共查询到19条相似文献,搜索用时 109 毫秒
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提出并研究了使用1,10-二氮杂菲分光光度法测定沉淀法白炭黑中铁含量的分析方法。其具体步骤为:首先用氢氟酸处理试样,使沉淀法白炭黑(二氧化硅)转化成四氟化硅气体逸出。而后在PH为4-5条件下,有盐酸羟胺处理剂将残留液中的三价铁离子还原成二价离子,加入1,10-二氮杂菲显色剂(与二价铁离子反应可生成橙红色络合物),再用分光光度法测定其中的铁含量。实验表明:本方法原理可靠,分析步骤简便,抗铜,锰离子干 相似文献
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火焰原子吸收光谱法测定白炭黑总铁含量 总被引:1,自引:0,他引:1
采用硫酸沉淀法生产白炭黑(沉淀水合二氧化硅),管道容器的腐蚀程度只有从白炭黑成品总铁含量中发现。由此可见,总铁含量测定在白炭黑生产中是不可缺少的。采用经典的邻菲啰啉分光光度法测定铁含量,操作较为繁琐,耗时长,干扰较多,不能满足快速分析的要求。 相似文献
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在0.1mol/LHAc—NaAc(pH4.0)的支持电解质中,使用0.1g/L邻菲啉(o-phen),采用经典分光光度法测定铁离子;同时,以络合物吸附波极谱法测定铅离子.检测下限可达1.5×10 ̄(10)mol/L。该方法的回收率为99.2%~100.4%,选择性好。 相似文献
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高纯钛氧化物中微量铁的萃取分光光度测定 总被引:2,自引:0,他引:2
利用二氯乙烷萃取邻二氮菲-铁(Ⅱ)-苦味酸盐三元配合物,可以藉分光光度法测定钛氧化物中的微量铁,表观摩尔吸光系数为1.22×10^5。方法灵敏,干扰少,已用于高纯钛氧化物中微量铁的测定。 相似文献
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利用二氯乙烷萃取邻二氮菲-铁(Ⅱ)-苦味酸盐三元配合物,可以藉分光光度法测定钛氧化物中的微量铁,表观摩尔吸光系数达1.22×105。方法灵敏、干扰少,已用于高纯钛氧化物中微量铁的测定。 相似文献
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探索了用氯化亚锡还原光度法代替原用分光光度法测定锅沪蒸汽冷凝液中的微量PO43-。实验最大吸收λ=700nm,表观摩尔吸收系数ε=1.8×104L·mol-1·cm-1,PO43-含量在2.5×10-5~6.0×10-4mg/ml内服从比尔定律,测定回收率为93%~106%,标准偏差3.9(n=7)。已应用于实际生产中,结果满意 相似文献
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A wet glass surface brought in contact with metallic iron acquires a brown stain which cannot be removed easily. This phenomenon was observed by the industry interested in the automatic washing of glass containers. Iron in contact with wet glass surfaces will produce a chemically detectable contamination in one minute and a visible stain in ten minutes. This reaction of the glass surface with iron is galvanic in nature. Iron immersed in water sends positively charged ferrous ions into solution and leaves the metal with a negative charge. In the neighborhood of the iron, a negative electrical potential is established in the glass surface which helps to attract the positively charged ions from the solution. The stain is a result of the interaction of the glass surface and the iron ions, thus leading through oxidation to the formation of an insoluble, colored ferric hydrosilicate. The staining can be prevented by reagents which (1) prohibit the corrosion of the iron, (2) block the active centers of the silica gel, and (3) produce anionic iron complexes. 相似文献
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The low natural abundance and the long spin lattice relaxation time of 29Si lead to long measurement times and/or low signal-to-noise ratios using 29Si magic angle spinning NMR spectroscopy. By contrast, samples containing paramagnetic iron ions have much shorter relaxation times, making measurements up to seven times more efficient, but at the same time making quantitative analysis unreliable. To solve the problem, the spin-lattice relaxation times of ordinary Portland cement (opc) and silica fume with and without iron content has been determined with inversion recovery experiments. The effect of varying the spectrum repetition time on the quantitative analysis is demonstrated for mixtures of opc with silica fume. For opc and silica fume with iron impurities repetition times as short as 5 s has permitted accurate quantitative analysis of the silicates present in these materials. 相似文献
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A new spectrophotometric method for the determination of ferrous iron in the presence of ferric iron
Leandro Herrera Pauline Ruiz Juan C. Aguillon Alexis Fehrmann 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1989,44(3):171-181
A new spectrophotometric method for the determination of ferrous iron concentration in samples containing ferric iron is presented. This new method is a modification of the Muir o-phenanthroline ferrous iron determination method. The new method consists of the quantitative spectrophotometric determination of Fe(II) by o-phenanthroline, but in which the ferric iron is complexed with sodium fluoride to eliminate interferences. A critical experimental comparison between the Muir spectrophotometric method, the Kolthoff titrametric method and the new proposed method is presented. Whenever Fe(III) accounts for more than 50% of the total iron in a sample, the method of Muir overestimates Fe(II). The proposed method has a range of 1–10 μg ferrous iron. It is as insensitive to other metal ions as the original method of Muir and is insensitive to Fe(III) up to a point where Fe(III) might be as high as 95% total iron. The proposed method is suitable for Fe(II) determination in bacterial leaching systems, where Fe(II) might be as low as 1% of total iron. 相似文献
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Masakazu Kawashita Fumiaki Miyaji Tadashi Kokubo Gikan H. Takaoka Isao Yamada Yasuo Suzuki Kenji Kajiyama 《Journal of the American Ceramic Society》1999,82(3):683-688
A chemically durable glass that contains a large amount of phosphorus is useful for in situ irradiation of cancers. It can be activated to be a β-emitter with a half-life of 14·3 d by using neutron bombardment. Microspheres of the activated glass that are injected to tumors can irradiate the tumors directly with β-rays without irradiating neighboring normal tissues. In the present study, P+ ions in various doses have been implanted into a pure silica glass in a plate form at 200 keV. Almost all the implanted phosphorus is present in the inner region of the glass rather than in the surface region, taking the form of phosphorus colloids for all the doses in the range of 5 × 1016 -1 × 1018 cm-2 . A large number of amorphous phosphorus colloid particles with diameters of 10-150 nm are formed in the silica glass that has been implanted with a dose of 1 × 1018 cm-2 ; these colloid particles are distributed widely in a layer that is centered at a depth of 200-250 nm. All the investigated glasses hardly release any phosphorus and silicon into water at a temperature of 95°C, even after 7 d. A silica glass that has been implanted with P+ ions at 200 keV with a dose of 1 × 1018 cm-2 is believed to be useful as a radiotherapy glass with sufficient phosphorus content and high chemical durability. 相似文献
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采用高温焙烧-酸洗方法除石英砂Fe杂质,实验结果表明,900℃焙烧最佳时间为180 min;焙烧后90℃水浴混酸酸洗360 min,石英砂中Fe去除率可达88.3%,Fe杂质含量降为34.61μg/g.通过扫描电子显微镜(SEM)表征该方法处理前后石英砂形貌,结果表明处理后石英砂表面出现明显裂纹和蚀坑,有助于酸液浸入颗粒内部,提高Fe去除率.利用收缩未反应芯模型对实验数据拟合,该酸洗反应控速步骤为产物内扩散控制,焙烧处理后酸洗反应更快,Fe去除率更高,活化能更低.经900℃焙烧,保温180 min处理石英砂,酸洗反应的活化能是30.88 kJ/mol,未焙烧酸洗反应活化能为36.18 kJ/mol,焙烧后酸洗反应活化能下降了17.2%,说明焙烧处理有利于石英砂的酸洗. 相似文献
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A new simple method was developed to synthesize silica nanowires by physical thermal evaporation of a mixture of silica particles
and iron trichloride. The silica nanowires have diameters from 30 to 50 nm, and lengths of ~10 μm, with iron particles at
their tips. The growth mechanism of the amorphous silica nanowires follows vapor–liquid–solid model. A broad blue–green photoluminescence
band with defined maximum peak energy of ~2.45 eV is observed at room temperature revealing that the silica nanowires could
have potential applications in optoelectronic devices. 相似文献
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《Fuel》2005,84(2-3):305-309
Silica gel chemically modified with 2-aminotiazole groups (SiAT), was used for preconcentration of cupper, zinc, nickel and iron from gasoline, normally used as a engine fuel. Surface characteristics and surface area of the silica gel were obtained before and after chemical modification using FT-IR, Kjeldhal and surface area analysis (B.E.T.). The retention and recovery of the analyte elements were studied by applying batch and column techniques. The experimental parameters, such as shaking time in batch technique, flow rate and concentration of the eluent (HCl—0.25–2.00 mol l−1) and the amount of silica, on retention and elution, have been investigated. Detection limits of the method for cupper, iron, nickel and zinc are 0.8, 3, 2 and 0.1 μg l−1, respectively. The sorption–desorption of the studied metal ions made possible the development of a preconcentration method for metal ions at trace level in gasoline using flame AAS for their quantification. 相似文献