晶须CaCO3和PTFE填充聚醚醚酮复合材料的摩擦学性能

用MM200磨损试验机和45钢环配副,研究不同含量碳酸钙(CaCO3)晶须和10%的聚四氟乙烯(PTFE)共同填充聚醚醚酮(PEEK)复合材料的摩擦磨损性能,用扫描电镜观察磨损表面形貌并分析磨损机理。结果表明,随着复合材料中晶须含量增加,摩擦系数持续降低,最低可降到纯PEEK的1/2;复合材料的磨损率随晶须含量的增加先大幅度减小后又缓慢回升,当晶须含量为15%-20%时,磨损率降至3.3×10-7mm3/Nm,仅为纯PEEK的3.6%,20?CO3/10%PTFE/PEEK综合摩擦学性价比较好。CaCO3晶须增强PEEK减少了复合材料在摩擦过程中摩擦副表面粘着和剥层,阻止基体树脂的热塑性变形,同时PTFE的优先粘着转移使得复合材料在对偶件表面形成连续、均匀的转移膜,两者协同有效降低摩擦系数和磨损率,提高材料的摩擦学性能。     

网络陶瓷增强铝基复合材料的摩擦磨损性能

采用压铸技术成功制备了网络陶瓷(骨架)增强铝基复合材料,研究了其在干摩擦条件下的滑动摩擦磨损行为.结果表明,复合材料的耐磨性能远优于基体合金,主要是由于网络陶瓷(骨架)裸露在磨损表面,成为微凸体,起承载作用,抑制或延迟了基体从轻微磨损向严重磨损的转变.同时将载荷分散至各个方向,抑制了磨损面基体合金因塑性变形产生的流失.     

自润滑纤维织物复合材料摩擦学性能研究

目的研究MoS_2和石墨填充对自润滑纤维织物复合材料摩擦学性能的影响。方法采用玄武三号栓-盘式摩擦磨损实验机,研究了石墨和MoS_2填充PTFE/棉纤纤维织物在不同载荷条件下的摩擦磨损性能,并采用扫描电镜观察了纤维织物复合材料的磨损表面和微观结构。结果在较低载荷下,填充5%MoS_2可以更有效地降低PTFE/棉纤纤维织物复合材料的磨损率;在较高载荷下,填充10%石墨可以更有效地降低PTFE/棉纤纤维织物复合材料的磨损率。载荷为219.52 N时,5%MoS_2填充PTFE/棉纤纤维织物复合材料的磨损率由未填充的1.28×10~(-14) m~3/(N·m)降低到0.61×10~(-14) m~3/(N·m),降低了50%;10%石墨填充PTFE/棉纤纤维织物复合材料的磨损率由1.28×10~(-14) m~3/(N·m)降低到0.91×10~(-14) m~3/(N·m),降低了28%。结论石墨和MoS_2填充在摩擦过程中减轻了磨粒的嵌入和切削作用,阻碍了复合材料的磨损,提高了PTFE/棉纤纤维织物复合材料的耐磨性能。     

三维连续镍-铝(骨架)增强铝基复合材料的磨损行为

采用真空吸铸和真空热处理技术制备了三维连续镍-铝(骨架)增强铝基复合材料,研究了其在干摩擦条件下的磨损行为.结果表明,复合材料的耐磨性能远优于基体合金.主要是由于硬的Ni2 Al3金属间化合物(骨架)裸露在磨损表面,成为微凸体,起承载作用,抑制或延迟了基体从轻微磨损向严重磨损的转变时间.同时将载荷分散至各个方向,抑制了磨损面基体合金因塑性变形产生的流失.基体合金的磨损机制为严重粘着磨损,复合材料的磨损为以磨粒磨损为主和轻微的粘着磨损.     

生理盐水润滑下PEEK/WK复合材料的摩擦学性能

为研究生理盐水润滑条件下碳酸钙晶须含量、载荷大小、滑动速度因素对PEEK/CaCO3复合材料摩擦学性能的影响规律,并考察复合材料的摩擦学稳定性,在自制改性偶联剂处理晶须表面的基础上制备了PEEK/CaCO3复合材料,利用MMW1A立式万能摩擦磨损试验机对复合材料的摩擦学性能进行测试,用扫描电子显微镜(SEM)对磨损表面形貌进行扫描分析表征。结果表明,晶须含量对复合材料摩擦学性能影响明显,在0.9%的生理盐水润滑条件下PEEK/CaCO3复合材料随着晶须含量的增加,摩擦因数及比磨损率均呈现先减小后增大现象;当晶须质量分数为15%左右时,复合材料的摩擦因数达到最低值,同时比磨损量相对最低,复合材料与摩擦副的磨合过程相对平稳,具有较好的摩擦学性能,表现为粘着腐蚀磨损特征。外加载荷、滑动速度增大,材料的摩擦因数增大,比磨损率增加。     

三维网络陶瓷增强铝基复合材料的干摩擦磨损性能

设计和制备了一种新型的三维网络陶瓷(骨架)增强铝合金复合材料.研究了铝合金及不同成分复合材料在不同温度及载荷下的摩擦系数和磨损率;用扫描电镜(SEM)观察其磨损表面,并分析了三维网络陶瓷(骨架)对铝合金磨损机制的影响.结果表明:复合材料的耐磨性远优于铝合金,而且随着三维网络陶瓷体积分数、温度及载荷的增加,复合材料的抗磨损性能明显提高;这种新型复合材料的摩擦系数随载荷变化保持稳定;在很宽的温度范围内,摩擦系数的稳定性均优于铝合金.这是由于三维网络陶瓷在磨损表面形成硬的微凸体起承载作用,其独特的结构制约了基体合金的塑性变形和高温软化,有利于磨损表面氧化膜的留存.     

用于高铁桥梁支座滑板的Go/CF/PTFE复合材料摩擦学特性研究

通过冷压成型和真空热压烧结法制备出了用于高铁桥梁支座滑板的石墨烯(Go)和碳纤维(CF)填充聚四氟乙烯(PTFE)复合材料,并对Go/CF/PTFE复合材料的力学性能、微观组织及摩擦学特性进行了分析。结果表明:适量添加Go和CF能有效提高复合材料试样的力学性能和摩擦磨损性能。CF与Go的加入改变了复合材料试样摩擦磨损形式,磨损形式由粘着磨损与犁削磨损转变为疲劳磨损。CF在基体材料中的均匀分布,起到了裂纹钉扎和桥联作用,有效阻止了裂纹的萌生和扩展,增加了裂纹拓展的阻力,从而提高了复合材料的力学性能和摩擦磨损性能。     

TiN/Ag涂层在真空环境下的摩擦学行为

目的 银具有低的剪切强度,可以降低涂层的摩擦磨损,在TiN硬质涂层中引入软金属Ag,以期拓展其在摩擦学领域的应用范围.方法 采用多弧离子镀沉积技术,在SUS304不锈钢基底上成功制备了TiN/Ag复合涂层.利用扫描电子显微镜、纳米压痕仪、RST3划痕仪,分析了TiN/Ag涂层的微观结构和机械性能.利用CSM(大气)和HVTRB(真空)摩擦磨损试验机评估了TiN/Ag涂层的摩擦学性能.结果 TiN/Ag涂层结构致密,厚度为1.2μm,硬度约为28.4 GPa.摩擦学测试表明,真空环境下的摩擦因数远低于大气环境下的摩擦因数,大气环境下的磨损机理主要为粘着磨损与磨粒磨损,而真空环境下主要表现为机械抛光及摩擦转移膜.真空环境下TiN/Ag涂层不同载荷下的摩擦试验表明,1 N载荷条件下,摩擦因数值低至0.07,且涂层发生轻微磨损;3 N载荷条件下,机械能和热应力使得摩擦界面中的Ag发生扩散,摩擦因数迅速增加到0.42左右;5 N载荷条件下,摩擦因数呈现较明显的波动,随着滑动次数的增加,摩擦因数最高达到1.0,涂层表面发生软化形成犁沟效应,而导致涂层失效.结论 TiN/Ag涂层中Ag掺杂可显著降低涂层的内应力,抑制摩擦过程中涂层微裂纹的扩展,适当载荷下能够有效地改善TiN硬质涂层真空下的摩擦学性能.     

载荷对颗粒增强铁基复合材料摩擦性能的影响

研究了颗粒增强铁基复合材料(PR MMCs)在不同载荷下的摩擦性能.结果表明复合材料比高速钢的磨损系数低两个数量级,有更好的耐磨性;复合材料的摩擦系数随着载荷增加先增加后降低;复合材料随着载荷的增加,磨损机理由小载荷下切削剥层磨损为主要磨损,逐渐转化为氧化磨损和磨粒磨损,进一步增加载荷,粘着剥层磨损为主要磨损.     

石墨增强聚酰亚胺在海水中的摩擦学性能

目的为石墨增强聚酰亚胺复合材料在海水环境下的摩擦学应用提供实验依据。方法利用SST-ST销/盘摩擦试验机,研究了质量分数为15%石墨增强聚酰亚胺复合材料与17-4PH不锈钢组成的摩擦副在海水介质中的摩擦学性能,并与干摩擦和纯水润滑条件下的摩擦学性能进行比较。结果聚酰亚胺复合材料在干摩擦下的摩擦系数和磨损体积最大,分别为0.134、1.930 mm~3。干摩擦条件下,聚酰亚胺复合材料的磨损表面存在较深的犁沟,在犁沟周围出现了材料塑性流动及粘着剥落现象,对偶件表面有聚酰亚胺复合材料转移。磨损机理主要表现为磨粒磨损、材料塑性变形以及粘着和剥落。在纯水润滑下,聚酰亚胺复合材料表面存在较多材料粘着撕裂现象,同时存在宽浅不一的犁沟,磨损机理主要为粘着磨损和磨粒磨损。在海水润滑下,复合材料的摩擦系数和磨损体积最小,分别为0.086、1.235 mm~3,材料磨损表面十分光滑,只有沿运动方向存在少量轻微犁沟,磨损机理主要表现为磨粒磨损。结论石墨增强聚酰亚胺复合材料在海水中的摩擦学性能优于干摩擦和纯水环境下的摩擦学性能。     

Effects of environment on dry sliding wear behavior of silver–copper based composites containing tungsten disulfide

Silver based composites containing different amounts of WS₂ were prepared by hot-pressing method and their tribological behaviors were investigated against coin silver under humid air, dry nitrogen and vacuum on a ball-on-disk tester with normal load of 5 N. The components of composites, microstructure of debris and worn surface were characterized using XRD SEM, EDS and XPS. It is demonstrated that environmental conditions significantly affect the tribological behavior of silver based composites. The friction coefficient is the highest in humid air, and the lowest in dry nitrogen. It is found that the friction and wear behavior of the composites are strongly depended on the characteristics of the lubrication film forming in different operating environments, such as thickness and composition. In addition, it is indicated that the dominant wear mechanisms of silver based composites are abrasive wear and delamination under different conditions.     

自润滑型铝合金硬质阳极氧化膜的摩擦磨损性能

为了提高铝合金硬质阳极氧化膜减摩耐磨性能,在硬质氧化膜的微孔中引入PTFE润滑性粒子,制备了具有自润滑性能的复合膜,并用M-2000型摩擦试验机对其摩擦磨损性能进行了研究。结果表明,制备条件对复合膜的减摩耐磨性能有较大影响。随电流密度的增大,膜的摩擦系数变化不大,耐磨损性能增加;随H2SO4浓度的增加,膜的摩擦系数降低,耐磨损性能降低。此外,复合膜的摩擦系数和耐磨性能随载荷的增加逐渐减小,高速（0．84m／s）下的摩擦系数比低速（0．42m／s）下的摩擦系数平均高0．17。     

TiC颗粒增强镍基合金复合涂层的摩擦学性能及磨损预测模型(英文)

运用等离子喷涂技术在铝合金表面制备TiCP/镍基合金复合涂层,研究干摩擦条件下载荷、速度和温度对复合涂层摩擦磨损行为与机理的影响规律;建立了基于最小二乘支持向量机(LS-SVM)的复合涂层磨损预测模型。结果表明:在不同摩擦条件下,TiCP/镍基合金复合涂层的摩擦因数和磨损质量均低于镍基合金涂层。LS-SVM模型对摩擦因数和磨损失重的预测时间仅为BP-ANN模型的12.93%,其预测精度分别比BP-ANN模型提高了58.74%和41.87%,可有效预测干摩擦条件下TiCP/镍基合金复合涂层的摩擦磨损行为。     

Relationship Between the Integrity of Lubricating Film and the Tribological Behavior on TiAl-Ag Self-Lubricating Composites

To explore the relationship between the integrity of the lubricating film and the tribological behavior of a metal matrix self-lubricating composite, the friction and wear experiments of TiAl-Ag self-lubricating composites were carried out with a ball-on-disk configuration. Besides, an approximate model was developed for analyzing the relationship based on Blau’s theory. The research results suggest that the friction and wear behavior of the TiAl-Ag self-lubricating composites changes in accordance with the formation conditions of the Ag-rich lubricating film. Specifically, the friction coefficients and wear rates of the TiAl-Ag self-lubricating composites decreased from high levels at full composite–counterface ball contact to low levels at full-film lubrication. Hence, the integrity of the lubricating film is a possible criterion for the self-lubricating property of the self-lubricating composites.     

Tribological behavior of Ni/Sn metallic multilayer composites

The tribological behavior of Ni/Sn multilayer composites was studied. Composites with varied layer thickness and tin volume fraction were prepared by electrodeposition. The coefficient of friction and wear rate of these composites were characterized by pin-on-disk and block-on-ring tests. Both results suggested that soft tin acted as a solid lubricant between the contacting surfaces. Tin-rich films were detected on both the specimen and the steel wear pair surfaces, and wear resistance greatly depended on the thickness, area coverage, composition, and stability of this interfacial film. Specimens with a lower tin content and/or a thinner layer spacing exhibited enhanced wear resistance compared to those with a higher tin content and/or thicker layers. This was attributed to both the solid-lubricating effect of the tin and the enhanced mechanical properties of the multilayered composites.     

CNTs-Cu和C-Cu复合材料的载流摩擦学行为(英文)

采用粉末冶金方法在相同的工艺条件下制备CNTs-Cu和C-Cu复合材料。采用销盘式载流摩擦磨损试验机对两种材料的载流摩擦学行为进行研究。结果表明:铜基复合材料的摩擦因数和磨损率均随着增强体含量的增加而减小,随着电流密度的增加而增大;电流对C-Cu复合材料的影响更加显著;C-Cu复合材料的主导磨损机制是电弧烧蚀和粘着磨损,而CNTs-Cu复合材料的主导磨损机制是粘着磨损和塑性流动变形。     

Comparative study on the wear behavior of long and short glass fiber reinforced plastics

In recent years, the fiber reinforced composites have been used more in tribological applications where the sliding surfaces requires a high wear resistance and a low co-efficient of friction. The growth of GFRP is significantly higher than that of steel. No engineer or designer can ignore the growth of GFRP, but the decision to use a new material is difficult, yet important. The comparative tribological performance of short and long glass fiber-epoxy composites, under varying load and sliding velocities, is reported in this investigation. Besides conventional weighing, the coefficient of friction, contact temperature, and wear rate were determined. The worn surfaces of the specimens were examined by a Scanning Electron Microscope (SEM). The wear mechanisms and the transitions that govern the tribological behavior of the composites between them are discussed in detail. It was found that the epoxy reinforced with a long glass fiber exhibited a reduced wear rate than the short glass fiber.