高温形状记忆合金的研究进展

本文综述了近年来有关高温形状记忆合金的最新研究进展。重点介绍了ＣｕＡｌＮｉ基，ＮｉＴｉ基及ＮｉＡｌ基三大系列高温形状记忆合金。概括了有关合金的设计，马氏体相变及形状记忆效应，显微结构特征，合金相稳定性及热处理效应，材料制备及生产加工工艺及性能等。     

High‐Entropy Alloys: Potential Candidates for High‐Temperature Applications – An Overview

Multi‐principal elemental alloys, commonly referred to as high‐entropy alloys (HEAs), are a new class of emerging advanced materials with novel alloy design concept. Unlike the design of conventional alloys, which is based on one or at most two principal elements, the design of HEA is based on multi‐principal elements in equal or near‐equal atomic ratio. The advent of HEA has revived the alloy design perception and paved the way to produce an ample number of compositions with different combinations of promising properties for a variety of structural applications. Among the properties possessed by HEAs, sluggish diffusion and strength retention at elevated temperature have caught wide attention. The need to develop new materials for high‐temperature applications with superior high‐temperature properties over superalloys has been one of the prime concerns of the high‐temperature materials research community. The current article shows that HEAs have the potential to replace Ni‐base superalloys as the next generation high‐temperature materials. This review focuses on the phase stability, microstructural stability, and high‐temperature mechanical properties of HEAs. This article will be highly beneficial for materials engineering and science community whose interest is in the development and understanding of HEAs for high‐temperature applications.     

Metal Alloys for Fusion‐Based Additive Manufacturing

Metal additive manufacturing (AM) is an innovative manufacturing technique, which builds parts incrementally layer by layer. Thus, metal AM has inherent advantages in part complexity, time, and waste saving. However, due to its complex thermal cycle and rapid solidification during processing, the alloys well suit and commercially used for metal AM today are limited. Therefore, it is important to understand the alloying strategy and current progress with materials performance to consider alloy development for metal AM. This review presents the current range of alloys available for metal AM, including titanium, steel, nickel, aluminum, less common alloys (including Mg alloys, metal matrix composites alloys, and low melting point alloys), and compositionally complex alloys (including bulk metallic glasses and high entropy alloys) with a focus on the relationship between compositions, processing, microstructures, and properties of each alloy system. In addition, some promising alloy systems for metal AM are highlighted. Approaches for designing and optimizing new materials for metal AM have been summarized.

     

Spray‐Deposited Al‐Si (Osprey CE) Alloys and their Properties

Osprey Metals Ltd. has developed a new family of lightweight, low expansion aluminium‐silicon alloys to suit electronic applications, containing between 30 and 70 wt.% aluminium. They are produced using the Osprey spray deposition process, which achieves homogeneous and isotropic properties. Their advantageous physical characteristics, combining low thermal expansion, high thermal conductivity and low density are particularly suited for packaging electronic circuitry. These CE (controlled expansion) alloys are easy to machine to tight tolerances using standard machine tools and they can be electroplated with gold, silver or nickel finishes without difficulty. This paper focuses on the measurement of mechanical (flexural strength) and thermo‐mechanical properties (CTE, thermal diffusivity and specific heat) of these alloys, carried out in collaboration with AMTT. The property measurements were consistent with those measured previously elsewhere, apart from the CTE values, which deviated significantly and were at variance with values predicted from a rule of mixtures. This discrepancy was resolved in a short follow‐up series of measurements carried out under conditions corresponding more closely to temperature equilibrium.     

A Liquid‐Metal‐Enabled Versatile Organic Alkali‐Ion Battery

Despite the high specific capacity and low redox potential of alkali metals, their practical application as anodes is still limited by the inherent dendrite‐growth problem. The fusible sodium–potassium (Na–K) liquid metal alloy is an alternative that detours this drawback, but the fundamental understanding of charge transport in this binary electroactive alloy anode remains elusive. Here, comprehensive characterization, accompanied with density function theory (DFT) calculations, jointly expound the Na–K anode‐based battery working mechanism. With the organic cathode sodium rhodizonate dibasic (SR) that has negligible selectivity toward cations, the charge carrier is screened by electrolytes due to the selective ionic pathways in the solid electrolyte interphase (SEI). Stable cycling for this Na–K/SR battery is achieved with capacity retention per cycle to be 99.88% as a sodium‐ion battery (SIB) and 99.70% as a potassium‐ion battery (PIB) for over 100 cycles. Benefitting from the flexibility of the liquid metal and the specially designed carbon nanofiber (CNF)/SR layer‐by‐layer cathode, a flexible dendrite‐free alkali‐ion battery is achieved with an ultrahigh areal capacity of 2.1 mAh cm^?2. Computation‐guided materials selection, characterization‐supported mechanistic understanding, and self‐validating battery performance collectively promise the prospect of a high‐performance, dendrite‐free, and versatile organic‐based liquid metal battery.     

Mo‐Si‐B Alloys for Ultrahigh‐Temperature Structural Applications

A continuing quest in science is the development of materials capable of operating structurally at ever‐increasing temperatures. Indeed, the development of gas‐turbine engines for aircraft/aerospace, which has had a seminal impact on our ability to travel, has been controlled by the availability of materials capable of withstanding the higher‐temperature hostile environments encountered in these engines. Nickel‐base superalloys, particularly as single crystals, represent a crowning achievement here as they can operate in the combustors at ～1100 °C, with hot spots of ～1200 °C. As this represents ～90% of their melting temperature, if higher‐temperature engines are ever to be a reality, alternative materials must be utilized. One such class of materials is Mo‐Si‐B alloys; they have higher density but could operate several hundred degrees hotter. Here we describe the processing and structure versus mechanical properties of Mo‐Si‐B alloys and further document ways to optimize their nano/microstructures to achieve an appropriate balance of properties to realistically compete with Ni‐alloys for elevated‐temperature structural applications.     

High‐Temperature Corrosion of NiTi‐Shape‐Memory Alloys

Semi‐finished products and components made of NiTi‐shape‐memory alloys (NiTi‐SMA) are often subjected to heat treatment after their fabrication. During this heat treatment, oxide layers begin to form which contain a high amount of titanium. In this investigation special attention was drawn to the selective oxidation of Ti because a TiO_X‐layer can represent a Ni‐barrier and may therefore be of special use for medical applications. A comparison of the following three samples was carried out: A sample oxidised at room temperature, another that was heat‐treated in ambient air (600 °C/1min) and a third sample that was subjected to a heat treatment (600 °C/1min) in an atmosphere that oxidises titanium but reduces NiO in order to achieve a selective oxidation of the titanium. The analysis of the oxide layers was carried out by means of x‐ray photoelectron spectroscopy (XPS). It was shown that the ratio of titanium to nickel in the oxide layer can be substantially increased when performing the annealing treatments in a partial reducing atmosphere. Furthermore, a thermo‐gravimetric investigation of the material was carried out at 600 °C in dry air in order to estimate the growth of the oxide layers.     

高强度铝合金的氢脆

氢脆是高强度铝合金在腐蚀环境中应用遇到的突出问题。本文简要介绍了高强度铝合金中的氢脆现象，氢脆特点，影响氢脆敏感性的因素以及氢脆理论等，并对这一研究领域的未来进行了展望。     

Mechanical properties of friction stir butt‐welded Al‐5086 H32 plate

Al‐5086 H32 plates with a thickness of 3 mm were friction stir butt‐welded using different welding speeds at a tool rotational speed of 1600 rpm. The effect of welding speed on the weld performance of the joints was investigated by conducting optical microscopy, microhardness measurements and mechanical tests (i.e. tensile and bend tests). The effect of heat input during friction stir welding on the microstructure, and thus mechanical properties, of cold‐rolled Al‐ 5086 plates was also determined. The experimental results indicated that the maximum tensile strength of the joints, which is about 75 % that of the base plate, was obtained with a traverse speed of 200 mm/min at the tool rotational speed used, e.g. 1600 rpm, and the maximum bending angle of the joints can reach 180^o. The maximum ductility performance of the joints was, on the other hand, relatively low, e.g. about 20 %. These results are not unexpected due to the loss of the cold‐work strengthening in the weld region as a result of the heat input during welding, and thus the confined plasticity within the stirred zone owing to strength undermatching. Higher joint performances can also be achieved by increasing the penetration depth of the stirring probe in butt‐friction stir welding of Al‐5086 H32 plates.     

Fatigue crack growth behavior of X2095 Al–Li alloy

Microstructures and micro-textures of X2095 Al–Li alloy in as-received/superplastic state were characterized by means of SEM/BDS, X-ray diffraction and orientation imaging microscopy (OIM). It was observed that the microstructure of the alloy was typical of a particulate-reinforced composite material, consisting of aluminum matrix and homogeneously distributed T_B(Al₇Cu₄Li) particles with a volume fraction of about 10%. Brass-type texture was the dominant texture component. Both constant amplitude and near-threshold fatigue crack growth rates of the alloy in the L–T and T–L orientations were determined at different stress ratios. Particular attention was paid to the role of the T_B phase in the fatigue crack growth. When a fatigue crack approached a T_B particle, the crack basically meandered to avoid the particle. The T_B particles thus provided a strong resistance to the propagation of fatigue crack by promoting crack deflection and the related crack closure effects. The fatigue crack propagation behavior has been explained by the microstructural features, micro-textures, cracking characteristics and crack closure effects.