Quantitative multimolecular marker approach to investigate the spatial variability of the transfer of pollution from the Fensch River to the Moselle River (France)

The lipidic fraction from 8 sediments sampled at the confluence between the Fensch River (FR) and the Moselle River (MR) have been analyzed by gas chromatography-mass spectrometry (GC-MS) in order to investigate the transfer of organic micropollutants from the FR to the MR. Molecular markers have been quantified and classified into five categories: natural, petrogenic, pyrogenic and sewage water markers and non-specific molecules. This classification coupled with the quantification of the molecules allows the comparison between anthropogenic and natural inputs and the source apportionment of anthropogenic molecules that are not covalently bound to sedimentary organic macromolecules. The transfer and the fate of organic micropollutants in river sediments seem to be controlled by the water flow. Low water flow conditions induce the settling of fine particles, which could limit the biodegradation. This leads to the preservation of the original anthropogenic fingerprint that is rich in low molecular weight molecules. In high water flow conditions, sediments are mainly composed of coarse particles, limiting the preservation of organic matter, which leads to a persistent anthropogenic fingerprint, mainly composed of high molecular weight compounds.     

Quantitative assessment of estrogenic activity in the water environment of Korea by the E-SCREEN assay

In this study, the E-SCREEN assay was optimized and validated for the sensitive quantitative determination of the total estrogenicity in river samples. River water and sediment samples were collected and analyzed with the E-SCREEN. River water (10 l) was extracted using combined solid-phase extraction in static adsorption mode with Soxhlet extraction. Estrogenic pollutants adsorbed to the XAD-4 resin were recovered with 98.24 +/- 5.90% efficiency by elution with ethyl acetate and dichloromethane (1:9). The detection limit by 17beta-estradiol equivalent concentration (EEQ) of the E-SCREEN assay was 8.03 pg EEQ/l. Among the water samples, the estrogenic activity was observed to be higher downstream of the Kumho river (7.43 ng EEQ/l) and upstream of Kum river (2.05 ng EEQ/l) than in other samples. More than 3 mg of equivalent sediment samples from the Kumho river, Kum river and Miho stream showed partial agonistic effects, and the Mankyung river showed a partial agonistic effect with only 1.5 mg of sediment. The highest value of RPE was 83.34 downstream of the Kumho river, and the lowest value of RPE was 6.52 downstream of the Miho stream. Full estrogen agonistic activities were observed downstream of the Kumho river and upstream of the Kum river. The partial agonistic activity was observed in upstream of the Kumho river, downstream of the Mankyung river, and upstream of the Miho stream, and no agonistic action was observed downstream of the Kum river or Miho stream, or upstream of the Mankyung river. The total estrogenic activity in the river water and sediment samples was between 0.50 pg/L and 7.4 ng/L, 3.39 pg/g and 10.70 pg/g.     

Impact of a highly contaminated river on a more important hydrologic system: changes in organic markers

The Fensch River is a tributary of the Moselle River. It is a highly contaminated river that drains an industrial area. The objective of this preliminary study is to determine its impact on the Moselle River by analysing the extractable organic matter (EOM) coming from the sediments at the molecular scale. EOM is described in term of aromatic hydrocarbons, aliphatic hydrocarbons and polar compounds. EOM coming from Fensch River sediments is mainly composed of anthropogenic molecules. Aromatic hydrocarbons are dominated by parent Polycyclic Aromatic Hydrocarbons (PAHs) underlining the pyrogenic origin of this fraction. Aliphatic hydrocarbons consist of diagenetic hopanes and a broad UCM that are characteristics of thermal mature organic matter. Upstream the confluence the EOM of the Moselle River is mainly from vegetal origin. It is composed of high molecular weight n-alkanes with an odd over even predominance, degredation products of phytol and stigmasterol. The occurrence of PAHs and diagenetic hopanes underlines that the Moselle River is already contaminated before the confluence. The Fensch River input drastically changes the EOM of the Moselle River. Amount of PAHs is doubled and the fingerprints of both aliphatic hydrocarbons and polar compounds highlight the combination of both natural and anthropogenic sources.     

An assessment of anthropogenic source impacts on mercury cycling in the Willamette Basin, Oregon, USA

In Oregon's Willamette River Basin (Basin), methylmercury levels in fish triggered health advisories and required development of a mercury Total Maximum Daily Load (TMDL) for the Willamette River. A seasonally-responsive dynamic systems model is used to identify the principal sources of natural and anthropogenic mercury, the relative contributions of these sources to the river, the impact of hypothetical reductions in specific natural and anthropogenic sources on mercury levels in surface water, sediment, and fish tissue, and the degree to which any such changes would be clearly discernible to environmental managers and Basin stakeholders. Two scenarios are modeled: "PRES", which considered all currently known natural and anthropogenic mercury sources and "LEEM", which (hypothetically) eliminated all local, but not global, anthropogenic sources and greatly lowered native soil erosion rates. Elimination of local air emissions reduces runoff of air-deposited mercury by approximately 34% and advection from the Basin by approximately 12%, while lowering erosion rates reduces particulate runoff by approximately 57%, deposition from the water column to surficial sediment by approximately 33%, and fluvial load by approximately 24%; for a net reduction of 25.6% in the total mercury load to the river. Such hypothetical reductions bring methylmercury concentrations in predatory fish to levels that would allow restoration of fish consumption as a beneficial use. However, several factors, primarily technical feasibility and global sources, may impede attempts to attain this beneficial use. Actualizing the hypothetical 100% elimination of local anthropogenic sources and a >50% reduction in erosion could pose significant technical challenges. Because local anthropogenic emissions make relatively smaller contributions to the Basin than do persistent global sources (sources over which there is little, if any, possibility of local control), localized environmental management actions alone may not be adequate to address mercury impacts within the Basin.     

Water quality assessment of the River Kabul at Peshawar, Pakistan: Industrial and urban wastewater impacts

Untreated wastewater discharges may have significant short term and long term effects on the quality of a river system. Present study was undertaken to assess the present status of the water quality of the River Kabul near Peshawar in Pakistan. Seven sites were sampled upstream and downstream in the River Kabul in 2009. Samples were also taken from waste water channel (Budni Drain) that carries waste-water of Peshawar Industrial Estate as well as the domestic sewers to assess the pollution contribution of these sources to the River Kabul. Physico-chemical and microbiological parameters of the samples were analyzed during the study, as well as possible sources of contamination were investigated. The study showed that the pollution level in river is rising from upstream (at city entrance) to downstream (at city exit) due to discharge of domestic waste water effluents, agricultural activities, and solid waste dumping directly into the river.     

Factors influencing development of management strategies for the Abou Ali River in Lebanon I: spatial variation and land use

Surface water bodies are progressively subject to increasing stress as a result of environmentally degrading processes primarily related to anthropogenic activities. This study assesses and examines the impact of land use and land-based activities on the spatial variation in water quality of the Abou Ali River in North Lebanon. It is the first detailed study of its kind in Lebanon and adds to the existing knowledge by shedding light on a relatively small Mediterranean river in a developing country where there is a paucity of such studies. The assessment was conducted at the end of the dry season in 2002 and 2003 and the end of the wet season in 2003 and 2004. The study has demonstrated the importance of anthropogenic influences on the water quality of the Abou Ali River Basin, as concentrations of most contaminants were higher at locations with greatest human activity. The most adversely affected area was the section of the river that flows through an entirely urbanized and highly populated region, the Tripoli conurbation. Upstream rural sites were enriched by contaminants primarily from non-point sources such as agricultural runoff and poultry litter whereas contaminant concentrations at the urban sites were enriched by a combination of sewage discharge and flow of contaminants from upstream. If the Abou Ali River is to be utilized as a managed water resource and its water quality sustained, point source discharges will require treatment and land use management must be planned to minimize the impact of diffuse source pollution on the river. A high priority should be given to the implementation and enforcement of the precautionary and polluter pays principles. Moreover, an effective legal, economic and institutional framework is required to encourage investment in waste reduction and control and to introduce environmentally sound practices.     

Water quality monitoring during the construction of the M3 motorway in Ireland

The M3 motorway in Ireland was constructed between the years 2007 and 2010. The motorway crosses the River Boyne, which is a designated salmonid water under the EU Freshwater directive, and its tributaries. The paper describes the measures taken to mitigate any potential impacts which the road scheme might have had on the aquatic environment and the water quality of the Boyne watercourses before‐, during‐ and post‐construction. The success of the mitigation measures undertaken is assessed by: (a) comparing pre‐construction, during‐construction and post‐construction water quality data, (b) comparing measured water quality with relevant standards, (c) comparing water quality data upstream and downstream of river crossings, (d) the establishment of a pilot‐scale real‐time water quality monitoring station at the downstream end of the works before discharge into the river Boyne. The study concluded that the measures taken have been successful in minimising the water quality impacts associated with the road scheme.     

First observation of intersex cyprinids in the Po River (Italy)

Barbel (Barbus plebejus, Cyprinidae) were captured in the Po River, upstream and downstream from the confluence of the Lambro River, a polluted tributary of the major Italian watercourse. The gonads of the two groups of barbel have been histologically examined, and only the downstream specimens showed histo-morphological alterations that can be related to the Lambro tributary as a source to the main river of endocrine disrupting chemicals, possibly with estrogenic effects. In fact, 50% of the barbel captured (8 of 16 fish) in the downstream reach showed intersex gonads.     

Eutrophication downstream from small reservoirs in mountain rivers of Central Spain

In this research we examined the hypothesis that upper reaches of rivers and streams can experience eutrophication as a consequence of deep releases from dams. Field studies were conducted in four mountain rivers (Tormes, Riaza, Eresma and Miraflores Rivers) of Central Spain. The watersheds of these rivers are underlain by siliceous rocks. A small deep-release storage reservoir is found in the upper reaches of each river. Two sampling sites, upstream and downstream from the reservoir, were established in stony riffles of each impounded river. Significant (P < 0.01) increases in conductivity and nutrient (NO3-N, NH4-N, PO4-P) concentrations downstream from the reservoirs were measured. Significant (P < 0.01) increases in periphyton chlorophyll a and ash-free dry biomass were also quantified at downstream sites. Significant (P < 0.01) correlation coefficients indicated that phosphate would play a more important role as the limiting nutrient for periphyton. Relative abundances of macroinvertebrate scrapers and collector-gatherers increased downstream from the reservoirs. Furthermore, taxon dominance, total density and total biomass of macroinvertebrates tended to be higher at downstream sites than at upstream sites. In contrast, taxon diversity and relative abundance of macroinvertebrate shredders decreased downstream from the reservoirs. It is concluded that small deep-release storage reservoirs, located in upper reaches of siliceous rivers, can act as nutrient sources, causing eutrophication downstream. Nutrients would ultimately come from land/forest runoff. The fact that terrestrial vegetation was not completely removed before filling reservoirs could also contribute to the eutrophication process.     

Effect of phosphorus stripping on water chemistry and diatom ecology in an eastern lowland river

The effect of nutrient removal at Ashford sewage treatment works on the benthic diatom ecology of the River Stour was studied. This paper describes assemblages above and below the works both before and after phosphorus stripping was installed. Taxa typical of eutrophic conditions dominated all samples, including those upstream of the works, suggesting that the river was already eutrophic before receiving the sewage effluent. Once nutrient removal was installed, phosphorus concentrations measured downstream of the works were similar to those measured upstream; however, there was little change in the diatom flora. Analysis of chemical data collected from the site suggest that the river may be nitrogen-limited for part of the year, and that, even with phosphorus stripping installed, the river still exceeds the Environment Agency's proposed interim targets for phosphorus concentrations in a eutrophic river.     

Arsenic speciation in the River Zenne, Belgium

Arsenic species have been assessed in the Zenne River, a sewage contaminated tributary of the Scheldt estuary, in winter 2003. The highest total dissolved As concentrations were found in the middle part of the river with values up to 3.6 microg L(-1). Particulate As concentrations increase towards the mouth of the River with highest levels of 2 microg L(-1). A very good correlation between the % of dissolved As and % of dissolved Fe was observed. They both linearly decrease with the amount of dissolved oxygen. In the middle part of the Zenne River where the oxygen levels were lowest, even below 1 mg L(-1), As(III) was the dominant species. In the other parts (upstream and downstream) of the river, As(V) was dominant. A linear relation between the measured redox values and those calculated via the As(III)/As(V) couple exists, but the range of measured Eh values is much larger than the calculated ones. No methylated dissolved As species were found during our survey.     

Adaptive capabilities of hydrobionts to aqueous medium with different physicochemical parameters

The causes and physiological-biochemical mechanisms of migration of marine species of hydrobionts to fresh waters of the Dnieper River and the cascade of its reservoirs have been investigated. The possible adaptation of marine fish species and invertebrates is related to the economic human activity: regulation of river runoff, creation of a cascade of reservoirs with large water-surface area, anthropogenic pollution of natural water, and also changes of climate conditions on the Earth (global warming). It is presumed that these processes result in significant change of physicochemical indicators of aquatic medium. One can observe the rise of mineralization, increase of the number of biogenic compounds, variation of their ratio in fresh water that, in turn, allows the marine species of hydrobionts to adapt to new conditions and advance upstream.     

Characteristics of humic substances in the Kuji River waters as determined by high-performance size exclusion chromatography with fluorescence detection

Direct measurement by high-performance size exclusion chromatography with fluorescence detection was applied to the characterization of humic substances in river waters from the Kuji River system, which runs through forest hills and an agricultural plain in Japan. The monitoring wavelength of excitation 320 nm and emission 430 nm corresponds to the fluorescence maxima for aquatic fulvic acid. Chromatograms of the river waters showed four peaks; each peak position was in good agreement among these samples. Peak height ratios for the samples from the upstream Kuji River and its tributaries were different from those of the midstream and downstream sections of the Kuji River, which may reflect differences in the characteristics of humic substances and other organic materials supplied from soil to river.     

The water quality of the River Thame in the Thames Basin of south/south-eastern England

The water quality of the River Thame, a tributary of the River Thames in the Thames basin, is described in relation to point and diffuse contaminant inputs and runoff from permeable and impermeable bedrock geology with their own characteristic water quality. The data is examined to see if the market town of Aylesbury in the upper part of the catchment influences water quality. Previous studies highlighted the influence of Aylesbury sewage treatment works (STW) on soluble reactive phosphorus (SRP) concentrations in the river before and after phosphorus (P) stripping at the STW. Variations in water quality along the river are described and the study indicates that, apart from SRP, water quality determinants seem to be relatively unaffected by Aylesbury. The Thame water quality is compared with other catchment typologies and it is very similar to that of the main stem of the Thames even though the Thames is mainly Chalk groundwater fed. Differences in water quality largely link to the amount of STW effluent within the rivers and to the endmember compositions of the groundwater and near surface water sources.     

Hydrological assessment of flow dynamic changes by storm sewer overflows and combined sewer overflows on an event-scale in an urban river

In addition to assessing the impacts of water quality changes in urban rivers caused by storm water sewer overflows (SWO) and combined sewer overflows (CSO), the extent to which flow dynamics are changed by these structures must be understood in order to define hydrological assessment criteria to guide sustainable water management strategies as required by the European Community (EC) Water Framework Directive. In this study, the quantitative impacts of SWOs and CSOs on the flow dynamics of an urban river and their variability are investigated. For four single runoff events, hydrological measurements were accomplished in the River Dreisam, upstream and downstream of the city of Freiburg, in southwest Germany. As the catchment is widely free of urban areas upstream of the city, comparison with downstream locations allowed quantification of Freiburg's effects on the changes in the hydrograph on an event scale. The proposed hydrological parameter—flow acceleration, peak discharge, and discharge dosage—were shown to be appropriate to assess the impacts of SWOs and CSOs on flood hydrographs in urban rivers.     

The effects of unpaved roads on suspended sediment concentration at varying spatial scales – a case study from Southern Brazil

Unpaved roads may induce adverse effects on downstream water resources by increasing suspended sediment concentration (SSC). This study documents the localized impacts on stream SSC of six unpaved road–stream crossings in the rural Guabiroba River Catchment, in southern Brazil. Results demonstrated that SSC values downstream of road–stream crossings was between 3.5 and 10 times higher than upstream SSC at all third‐ and fourth‐order stream locations. However, downstream values were statistically undistinguishable from those collected upstream of road–stream crossings at fifth‐order sampling sites. These findings suggest that localized road effects on stream SSCs are scale‐dependent in that these are important for low‐order headwater streams yet undetectable for their higher order counterparts. Findings point to the importance of low‐order stream crossings in increasing SSC and the need to further explore the role of unpaved roads as agents of water quality degradation in agriculturally active rural settings.     

Density currents in the Chicago River: characterization, effects on water quality, and potential sources

Bidirectional flows in a river system can occur under stratified flow conditions and in addition to creating significant errors in discharge estimates, the upstream propagating currents are capable of transporting contaminants and affecting water quality. Detailed field observations of bidirectional flows were made in the Chicago River in Chicago, Illinois in the winter of 2005-06. Using multiple acoustic Doppler current profilers simultaneously with a water-quality profiler, the formation of upstream propagating density currents within the Chicago River both as an underflow and an overflow was observed on three occasions. Density differences driving the flow primarily arise from salinity differences between intersecting branches of the Chicago River, whereas water temperature is secondary in the creation of these currents. Deicing salts appear to be the primary source of salinity in the North Branch of the Chicago River, entering the waterway through direct runoff and effluent from a wastewater-treatment plant in a large metropolitan area primarily served by combined sewers. Water-quality assessments of the Chicago River may underestimate (or overestimate) the impairment of the river because standard water-quality monitoring practices do not account for density-driven underflows (or overflows). Chloride concentrations near the riverbed can significantly exceed concentrations at the river surface during underflows indicating that full-depth parameter profiles are necessary for accurate water-quality assessments in urban environments where application of deicing salt is common.     

River flow and associated transport of sediments and solutes through a highly urbanised catchment, Bradford, West Yorkshire

The hydrological characteristics of catchments become drastically modified in response to urbanisation. The total contributions and dynamics of runoff, suspended sediment and solutes may change significantly and have important implications downstream where they may affect flooding, instream ecological habitat, water quality and siltation of river channels and lakes. Although an appreciation of the likely hydrological changes is crucial for effective catchment management they are still poorly understood. In this paper we present data from a network of river monitoring stations throughout the heavily urbanised Bradford catchment, West Yorkshire. Sites are upstream, within and downstream of the highly urbanised central part of the catchment. Flow, turbidity (calibrated to suspended sediment concentration) and specific conductance (surrogate for solute concentration), logged at 15-min intervals, are presented for a 12-month period (June 2000 to June 2001). The total amounts and dynamics of flow, solute and suspended sediment transport were investigated. Estimated total flow and suspended sediment transport for the monitoring period were found to be high in response to the high total rainfall. Flow and sediment transport regimes were extremely 'flashy' throughout the catchment and became increasingly flashy in a downstream direction. Suspended sediment discharged from the Bradford subcatchment makes an important contribution to downstream sediment transport on the river Aire at Beal. Data suggest that the urbanised part of the Bradford catchment is extremely important in contributing solutes to the Beck (river). Although flow and sediment are also contributed to the Bradford Beck in the urbanised part of the catchment the data suggest that significant amounts may enter the combined sewer system and bypass the river. Understanding the spatial and temporal variations of flow and the transport of suspended sediment and solutes in rivers in urbanized subcatchments is crucial to their effective management and monitoring. Furthermore, this knowledge may be extremely important to the management and monitoring of downstream rivers in large scale mixed catchments.     

跨东津河桥梁调研分析与设计

结合宁宣杭高速公路宁国至千秋关段东津河的特点,根据河流上下游建筑物的设置及使用情况,通过水文计算,合理确定了跨东津河桥梁的孔径布置,并阐述了该桥设计要点,对今后同类桥梁设计提供了一定经验。     

Short-term variability of dissolved trace element concentrations in the Marne and Seine rivers near Paris

The concentrations of dissolved trace elements (Li, B, Mn, Cu, As, Rb, Sr, Mo, Cd, Ba, Pb) in the Marne and Seine rivers in the Paris urban area were monitored over a 2-year period. The resulting data indicated moderate contamination of waters by the most toxic elements (Cu, As, Cd and Pb). The River Marne upstream and the River Seine downstream of the city of Paris displayed similar concentrations. However higher fluxes of trace elements were observed in the Seine than in the Marne due to their different discharges. Li, B, Rb, Sr and Ba concentrations were correlated with river discharge and concentrations were higher during high river flow. This was interpreted as a dilution by discharge from a major natural or anthropogenic source. Mn, Cu, Mo, Cd and Pb concentrations were not correlated with discharge. Dissolved Mn, Cu and Cd increased rapidly in summer, whereas the concentration of Mo decreased. These variations were attributed to redox processes. During summer when the dissolved oxygen concentrations decrease, Mn, Cu, Cd and Pb are released into solution whereas Mo is immobilised. Like metals, variations in arsenic contents were not linked with discharge. Its similarity with phosphate distribution suggests similar controls involving phytoplankton uptake and release from sediments through organic matter mineralization.