Use of large granular urea (LGU) to improve efficiency of broadcast urea in wetland rice cultivation

Laboratory and greenhouse experiments were conducted to determine whether the efficiency of broadcast urea in wetland rice cultivation can be improved by using large granules which penetrate the puddled soil. In laboratory experiments the penetration increased with increasing granule size. Penetration was improved by having only a waterfilm on the soil and by the granules entering the soil with speed.In pot experiments with rice, N concentrations in the floodwater were lower with large granular urea (LGU, 6 to 8 mm diameter) dropped from a height of 2 m or shot with force into the puddled soil than with either prilled urea (PU) or LGU placed on top of the soil (+0cm). N concentrations in the floodwater were reduced even further by placement of LGU at 1 and 4 cm depths (–1 and –4cm, respectively). At all rates of N, the N uptake by grain plus straw increased with decreasing N concentrations in the floodwater. The apparent recovery of N in grain plus straw increased in an experiment on sandy soil from 61 to 85% in the order PU +0cm, LGU +0cm, LGU dropped, LGU –1cm, LGU shot and LGU –4cm. In an experiment on clay soil apparent recovery increased from 47 to 90% in the order PU +0cm, LGU +0cm, LGU dropped, LGU –0cm, LGU shot, LGU –1cm and LGU –4cm. LGU placed at –1 and –4cm resulted in significantly greater N uptake by grain plus straw than the other treatments.The experiments showed that the efficiency of broadcast urea is improved by using large urea granules, at least when conditions are favourable for penetration into the puddled soil.     

Deep placement of urea supergranules in transplanted rice: Principles and practices

Rice is the most important food crop in the developing countries of Asia, where population densities are very high and overall dietary levels are not adequate. In south and southeast Asia, rainfed and irrigated transplanted rice occupies nearly two–thirds of the rice-growing area and produces more than 80% of the paddy rice. In these areas, prilled urea (PU) conventionally applied by farmers is very inefficiently used by transplanted rice largely because of serious losses (up to 60% of applied N) via NH₃ volatilization, denitrification, leaching, and/or runoff. In order to minimize N loss, especially loss due to denitrification, historically the Japanese have used different ways of deep placing fertilizer N. In 1975, IFDC proposed use of supergranules of urea (USG) in place of mudballs containing urea fertilizer to achieve the same agronomic benefits as achieved through the Japanese concept of deeppoint placement of fertilizer N in transplanted rice. USG can be prepared by melt-type processes (pan granulation, falling curtain, and fluid bed) and briquetting (a special type of compaction). The latter process seems to be the most cost-effective viable alternative. Small-scale briquetting machines have been developed to produce urea bgriquettes (UB) at village level at a rate of 200–250 kg h^?1. Basically, USG are large, discrete particles of ordinary urea [(NH₂)₂CO] containing 46% N as NH₂ (amide form); their weights may vary from 1 to 2 g per particle. USG from melt granulation process are nearly spherical with a relatively smooth surface, while UB from briquetting will be pillow-shaped with broken edges. Placement of USG can be done efficiently by handafter conventional line transplanting (e.g., researcher's method or IFDC transplanting guide method) orduring line transplanting (e.g., IFDC dispenser method) at the rate of one USG near the center of each four rice hills to a 7–10 cm soil depth. The IFDC methods have been developed mainly for economically disadvantaged small rice farmers of developing countries, especially those who transplant rice at random in rainfed areas. Other alternative manual methods such as incorporation of broadcast USG, random deep placement of USG by hand before line transplanting, or the deep placement by foot before or after transplanting may be less labor intensive; however, their agronomic efficiency has been low and highly variable, and they therefore cannot be recommended to farmers. Various continuous operation-type applicators (prototypes) have been developed in the Philippines, India, and China for mechanical deep placement of USG in line-transplanted rice. A few prototypes have been found to be labor saving and agronomically efficient when tested on research farms. However, several design-related problems associated with their metering mechanisms, placement depths, closing of furrows at the placement sites, output per workday, and/or operators' comfort, etc., need to be solved. In short, continuous operation-type applicators that are affordable and still efficient for deep placement of UB are not yet available for use on farmers' fields where floodwater and soil conditions vary substantially. The noncontinuous operation-type UB applicator prototype developed by IFDC is not as labor saving as the continuous operation-type applicators. However, its proper use with adequate practice can help to minimize the drudgery and to save up to 40% of the labor required for the hand placement method. This completely manual UB applicator, made of polyvinyl chloride (PVC) is simple to use, lightweight, and affordable as well as agronomically efficient on farmers' fields. As a result of diffusive transport and cation exchange, typically steep concentration gradients (or spatial distribution patterns) of ammonium exist at the placement sites and eventually control the rate and duration of availability of USG-N to the rice plants. USGper se is not a slow-release nitrogen fertilizer but behaves like a slowly available nitrogen fertilizer. Because the deep-placed USG-N is well protected from various N loss mechanisms (except leaching) at the placement sites in soils and the spatial ammonium concentration gradients help to improve its plant availability, (1) uptake of N by rice plants (recovery) is significantly increased, (2) relatively smaller amounts of USG-N as nonexchangeable ammonium and/or immobilized organic N stay in soil, and (3) eventually N losses (gaseous and runoff) are markedly decreased. Thus, this practice is agronomically efficient as well as environmentally safe. However, this practice should not be used in permeable soil with coarse texture and low cation exchange capacity (CEC) because the high loss of USG-N via leaching will significantly decrease N uptake by the rice plants and eventually grain yield too. Several hundred field trials conducted by national and international institutions in south and southeast Asia since 1975 have demonstrated the agronomic superiority of the deep placement of USG vis-a-vis split applications of PU in transplanted rice. In general, paddy yield responses to deep-placed USG tend to be more curvilinear than do those to split-applied PU, thus resulting in higher agronomic efficiency for deep-placed USG in the lower range of N rates (30–80 kg N ha^?1) than in the higher range of N rates (> 90 kg N ha^?1). Depending on agroclimate and N rates used, in general deep-placed USG can help to provide a saving of urea fertilizer of up to 65% with an average of 33% and can help to increase grain yields up to 50% with an average of 15% to 20% over that with the same amount of split-applied N as PU, especially in the lower range of N rates. USGper se is not an efficient nitrogen fertilizer, but the proper deep placement of USG in transplanted rice makes it agronomically efficient. In using USG, consideration of the following factors should help to ensure agronomic efficiency of deep-placed USG and increase the chances of obtaining additional yield.

1. Soil factors: Only use in soils having a low water percolation rate and a CEC ? 10 meq 100 g^?1 soil.
2. Plant factors: Give preference to short- to medium-duration dwarf rice varieties. For the longduration variety, basal deep-placed USG with a suitable topdressing of N as PU at panicle initiation stage would be helpful.
3. Management factors: Apply basally 30 to 60 kg USG-N ha^?1 using only USG of the right weight (1–2 g urea granule^?1). Place one supergranule for each four hills at 7–10 cm soil depth using the right plant population and modified spacing. Use modified 20 cm × 15 cm or 20 cm × 20 cm spacing to facilitate efficient placement of USG by hand or machine. Workers should always use the so-called traffic lane of the modified spacing for performing all post-transplanting field operations. When deep placement of USG is delayed after transplanting, extra care is necessary to close the holes left at the placement sites. When puddling is inadequate or improper and deep placement is done during transplanting, some care may be required to close the holes.

A scheme of small-scale production of UB at village level, using briquetting machines and locally available PU as a feedstock, looks promising for developing countries. The estimated production cost of UB is likely to be up to 10% higher than that of PU. In general, the estimated incremental benefit/cost ratios of hand deep-placed USG in line-transplanted rice are quite attractive, usually ?5 for small rice farmers of developing Asia. Technological and agroeconomic considerations suggest that the practice of hand deep placement of USGduring or after line transplanting appears to be a right agrotechnology for the resource-scarce small rice farmers of developing countries for efficiently using affordable doses of nitrogen (30–60 kg UB-N ha^?1) to significantly increase grain yields of transplanted rice. For other rice farmers who are not economically handicapped, who have access to irrigation, and who transplant rice in line and can afford to use high rates of N (> 90 kg N ha^?1), it can be an attractive practice, if appropriate machines for deep placement of USG have been developed. Therefore, research and development work is needed to develop affordable, labor-saving, and agronomically efficient continuous operation-type applicators for mechanical deep placement of UB. The use of USG as a source of N for transplanted rice has potential in developing countries. What is now required is to first develop practical stepwise and region-specific agrotechnologies consisting of appropriate UB supply schemes and rice farming systems based on hand or machine deep placement of UB in line-transplanted rice for different regions in a given country. Then it will be necessary to adopt an appropriate diffusion strategy for transfer of the region-specific agrotechnologies to the rice farmers. In this extension activity, long-term commitment and integrated efforts are required by national government organizations as well as by nongovernment organizations and the fertilizer industry.     

Efficiency of some modified urea fertilisers for wetland rice grown on a permeable soil

Split broadcast applications of prilled urea, deep point-placed urea supergranules (USG), and broadcast sulfur-coated urea (SCU) were compared as nitrogen sources for wetland rice (Oryza sativa L.) in two field experiments on a sandy soil (Typic Ustipsamment) with a high percolation rate (approx. 110 mm/day) in the Punjab, India. The USG was consistently less effective than the split urea and averaged 1 ton ha^–1 less rice yield at the highest nitrogen rate (116 kg N ha^–1). SCU produced the highest grain yields in both experiments; it averaged 1.7 ton ha^–1 more than did the split urea at the highest N rate.The fertilisers were then compared in field microplots; percolation was permitted or prevented so that the cause of the poor performance of USG could be elucidated. USG gave higher grain yield and N uptake in microplots that were not leached than in those that were leached. In leached microplots, the grain yields were higher from prilled urea than from USG treatments provided the placement pattern of the USG matched that of the field plots. Yields were not higher from treatments in which the USG were more closely spaced. In microplots in which leaching was prevented, the broadcast prilled urea was less effective than the deep-placed USG, which gave yields approximately 60% greater than those from split urea and the same as those from SCU. Broadcast prilled urea in undrained microplots caused high levels of ammonium (40 ppm) to develop in the floodwater where high pH (8.9) and high alkalinity (4.9 meq l^–1) may have led to extensive ammonia volatilisation. The use of USG and SCU in undrained microplots reduced floodwater ammonium levels to less than 3 ppm.Urea and ammonium leaching losses measured in fallow soil columns in the laboratory were much greater from USG than from prilled urea. Leaching losses from SCU were negligible. The data suggest that SCU is the preferred N source for rice soils having a high percolation rate and that USG is a poor alternative to split applications of prilled urea.     

Nitrogen deep-placement technologies for productivity, profitability, and environmental quality of rainfed lowland rice systems

The recovery of applied nitrogen by rice is low due to several loss processes operating in the ricefields. Split application of fertilizer suggested for increasing nitrogen-use efficiency is often not practical in rainfed lowland rice due to adverse soil–water situations. Hence, the entire required amount of N has to be applied in one single application when the water regime is favorable. A single broadcast application, however, increases N loss. Deep placement of urea supergranules (USG) has been proven to improve N fertilizer efficiency. The placement technology is best suited to conditions where the predominant N loss mechanism is ammonia volatilization rather than leaching or denitrification. Deep placement of USG thus has greater benefit over surface split application on soils with moderate to heavy texture, low permeability and percolation rate, and high cation exchange capacity and pH. Environments and management factors conducive to high ammonia volatilization potential would benefit most from deep-placement technology. Improved N recovery and efficiency of USG has been well-documented for lowland rice, but its market availability and methods to achieve placement pose problems. The technology has very limited adoption because USG is not commercially available or manufactured in most countries, and labor requirement is high with hand placement. Manual application creates more difficulties in handling the granules, besides taking 36–42 more hours per hectare, than 2 split broadcast applications of prilled urea. Applicators developed so far have not worked satisfactorily under standing water conditions and in direct-seeded rice conditions due to hardness of the soil. Hence, it is necessary to develop a suitable applicator to overcome these difficulties. Alternatively, for direct-seeded rice, N-fertilizers can be subsoil-banded near seedrows. The placement technology, if adopted by the farmers of the potential lowland areas in eastern India, is expected to give an additional production of 5.6 million tons of rice.     

Effectiveness of fall- versus spring-applied urea on barley

Field experiments were conducted in north-central and central Alberta to determine the effect of pellet size and depth of placement on yield and N uptake of barley from fall- and spring-applied urea. The application rate was 56 kg N ha^–1. Fall incorporated commercial urea (0.01 g) gave 792 kg ha^–1 lower yield and 15 kg ha^–1 less N uptake than similarly applied commercial urea in spring on the average for the five experiments. The effectiveness of fall-applied N tended to be greater with large urea pellets (2.5 g), especially when they were placed 15 cm deep. Specifically, the relative yield efficiency of fallversus spring-applied N was 77% when the larger pellets were placed 4 cm deep and 95% when placed 15 cm deep. However, large pellets were less effective than commercial urea when both were applied in spring at sowing or two weeks before.     

A comparative study of urea hydrolysis rate and ammonia volatilization from urea and urea calcium nitrate

A comparing of urea hydrolysis and NH₃ volatilization from urea supergranules and urea calcium nitrate (UCN, a new fertilizer produced by Norsk Hydro A/S, Norway) was made on two different flooded soil types, a high-CEC clay loam (Ås) and an intermediate-CEC clay loam (Kinn).Nitrogen loss by ammonia volatilization was reduced from 17% by surface application of urea supergranules (USG) on flooded Ås soil to 3% and 6% by UCN briquettes at either the same urea or nitrogen concentration as USG. A significant reduction was even found with the surface application of prilled UCN, 12% and 18% N-loss for prilled UCN and urea, respectively. The floodwater pH and NH ₄ ⁺ content was lower with UCN than urea, which reduced the potential for ammonia volatilization.NH₃-loss (5%) was significantly less when USG was surface applied on Kinn soil, while NH₃-loss from UCN briquettes was independent of soil type. The reduction in NH₃-loss from USG on Kinn soil was due to a decrease in the pH and NH ₄ ⁺ content of the floodwater caused by a reduced rate of urea hydrolysis.The rate of urea hydrolysis was lower with UCN than USG in both soils, but the difference between UCN and USG was greater in the Ås soil than in the Kinn soil. Three days after deep placement (10 cm), 18% of UCN urea and 52% of USG urea were hydrolyzed in Ås soil, while only 12% UCN and 17% USG were hydrolyzed in the Kinn soil.The surface application of USG on flooded soil reduced the rate of urea hydrolysis as compared to deep placement. 30% and 17% of USG urea was hydrolyzed after four days on Ås and Kinn soil, respectively. During the first few days the rate of hydrolysis of UCN was more affected by the soil type than the application method. Four days after surface application 32% and 13% UCN urea was hydrolyzed on Ås and Kinn soil, respectively. The rate of urea hydrolysis exhibited a zero-order reaction when USG and UCN-briquettes were point placed in flooded soils.     

Penetration depth of broadcast urea granules in puddled wetland rice soils

The efficiency of urea in wetland rice cultivation is known to be increased by placement below the soil surface. The penetration of broadcast urea into puddled soil might be a way to achieve placement of urea in soil. This paper combines an analysis of the free fall of urea granules in the atmosphere and a layer of water on the soil surface with measurements of granule penetration into puddled soils. The process of free fall can be described in terms of the height of fall in air, the depth of the water layer, and the terminal velocities and characteristic distances for free fall in air and water. The penetration depth of a particular granule with a particular velocity at the water/soil interface depends on the type of soil and its physical condition. Granule mass ranged from 0.1 to 0.5 g, granule velocity from 1 to 10 m s^–1, depth of the water layer from 0 to 30 mm and penetration depth from 0 to 35 mm. There is some indication that the penetration depth is proportional to the square root of the kinetic energy at the water/soil interface.     

Fate and efficiency of nitrogen fertilizers applied to wetland rice. I. The Philippines

Urea is the main form of fertilizer nitrogen applied to wetland rice. As part of an effort to evaluate the efficiency of nitrogen fertilizers, conventional urea and modified urea products such as sulfur-coated urea (SCU), urea supergranules (USG), and sulfur-coated urea supergranules (SCUSG) were compared with ammonium sulfate on an Aquic Tropudalf at the experimental farm of the International Rice Research Institute (IRRI) in the Philippines. The sulfur-coated materials were prepared in the laboratory and were not completely representative of commercial SCU. Two experiments were conducted in the wet season (1978, 1979) and one in the dry season (1979). All fertilizers were labeled with 5% or 10% excess¹⁵N so that the fertilizer-N balance at two or three sampling times during the growing season could be constructed and the magnitude of N loss assessed. The SCU, USG, and SCUSG were applied at transplanting, and the whole dose of nitrogen was¹⁵N-labeled. The urea and ammonium sulfate applications were split: two-thirds was broadcast and incorporated at transplanting, and one-third was broadcast at panicle initiation; only the initial dose was¹⁵N-labeled.Deep-point placement (10 cm) of urea supergranules (USG) between the rice hills consistently provided the highest plant recovery of¹⁵N in all experiments and at all harvest times; recoveries ranged from 48% to 75% with an average of approximately 58% at maturity. Among the fertilizers broadcast and incorporated before transplanting, average plant recoveries of¹⁵N were only approximately 34% and 26% from urea and ammonium sulfate, respectively. Plant recovery of¹⁵N from the broadcast and incorporated SCU (37%) was far inferior to that from USG. Sulfur coating of supergranules did not improve plant recovery over USG alone although sulfur coating delayed the plant uptake of¹⁵N from the USG.The¹⁵N not accounted for in the plant and soil was presumed lost. Loss of N from urea and ammonium sulfate was high (63%) in the dry season. Coating with sulfur gave a slight improvement, and deep placement of USG and SCUSG greatly reduced the losses. Losses of N were substantially lower in the wet season than in the dry season for broadcast and incorporated urea, SCU, and ammonium sulfate (9%–30%), whereas losses from deep-placed urea remained more or less the same as in the dry season. Net immobilization of¹⁵N from the broadcast fertilizers in the wet season ranged from 49% to 53% in the first experiment and from 16% to 32% in the second experiment, presumably because of aquatic weeds and green algae; immobilization was proportionally less at higher rates of fertilizer application. Deep placement reduced the extent of¹⁵N immobilization in the soil plus roots to less than 21% in all experiments.     

Fate and efficiency of nitrogen fertilizers applied to wetland rice. II. Punjab,India

Two modified urea products (urea supergranules [USG] and sulfur-coated urea [SCU]) were compared with conventional urea and ammonium sulfate as sources of nitrogen (N), applied at 58 kg N ha^–1 and 116 kg N ha^–1, for lowland rice grown in an alkaline soil of low organic matter and light texture (Typic Ustipsamment) having a water percolation rate of 109 mm day^–1. The SCU and USG were applied at transplanting, and the whole dose of nitrogen was¹⁵N-labeled; the SCU was prepared in the laboratory and was not completely representative of commercial SCU. The SCU was broadcast and incorporated, whereas the USG was point-placed at a depth of 7–8 cm. The urea and ammonium sulfate applications were split: two-thirds was broadcast and incorporated at transplanting, and one-third was broadcast at panicle initiation. All fertilizers except the last one-third of the urea and ammonium sulfate were labeled with¹⁵N so that a fertilizer-N balance at flowering and maturity stages of the crop could be constructed and the magnitude of N loss assessed.At all harvests and N rates, rice recovered more¹⁵N from SCU than from the other sources. At maturity, the crop recovered 38 to 42% of the¹⁵N from SCU and only 23 to 31% of the¹⁵N from the conventional fertilizers, urea and ammonium sulfate, whose recovery rates were not significantly different. In contrast, less than 9% of the USG-N was utilized. Fertilizer nitrogen uptake was directly related to the yield response from the different sources. Most of the fertilizer N was taken up by the time the plants were flowering although recovery did increase up to maturity in some treatments.Analysis of the soil plus roots revealed that less than 1% of the added¹⁵N was in the mineral form. Between 20 and 30% of the¹⁵N applied as urea, SCU, and ammonium sulfate was recovered in the soil plus roots, mainly in the 0–15 cm soil layer. Only 16% of the¹⁵N applied as USG was recovered in the soil, and this¹⁵N was distributed throughout the soil profile to a depth of 70 cm, which was the lowest depth of sampling.Calculations of the¹⁵N balance showed that 46 to 50% of the urea and ammonium sulfate was unaccounted for and considered lost from the system. Only 27 to 38% of the¹⁵N applied as SCU was not recovered at maturity, but 78% of the USG application was unaccounted for. The extensive losses and poor plant recovery of USG at this site are discussed in relation to the high percolation rate, which is atypical of many ricegrowing areas.     

Initial and residual effects of nitrogen fertilizers on grain yield of a maize/bean intercrop grown on a Humic Nitosol and the fate and efficiency of the applied nitrogen

Initial and residual effects of nitrogen (N) fertilizers on grain yield of a maize/bean intercrop grown on a deep, well-drained Humic Nitosol (66% clay, 3% organic carbon) were evaluated. Enriched (¹⁵N) N fertilizer was used to study the fate of applied N in two seasons: using urea (banded) at 50 kg N ha^–1 in one season, and¹⁵N-enriched urea (banded), calcium ammonium nitrate (CAN, banded), and urea supergranules (USG, point placement) were applied in the other season (different field) at 100 kg N ha^–1. Nitrogen fertilizer significantly (P = 0.05) increased equivalent maize grain yield in each season of application with no significant differences between N sources, i.e., urea, CAN, and USG. Profitmaximizing rates ranged from 75 to 97 kg N ha^–1 and value: cost ratios ranged from 3.0 to 4.8. Urea gave the highest value: cost ratio in each season. Most (lowest measurement 81%) of the applied N was accounted for by analyzing the soil (to 150 cm depth) and plant material. Measurements for urea, CAN, and USG were not significantly different. The high N measurements suggest low losses of applied N fertilizer under the conditions of the study. Maize plant recovery ranged from 35 to 55%; most of this N (51–65%) was in the grain. Bean plant recovery ranged from 8 to 20%. About 34–43% of the applied N fertilizer remained in the soil, and most of it (about 70%) was within the top soil layer (0–30 cm). However, there were no significant equivalent maize grain increases in seasons following N application indicating no beneficial residual effect of the applied fertilizers.     

Influence of modified forms of urea and nitrogen levels on weed growth and grain yield of lowland rice

The growth of weeds and their subsequent reduction of rice yield as affected by N source neem cake coated urea (NCU), dicyandiamide coated urea (DCU), rock phosphate coated urea (RPCU), urea supergranules (USG) and prilled urea (PU) was studied on a clay loam soil at Coimbatore, India. Experiments were conducted in northeast monsoon (NEM) 1981, summer 1982, and southwest monsoon (SWM) 1982 seasons.The crop was associated with eleven weed species, and the dominant weeds wereEchinochloa crus-galli, Cyperus difformis andMarsilea quadrifolia. The weed flora varied between seasons. Deep placement of USG reduced the dry weight of weeds in NEM and summer seasons at 60, 90 and 120 Kg N ha^–1 whereas it increased the dry weight at 60 and 90 but not 120 Kg N ha^–1 in SWM season. The dry weight of weeds decreased with increased N rates for all N sources during NEM and summer seasons. In SWM season, dry weight of weeds increased with increased N rates for all N sources except USG. The grain yield of rice was drastically reduced with the deep placement of USG at 60 but not 120 Kg N ha^–1 in SWM season. The differential effect of the N sources between seasons was due to the change of the weed flora. Dominance ofE. crus-galli during SWM season had greater influence on weed dry weight and grain yield of rice.Nitrogen uptake by weeds was frequently greater in unfertilized plots, particularly in NEM and summer seasons. In SWM season, the apparent fertilizer N recovery by weeds was high for USG. It decreased from 53% for 60 Kg USG-N ha^–1 to 4% for 120 Kg USG-N ha^–1.Contribution from the part of Ph.D. work of the first author at Department of Agronomy, Tamil Nadu Agricultural University, Coimbatore-641 003, Tamil Nadu, India.     

Nitrogen-15 and sulfur-35 balances for fertilizers applied to transplanted rainfed lowland rice

A field experiment was conducted on a poorly-drained Aeric Paleaquult in northeastern Thailand to determine the effect of N and S fertilizers on yield of rainfed lowland rice (Oryza sativa L.) and to determine the fate of applied¹⁵N- and³⁵S-labeled fertilizers. Rice yield and N uptake increased with applied N but not with applied S in either sulfate or elemental S (ES) form. Rice yield was statistically greater for deep placement of urea as urea supergranules (USG) than for all other N fertilizer treatments that included prilled urea (PU), urea amended with a urease inhibitor (phenyl phosphorodiamidate), and ammonium phosphate sulfate (16% N, 8.6% P).The applied¹⁵N-labeled urea (37 kg N ha^–1) not recovered in the soil/plant system at crop maturity was 85% for basal incorporation, 53% for broadcast at 12 days after transplanting (DT), 27% for broadcast at 5–7 days before panicle initiation (DBPI), and 49% for broadcast at panicle initiation (PI). The basal incorporated S (30 kg ha^–1) not recovered in the soil/plant system at crop maturity was 37% for sulfate applied as single superphosphate (SSP) and 34% for ES applied as granulated triple superphosphate fortified with S (S/GTSP). Some basal incorporated¹⁵N and³⁵S and some broadcast¹⁵N at PI was lost by runoff. Heavy rainfall at 3–4 days after basal N incorporation and at 1 day after PI resulted in water flow from rice fields at higher elevation and total inundation of the 0.15-m-high¹⁵N and³⁵S microplot borders. Unrecovered¹⁵N was only 14% for 75 kg urea-N ha^–1 deep placed as USG at transplanting. This low N loss from USG indicated that leaching was not a major N loss mechanism and that deep placement was relatively effective in preventing runoff loss.In order to assess the susceptibility of fertilizer-S to runoff loss, a subsequent field experiment was conducted to monitor³⁵S activity in floodwater for 42 days after basal incorporation of SSP and S/GTSP. Maximum³⁵S recoveries in the floodwater were 19% for SSP after 7 days and 7% for S/GTSP after 1 day. Recovery of³⁵S in floodwater after 14 days was 12% for SSP and 3% for S/GTSP.This research suggests that on poorly drained soils with a low sorption capacity, a sizeable fraction of the fertilizer S and N remains in the floodwater following application. Runoff could then be an important mechanism of nutrient loss in areas with high probability for inundation following intense rainfall.     

Influence of Slurry Parameters on the Characteristics of Spray-Dried Granules

A systematic study has been performed to determine how the characteristics of granules prepared by spray drying aqueous alumina slurries are influenced by processing parameters: binder type (PEG Compound 20M or PEG-8000), solids loading (30 or 40 vol%), ammonium polyacrylate deflocculant level (0.35-1.00 wt%), and spray-dryer type. Correlations between slurry rheology and granule characteristics have been made, and a model for granule formation is presented. The packing density of the primary particles within the granules is lower for slurries with higher yield stress and is dependent on the slurry solids loading. Granules prepared using 0.35 wt% deflocculant (0.14 mg/m²), which correspond to high slurry yield stress, are of solid morphology, whereas higher deflocculant levels result in hollow granules that contain a single large open pore or crater. The degree to which particles are able to rearrange during drying influences the final granule density and is determined by the strength of the floc structure, as indicated by the slurry yield stress. When the yield stress is low, a crater may form from the inward collapse of the surface of a forming granule when the particle packing density in a droplet continues to increase after the droplet size becomes fixed by the formation of a rigid shell, leaving an internal void with internal pressure lower than that of the surrounding atmosphere.     

Fate of nitrogen fertilizer applied to lowland rice on a Sulfic Tropaquept

A field experiment was conducted on an acid sulfate soil in Thailand to determine the effect of N fertilization practices on the fate of fertilizer-N and yield of lowland rice (Oryza sativa L.). A delayed broadcast application of ammonium phosphate sulfate (16-20-0) or urea was compared with basal incorporation of urea, deep placement of urea as urea supergranules (USG), and amendment of urea with a urease inhibitor. Deep placement of urea as USG significantly reduced floodwater urea- and ammoniacal-N concentrations following N application but did not reduce N loss, as determined from an¹⁵N balance, in this experiment where runoff loss was prevented. The urease inhibitor, phenyl phosphorodiamidate (PPD), had little effect on floodwater urea- and ammoniacal-N, and it did not reduce N loss. The floodwater pH never exceeded 4.5 in the 7 days following the first N applications, and application of 16-20-0 reduced floodwater pH by 0.1 to 0.3 units below the no-N control. The low floodwater pH indicated that ammonia volatilization was unimportant for all the N fertilization practices. Floodwater ammoniacal-N concentrations following application of urea or 16-20-0 were greater on this Sulfic Tropaquept than on an Andaqueptic Haplaquoll with near neutral pH and alkaline floodwater. The prolonged, high floodwater N concentrations on this Sulfic Tropaquept suggested that runoff loss of applied N might be a potentially serious problem when heavy rainfall or poor water control follow N fertilization. The unaccounted-for¹⁵N in the¹⁵N balances, which presumably represented gaseous N losses, ranged from 20 to 26% of the applied N and was unaffected by urea fertilization practice. Grain yield and N uptake were significantly increased with applied N, but grain yield was not significantly affected by urea fertilization practice. Yield was significantly lower (P = 0.05) for 16-20-0 than for urea; however, this difference in yield might be due to later application of P and hence delayed availability of P in the 16-20-0 treatment.     

Significance of timing and method of N fertilizer application for the N-use efficiency in flooded tropical rice

N-use efficiency in flooded tropical rice is usually low. Fertilizer N losses result mainly from losses of volatile NH₃ after broadcast application of urea into floodwater between transplanting and early tillering which is a common practice of farmers. Losses appear predominantly during the first week after urea application. With broadcast and incorporation of N into soil at transplanting losses may be reduced but are still substantial. Deep placement of urea supergranules (USG) has not been adopted by farmers because it is very laborious. A new application technique, namely injection of dissolved urea into the upper soil layer, was developed by which fertilizer N losses were effectively minimized while at the same time allowing flexible timing of application independent of crop stage and water management. It provides N-use efficiency equal to that achieved by USG point placement but is less labor-intensive.     

Coated and modified urea materials for increasing nitrogen use efficiency of lowland rice in heavy clay soils

Conventional as well as modified nitrogen sources and application methods were evaluated under rainfed lowland conditions in heavy clay soils of Bihar, India for 4 years. Modified nitrogen sources, viz. sulfur-coated urea (SCU) and urea super-granules (USG) were tested against prilled urea (PU) under four levels of N (0, 29, 58 and 87 kg N/ha) in the wet season. A high yielding nonphotoperiod sensitive, long duration variety Pankaj was grown in all the four years.Point placement of USG and basal incorporation of SCU resulted in significantly higher panicle numbers per square meter, 100 grain weight and grain yield at all the levels of N tested. The unfilled grain percentage was lower in USG and SCU treatments.Regression analysis using a multifertilizer response model (MRM) showed that rice responded significantly to PU in three years out of four years, to SCU in four years and USG in three years.Economic analysis viz. input and output analysis based on the price of fertilizer (1 kg N as PU at $0.5; USG and SCU costing 10% more than PU), rough rice (ranging from 18.0 to 20.0 $ per ton) and labour wages at 1.0 $ per man day unit, also showed that USG and SCU are more input efficient than PU.     

Ammonia volatilization from point-placed urea in upland,sandy soils

The upland fertilization practice in Africa of placing N fertilizer below the soil surface near the plant might be facilitated through use of urea supergranules (USG). Since little is known about N losses from point-placed urea on light-textured African soils, laboratory studies were conducted in a forced-draft system to determine (a) the influence of soil properties on ammonia loss from USG and (b) to compare N loss from USG with that from broadcast N sources. Ammonia loss from 1.1 g USG placed at a 4-cm soil depth ranged from 2.9 to 62% of the added N on six light-textured soils. Ammonia loss was correlated with soil clay content (r = –0.93^**) but not with pH. A more detailed study on a soil from Niger revealed significantly less ammonia loss from either surfaced applied urea (18%) or surface-applied calcium ammonium nitrate (7%) than from USG placed at a 4-cm depth (67%). Amendment of surface-applied urea with 1.7% phenyl phosphorodiamidate (PPD), a urease inhibitor, essentially eliminated ammonia loss (1.9%). An¹⁵N balance confirmed that ammonia volatilization was the major loss mechanism for all N sources. The results suggest that point-placed urea may be prone to ammonia volatilization loss on light-textured African soils moistened by frequent light rainfall. In such cases, broadcast application of urea, CAN, or urea amended with PPD may be less prone to N loss.     

Urea-rubber matrices as slow-release fertilizers

The efficacy of a prototype slow-release fertilizer, urea-rubber matrix (URM) was assessed under flooded rice conditions. URM cuboids of size 0.5 × 1.0 × 0.4 cm were applied in comparison with prilled urea at levels of 50, 130 and 200 kg N ha^?1. URM was placed at the soil/solution interface in intimate association with rice seedlings whereas prilled urea was broadcast into the floodwater to simulate the normal application method of South East Asian farmers. URM cuboid sizes of 0.25 × 0.5 × 0.4 cm, 0.5 × 0.5 × 0.4 cm and 1.0 × 1.0 × 0.4 cm were similarly evaluated at a single rate of 130 kg N ha^?1; a broadcast URM treatment was also included. Different methods of prilled urea application including deep placement and split application were also studied at a single rate of 130 kg N ha^?1. It was found that the build-up of floodwater N (urea + NH ₄ ⁺ ) from URM during the 13 days following application was almost negligible irrespective of level or method of application. This was thought to result in low losses of N through ammonia volatilization as shown by higher rice grain yields in comparison with prilled urea at all levels of application. Deep-placed urea gave a comparable grain yield to that of broadcast URM. There was no significant difference in grain yield between URM applied by placement and by broadcast, suggesting that URM can be effectively applied either in intimate association with rice seedlings or by broadcasting to the rice field before, or after, planting. An attempt to predict the release of urea from URM was made using a diffusion-based simulation model. It was found that the model underestimated the actual release of urea from URM within the rhizosphere, probably due to the extensive penetration by rice roots of the URM cuboids.     

Nitrogen movement and uptake by rice fertilized with urea supergranules in two contrasting Mollisols

In a glasshouse experiment, the periodic movement, loss and uptake of N by lowland rice fertilized with point-placed urea supergranule (USG) was studied in two soils differing in texture. Movement of urea-N, NH ₄ ⁺ -N and NO ₃ ^- -N was significantly faster in Patharchatta sandy loam (Typic Hapludoll) than in Beni silty clay loam (Aquic Hapludoll) and was mostly downward with peak concentration near the placement site.Nitrogen in leachate was higher in Patharchatta sandy loam than in Beni silty clay loam. About 60–70% of leaching of urea-N took place within 2 days of USG placement. The leaching of NH ₄ ⁺ -N and NO ₃ ^- -N increased till 14 and 21 days of USG placement in Patharchatta sandy loam and Beni silty clay loam, respectively. Nitrogen leached through urea, NH ₄ ⁺ and NO ₃ ^- forms was, respectively, 64, 25 and 25% higher from sandy loam. During 49 days, 49 and 32% of the applied N was recovered by rice plants from silty clay loam and sandy loam, respectively.     

Movement and distribution of fertilizer nitrogen as affected by depth of placement in wetland rice

Experiments were conducted to monitor the movement and distribution of ammonium-N after placement of urea and ammonium sulfate supergranules at 5, 7.5, 10, and 15 cm. By varying depths of fertilizer placement, it is possible to determine the appropriate depth for placement machines. There were no significant differences in grain yields with nitrogen placed 5 and 15 cm deep. However, grain yields were significantly higher with deep placement of nitrogen than with split application of the fertilizer. The lower yields with split-applied nitrogen were due to higher nitrogen losses from the floodwater. The floodwater with split application had 78–98µg N ml^–1 and that with deep-placed nitrogen had a negligible nitrogen concentration.Movement of NH ₄ ⁺ -N in the soil was traced for various depths after fertilizer nitrogen application. The general movement after deep-placement of the ammonium sulfate supergranules was downward > lateral > upward from the placement site. Downward movement was prevalent in the dry season: fertilizer placed at 5–7.5 cm produced a peak of NH ₄ ⁺ -N concentration at 8–12 cm soil depth; with placement at 15 cm, the fertilizer moved to 12–20 cm soil depth. Fertilizer placed at 10 cm tended to be stable. In the wet season, deep-placed N fertilizer was fairly stable and downward movement was minimal.A substantially greater percentage of plant N was derived from¹⁵N-depleted fertilizer when deep-placed in the reduced soil layer than that applied in split doses. The percent N recovery with different placement depths, however, did not vary from each other. The results suggest that nitrogen placement at a 5-cm soil depth is adequate for high rice yields in a clayey soil with good water control. In farmers' fields where soil and water conditions are often less than ideal, however, it is desirable to place nitrogen fertilizer at greater depths and minimize NH ₄ ⁺ -N concentration in floodwater.