CuNiSnTi钎料钎焊立方氮化硼的焊接性与微观结构

研究了铜基活性钎料钎焊立方氮化硼的焊接性与微观结构,采用真空钎焊方法实现了CuNiSnTi活性钎料与c-BN的可靠连接.多元CuNiSnTi活性钎料对c-BN和基体钢都具有较好的润湿性能,提高钎焊温度可以改善活性钎料对c-BN的润湿性.在500℃时,CuNiSnTi活性钎料钎焊的c-BN超硬耐磨涂层仍具有极好的耐磨性能,与c-BN仍能保持较高的结合强度.采用SEM,XRD对界面观察和分析,并结合键参数理论的计算结果表明,CuNiSnTi活性钎料与c-BN发生冶金作用,形成了化合物型界面.     

TC4表面真空钎焊c-BN耐磨层的研究

采用AgCuInTi钎料在TC4表面真空钎焊c-BN耐磨层。研究了c-BN与AgCuInTi不同体积比的混合料与TC4钎焊后耐磨层的耐磨性,并对AgCuInTi钎料与c-BN的焊接性及界面微观结构进行了分析。结果表明:c-BN体积分数在50%左右时,钎焊工艺性较好,耐磨强度较高。AgCuInTi钎料对c-BN有较好的润湿性,两者界面结合紧密,并在界面处形成反应层。AgCuInTi钎料中的Ti元素向c-BN颗粒表面富集并与c-BN颗粒表面B和N元素发生反应,形成Ti B2和Ti N,实现了AgCuInTi钎料与c-BN颗粒的化学冶金结合。     

Ni-Cr合金钎料激光钎焊金刚石磨粒界面显微结构及形成机理（英文）

采用Ni-Cr合金钎料,在Ar气保护条件下,对金刚石磨粒进行了激光钎焊研究。采用扫描电镜(SEM)和能谱仪(EDS)及X射线衍射仪(XRD)分析金刚石磨粒与Ni-Cr钎料结合界面的组织结构与物相组成,并研究了钎料与金刚石界面处碳化物的形成机理。结果表明,激光钎焊过程中,在金刚石表面形成的富Cr层与金刚石表面的C元素反应生成碳化物Cr_3C_2。通过反应热力学与动力学分析显示,界面反应产物可以依靠置换反应形成,使金刚石磨粒与钎料实现了牢固结合。     

Ni-Cr合金钎料激光钎焊金刚石磨粒界面显微结构及形成机理

本文采用Ni-Cr合金钎料,在Ar气保护条件下,对金刚石磨粒进行了激光钎焊试验研究。采用扫描电镜(SEM)和能谱仪(EDS)及X射线衍射仪(XRD)分析金刚石磨粒与Ni-Cr钎料结合界面的组织结构与物相组成,并研究了钎料与金刚石界面处碳化物的形成机理。测试结果表明,激光钎焊过程中在金刚石表面附近形成的富Cr层与金刚石表面的C元素反应生成碳化物Cr3C2,通过反应热力学与动力学分析显示界面反应产物可以依靠置换反应形成,使金刚石磨粒与钎料实现了牢固结合。     

铜基钎料真空钎焊金刚石

采用铜基合金钎料,适当控制钎焊工艺,实现了金刚石与钢基体的高强度连接.借助扫描电镜(SEM)、X射线能谱(EDS)、X射线衍射(XRD)分析了真空加热条件下,对铜基合金钎料与金刚石之间的界面反应,钎焊面进行了表面形貌和结构分析.探讨了钎料与金刚右界面处碳化物的形成机理.阐明了在钎焊过程中Ti元素在金刚石界面形成富Ti层并与金刚石表面的C元素反应生成TiC、SnTi C是实现合金层与金刚石有较高结合强度的主要因素.钎料与钢基体在钎焊温度下发生组元间相互扩散,形成了固溶体及其化合物,从而实现钎料与钢基体的高强度结合,并对一系列铜基钎料进行了测试.     

激光钎焊金刚石磨粒界面微结构分析

采用Ni基合金钎料,在Ar气保护条件下,对金刚石磨粒进行了激光钎焊试验研究.采用扫描电镜(SEM)和能谱仪(EDS)及X射线衍射仪(XRD)对钎焊金刚石试样进行理化分析,探讨了钎料与金刚石界面处碳化物的形成机理.结果表明,激光钎焊过程中在金刚石表面附近形成的富Cr层与金刚石表面的C元素反应生成碳化物,在钢基体结合界面上Ni-Cr合金钎料和钢基体中的元素相互扩散形成化学冶金结合.     

SiC陶瓷真空钎焊接头界面结构及机理分析

采用Ti-Zr-Ni-Cu钎料对SiC陶瓷进行了真空钎焊,研究了SiC陶瓷真空钎焊接头的界面显微组织和界面形成机理.试验中采用扫描电子显微镜(SEM)对接头组织进行了观察,并进行了局部能谱分析.结果表明,接头界面产物主要有TiC,Ti5Si3,Zr2Si,Zr(s,s),Ti(s,s)+Ti2(Cu,Ni)和(Ti,Zr)(Ni,Cu)等.接头的界面结构可以表示为:SiC/TiC/Ti5Si3+Zr2Si/Zr(s,s)/Ti(s,s)+Ti2(Cu,Ni)/(Ti,Zr)(Ni,Cu).钎焊过程分为五个阶段:钎料与母材的物理接触;钎料熔化和陶瓷侧反应层开始形成;钎料液相向母材扩散、陶瓷侧反应层厚度增加,钎缝中液相成分均匀化;陶瓷侧反应层终止及过共晶组织形成;钎缝中心金属间化合物凝固.在钎焊温度960℃,保温时间10 min时,接头抗剪强度可达110 MPa.     

铜-铝异种金属钎焊材料的研究现状

从钎剂和钎料两方面对国内外有关铜-铝异种接头钎焊材料的研究成果进行了综述,重点介绍了铜-铝异种接头钎焊连接过程中无腐蚀性钎剂和钎料成分对钎焊接头结合机理、界面反应、金属间化合物的微观结构及生长规律等的影响。然而,铜-铝异种接头钎焊材料的应用过程中仍存在以下问题:无腐蚀性钎剂熔化温度和价格均较高,适用范围较窄;铝硅系钎料熔化温度较高,铝合金容易过烧熔蚀;钎料洁净度低,钎缝处容易出现氧化夹杂,影响钎焊接头的力学性能。     

SiC陶瓷真空钎焊接头界面结构及机理分析

采用Ti-Zr-Ni-Cu钎料对SiC陶瓷进行了真空钎焊,研究了SiC陶瓷真空钎焊接头的界面显微组织和界面形成机理.试验中采用扫描电子显微镜(SEM)对接头组织进行了观察,并进行了局部能谱分析.结果表明,接头界面产物主要有TiC,Ti₅Si₃,Zr₂Si,Zr(s,s),Ti(s,s)+Ti₂(Cu,Ni)和(Ti,Zr)(Ni,Cu)等.接头的界面结构可以表示为:SiC/TiC/Ti₅Si₃+Zr₂Si/Zr(s,s)/Ti(s,s)+Ti₂(Cu,Ni)/(Ti,Zr)(Ni,Cu).钎焊过程分为五个阶段:钎料与母材的物理接触;钎料熔化和陶瓷侧反应层开始形成;钎料液相向母材扩散、陶瓷侧反应层厚度增加,钎缝中液相成分均匀化;陶瓷侧反应层终止及过共晶组织形成;钎缝中心金属间化合物凝固.在钎焊温度960℃,保温时间10 min时,接头抗剪强度可达110 MPa.     

铜基钎料焊接金刚石的界面结构与强度

选用Cu-Sn-Ti活性钎料在钢基体上焊接金刚石磨粒,研究钎料合金与金刚石焊接界面的组织形貌与物相组成,分析不同钎焊温度对焊接界面结构及结合强度的影响.结果表明,钎料合金元素与金刚石在钎焊过程中发生化学反应,生成化合物TiC,CuTi和CuSn等,实现了铜基钎料、金刚石颗粒与钢基体之间的化学冶金结合.当钎焊温度为880～930℃时,均可获得连接良好的钎焊接头;钎焊温度900℃时,焊接界面形成的化合物层均匀连续且界面致密,此时在相同磨削条件下,钎焊金刚石试件的磨损失重很小,达到了焊接界面的强力结合.     

Influence of Ti on microstructure and strength of c-BN/ Cu-Ni-Sn-Ti composites

The c-BN grain has been brazed with Cu-Ni-Sn-Ti filler metal in vacuum at 1373 K holding for 600 s. The microstructure of the interface between c-BN grain and Cu-Ni-Sn-Ti filler metal has been studied using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS). The composition of the interface has been analyzed by X-ray diffraction analyzer (XRD). Experimental results showed that the reaction layer appeared at the interface between the c-BN grain and the filler metal. The reaction layer mainly consisted of TiN, TiB and TiB₂. And the thickness of the reaction layer increases with the increase of Ti content in the filler metal. When Ti content in the filler metal exceeds 15 wt.%, microcracks form at c-BN side of the interface because of the increase of TiN, CuTi and Cu₃Ti₂ brittle phases and residual stresses, leading to a decrease of the tensile strength of c-BN/Cu-Ni-Sn-Ti composites. Ti content in the filler metal had obvious influence on microstructure and strength of c-BN/ Cu-Ni-Sn-Ti composites. The maximum tensile strength reached 105.1 MPa with 10 wt.% Ti content in the filler metal.     

Microstructure and strength of brazed joints of TiB2 cermet to TiAl-based alloys

In this study, TiB2 cermet and TiAl-based alloy are vacuum brazed successfully by using Ag-Cu-Ti filler metal.The microstructural analyses indicate that two reaction products, Ti ( Cu, Al ) 2 and Ag bused solid solution ( Ag ( s. s ) ) , are present in the brazing seam, and the iuterface structure of the brazed joint is TiB2/TiB2 Ag ( s. s ) /Ag ( s. s ) Ti ( Cu,Al)2/Ti( Cu, Al)2/TiAl. The experimental results show that the shear strength of the brazed TiB2/TiAl joints decreases us thebrazing time increases at a definite brazing temperature. When the joint is brazed at 1 223 K for 5 min, a joint strength up to 173 MPa is achieved.     

Growth behavior of interfacial compounds in galvanized steel joints with CuSi_3 filler under arc brazing

1Introduction Arc brazing is a relatively new joining technique.The main advantages over existing commercially available joining processes are its low cost and potential for being easily incorporated as a workstation in the production chain.This will sign…     

TiNiB高温钎料钎焊TiAl基合金接头微观组织

采用电弧熔炼TiNiB合金作为高温钎料对TiAl合金进行钎焊,研究了接头界面组织的形成及其随钎焊温度变化的演化过程.电弧熔炼的TiNiB合金钎料主要由Ti-Ni与TiNi3共晶组织及弥散分布的块状TiB2组成,DTA测试曲线表明钎料的熔点为1 120℃.钎焊过程中,TiAl基体向液态钎料中的溶解量决定了钎焊接头界面组织的形成及其演化过程.随着活性元素Ti和Al向液态钎料溶解量的增加,靠近钎缝侧的TiAl基体发生固态相变转化为β层;钎缝组织演化为Ti-Al-Ni三元化合物,并伴有少量的β相;块状的TiB2在过量活性元素Ti存在的情况下逐渐转变为长条状的TiB相.     

Microstructure and mechanical properties of the SiC/Nb joint brazed using AgCuTi+B4C composite filler metal

The residual stress is considered to be the driving force for the failure of ceramic/metal brazing joint. In this paper, the residual stress in a SiC/Nb joint is alleviated by using AgCuTi+B₄C composite brazing filler. SEM, EDS and XRD are applied to characterised the microstructure of the joint, which is determined to be SiC/Ti₃SiC₂/Ag(s,s)+Cu(s,s)+TiB+TiC/TiCu+ Nb(s,s)/Nb. The effects of the B₄C strengthening phase mass fraction and the brazing temperature on the microstructure and the mechanical properties of the joint are investigated. It is found that the reaction products between B₄C and the brazing filler (TiB whisker and TiC particles) uniformly distribute inside the joint if the mass fraction of the B₄C is not higher than 1.5 wt% and when the amount of B₄C reaches 2 wt%, the reaction products begin to agglomerate. With the rising of the brazing temperature, the thickness of the Ti₃SiC₂ reaction layer next to the ceramic increases and when the brazing temperature reaches 910 °C, another reaction layer of Ti₅Si₃ can be found adjacent to the Ti₃SiC₂ reaction layer. The strength of the joint first increases and then decreases with the increase of both the strengthening phase and the brazing temperature. The highest shear strength of the joint reaches 98 MPa when the joint is achieved at 890 °C using AgCuTi+1.5 wt%B₄C brazing filler.     

Growth behavior of interfacial compounds in galvanized steel joints with CuSi3 filler under arc brazing

The galvanized steels were joined using a TIG arc brazing process with CuSi₃ as the filler metal. The arcing time ranged from 1 s to 5 s with arcing current of 70 A in flowing argon. The possible reaction products at the interface were confirmed using thermodynamics, SEM, and EDS methods. The results show that a fragmention behavior in some whisker-like intermetallic compounds happens, and that there are two layers of Fe₂Si and Fe₅Si₃ formed at the interface of the galvanized steel and copper filler. From this, the schematic cycle of the interface growth behavior of Fe/Si compounds and the fragmentation behavior of whisker-like intermetallic compounds are developed.     

TC4钛合金/304不锈钢异种材料蜂窝结构钎焊工艺

采用Ti-37.5Zr-15Cu-10Ni和Ag-28Cu两种钎料分别对TC4钛合金面板/304不锈钢蜂窝芯异种材料蜂窝结构进行了钎焊,对钎焊界面组织和蜂窝结构的力学性能进行了对比分析. 结果表明,Ti基钎料与304不锈钢蜂窝芯箔材界面润湿反应性能较差且Ti基钎料钎缝显微硬度较高,导致钎焊界面强度低,蜂窝拉伸力学性能差. Ag基钎料与304不锈钢蜂窝芯箔材和TC4面板均发生显著的界面反应,钎焊温度830 ℃,保温时间10 min时,蜂窝抗拉强度为10.35 MPa,呈蜂窝芯破坏特征. Ag基钎料蜂窝抗拉强度明显优于Ti基钎料结果,适用于TC4钛合金面板/304不锈钢蜂窝芯异种材料蜂窝钎焊.     

Fluxless laser brazing of aluminium alloy to galvanized steel using a tandem beam – dissimilar laser brazing of aluminium alloy and steels

Tandem beam brazing with aluminium filler metal (BA4047) was conducted in order to develop the fluxless laser brazing technique of aluminium alloy (AA6022) to galvanized steels (GA and GI steels). Laser powers of tandem beam and offset distance of preheating beam from the root to the steel base metal were varied. Sound braze beads could be obtained by optimizing the preheating and main beam powers under the offset distances of 0–1 mm. A small amount of zinc remained at the braze interface between galvanized steels and the braze metal. The reaction layer consisting of Fe–Al intermetallic compounds was also formed at the steel interface, and the thickness of reaction layer could be predicted during the laser brazing (thermal cycle) process based on the growth kinetics with the additivity rule. The metal flow analysis of the melted filler metal on joints revealed that wettability and spreadability of the filler metal on the GI steel joint were superior to those on the GA steel joint. The fracture strength of the lap joint attained approx. 55–75% of the base metal strength of aluminium alloy. It was concluded that fluxless laser brazing could be successfully performed by using a tandem beam because the zinc coat layer acted as the brazing flux.     

Brazing of Coated Al Foil Filler to AIN CeramicEI北大核心CSCD

The wettabilities of molten metals on ceramics are poor normally. In order to improve the wettability, all existing ceramic brazing methods introduce a compound transition layer formed by the reaction of active metal and ceramic. The transition layer between brazing seam and ceramic however creates negative effect on the properties of brazing joints. Although Al is the scarce metal which can wet some ceramics such as AIN and Al2O without reaction, the difficulty of removing oxide layer on surface prevents it being ceramic brazing filler. This work proposed a kind of coated Al foil filler able to remove its own Al2O3 film and an elevating temperature brazing process to enhance Al/AIN joint strength. Removing Al2O3. film effect of vapor deposited Ni/Al double layer film on Al foil and the effect of brazing temperature on improving joint strength were studied. The results showed that due to buried by Ni/Al double layer film, Al2O3 film on Al foil original surface broken and was swept in Al-1%Ni (atomic fraction) alloy liquid during heating and melting process. As a result, the direct brazing of Al to AIN without interface reaction transition layer was realized. The joint strength was significantly enhanced by elevating brazing temperature. When brazing at 680 degrees C, the joint fractured along the interface between Al seam and AIN and the sheer strength was 79 MPa because of Al liquid not wetting AIN. With the elevating of brazing temperature, the wettability and interface strength of Al/AIN improved. The fracture gradually transferred to brazing seam from interface. The joint strength increased and reached to the maximum value of 146 MPa at 840 degrees C.     

Ti—30Ni钎缝的界面反应及金相观察

研究了钛在真空钎焊过程中钎焊温度,保温时间及装配间泽界面反应程度的影响。钎焊过程中钎料组元镍和基体金属钛之间存在着明显的相互扩散过程,即基体金属钛向钎料的溶解和钎料组元镍向基体钛的扩散。镍向钛基体扩散的结果形成了一个明显的扩散层,镍在扩散层内主要以Ｔ２Ｎｉ化合物形式存在,并且存在较大的晶间渗入倾向。