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1.
Measuring the anisotropy of the field‐effect mobility provides insight into the correlation between molecular packing and charge transport in organic semiconductor materials. Single‐crystal field‐effect transistors are ideal tools to study intrinsic charge transport because of their high crystalline order and chemical purity. The anisotropy of the field effect mobility in organic single crystals has previously been studied by lamination of macroscopically large single crystals onto device substrates. Here, a technique is presented that allows probing of the mobility anisotropy even though only small crystals are available. Crystals of a soluble oligothiophene derivative are grown in bromobenzene and drop‐cast onto substrates containing arrays of bottom‐contact gold electrodes. Mobility anisotropy curves are recorded by measuring numerous single crystal transistor devices. Surprisingly, two mobility maxima occur at azimuths corresponding to both axes of the rectangular cyclohexyl‐substituted quaterthiophene (CH4T) in‐plane unit cell, in contrast to the expected tensorial behavior of the field effect mobility.  相似文献   

2.
A method of patterning large arrays of organic single crystals is reported. Using single‐walled carbon nanotube (SWNT) bundles as patterned templates, several organic semiconductor materials were successfully patterned, including p‐type pentacene, tetracene, sexiphenylene, and sexithiophene, as well as n‐type tetracyanoquinodimethane (TCNQ). This study suggests that the selective growth of crystals onto patterned carbon nanotubes is most likely due to the coarse topography of the SWNT bundles. Moreover, we observed that the crystals nucleated from SWNT bundles and grew onto SWNT bundles in a conformal fashion. The dependence of the number of crystals on the quantity of SWNT bundles is also discussed. The crystal growth can be directly applied onto transistor source‐drain electrodes and arrays of organic single‐crystal field effect transistors are demonstrated. The results demonstrate the potential of utilizing carbon nanotubes as nucleation templates for patterning a broad range of organic materials for applications in optoelectronics.  相似文献   

3.
Polymer dielectrics with intrinsic mechanical flexibility are considered as a key component for flexible organic field‐effect transistors (OFETs). However, it remains a challenge to fabricate highly aligned organic semiconductor single crystal (OSSC) arrays on the polymer dielectrics. Herein, for the first time, a facile and universal strategy, polar surface‐confined crystallization (PSCC), is proposed to grow highly aligned OSSC arrays on poly(4‐vinylphenol) (PVP) dielectric layer. The surface polarity of PVP is altered periodically with oxygen‐plasma treatment, enabling the preferential nucleation of organic crystals on the strong‐polarity regions. Moreover, a geometrical confinement effect of the patterned regions can also prevent multiple nucleation and misaligned molecular packing, enabling the highly aligned growth of OSSC arrays with uniform morphology and unitary crystallographic orientation. Using 2,7‐dioctyl[1]benzothieno[3,2‐b]benzothiophene (C8‐BTBT) as an example, highly aligned C8‐BTBT single crystal arrays with uniform molecular packing and crystal orientation are successfully fabricated on the PVP layer, which can guarantee their uniform electrical properties. OFETs made from the C8‐BTBT single crystal arrays on flexible substrates exhibit a mobility as high as 2.25 cm2 V?1 s?1, which has surpassed the C8‐BTBT polycrystalline film‐based flexible devices. This work paves the way toward the fabrication of highly aligned OSSCs on polymer dielectrics for high‐performance, flexible organic devices.  相似文献   

4.
In organic thin film transistors (OTFTs), charge transport occurs in the first few monolayers of the semiconductor near the semiconductor/dielectric interface. Previous work has investigated the roles of dielectric surface energy, roughness, and chemical functionality on performance. However, large discrepancies in performance, even with apparently identical surface treatments, indicate that additional surface parameters must be identified and controlled in order to optimize OTFTs. Here, a crystalline, dense octadecylsilane (OTS) surface modification layer is found that promotes two‐dimensional semiconductor growth. Higher mobility is consistently achieved for films deposited on crystalline OTS compared to on disordered OTS, with mobilities as high as 5.3 and 2.3 cm2 V?1 s?1 for C60 and pentacene, respectively. This is a significant step toward morphological control of organic semiconductors which is directly linked to their thin film charge carrier transport.  相似文献   

5.
Solution-processed organic crystals are important in field-effect transistors because of their highly ordered molecular packing and ease of device fabrication. For practical applications, the patterning of organic crystal transistor arrays is critical. However, uniformity, which concerns the variation in electrical performance among devices fabricated simultaneously on the same substrate, is a common consideration in the commercial applications of the solution-processed organic crystal transistor arrays. Here, a simple approach for fabricating field-effect transistor arrays based on organic plate-like crystals is reported. Through this method, a direct spin-coating process from a mixture solution of organic semiconductor and polymer dielectric can produce organic plate-like crystals. The grain size of the crystals is observed to be hundreds of micrometers. By controlling the concentrations of the active materials, the transistor arrays exhibit high uniformity and good device performance. The results presented in this work promise that this approach is a comparable technology to hydrogenated amorphous silicon-based FETs and is a great candidate for practical applications in electronic devices.  相似文献   

6.
Fabrication of organic field‐effect transistors (OFETs) using a high‐throughput printing process has garnered tremendous interest for realizing low‐cost and large‐area flexible electronic devices. Printing of organic semiconductors for active layer of transistor is one of the most critical steps for achieving this goal. The charge carrier transport behavior in this layer, dictated by the crystalline microstructure and molecular orientations of the organic semiconductor, determines the transistor performance. Here, it is demonstrated that an inkjet‐printed single‐droplet of a semiconducting/insulating polymer blend holds substantial promise as a means for implementing direct‐write fabrication of organic transistors. Control of the solubility of the semiconducting component in a blend solution can yield an inkjet‐printed single‐droplet blend film characterized by a semiconductor nanowire network embedded in an insulating polymer matrix. The inkjet‐printed blend films having this unique structure provide effective pathways for charge carrier transport through semiconductor nanowires, as well as significantly improve the on‐off current ratio and the environmental stability of the printed transistors.  相似文献   

7.
This work innovatively develops a dual solution‐shearing method utilizing the semiconductor concentration region close to the solubility limit, which successfully generates large‐area and high‐performance semiconductor monolayer crystals on the millimeter scale. The monolayer crystals with poly(methyl methacrylate) encapsulation show the highest mobility of 10.4 cm2 V?1 s?1 among the mobility values in the reported solution‐processed semiconductor monolayers. With similar mobility to multilayer crystals, light is shed on the charge accumulation mechanism in organic field‐effect transistors (OFETs), where the first layer on interface bears the most carrier transport task, and the other above layers work as carrier suppliers and encapsulations to the first layer. The monolayer crystals show a very low dependency on channel directions with a small anisotropic ratio of 1.3. The positive mobility–temperature correlation reveals a thermally activated carrier transport mode in the monolayer crystals, which is different from the band‐like transport mode in multilayer crystals. Furthermore, because of the direct exposure of highly conductive channels, the monolayer crystal based OFETs can sense ammonia concentrations as low as 10 ppb. The decent sensitivity indicates the monolayer crystals are potential candidates for sensor applications.  相似文献   

8.
Organic single crystals have a great potential in the field of organic optoelectronics because of their advantages of high carrier mobility and high thermal stability. However, the application of the organic single crystals in light‐emitting devices (OLEDs) has been limited by single‐layered structure with unbalanced carrier injection and transport. Here, fabrication of a multilayered‐structure crystal‐based OLED constitutes a major step toward balanced carrier injection and transport by introducing an anodic buffer layer and electron transport layer into the device structure. Three primary color single‐crystal‐based OLEDs based on the multilayered structure and molecular doping exhibit a maximum luminance and current efficiency of 820 cd cm?2 and 0.9 cd A?1, respectively, which are the highest performance to date for organic single‐crystal‐based OLEDs. This work paves the way toward high‐performance organic optoelectronic devices based on the organic single crystals.  相似文献   

9.
Trap states, present in any semiconductor, have a large influence on charge transport as well as various other physical processes relevant for device performance. Therefore, quantifying the density of trap states (trap DOS) in a semiconductor is a crucial step towards understanding and improving field-effect transistors (FET), organic photovoltaic cells (OPV) and organic light-emitting diodes (OLED). We present a method to determine the free vs. total charge carrier density in FETs, and therefore the trap DOS, through full normalization of the transfer curve. We apply this method to many different materials, prepared under a wide range of processing conditions, e.g. organic single crystals, thermally evaporated and inkjet printed thin-films, leading to various degrees of order/disorder. They are compared to inorganic thin-films. A quantitative analysis of the spectral density of the trap DOS reveals the trap DOS in p- and n-type semiconductors to be very similar provided they have a similar morphology. The variation by 3 orders of magnitude is dominated by the degree of crystalline order. Further, the trap DOS in organic materials is essentially the same as in inorganic materials, again, provided they have a similar morphology. Surprisingly, ink-jet printed organic polymers have a relatively low trap DOS, which is in between the one of organic single crystals and thin-films.  相似文献   

10.
The preparation of uniform large‐area highly crystalline organic semiconductor thin films that show outstanding carrier mobilities remains a challenge in the field of organic electronics, including organic field‐effect transistors. Quantitative control over the drying speed during dip‐coating permits optimization of the organic semiconductor film formation, although the kinetics of crystallization at the air–solution–substrate contact line are still not well understood. Here, we report the facile one‐step growth of self‐aligning, highly crystalline soluble acene crystal arrays that exhibit excellent field‐effect mobilities (up to 1.5 cm V?1 s?1) via an optimized dip‐coating process. We discover that optimized acene crystals grew at a particular substrate lifting‐rate in the presence of low boiling point solvents, such as dichloromethane (b.p. of 40.0 °C) or chloroform (b.p. of 60.4 °C). Variable‐temperature dip‐coating experiments using various solvents and lift rates are performed to elucidate the crystallization behavior. This bottom‐up study of soluble acene crystal growth during dip‐coating provides conditions under which one may obtain uniform organic semiconductor crystal arrays with high crystallinity and mobilities over large substrate areas, regardless of the substrate geometry (wafer substrates or cylinder‐shaped substrates).  相似文献   

11.
The first ambipolar light‐emitting transistor of an organic molecular semiconductor single crystal, tetracene, is demonstrated. In the device configuration, electrons and holes injected from separate magnesium and gold electrodes recombined radiatively within the channel. By varying the applied voltages, the position of the recombination/emission zone could be moved to any position along the channel. Because of the changes made to the device structure, including the use of single crystals and polymer dielectric layers and the adoption of an inert‐atmosphere fabrication process, the set of materials that can be used for light‐emitting transistors has been expanded to include monomeric molecular semiconductors.  相似文献   

12.
Organic single crystals have attracted great attention because of their advantages of high charge‐carrier mobility, high chemical purity, and potential for flexible optoelectronic devices. However, their intrinsic properties of sensitive to organic solvent and fragile result in a difficulty in the fabrication of the organic crystal‐based devices. In this work, a simple and non‐destructive technique of template stripping is employed to fabricate single‐crystal‐based organic light‐emitting devices (OLEDs). Efficient and uniform carrier injection induced by an improved contact between crystals and both top and bottom electrodes is realized, so that a homogeneous and bright electroluminescence (EL) are obtained. Highly polarized EL and even white emission is also observed. Moreover, the crystal‐based OLEDs exhibit good flexibility, and keep stable EL under a small bending radius and after repeated bending. It is expectable that this technique would support broad applications of the organic single crystals in the crystal‐based optoelectronic devices.  相似文献   

13.
Charge carrier mobility is an important characteristic of organic field‐effect transistors (OFETs) and other semiconductor devices. However, accurate mobility determination in FETs is frequently compromised by issues related to Schottky‐barrier contact resistance, that can be efficiently addressed by measurements in 4‐probe/Hall‐bar contact geometry. Here, it is shown that this technique, widely used in materials science, can still lead to significant mobility overestimation due to longitudinal channel shunting caused by voltage probes in 4‐probe structures. This effect is investigated numerically and experimentally in specially designed multiterminal OFETs based on optimized novel organic‐semiconductor blends and bulk single crystals. Numerical simulations reveal that 4‐probe FETs with long but narrow channels and wide voltage probes are especially prone to channel shunting, that can lead to mobilities overestimated by as much as 350%. In addition, the first Hall effect measurements in blended OFETs are reported and how Hall mobility can be affected by channel shunting is shown. As a solution to this problem, a numerical correction factor is introduced that can be used to obtain much more accurate experimental mobilities. This methodology is relevant to characterization of a variety of materials, including organic semiconductors, inorganic oxides, monolayer materials, as well as carbon nanotube and semiconductor nanocrystal arrays.  相似文献   

14.
Soluble small molecule organic semiconductors combine the high-performance of small molecule organic semiconductors with the versatile processability of polymeric materials, but the control of device performance and uniformity is challenged by the complex film microstructure formed in these materials, and its strong dependence on processing conditions. These films crystallize via a nucleation and growth mechanism that can be difficult to control. In this study we used highly fluorinated self-assembled monolayers (SAMs) to modify the surface of the source and drain contacts and improve the performance of organic thin-film transistors (OTFTs) through controlling film microstructure and lowering the contact resistance. We reached charge carrier mobilities as high as 5.7 cm2/V in 2,8-Difluoro-5,11-bis(triethylsilylethynyl) anthradithiophene (diF-TES ADT), one order of magnitude greater than what we obtained in devices on untreated substrates, and on par with the value reported for single crystal devices. Kelvin probe measurements distinguished an increase in the work function between 0.28 eV and 0.5 eV, depending on the molecular structure of the SAM. Selected area electron diffraction (SAED) confirmed the preferential “edge-on” molecular orientation of the semiconductor. We discuss the device performance in relation to the film morphology and contact resistance.  相似文献   

15.
《Organic Electronics》2014,15(1):211-215
The understanding of the charge carrier transport in electronic materials is of crucial interest for the design of efficient devices including especially the restraints that arise from device miniaturization. In this work the performance of organic thin-film and single crystal field-effect transistors with the same active material was studied in detail focusing on the high current density regime, where a pronounced non-hysteretic maximum in the transconductance was found. Interestingly, in this operation mode for both, thin films and single crystals, comparable densities of free and gate-induced charge carriers were estimated. Kelvin probe microscopy was used to measure the contact potential difference and the electrical field along the transistor channel during device operation exhibiting the formation of local space charges in the high current density regime.  相似文献   

16.
The softness and anisotropy of organic semiconductors offer unique properties. Recently, solution‐sheared thin‐films of 6,13‐bis(triisopropylsilylethynyl) pentacene (TIPS‐P) with nonequilibrium single‐crystal domains have shown much higher charge mobilities than unstrained ones (Nature 2011 , 480, 504). However, to achieve efficient and targeted modulation of charge transport in organic semiconductors, a detailed microscopic understanding of the structure–property relationship is needed. In this work, motivated by the experimental studies, the relationship between lattice strain, molecular packing, and charge carrier mobility of TIPS‐P crystals is elucidated. By employing a multiscale theoretical approach combining nonequilibrium molecular dynamics, first‐principles calculations, and kinetic Monte Carlo simulations using charge‐transfer rates based on the tunneling enabled hopping model, charge‐transport properties of TIPS‐P under various lattice strains are investigated. Shear‐strained TIPS‐P indeed exhibits one‐dimensional charge transport, which agrees with the experiments. Furthermore, either shear or tensile strain lead to mobility enhancement, but with strong charge‐transport anisotropy. In addition, a combination of shear and tensile strains could not only enhance mobility, but also decrease anisotropy. By combining the shear and tensile strains, almost isotropic charge transport could be realized in TIPS‐P crystal with the hole mobility improved by at least one order of magnitude. This approach enables a deep understanding of the effect of lattice strain on charge carrier transport properties in organic semiconductors.  相似文献   

17.
Application-oriented patterned growth of organic semiconductor (OSC) thin films with single crystalline domains is crucial for fabricating sophisticated high-performance organic-electronic and optoelectronic devices; however, fabricating these patterned nanometer-thick crystals in a simple, fast, and effective manner is a difficult task with a roll-to-roll printing process. Here, a simple bar-coating approach to form an array of single-crystal-like OSC thin-film patterns at a rate of a few millimeters per second is introduced. To this end, the processing parameters of a gap-controlled bar-coating method is optimized, including coating speed, crystal nucleation, and solution fluidics, which allow a high degree of morphological control of bar-coated OSC films in an area of several centimeters. In particular, it is demonstrated that the solutal-Marangoni flow induced by a suitable solvent additive can considerably improve molecular mass transport and induce favorable vertical phase separation. Thus, organic transistors based on the OSC patterns fabricated with the additive-assisted bar coating show a field-effect mobility of up to 20 cmV−1 s−1 and superior operational stability. The proposed bar coating method will facilitate an industry-level application of organic electronics.  相似文献   

18.
The properties of organic‐semiconductor/insulator (O/I) interfaces are critically important to the operation of organic thin‐film transistors (OTFTs) currently being developed for printed flexible electronics. Here we report striking observations of structural defects and correlated electrostatic‐potential variations at the interface between the benchmark organic semiconductor pentacene and a common insulator, silicon dioxide. Using an unconventional mode of lateral force microscopy, we generate high‐contrast images of the grain‐boundary (GB) network in the first pentacene monolayer. Concurrent imaging by Kelvin probe force microscopy reveals localized surface‐potential wells at the GBs, indicating that GBs will serve as charge‐carrier (hole) traps. Scanning probe microscopy and chemical etching also demonstrate that slightly thicker pentacene films have domains with high line‐dislocation densities. These domains produce significant changes in surface potential across the film. The correlation of structural and electrostatic complexity at O/I interfaces has important implications for understanding electrical transport in OTFTs and for defining strategies to improve device performance.  相似文献   

19.
Simultaneously integrating efficient optical gain and high charge carrier mobility in organic semiconductors for multifunctional optoelectronic applications is challenging. Here, a new thiophene/phenylene derivative, 5,5′‐bis(2,2‐diphenylvinyl)‐bithiophene (BDPV2T), containing an appropriate butterfly molecular configuration in a π‐conjugated structure, is designed to achieve both solid‐state emission and charge transport properties. The prepared BDPV2T crystals exhibit excellent light‐emitting characteristics with a photoluminescence quantum yield of 30%, low light‐amplification threshold of 8 kW cm?2, high optical net gain up to 70 cm?1, and high charge carrier mobility up to 1 cm2 V?1 s?1 in their J‐aggregate single crystals. These BDPV2T single crystal characteristics ensure their application potential for photodetectors, field‐effect transistors, and light‐emitting transistors. High optoelectronic performances are achieved with photoresponsivity of 2.0 × 103 A W?1 and light on/off ratio of 5.4 × 105 in photodetectors, and efficient ambipolar charge transport (µh: 0.14 cm2 V?1 s?1, µe: 0.02 cm2 V?1 s?1) and electroluminescence characteristics in light‐emitting transistors. The remarkably integrated optoelectronic properties of BDPV2T suggest it is a promising candidate for organic multifunctional and electrically pumped laser applications.  相似文献   

20.
The dielectric‐semiconductor interfacial interactions critically influence the morphology and molecular ordering of the organic semiconductor molecules, and hence have a profound influence on mobility, threshold voltage, and other vital device characteristics of organic field‐effect transistors. In this study, p‐channel small molecule/polymer (evaporated pentacene and spin‐coated poly(3,3?;‐didodecylquarterthiophene) – PQT) and n‐channel fullerene derivative ({6}‐1‐(3‐(2‐thienylethoxycarbonyl)‐propyl)‐{5}‐1‐phenyl‐[5,6]‐C61 – TEPP‐C61) show a significant enhancement in device mobilities ranging from ~6 to ~45 times higher for all classes of semiconductors deposited on sol–gel silica gate‐dielectric than on pristine/octyltrichlorosilane (OTS)‐treated thermally grown silica. Atomic force microscopy, synchrotron X‐ray diffraction, photoluminescence/absorption, and Raman spectroscopy studies provide comprehensive evidences that sol–gel silica dielectrics‐induced enhancement in both p‐ and n‐channel organic semiconductors is attributable to better molecular ordering/packing, and hence reduced charge trapping centers due to lesser structural defects at the dielectric‐semiconductor interface.  相似文献   

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