating. In this research, experimental design with orthogonal arrays efficiently provides enough information with the least number of experiments, reducing the cost and time. A radial basis function (RBF) network for the wear behavior is adopted. The friction and tribological properties of zirconia coatings were investigated. The microstructural feature of the coatings is also addressed in this study. It is found that the worn volumes of plasma-sprayed zirconia coatings after wear tests are greatly improved by the optimal parameters. The relationships between the microstructure of the worn surface and their properties are examined, and the results reveal a higher wear resistance and a lower worn surface roughness with a large amount of plastic deformations. These wear resistant structures formed as a result of a dense lamellar formation during sprayed zirconia coatings. The RBF network can be established efficiently. A comparison of the predicted results with that of the RBF network and the Taguchi method predictor shows average errors of 2.735% and 9.191% for the RBF network and the Taguchi method, respectively. It is experimentally confirmed that the RBF network predictions are in agreement with the experiments, and it can be reliably used for the prediction of wear for plasma sprayings. The experimental results demonstrate that the RBF network used for a statistically designed experiment is an effective, efficient, and intelligent approach for developing a robust, high efficiency, and high-quality zirconia coating process. 相似文献
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In-situ SiC nanowire (SiCnw)/pyrolytic carbon (PyC) core-shell structures were introduced to mainly improve the thermal shock performance of chemical vapor deposition (CVD)-SiC coating on carbon/carbon (C/C) composites. The microstructure, phase composition, and mechanical properties of the CVD-SiC coating toughened by SiCnw/PyC core-shell structures were studied as well. The results show that the introduction of SiCnw/PyC core-shell structures can effectively alleviate the mismatch of coefficient of thermal expansion (CTE) between SiC coating and C/C substrate, thus enhancing the thermal shock resistance of the coating. Furthermore, the increased numbers of interfaces in the SiC coating owing to the addition of core-shell structures are beneficial to the mechanical properties of the coating after thermal shock test. 相似文献
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基于自适应神经网络的芳烃异构化过程建模 总被引:2,自引:1,他引:1
颜学峰 《化工自动化及仪表》2006,33(5):6-8
针对芳烃异构化过程(AHIP)中影响对二甲苯(PX)产率的因素众多且复杂等特点,提出一种自适应神经网络(Adaptive ANN)以建立AHIP的各因素与PX产率的关联模型.Adaptive ANN将样本分成训练样本和校验样本,并设计过拟合判据参数.通过训练样本对网络进行训练,训练过程中以模型对校验样本的预测性能为指标,通过过拟合判据参数的计算自适应地在获得具有最佳预测性能模型时终止网络训练,克服了传统的神经网络以模型的拟合精度为指标,造成训练时间过长和过拟合等缺点. 相似文献
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水性环氧涂料是水性涂料发展的重要品种之一,水性环氧涂料用固化剂是影响其涂料性能的主要因素之一,因此开发新型水性环氧涂料用固化剂则别具现实意义.文中对水性环氧涂料用固化剂的发展历程作了探讨,并对各类水性环氧涂料用固化剂的特点进行扼要的解说,从中探索出水性胺加成物固化剂是水性环氧涂料用固化剂中最具发展前景的品种. 相似文献
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纳米针状羟基磷灰石涂层的制备及其性能的研究 总被引:37,自引:8,他引:29
用电化学沉积法在钛合金上形成涂层,随后在碱性过热蒸气中进行水热处理,最后进行高温真空烧结。用扫描电镜,X射线衍射和红外光谱对涂层的组织结构和化学成分进行了分析,测量了涂层的粘接拉伸强度,将涂层浸泡于Tyrode生理盐液中考虑其抗溶解特性。 相似文献