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取代芳酰胺基丙基杂氮硅三环化合物的合成 总被引:1,自引:1,他引:0
通过氨丙基杂氮硅三环与取代苯甲酰氯的酰基化反应,合成了7种取代芳酰胺基丙基杂氮硅三环化合物,产率49%-83%;用^1H NMR和IR等方法对其结构进行了鉴定,并初步探讨了反应条件。 相似文献
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采用乙醇、丙酮、离子液体/N-甲基吡咯烷酮(ILs/NMP)和在微波辅助下ILs/NMP分别对宁夏双马烟煤(SM)、宁夏鸳鸯湖烟煤(YYH)、云南莲花塘褐煤(LHT)、内蒙古通辽褐煤(TL)进行分级萃取,依次得到了萃取物(E 1~E 4)和萃余煤(R 1~R 4)。利用气相色谱质谱联用(GC/MS)对E 1~E 4进行分析,傅立叶变换红外光谱(FT-IR)对R 1~R 4进行分析。结果表明:经乙醇、丙酮分级萃取之后,不同种类的亲水型离子液体对同一种煤的萃取率不同,亲水型离子液体与疏水型离子液体对同一种煤的萃取效果也不同,疏水型离子液体的萃取率更高。[Bmim]NTf 2/NMP的可检测化合物中发现酰胺类化合物,[Bmim]Cl/NMP的可检测化合物没有发现酰胺类化合物。分级萃取的萃余煤(R 1~R 4)中脂肪族化合物,芳香族化合物及含氮化合物的含量逐级减少,相应地,它们在萃取液中含量增大。微波辅助下,离子液体的加入可使煤中强键断裂,使萃取液中含氮化合物的种类明显增加。 相似文献
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Prior electrophoretic and morphological studies have identified two closely related, economically important tephritid flies,R. mendax (Curran) andR. pomonella (Walsh), which infest the fruits of ericaceous and rosaceous plants, respectively. Further studies also have shown consistent differences among these species in their ovipositional preferences for apples and highbush blueberries and have determined that their ovipositional behavior is elicited by extracts obtained from these fruits. In this paper we report the results of an experiment that tested whether these species show distinct electroantennogram (EAG) responses to a large array of compounds present in gas chromatograph-fractionated pentane extracts of apples and highbush blueberries.R. mendax andR. pomonella flies were found to have significant differences in their antennal sensitivity to 11 blueberry and nine apple extract peaks, which correspond to 24.4% of all blueberry and 25.0% of all apple peaks that elicited a measurable EAG response from either species. Interspecific differences in peripheral sensitivity were more pronounced for blueberry than apple extract;R. pomonella flies were most sensitive to blueberry compounds with low retention times, whereasR. mendax flies responded to blueberry compounds with a broader range of retention times. Both species were most sensitive to apple peaks with high retention times. The retention times of most apple and blueberry peaks that elicited EAG responses fromR. mendax andR. pomonella flies were different from the retention times of seven attractant fruit esters that were previously identified by Fein et al. (1982). The identification of these unknown apple and blueberry compounds could lead to the discovery of new chemical cues that mediate the host-plant preferences of these sibling species. 相似文献
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Aynaz Meshkat Mohammad Javad Vaezi Ali Akbar Babaluo Masoud Gohar Geranbaha 《Journal of the European Ceramic Society》2018,38(15):5074-5081
The effects of suspension concentration, number of coating stages and dipping time on seeding quality of DD3R particles on the ceramic supports were investigated. The supports were immersed in aqueous suspensions (0.1, 0.2 and 0.3?wt. %) of the DD3R seeds for three different dipping times 30, 90 and 240?s with different stages of 1, 2 and 3. The SEM analysis was used to study the quality of the seeded layers. The optimized seeding conditions of 0.2?wt. % suspension concentration, 2 number of coating stages and 30?s for dipping time leaded to obtain a uniform seeded layer with monolayer structure. The DD3R zeolite membrane was synthesized via hydrothermal method under the optimized seeding conditions. The XRD and SEM analyses confirmed the synthesis of DD3R membrane with proper quality. The single gas permeation results showed a good performance in the separation of CO2 from CH4. 相似文献
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Anne Genevieve Bagnères Jean Luc Clément Murray S. Blum Ray F. Severson Catherine Joulie Catherine Lange 《Journal of chemical ecology》1990,16(12):3213-3244
Colonies ofReticulitermes flavipes andR. santonensis were collected from the southeastern United States (Georgia) and the southwest of France (Charente-maritime). Defensive compounds and cuticular hydrocarbons were identified by gas chromatography-mass spectrometry and quantified by gas chromatography using an internal standard for each caste and all colonies. These analyses show that although the cuticular hydrocarbons ofR. santonensis in Europe andR. flavipes in Georgia are identical, their relative proportions are different. However, the defensive compounds synthesized by their soldiers are different. A strong chemical polymorphism between sympatric colonies ofR. flavipes in the SW United States was detected in terms of both the hydrocarbons of the workers and soldiers and in the defensive secretions of the soldiers. The six defensive secretion phenotypes are based on the presence or absence of terpenes whereas the cuticular hydrocarbon phenotypes are based on significant differences in the proportions of the various components. A multivariate analysis (analysis of principal components) clearly permitted discrimination of four phenotypes (three inR. flavipes and one inR. santonensis) without intermediates. The hydrocarbons responsible for these variations were identified, and it was shown that the variations are neither seasonal nor geographic. The phenotypes of the cuticular hydrocarbons (workers and soldiers) and defensive compounds are linked in each colony, forming in three groups inR. flavipes Georgia, one subdivided into four subgroups according to the defensive secretion phenotypes. The role of these polymorphisms is discussed and ethological tests indicate that the chemical polymorphism do not determine aggressive behavior. The taxonomic significance of these results is considered and two hypothesis are formulated: (1) We only detected a strong genetic polymorphism in one unique species, and we believe thatR. santonensis was introduced into Europe in the last century from oneR. flavipes colony. (2) Chemical variability characterizes the sibling species that can be grouped into the same subspeciesR. flavipes. Unknown mechanisms of reproductive isolation separate them. 相似文献
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The influence of some paraffinic oils on rheological properties, dynamic properties, and behavior at low temperature of various ethylene–propylene–diene monomer rubber (EPDM) compounds was studied. Three different types of EPDM, Dutral TER 4049, Dutral Ter 4038, and Nordel IP 4770 R, and five different paraffinic oils were used. The properties of the compounds were evaluated with reference to the oil characteristics: viscosity, composition, glass transition temperature, and solubility parameter. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1825–1834, 2005 相似文献
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