Production and transport of urban wet weather pollution in combined sewer systems: the “Marais” experimental urban catchment in Paris

An experimental catchment area was set up in the centre of Paris (France) so as to follow up the quality of wet weather flows from the entry to the exit of a combined sewer network. The distinctive characteristic of this site is its location in a town centre and the extent of the equipment used to monitor the water pollution over the whole length of its course through the catchment area. The results obtained show a change in quality between the runoff entering the sewer network and the combined storm water flow at the sewer's outlet, which cannot be explained only by the mixture with domestic wastewater. In particular, an increase was observed in the concentrations of suspended solids (SS), VSS, COD, BOD and Cu, in the proportion of pollutants linked to particles and in the characteristics of the particles. A calculation of the total masses going in and out of the sewer network during a rainfall event shows that the erosion of in-sewer pollution stocks is the main source of particles and of organic matter in wet weather flows, whereas heavy metals loads originated from roof runoff, due to the corrosion of metallic roofs. Particles eroded from the sewer sediments during rain events were found to be quite different from the particles of type A deposits and organic biofilms. Nevertheless, they have mean organic and metallic loads that are of the same order of magnitude as the particles of the organic layer at water sediment interface. A change in the chemical form of heavy metals was noticed during the transport in the sewer and it is suspected that a fraction of the dissolved metals from the runoff is adsorbed on sewer sediments.     

Contributions of wastewater, runoff and sewer deposit erosion to wet weather pollutant loads in combined sewer systems

An observatory of urban pollutants was created in Paris for the purpose of assessing the dynamics of wastewater and wet weather flow (WW and WWF) pollutant loads within combined sewers. This observatory is composed of six urban catchments, covering land areas ranging in size from 42 ha to 2581 ha. For a wide array of parameters including total suspended solids (TSS), chemical and biochemical oxygen demand (COD and BOD₅), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), heavy metals (Cu and Zn) and polycyclic aromatic hydrocarbons (PAHs), this article is intended to evaluate the contributions of wastewater, runoff and in-sewer processes to WWF pollutant loads through the use of an entry–exit mass balance approach. To achieve this objective, a total of 16 rain events were sampled on these sites between May 2003 and February 2006. This study has confirmed that at the considered catchment scale (i.e. from 42 ha to 2581 ha) the production and transfer processes associated with WWF pollutant loads do not vary with basin scale. Entry–exit chemical mass balances over all catchments and for a large number of rain events indicate that wastewater constitutes the main source of organic and nitrogenous pollution, while runoff is the predominant source of Zn. For Cu, PAHs and TSS, the calculation underscores the major role played by in-sewer processes, specifically by sediment erosion, as a source of WWF pollution. A significant loss of dissolved metals was also observed during their transfer within the sewer network, likely as a consequence of the adsorption of dissolved metals on TSS and/or on sewer deposits. Moreover, the nature of eroded particles was examined and compared to the various sewer deposits. This comparison has highlighted that such particles exhibit similar organic and PAH contents to those measured in the organic layer, thus suggesting that the deposit eroded during a wet weather period is organic and of a nature comparable to the organic layer. Despite the extent of initial field investigations, no organic deposit was observed to be present on sewer lines within the catchments, which implies that this organic deposit is probably present in another form or to be found elsewhere in the main trunks.     

Wastewater quality and pollutant loads in combined sewers during dry weather periods

An observatory of urban pollutants was created in Paris in order to assess, at the urban catchment scale, the quality of sanitary sewage and pollutant loads during dry weather periods in the Paris combined sewer. Investigations were carried out for six urban catchments (varying from 42 to 2580 ha) focusing on a wide range of parameters, including: suspended solids (SS), chemical and biochemical oxygen demand (COD and BOD₅), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), heavy metals (Cd, Cu, Pb, Zn), and aliphatic and polycyclic aromatic hydrocarbons (AHs and PAHs). Despite the marginal intra-site variability of some pollutants, which serves to reflect the impact of point sources, this work attests to the spatial homogeneity, at the physical scales considered, of wastewater quality and pollutant loads within the Paris combined sewer network. These results imply that similar production and transfer processes are occurring within sewers during dry weather periods and strongly suggest that data obtained on one specific catchment could be extrapolated to smaller or larger catchments that display quite similar land use and sewer characteristics.     

Source characterisation and loads of metals and pesticides in urban wet weather discharges

Contaminants in urban wet weather discharges originate from a number of sources such as materials from wet and dry atmospheric deposition, wastewaters, urban surface erosion, traffic-related activities, in-sewer deposits, etc. In the current study, four contributions (rainwater, dry atmospheric deposition, dry weather discharge and catchment surface + possible erosion of in-sewer deposits) to the total concentrations of priority substances have been assessed at the outlet of two urban catchments (one residential catchment with a combined system and one industrial area with a separate stormwater system) for 12 storm events (six for each catchment). Mass balances were calculated for seven metals and four pesticides, as well as for total suspended solids and chemical oxygen demand. The respective contributions of dry and wet atmospheric deposition, wastewater and catchment surface differ for each pollutant type, corresponding to different land use, activities, environments and sewer systems. For most of the pollutants, the catchment surface appears to be the main contribution, with significant storm event variability, excepted for atrazine in one catchment.     

Trace element carriers in combined sewer during dry and wet weather: an electron microscope investigation

The nature of trace element carriers contained in sewage and combined sewer overflow (CSO) was investigated by TEM-EDX-Electron diffraction and SEM-EDX. During dry weather, chalcophile elements were found to accumulate in sewer sediments as early diagenetic sulfide phases. The sulfurization of some metal alloys was also evidenced. Other heavy metal carriers detected in sewage include metal alloys, some iron oxihydroxide phases and neoformed phosphate minerals such as anapaite. During rain events, the detailed characterization of individual mineral species allowed to differentiate the contributions from various specific sources. Metal plating particles, barite from automobile brake, or rare earth oxides from catalytic exhaust pipes, originate from road runoff, whereas PbSn alloys and lead carbonates are attributed to zinc-works from roofs and paint from building siding. Soil contribution can be traced by the presence of clay minerals, iron oxihydroxides, zircons and rare earth phosphates. However, the most abundant heavy metal carriers in CSO samples were the sulfide particles eroded from sewer sediments. The evolution of relative abundances of trace element carriers during a single storm event, suggests that the pollution due to the "first flush" effect principally results from the sewer stock of sulfides and previously deposited metal alloys, rather than from urban surface runoff.     

Characteristics of wet and dry weather heavy metal discharges in the Yeongsan Watershed, Korea

A comprehensive water quality monitoring program was conducted in the Yeongsan (YS) River, Korea from 2005 to present to investigate wet and dry weather pollutant discharge in an attempt to establish point and non-point pollution management strategies. As part of this monitoring program, 11 heavy metal species were measured during dry and wet weather conditions in the YS River, where Gwangju City (GJ), a subcatchment of the YS River, was further monitored to clarify the responsibility of different metal species discharged into the mainstream. Monthly grab water samples showed that greater amounts of metals along the YS River were discharged during the wet summer months due largely to storm runoff. In addition, further monitoring results revealed that GJ, a highly urbanized area, was a significant contributor of the heavy metals being discharged into the YS River during both wet and dry weather. The most abundant metal species discharged from GJ were manganese, aluminum and iron with different contributions of wet and dry weather flows to the total discharge load. Wet weather flow was a significant contributor to the annual dissolved metal loads, accounting for 44-93% of the annual load depending on the metal species, with the exception of chromium and cadmium (9% and 27%, respectively). Mostly, metal loads during wet weather were shown to be proportional to the rainfall depth and antecedent dry period. A substantial fraction of metals were also associated with solids, suggesting that sedimentation might be an appropriate management practice for reducing the metal load generated in GJ. Overall, although dissolved metal concentrations in YS River were at an acceptable level for aquatic community protection, continual metal discharge throughout the year was considered to be a potential problem in the long-term due to gradual water quality degradation as well as continuous metal accumulation in the system.     

武汉市汉阳区的暴雨径流污染特征

为研究合流制城区的暴雨径流污染特征，在武汉市汉阳区的4个合流制集水区布置了监测断面，对暴雨径流过程中的水质、水量进行了连续监测。结果表明：污染物浓度的峰值一般提前或同步于径流量的峰值，初期径流污染较重；采用污染物浓度变异指数可以反映不同集水区暴雨径流污染的差异性；汉阳城区暴雨径流的SS、COD、TP和TN平均浓度分别为601．1、299．2、0．88和12．26mg／L，同珠海市相比，其暴雨径流污染水平明显要高。     

Determination of aliphatic hydrocarbons in urban runoff samples from the "Le Marais" experimental catchment in Paris centre

Aliphatic hydrocarbons were assessed in runoff and waste waters from an urban catchment located in Paris. Runoff were sampled from different types of urban surfaces (11 roofs representing four different covering materials, two courtyards and six streets). Waste water samples were collected at the catchment outlet during dry and wet weather periods as well. This paper gives an overview of the results on the concentration and distribution points of view for both the particulate and the dissolved phases. Results were discussed on the basis of the median. Accordingly, the temporal variability was taken into account. Thus, the concentration medians ranged from 345 to 827, from 297 to 790, and from 393 to 1,359 microg L(-1) in the roof, courtyard and street samples, respectively. The levels found at the catchment outlet during dry and wet weather periods were of the same order of magnitude, i.e. 700 microgL(-1). The particulate phase represented 85% of the total aliphatic hydrocarbon content whatever the sample.     

Transport of stormwater pollutants through a roadside grassed swale

Investigations of the pollutant trapping capability of a grassed swale receiving runoff from a road with a traffic intensity of 8,000 vehicles/day were carried out in central Luleå, Sweden. Transport and retention of suspended solids, particles and heavy metals (copper, lead and zinc) were analysed. The sampling was carried out during seven rain events. The results show that once pollutants are trapped in a grassed swale they are not permanently bound to vegetation or soil. A roadside grassed swale may be regarded as a stormwater treatment facility that attenuates the peaks in pollutant loads, without being capable of producing consistently high removal rates.     

Stochastic modeling of total suspended solids (TSS) in urban areas during rain events

The load of total suspended solids (TSS) is one of the most important parameters for evaluating wet-weather pollution in urban sanitation systems. In fact, pollutants such as heavy metals, polycyclic aromatic hydrocarbons (PAHs), phosphorous and organic compounds are adsorbed onto these particles so that a high TSS load indicates the potential impact on the receiving waters. In this paper, a stochastic model is proposed to estimate the TSS load and its dynamics during rain events. Information on the various simulated processes was extracted from different studies of TSS in urban areas. The model thus predicts the probability of TSS loads arising from combined sewer overflows (CSOs) in combined sewer systems as well as from stormwater in separate sewer systems in addition to the amount of TSS retained in treatment devices in both sewer systems. The results of this TSS model illustrate the potential of the stochastic modeling approach for assessing environmental problems.     

A survey of heavy metals in municipal wastewater in combined sewer systems during wet and dry weather periods

During wet weather, combined sewer system overflows affect the quality of water in watercourses. For planning overflows, the lowest possible load of priority substances according to Directive 2008/105/EC is crucial and the knowledge of variability in concentrations of elements in the sewer system is necessary. The behaviour of heavy metals in a sewer system was observed in the course of dry weather flow (DWF) and wet weather flow (WWF). We found, from the comparison of concentration medians for the WWF and DWF that during wet weather periods, an increase in the concentrations of As, Cr, Cd, Pb, Mn and Fe occurs in the sewer system and the effect of nonpoint sources manifests itself. Zn, Cu and Ni concentrations decreased during wet weather periods, and Hg concentrations did not significantly change. During the WWF period, a considerable nonhomogeneity of the sewage system was demonstrated.     

Understanding the physical processes of pollutant build-up and wash-off on roof surfaces

Pollutants originating with roof runoff can have a significant impact on urban stormwater quality. This signifies the importance of understanding pollutant processes on roof surfaces. Additionally, knowledge of pollutant processes on roof surfaces is important as roofs are used as the primary catchment surface for domestic rainwater harvesting. In recent years, rainwater harvesting has become one of the primary sustainable water management techniques to counteract the growing demand for potable water.This paper presents the outcomes of an in-depth research study into particulate matter build-up and wash-off for roof surfaces. In this research, particulate matter was considered as the indicator pollutant where the processes related to other pollutants can be predicted based on the understanding generated for particulate matter. The study outcomes confirm that the build-up process on roof surfaces is comparatively similar to road surfaces. However, particle loads collected from roofs were significantly less compared to road surfaces and much finer in texture. Wash-off from roofs also showed significant similarities to wash-off from roads. A relatively high concentration of particulate matter was noted during the initial part of storm events. Furthermore, the amount of particulate matter remaining on the roof surfaces was significantly high for less intense rain events.     

Grey-box modelling of pollutant loads from a sewer system

Using a compact measuring unit with on-line meters for UV absorption and turbidity, it is possible to determine concentrations of organic load (chemical oxygen demand (COD) and suspended solids (SS)) anywhere in a sewer system. When measurements of the flow are available as well, the pollutant mass flow at the measuring point can be calculated.The measured data are used to estimate different models describing the load of pollutants in the sewer. A comparison of the models shows that a grey-box model is most informative and best in terms measured by the multiple correlation coefficient. The grey-box model is a state-space model, where the state represents the actual amount of deposition in the sewer, and the output from the model is the pollutant mass flow to the wastewater treatment plant (WWTP). The model is formulated by means of stochastic differential equations. Harmonic functions are used to describe the dry weather diurnal load profiles. It is found that the accumulation of deposits in the sewer depends on previous rain events and flows.By means of on-line use of the grey-box models, it is possible to predict the amount of pollutants in a first flush at any time, and hence from the capacity of the plant to decide if and when the available detention basin is to be used for storage of wastewater. The mass flow models comprise an important improvement of the integrated control of sewer and WWTP including control of equalisation basins in the sewer system. Further improvements are expected by the introduction of an additive model where dry weather situations and storm situations are modelled separately before addition to the resulting model.     

Contribution of trace metals from atmospheric deposition to stormwater runoff in a small impervious urban catchment

The contribution of atmospheric deposition to emissions of trace metals in stormwater runoff was investigated by quantifying wet and dry deposition fluxes and stormwater discharges within a small, highly impervious urban catchment in Los Angeles. At the beginning of the dry season in spring 2003, dry deposition measurements of chromium, copper, lead, nickel, and zinc were made monthly for 1 year. Stormwater runoff and wet deposition samples also were collected, and loading estimates of total annual deposition (wet+dry) were compared with annual stormwater loads. Wet deposition contributed 1-10% of the total deposition inside the catchment, indicating the dominance of dry deposition in semi-arid regions such as Los Angeles. Based on the ratio of total deposition to stormwater, atmospheric deposition potentially accounted for as much as 57-100% of the total trace metal loads in stormwater within the study area. Despite potential bias attributable to processes that were not quantified in this study (e.g., resuspension out of the catchment or sequestration within the catchment), these results demonstrate atmospheric deposition represents an important source of trace metals in stormwater to waterbodies near urban centers.     

Spatial variability of the characteristics of combined wet weather pollutant loads in Paris

An on-site observatory of urban pollutant loads in combined sewers has been created in Paris in order to investigate wet weather pollutant loads at different spatial scales. This observatory is composed of six urban catchments, covering areas from 41 to 2581ha. For a wide range of parameters including suspended solids (SS), volatile suspended solids (VSS), chemical oxygen demand (COD), biochemical oxygen demand (BOD5), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), metals (Cd, Cu, Pb, Zn), aliphatic hydrocarbons and polycyclic aromatic hydrocarbons (AHs and PAHs), this article serves to evaluate the potential scale effect on wet weather flow (WWF) quality. Although the extensive data set compiled herein has emphasized the high variability in WWF quality from one rain event to the next, no scale effect could be observed for a given rain event on pollutant concentrations, distributions between dissolved and particulate phases, pollutant contents and loads. Such results are of prime importance since they suggest (i) no spatial scale influence on WWF quality for the considered catchments and (ii) similar dominant sources and transfer processes at the various spatial scales.     

Particles and associated metals in road runoff during snowmelt and rainfall

This study analysed road runoff in northern Sweden with respect to the concentrations of and the loads of particles in different size fractions (4-6, 6-9, 9-15, 15-25, 25-40, and 40-120 mum) between a snowmelt period and a rainfall period, as well as during events within each period. There are also comparisons of the transport of different particle sizes between the two periods and during events within the periods and discussions on how different metals are associated with the varying particle sizes. The results showed, on average, eight times higher concentrations and five times higher loads of particles during the snowmelt period compared to the rain period for all particle size intervals. Using a t-test with 14 degrees of freedom, at a 90% and 95% confidence level, the mean- and the event mean concentrations of all particle size intervals were higher during the melt period compared to the rain period. Also, the particle concentrations for both periods decrease as the particle size increases. During the snowmelt and rainfall period, important factors influencing the concentrations and loads were the availability of material, the intensity of the lateral flow for the transport of the particles, and, additionally, for the rain period, the length of dry weather in between events. During the melt period, investigated particle sizes and TSS were highly correlated with total concentrations of Cd, Cu, Ni, Pb, and Zn. During the rain period, the correlations between total metal concentrations and the different particle sizes were not as significant.     

Priority pollutants in wastewater and combined sewer overflow

Implementation of the European Water Framework Directive and its affiliated directives requires Member States to improve their understanding of priority pollutants (PPs) in urban areas and obviously within wastewater systems. As a direct consequence, this study is intended to furnish data on both PP occurrence and the significance of concentrations in wastewater during dry and wet periods within combined sewers. Various sampling sites within the Paris combined sewer network were selected; for each sample, a total of 66 determinants, including metals, polycyclic aromatic hydrocarbons (PAHs), pesticides, organotins, volatile organic compounds, chlorobenzenes, phthalates and alkylphenols, were analysed. A broad range of PPs was observed in wastewater during dry as well as wet weather periods. Of the 66 elements investigated, 33 and 40 priority substances could be observed in raw sewage and wet weather effluent, respectively. As expected, a majority of metals were present in all samples, reflecting their ubiquitous nature. For both periods, chlorobenzenes and most of the pesticides always remained below the limit of quantification, while the majority of other organic pollutants assessed were identified within the microg l(-1) range. As highlighted by the larger number of substances detected in wet weather samples and the significance of their concentrations, runoff via atmospheric inputs and/or surface leaching was found to induce a wider range of PPs (n=40) and lead to higher concentrations of certain metals, PAHs, pesticides and other individual compounds. The data generated during this survey, which constitutes one of the first studies conducted in Europe to report concentrations for a variety of priority substances in wastewater within combined sewers, may be used in the future to identify PPs of potential significance for dry and wet weather periods and targeted for further investigation.     

合流制排水管道沉积物及其模型研究进展

在合流制排水系统中,管道沉积物不但影响系统的正常运行,而且在雨天时随着溢流排放被冲刷释放,造成雨天出流污染负荷的增加,成为水体面源污染的重要组成部分。因此,开展排水管道沉积物的研究不仅有利于改善排水系统的运行状况,也有利于水体污染的控制。介绍了排水管道沉积物的来源、构成、性质以及国外管道沉积物的模型研究进展,并总结了其中的不足,以期为我国开展此方面的研究提供参考依据、基础以及研究方向。     

PCB dry and wet weather concentration and load comparisons in Houston-area urban channels

All 209 PCB congeners are quantified in water in both dry and wet weather urban flows in Houston, Texas, USA. Total water PCBs ranged from 0.82 to 9.4 ng/L in wet weather and 0.46 to 9.0 ng/L in dry. Wet weather loads were 8.2 times higher (by median) than dry weather with some increases of over 100-fold. The majority of the PCB load was in the dissolved fraction in dry weather while it was in the suspended fraction in wet weather. Dissolved PCB loads were correlated with rain intensity and highly developed land area, and a multiple linear regression (MLR) equation was developed to quantify these correlations. PCA generated five PCB components with nearly all positive loadings. They were interpreted as DOC-associated A1248, wet weather primarily suspended fraction A1254/A1260 likely from building sealants, truly dissolved-associated wastewater dechlorination, watershed-sourced PCB 11, and monochlorinated PCBs (likely connected to a different state or source of dechlorination). The PCB 11 component was statistically higher in wet versus dry weather when no other component showed such clear distinctions. Hierarchical cluster analysis (HCA) did not always group dry and wet weather samples from the same location together illustrating the different congener composition that often exists between dry and wet conditions. Four wet weather samples from high percentage developed land (> 90%) watersheds had nearly the same fingerprint suggesting a generic “urban” signature in runoff, which in this case was caused by residual A1254/A1260 PCB stocks and currently produced PCB 11 in consumer goods.     

Towards the determination of an optimal scale for stormwater quality management: Micropollutants in a small residential catchment

Stormwater and atmospheric deposits were collected on a small residential urban catchment (0.8 ha) near Paris in order to determine the levels of certain micropollutants (using a preliminary scan of 69 contaminants, followed by a more detailed quantification of PAHs, PCBs, alkylphenols and metals). Atmospheric inputs accounted for only 10%–38% of the stormwater contamination (except for PCBs), thus indicating substantial release within the catchment. On this small upstream catchment however, stormwater contamination is significantly lower than that observed downstream in storm sewers on larger adjacent urban catchments with similar land uses. These results likely stem from cross-contamination activity during transfers inside the sewer system and underscore the advantages of runoff management strategies at the source for controlling stormwater pollutant loads. Moreover, it has been shown that both contamination levels and contaminant speciation evolve with the scale of the catchment, in correlation with a large fraction of dissolved contaminants in upstream runoff, which differs from what has been traditionally assumed for stormwater. Consequently, the choice of treatment device/protocol must be adapted to the management scale as well as to the targeted type of contaminant.