Dynamic switching of the chiral beam on the spiral plasmonic bull's eye structure [Invited

A polarization-dependent switchable plasmonic beaming structure composed of metallic hole surrounded by double spiral dielectric gratings is proposed. The main mechanism of the proposed structure is based on the angular momentum change of surface plasmon caused by the spiral geometry. On- and off-states of the proposed device are determined by the condition whether the rotating direction of incident polarization is the same as or opposite of the direction of the spiral rotations. Qualitative analytical expressions of the switching mechanisms and full-vectorial numerical results are presented.     

Symmetry breaking in plasmonic nanocavities: subradiant LSPR sensing and a tunable Fano resonance

A metallic nanostructure consisting of a disk inside a thin ring supports superradiant and very narrow subradiant modes. Symmetry breaking in this structure enables a coupling between plasmon modes of differing multipolar order, resulting in a tunable Fano resonance. The LSPR sensitivities of the subradiant and Fano resonances are predicted to be among the largest yet for individual nanostructures.     

Frequency-controlled localization of optical signals in graded plasmonic chains

We study theoretically the optical response of graded linear arrays of noble metal nanospheres in which the center-to-center distances and/or the radii of the spheres change linearly along the chain. A strong asymmetry of the system response with respect to the direction of incidence of the incoming light is revealed. We show that for light propagating from smaller to larger spheres the optical signal can be localized in a controlled way at an arbitrary subset of a few neighboring spheres by adjusting the wavelength of the incoming field. This opens new opportunities to control the flow of electromagnetic energy at the nanometer scale.     

Symmetry breaking in a plasmonic metamaterial at optical wavelength

We numerically study the effect of structural asymmetry in a plasmonic metamaterial made from gold nanowires. It is reported that optically inactive (i.e., optically dark) particle plasmon modes of the symmetric wire lattice are immediately coupled to the radiation field, when a broken structural symmetry is introduced. Such higher order plasmon resonances are characterized by their subradiant nature. They generally reveal long lifetimes and distinct absorption losses. It is shown that the near-field interaction strongly determines these modes.     

Photoluminescence plasmonic enhancement in InAs quantum dots coupled to gold nanoparticles

Photoluminescence enhancement due to dipole field from gold nanoparticles was observed at 77 K for GaAs capped InAs quantum dots. The gold nanoparticles were coupled to the surface of the cap layer by using dithiol ligands. The enhancement was investigated as a function of the GaAs capped layer thickness. An order of magnitude enhancement in the emission was observed in samples with a cap thickness of 12 nm. This enhancement however is drastically decreased in samples with a cap thickness of 200 nm. The observed enhancement is interpreted in terms of photon scattering from the large dipole scattering cross section.     

The substrate effect on optical response of plasmonic metamaterials

Double negative-index plasmonic metamaterials can be integrated with plasmonic photonic circuits to be applied to optical devices. The previous work fabricated the plasmonic metamaterials layers by growing gold nanostructures on glass substrate utilizing the direct current magnetron sputtering technique at room temperature. Herein, we study the effect of copper and titanium dioxide nanoparticles as a substrate on the optical response of these layers. Thin-film characterizations were analyzed by transmission electron microscopy, field emission scanning electron microscopy, powder X-ray diffraction, and UV–Visible spectroscopy. Moreover, the optical properties of thin films are described via the film matrix method, which also discusses and confirms the optical gain property of fabricated layers.

     

Direct near-field optical imaging of higher order plasmonic resonances

We map in real space and by purely optical means near-field optical information of localized surface plasmon polariton (LSPP) resonances excited in nanoscopic particles. We demonstrate that careful polarization control enables apertureless scanning near-field optical microscopy (aSNOM) to image dipolar and quadrupolar LSPPs of the bare sample with high fidelity in both amplitude and phase. This establishes a routine method for in situ optical microscopy of plasmonic and other resonant structures under ambient conditions.     

Enhancing single-nanoparticle surface-chemistry by plasmonic overheating in an optical trap

Surface-chemistry of individual, optically trapped plasmonic nanoparticles is modified and accelerated by plasmonic overheating. Depending on the optical trapping power, gold nanorods can exhibit red shifts of their plasmon resonance (i.e., increasing aspect ratio) under oxidative conditions. In contrast, in bulk exclusively blue shifts (decreasing aspect ratios) are observed. Supported by calculations, we explain this finding by local temperatures in the trap exceeding the boiling point of the solvent that cannot be achieved in bulk.     

Enhanced optical trapping and arrangement of nano-objects in a plasmonic nanocavity

Gentle manipulation of micrometer-sized dielectric objects with optical forces has found many applications in both life and physical sciences. To further extend optical trapping toward the true nanometer scale, we present an original approach combining self-induced back action (SIBA) trapping with the latest advances in nanoscale plasmon engineering. The designed resonant trap, formed by a rectangular plasmonic nanopore, is successfully tested on 22 nm polystyrene beads, showing both single- and double-bead trapping events. The mechanism responsible for the higher stability of the double-bead trapping is discussed, in light of the statistical analysis of the experimental data and numerical calculations. Furthermore, we propose a figure of merit that we use to quantify the achieved trapping efficiency and compare it to prior optical nanotweezers. Our approach may open new routes toward ultra-accurate immobilization and arrangement of nanoscale objects, such as biomolecules.     

Enhancement of immunoassay's fluorescence and detection sensitivity using three-dimensional plasmonic nano-antenna-dots array

Protein detection is universal and vital in biological study and medical diagnosis (e.g., cancer detection). Fluorescent immunoassay is one of the most widely used and most sensitive methods in protein detection (Giljohann, D. A.; Mirkin, C. A. Nature2009, 462, 461-464; Yager, P.; et al. Nature2006, 442, 412-418). Improvements of such assays have many significant implications. Here, we report the use of a new plasmonic structure and a molecular spacer to enhance the average fluorescence of an immunoassay of Protein A and human immunoglobulin G (IgG) by over 7400-fold and the immunoassay's detection sensitivity by 3,000,000-fold (the limit of detection is reduced from 0.9 × 10(-9) to 0.3 × 10(-15) molar (i.e., from 0.9 nM to 300 aM), compared to identical assays performed on glass plates). Furthermore, the average fluorescence enhancement has a dynamic range of 8 orders of magnitude and is uniform over the entire large sample area with a spatial variation ±9%. Additionally, we observed that, when a single molecule fluorophore is placed at a "hot spot" of the plasmonic structure, its fluorescence is enhanced by 4 × 10(6)-fold, thus indicating the potential to further significantly increase the average fluorescence enhancement and the detection sensitivity. Together with good spatial uniformity, wide dynamic range, and ease to manufacture, the giant enhancement in immunoassay's fluorescence and detection sensitivity (orders of magnitude higher than previously reported) should open up broad applications in biology study, medical diagnosis, and others.     

Nanoparticle layer deposition for plasmonic tuning of microstructured optical fibers

Plasmonic nanoparticles with spectral properties in the UV-to-near-IR range have a large potential for the development of innovative optical devices. Similarly, microstructured optical fibers (MOFs) represent a promising platform technology for fully integrated, next-generation plasmonic devices; therefore, the combination of MOFs and plasmonic nanoparticles would open the way for novel applications, especially in sensing applications. In this Full Paper, a cost-effective, innovative nanoparticle layer deposition (NLD) technique is demonstrated for the preparation of well-defined plasmonic layers of selected particles inside the channels of MOFs. This dynamic chemical deposition method utilizes a combination of microfluidics and self-assembled monolayer (SAM) techniques, leading to a longitudinal homogeneous particle density as long as several meters. By using particles with predefined plasmonic properties, such as the resonance wavelength, fibers with particle-adequate spectral characteristics can be prepared. The application of such fibers for refractive-index sensing yields a sensitivity of about 78 nm per refractive index unit (RIU). These novel, plasmonically tuned optical fibers with freely selected, application-tailored optical properties present extensive possibilities for applications in localized surface plasmon resonance (LSPR) sensing.     

Spontaneous emission by an ensemble of dipoles coupled to a plasmonic nanoresonator

ABSTRACT

Spontaneous emission from ensembles of quantum emitters (QEs) such as atoms, molecules or semiconductor quantum dots can be greatly enhanced by cooperative effects arising from electromagnetic correlations. We describe a cooperative mechanism for emission of light by an ensemble of QEs based upon cooperative energy transfer from QEs to localized surface plasmons in metal-dielectric structures followed by plasmon radiation at a rate that scales with the ensemble size. For large QE ensembles saturating the plasmon mode volume, we derive universal, i.e. independent of local field distribution, expression for cooperative Purcell factor that can by far exceed the field enhancement limits for individual QE in a hot spot. We also derive radiated power spectrum that retains the plasmon resonance lineshape and, in contrast to common cooperative mechanisms, is insensitive to natural variations of QEs' emission frequencies.     

Designed ultrafast optical nonlinearity in a plasmonic nanorod metamaterial enhanced by nonlocality

All-optical signal processing enables modulation and transmission speeds not achievable using electronics alone. However, its practical applications are limited by the inherently weak nonlinear effects that govern photon-photon interactions in conventional materials, particularly at high switching rates. Here, we show that the recently discovered nonlocal optical behaviour of plasmonic nanorod metamaterials enables an enhanced, ultrafast, nonlinear optical response. We observe a large (80%) change of transmission through a subwavelength thick slab of metamaterial subjected to a low control light fluence of 7 mJ cm(-2), with switching frequencies in the terahertz range. We show that both the response time and the nonlinearity can be engineered by appropriate design of the metamaterial nanostructure. The use of nonlocality to enhance the nonlinear optical response of metamaterials, demonstrated here in plasmonic nanorod composites, could lead to ultrafast, low-power all-optical information processing in subwavelength-scale devices.     

Enhancement of optical nonlinearity in binary metal-nanoparticle arrays

Periodic binary metal-nanoparticle arrays, comprising of Au and Fe, were fabricated on quartz substrates using nanosphere lithography and pulsed laser deposition technique. The dimension of the obtained triangular Au(Fe) particles was about 80 nm which was defined by the single-layer masks prepared by self-assembly of polystyrene nanospheres with radius R = 100 nm. The structural characterization of the particle arrays was investigated by atomic force microscopy. In the optical absorption spectra, the metal-nanoparticle arrays show a strong absorption peak of ~ 550 nm due to the surface plasmon resonance of metal particles. The nonlinear optical properties of the nanoparticle arrays were determined using a single beam z-scan method at a wavelength of 532 nm with laser duration of 55 ps. By adding Fe, the resonant absorption of Au particles was quenched, and the figure of merit χ⁽³⁾/α (with χ⁽³⁾ being the third-order nonlinear susceptibility, α being the absorption coefficient) was obviously increased. The obtained maximum χ⁽³⁾/α is about 6.15 × 10^− 12 esu cm. The results show that periodic Au + Fe nanoparticle arrays exhibit a large nonlinear optical property with fast response.     

Combined electrochromic and plasmonic optical responses in conducting polymer/metal nanoparticle films

Poly(3,4-ethylenedioxithiophene)/poly(styrene sulphonate) (PEDOT/PSS) aqueous dispersions were mixed with aqueous gold nanoparticle and aqueous silver nanoparticle colloids. PEDOT/gold nanoparticles (Au NP) and PEDOT/silver nanoparticles (Ag NP) films were obtained by solvent casting the corresponding aqueous solutions. The nanocomposite films showed the optical characteristics associated with both the surface plasmon absorption resonance of the metal nanoparticles and the excitation of the bipolaron band of the conducting polymer. As an interesting application we demonstrate the use of metal nanoparticles to tune the color of PEDOT based electrochromic films from blue to violet in the case of Au NP or green in the case of Ag NP.     

Accurate determination of plasmonic fields in molecular junctions by current rectification at optical frequencies

Current rectification, i.e., induction of dc current by oscillating electromagnetic fields, is demonstrated in molecular junctions at an optical frequency. The magnitude of rectification is used to accurately determine the effective oscillating potentials in the junctions induced by the irradiating laser. Since the gap size of the junctions used in this study is precisely determined by the length of the embedded molecules, the oscillating potential can be used to calculate the plasmonic enhancement of the electromagnetic field in the junctions. With a set of junctions based on alkyl thiolated molecules with identical HOMO-LUMO gap and different lengths, an exponential dependence of the plasmonic field enhancement on gap size is observed.     

Enhancement of the low-temperature catalytic graphitization of polyacrylonitrile by incorporating Cu nanostructures as plasmonic photocatalyst

Journal of Materials Science - Here, we systematically investigate the chemical process of low-temperature catalytic graphitization of polyacrylonitrile (PAN) by using roughened copper (Cu)...     

Enhancement of optical nonlinearity in periodic gold nanoparticle arrays

Linear and nonlinear optical properties of periodic triangular Au nanoparticle arrays were investigated. We compared the optical nonlinearity of periodic Au nanoparticle arrays with that of the ultra-thin gold film consisting of randomly distributed spheroidal clusters. A pronounced enhancement of the third-order nonlinear optical susceptibility χ((3)) in Au arrays was observed, and the figure of merit, χ((3))/α, of the periodic nanoparticle arrays is one order of magnitude larger than that of the ultra-thin film. Such an enhancement of the optical nonlinearity could be due to the strong local field near the triangular nanoparticles.     

Mutual synchronization of switching processes in coupled Lorenz systems

A numerical analysis is made of the synchronization of the mean switching frequencies in two symmetrically coupled Lorenz systems functioning in a chaotic regime. The observed effect on the coupling-mismatch parameter plane corresponds to a region of synchronization of the switching processes, within which the mean switching frequencies coincide to a given accuracy. Pis’ma Zh. Tekh. Fiz. 23, 14–19 (April 26, 1997)     

A quantum description of linear,and non-linear optical interactions in arrays of plasmonic nanoparticles

A quantum theory for describing the interaction of photons and plasmons, in one- and two-dimensional arrays is presented. Ohmic losses and inter-band transitions are not considered. We use macroscopic approach, and quantum field theory methods including S-matrix expansion, and Feynman diagrams for this purpose. Non-linear interactions are also studied, and increasing the probability of such interactions, and its application are also discussed.