Comparison of Solute Transport in Three Composite Liners

Three composite landfill liners were compared in this study based on leakage rate, mass flux, and sorptive capacity. One composite liner consisted of a geomembrane and a geosynthetic clay liner (GCL). The other two had a geomembrane and a thicker soil barrier (61 or 122 cm). The analyses employed one- and three-dimensional numerical models that were developed for analyzing contaminant transport through defects in the geomembrane component of composite liners and diffusion of volatile organic compounds through intact composite liners (i.e., composite liners without holes in the geomembrane). Cadmium was used to represent inorganic leachate constituents and toluene was used to represent organic leachate constituents. The composite liner, having a GCL had the lowest leakage rate of the three composite liners. For cadmium, the mass flow rate and sorptive capacity for the three composite liners varied within an order of magnitude. However, for toluene, the mass flux from the GCL composite liner was two to three orders of magnitude greater than that through composite liners having a thicker soil liner. Additionally, for leachate having similar concentrations of cadmium and toluene, the mass flux of toluene can be as much as seven orders of magnitude greater than that for cadmium. For toluene, the sorptive capacity of thicker liners was an order of magnitude greater than that for the GCL composite liner. Similar behavior is expected for other inorganic and organic solutes.     

Use of Organoclay as Secondary Containment for Gasoline Storage Tanks

Conventional clay liners, which are widely used as hydraulic barriers to water, have been shown to be adversely affected by organic fluids. However, the addition of quaternary amines into bentonite greatly enhances its compatibility with organic fluids and thus allows the clay barrier technology to be extended to the treatment of organic contaminants. In this study, an organically modified clay was studied for use as a secondary containment for gasoline underground storage tanks. Free swelling and hydraulic conductivity tests were performed on organoclay, pure bentonite, and natural soils. Results show that organoclay has a large swelling capacity in gasoline, whereas bentonite and natural soils shrink when immersed in gasoline. The hydraulic conductivities of bentonite and natural soils to gasoline are 2–5 orders of magnitude higher than that to water. In contrast, the hydraulic conductivity decreases by 2 orders of magnitude for organoclay and this low value can be maintained even under freeze-thaw and dry-wet cycles.     

Numerical Characterization of Advective Gas Flow through GM/GCL Composite Liners Having a Circular Defect in the Geomembrane

Numerical experiments were conducted to understand the effect of geometric and transport characteristics of a geomembrane-geosynthetic clay liner (GM/GCL) composite liner on gas leakage rate through a circular defect in the geomembrane (GM). The originality of the approach proposed in this paper rests on the use of a new conceptual two-layered system for modeling of GM/GCL composite liners where the interface zone between the GM and geosynthetic clay liner (GCL) has been merged with the GCL cover geotextile and handled as one layer; the GCL bentonite layer was considered the second layer. The role of the carrier geotextile layer was ignored since it can be considered as a no pressure loss layer. Analysis of numerical simulation results shows the existence of a constitutive leakage flow surface which enables evaluation of the leakage flow state for different geometric and transport properties of GM/GCL composite liners. Furthermore, the determined surface was also exploited to evaluate gas leakage rates under the framework of the Forchheimer’s analytical solution. The gas leakage rate predictions were found to be in good agreement with experimental results obtained at different GCL moisture content.     

Predicting Leakage through Composite Landfill Liners

Leakage through composite landfill liners having various characteristics was analyzed using existing analytical and numerical models developed for the study. Three-dimensional numerical models were used to analyze leakage through circular defects and two-dimensional numerical models were used to analyze leakage from defective seams. Leakage rates predicted with the numerical models were compared to leakage rates predicted using existing equations and analytical models currently being used. These comparisons show that existing equations and analytical models all have limitations and no universal equation or method is available for predicting leakage rates. To overcome some of the deficiencies in the existing equations and models, new equations were developed based on results from the numerical models. Recommendations are made for using the new equations, existing equations, and analytical models to predict leakage rates in thick composite liners having a geomembrane overlaying a compacted soil liner and thin composite liners having a geomembrane overlaying a geosynthetic clay liner.     

Evaluating the Long-Term Performance of Geosynthetic Clay Liners Exposed to Freeze-Thaw

An important consideration for landfill liners and covers constructed in the frost zone of cold climates is the possible deterioration in performance due to freeze-thaw cycling over the design life of the liner or cover system. Several examples in the literature show that geosynthetic clay liners can withstand a limited number of freeze-thaw events, but data on long-term freeze-thaw performance are lacking. The objective of this study was to examine the long-term performance of geosynthetic clay liners exposed to repeated freeze-thaw cycles, encompassing their application as a final cover as well as a bottom liner. Measurements of hydraulic conductivity were performed after as many as 150 freeze-thaw cycles, with no appreciable increases observed.     

Optimal Design of a Compacted Soil Liner Containing Sorptive Amendments

The design of a compacted soil liner that includes sorptive amendments is presented and evaluated as a combinatorial optimization problem. An objective function based on the materials costs, opportunity costs, and construction costs of the liner was used to evaluate the effect of incorporating four sorptive materials: benzyltriethylammnonium-bentonite, hexadecyltrimethylammonium-bentonite, shale, and granular activated carbon (GAC) into a compacted clay liner in order to mitigate transport of organic solutes through the liner. The results from this study indicate that the inclusion of sorptive amendments as a component in compacted soil liners can effectively retard the transport of organic contaminants through the liner without violating regulatory hydraulic conductivity requirements. In all cases when aqueous transport was considered as a constraint in the objective function formulation, the resulting liner always contained some amount of sorptive amendment. In general, shale and GAC were selected for use in the sorptive liner design for all organic solutes tested. The modeling framework presented in this study is general and could be used to evaluate other types of sorptive materials or additional constraints, and thus represents a flexible new tool for the design of compacted soil liners.     

Transit-Time Design for Diffusion through Composite Liners

Transit-time design methods are presented in this paper for determining the design thickness for composite liners consisting of a geomembrane and a compacted soil liner or geosynthetic clay liner. The design methods are based on a closed-form analytical solution for transient solute diffusion of volatile organic compounds in a composite liner and results from a numerical model. An analytical solution for diffusion in a two-layer soil profile, which is useful for transit-time design of composite liners, is also presented. The analytical solutions are used to develop graphical solution charts that can be used to design composite liners for which the effluent concentration and contaminant flux are less than a specified value. Design examples are included for a composite liner having a compacted soil liner and a composite liner having a geosynthetic clay liner. The method is relatively simple to apply and can be used for preliminary design of composite liners, evaluating experimental results, and verifying more complex numerical models.     

Modeling of Clay Liner Desiccation

The potential for the desiccation of clay liner component of composite liners due to temperature field generated by breakdown of organic matter in municipal solid waste landfills is examined using a model proposed by Zhou and Rowe. In these analyses, a set of fully coupled governing equations expressed in terms of displacement, capillary pressure, air pressure, and temperature increase are used, and numerical results are solved by using finite element method with a mass-conservative numerical scheme. The model results are shown to be in encouraging agreement with experimental data for a problem involving heating of a landfill liner. The fully coupled transient fields (temperature, horizontal stress change, suction head, and volumetric water content) are then examined for two types of composite liner system, one involving a geomembrane over a compacted clay liner (CCL) and the other involving a geomembrane over a geosynthetic clay liner (GCL). It is shown that there can be significant water loss and horizontal stress change in both the CCL and GCL liner even with a temperature increase as small as 20°C. The time to reach steady state decreases as boundary temperature increases. Under a 30°C temperature increase, it takes 5 years to reach the steady state water content with a GCL liner but 50 years with a CCL liner. The effects of various parameters, such as hydraulic conductivity and thickness of the liner, on the performance of the liner are discussed.     

Compatibility with Jet A-1 of a GCL Subjected to Freeze–Thaw Cycles

Needle-punched geosynthetic clay liner (GCL) specimens subjected to 0, 5, and 12 freeze–thaw cycles in the laboratory, and GCL specimens recovered from a composite barrier wall in the Canadian Arctic after 1 and 3 years were examined to assess the hydraulic conductivity/permeability with respect to both deionized deaired water and Jet A-l. The GCL specimens recovered from the field after 3 years had a hydraulic conductivity with respect to water that was approximately 30% less than that of the GCL specimens subjected to 12 initial freeze–thaw cycles in the laboratory, suggesting that the laboratory conditions are more severe than field conditions. The combined effects of both the freeze–thaw cycles and Jet A-l permeation increased the permeability. This increase is attributed to the creation of macropores in the GCL due to freezing and to an expansion of free-pore space due to contraction of the double layer caused by permeation of Jet A-l. Although there was an increase in permeability due to the combined effect of freeze–thaw and permeation by Jet A-l, the effect was relatively small and the results suggest that the GCL continued to exhibit good performance as a hydraulic barrier when subject to extreme climatic conditions and hydrocarbons both in the laboratory and in the field.     

Organo-Illite as a Low Permeability Sorbent to Retard Migration of Anionic Contaminants

Landfill leachate, often having high concentrations of metal cations, anions, and organic compounds, presents a great threat to nearby groundwater. Due to negative charges on soil particles, regular clay liners cannot effectively retard the movement of anionic contaminants such as chromate. In this paper, a natural illite was modified by cationic surfactants with different chain lengths and tested for its chromate removal efficiency. When the surfactant tail group is relatively short and the solution critical micelle concentration is high, the sorbed surfactant molecules form a monolayer on illite, resulting no chromate sorption by the organo-illite. As the chain length of surfactant tail group increases, the critical micelle concentration reduces and the surfactant molecules sorb as admicelles on illite with the surfactant sorption exceeding the illite’s cation-exchange capacity. Such admicelle modification makes the organoclay capable of retaining chromate instantaneously and retarding the movement of chromate by 1–2 orders of magnitude. The illite’s hydraulic conductivity showed a slight increase after surfactant modification, from 1×10?7 to 8×10?7?cm/s, probably due to reduced packing density after modification. Chromate breakthrough data from column transport experiments were well described by a one-dimensional advection-dispersion model that incorporated Langmuir sorption.     

Laboratory Evaluation of Sand Underdrains

Constant-head hydraulic conductivity tests are performed on layered heterogeneous porous media to evaluate the use of underdrains to calculate the hydraulic conductivity of an overlying, less permeable medium. The layered profiles consist of a barrier layer comprising sand mixed with 10% kaolin, overlying a foundation layer comprising sand mixed with only 5% kaolin. Underdrains are evaluated by replacing excavated portions of the foundation layer with only sand. The results indicate that preferential flow of water occurs around, rather than through, the sand underdrains resulting in an underestimate of the measured hydraulic conductivity of the barrier layer assuming 1D, saturated flow in accordance with standard practice. The observed preferential flow effect is consistent with previously published numerical simulations of unsaturated flow through similarly layered heterogeneous soil profiles that indicate lateral flow around underdrains due to the contrast in unsaturated properties of the soils. The results of this study have important ramifications with respect to the use of underdrains to measure in situ hydraulic conductivity of compacted clay liners for waste containment.     

Hydraulic Conductivity of Geosynthetic Clay Liners Exhumed from Landfill Final Covers

Samples of geosynthetic clay liners (GCLs) from four landfill covers were tested for water content, swell index, hydraulic conductivity, and exchangeable cations. Exchange of Ca and Mg for Na occurred in all of the exhumed GCLs, and the bentonite had a swell index similar to that for Ca or Mg bentonite. Hydraulic conductivities of the GCLs varied over 5 orders of magnitude regardless of cover soil thickness or presence of a geomembrane. Hydraulic conductivity was strongly related to the water content at the time of sampling. Controlled desiccation and rehydration of exhumed GCLs that had low hydraulic conductivity (10?9?to?10?7?cm/s) resulted in increases in hydraulic conductivity of 1.5–4 orders of magnitude, even with overburden pressure simulating a 1-m-thick cover. Comparison of these data with other data from the United States and Europe indicates that exchange of Ca and/or Mg for Na is likely to occur in the field unless the overlying cover soil is sodic (sodium rich). The comparison also shows that hydraulic conductivities on the order of 10?6?to?10?4?cm/s should be expected if exchange occurs coincidently with dehydration, and the effects of dehydration are permanent once the water content of the GCL drops below approximately 100%. Evaluation of the field data also shows that covering a GCL with a soil layer 750–1,000?mm thick or with a geomembrane overlain by soil does not ensure protection against ion exchange or large increases in hydraulic conductivity.     

Hydraulic Conductivity and Swell of Nonprehydrated Geosynthetic Clay Liners Permeated with Multispecies Inorganic Solutions

The influence of multispecies inorganic solutions on swelling and hydraulic conductivity of non-prehydrated geosynthetic clay liners (GCLs) containing sodium bentonite was examined. Ionic strength and the relative abundance of monovalent and divalent cations (RMD) in the permeant solution were found to influence swell of the bentonite, and the hydraulic conductivity of GCLs. Swell is directly related to RMD and inversely related to ionic strength, whereas hydraulic conductivity is directly related to ionic strength and inversely related to RMD. RMD has a greater influence for solutions with low ionic strength (e.g., 0.05?M), whereas concentration effects dominate at high ionic strength (e.g., 0.5?M). No discernable effect of cation species of similar valence was observed in the swell or hydraulic conductivity data for test solutions with similar ionic strength and RMD. A strong relationship between hydraulic conductivity and free swell was found, but the relationship must be defined empirically for a particular bentonite. A regression model relating hydraulic conductivity of the GCL to ionic strength and RMD of the permeant solution was developed. Predictions made with the model indicate that high hydraulic conductivities (i.e., >10?7?cm/s) are not likely for GCLs in base liners in many solid waste containment facilities. However, for wastes with stronger leachates or leachates dominated by polyvalent cations, high hydraulic conductivities may occur.     

Volatile Organic Compound (VOC) Transport through Compacted Clay

Movement of volatile organic compounds (VOCs) through compacted clay liners was investigated using laboratory-scale column and tank tests. Hydraulic conductivity of the compacted clay was not significantly impacted by the introduction of VOCs in concentrations up to 20 mg∕L. Soil-water partition coefficients of the seven VOCs tested had a strong logarithmic relationship with the octanol-water partition coefficient. Partition coefficients from batch tests were in good agreement with those measured directly on soil samples at the termination of the column∕tank tests. The VOCs were degraded in the clay, with estimated half-lives ranging from 2 to 116 days. Mechanical dispersion was not significant in the range of the hydraulic conductivities of the test specimens (i.e., <10?7 cm∕s). Effective molecular diffusion coefficients were mostly in 10?6 cm2∕s and generally decreased with increasing aqueous solubility. Mass transport parameters of VOCs in clay liners can be estimated from laboratory batch tests and properly prepared small-scale column tests. However, accounting for degradation of VOCs and minimizing the number of transport parameters that are simultaneously estimated from a single response-time record are important considerations for accurate determination of transport parameters.     

Analytical Solution for Diffusion of VOCs through Composite Landfill Liners

Analytical solutions are presented for analyzing volatile organic compound (VOC) diffusion through intact composite landfill liners for two scenarios with boundary conditions at the base of either a VOC concentration of zero or a VOC mass flux of zero. A time-dependent concentration top boundary condition is included in the presented analytical solutions to model typical variations of VOC concentration in the leachate over time. The presented solutions are verified against alternative numerical solutions and applied to analyze dichloromethane diffusion through a composite liner. The analytical solutions are found to provide useful predictions of VOC concentration and mass flux for the design of composite liners. VOC concentrations and fluxes at the base of the composite liner at 30?years predicted by consideration of representative transient variation in leachate concentration, for an example problem, are nearly half of those when a constant leachate concentration assumed.     

Effect of Desiccation on Compacted Natural Clays

Specimens prepared from eight natural clayey soils used for clay liners and covers were subjected to cycles of wetting and drying. Volumetric shrinkage strains were recorded during drying. Specimens in which cracks formed during drying were subjected to hydraulic conductivity testing. Results of the study indicate that volumetric shrinkage strains are influenced by soil properties and compaction conditions. Volumetric shrinkage strain increased with increasing plasticity index and clay content, and as the compaction water content increased or decreased relative to optimum water content. Volumetric shrinkage strain decreased with increasing compactive effort. Specimens with the largest volumetric shrinkage strains typically contained the largest number of cracks. Hydraulic conductivity testing indicated that cracking of the specimens resulted in an increase in hydraulic conductivity, sometimes as large as three orders of magnitude.     

Lactate Transport in Soil by DC Fields

Electrokinetic injection of lactate, a negatively charged biodegradable organic, in homogeneous soils is evaluated. Net lactate migration rate on the order of 5?cm2/V?day is measured in sand from cathode towards the anode. The ionic injection in sand was dependent on current density; however, the increase in electric current did not result in an equivalent increase in lactate transport due to development of an appreciable electroosmotic (EO) flow from the anode to the cathode. While high EO flow (ke on the order 10?6 to 10?5?cm2/V?s) occurred in clay samples, ion migration from cathode to anode is the dominant transport process under relatively high current density (5.3?A/m2 in this study) and can be used as an effective transport mechanism for negatively charged additives. An effective lactate reactive transport rate of more than 3?cm/d (under 1?V/cm) can be achieved in clays, which is at least two orders of magnitude greater than hydraulic injection under unit hydraulic gradient. Even though lactate concentrations in the clay were below 10% of the boundary value due to biological transformation, these concentrations (few 100?s?mg/L) are high enough to maintain microbial activities capable of degrading organic contaminants. At the same time, control experiments showed that, while lactate adsorption was negligible, hydraulic injection under a unit gradient was ineffective because of the low hydraulic conductivity of clay and the biodegradation of lactate.     

Effect of Wet-Dry Cycling on Swelling and Hydraulic Conductivity of GCLs

Atterberg limits, free swell, and hydraulic conductivity tests were conducted to assess how wet-dry cycling affects the plasticity and swell of bentonite, and the hydraulic conductivity of geosynthetic clay liners (GCLs) hydrated with deionized (DI) water (pH 6.5), tap water (pH 6.8), and 0.0125-M CaCl2 solution (pH 6.2). The plasticity of bentonite hydrated with DI water increased during each wetting cycle, whereas the plasticity of bentonite hydrated with tap water and CaCl2 decreased during each wetting cycle. Wet-dry cycling in DI water and tap water had little effect on swelling of the bentonite, even after seven wet-dry cycles. However, swelling decreased dramatically after two wetting cycles with CaCl2 solution. Hydraulic conductivity of GCL specimens remained low during the first four wetting cycles (～1 × 10?9 cm∕s). However, within five to eight cycles, the hydraulic conductivity of all specimens permeated with the 0.0125-M CaCl2 solution increased dramatically, to as high as 7.6 × 10?6 cm∕s. The hydraulic conductivity increased because cracks, formed during desiccation, did not fully heal when the bentonite rehydrated. In contrast, a specimen continuously permeated for 10 months with the 0.0125-M CaCl2 solution had low hydraulic conductivity (～1 × 10?9 cm∕s), even after eight pore volumes of flow.     

Field Performance of a Compacted Clay Landfill Final Cover at a Humid Site

A study was conducted in southern Georgia, USA, to evaluate how the hydraulic properties of the compacted clay barrier layer in a final landfill cover changed over a 4-year service life. The cover was part of a test section constructed in a large drainage lysimeter that allowed continuous monitoring of the water balance. Patterns in the drainage (i.e., flow from the bottom of the cover) record suggest that preferential flow paths developed in the clay barrier soon after construction, apparently in response to desiccation cracking. After four years, the clay barrier was excavated and examined for changes in soil structure and hydraulic conductivity. Tests were conducted in situ with a sealed double-ring infiltrometer and two-stage borehole permeameters and in the laboratory on hand-carved blocks taken during construction and after four years of service. The in situ and laboratory tests indicated that the hydraulic conductivity increased approximately three orders of magnitude (from ≈ 10?7?to? ≈ 10?4?cm?s?1) during the service life. A dye tracer test and soil structure analysis showed that extensive cracking and root development occurred throughout the entire depth of the barrier layer. Laboratory tests on undisturbed specimens of the clay barrier indicated that the hydraulic conductivity of damaged clay barriers can be underestimated significantly if small specimens (e.g., tube samples) are used for hydraulic conductivity assessment. The findings also indicate that clay barriers must be protected from desiccation and root intrusion if they are expected to function as intended, even at sites in warm, humid locations.     

A New Landfill Liner to Reduce Ground-Water Contamination from Heavy Metals

A series of permeameters (columns) was used to evaluate the effects of the percolation of water and 1,000 μg∕mL of zinc chloride solution through a mixture of montmorillonite clay, sand, and lime. The column test results show that the addition of lime changes the chemical and physical properties of the clay. The hydraulic conductivities for the mixture of clay with different percentages of lime at first increases with increasing lime and then decreases with increasing lime. The breakthrough curves indicate that the Zn(II) capture is increased and Zn(II) breakthrough is delayed with increasing lime addition. Lime also enhances the clay∕lime mixture's ability to resist puncture by sharp objects. Based on the effects of lime on Zn(II) captured by the clay, an explanation for the interacting effects of lime and Zn(II) capture on changing hydraulic conductivity is suggested. The results of this research demonstrate the potential of using lime-treated clay liners for landfills. Such liners would have lower hydraulic conductivity, better resistance to puncture, and enhanced ability to capture heavy metals.