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微藻油脂制备生物柴油的研究 总被引:24,自引:0,他引:24
利用正己烷从异养生长的小球藻(脂类化合物含量高达细胞干重的55%,是自养藻细胞(14%)的4倍)细胞中提取获得了大量油脂。这些异养微藻油脂在30℃、醇油物质的量比为56∶1以及浓硫酸催化条件下经酯交换反应4h可形成高质量的生物柴油。微藻生物柴油的密度为0.864kg.L-1、粘度5.2×10-4(40℃)、热值高达41MJ.kg-1。这些特征与传统柴油相当,且微藻生物柴油具有更低的冷滤点(-11℃)及良好的发动机低温启动性能,因此其应用价值更高。 相似文献
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余臻 《福建能源开发与节约》2004,(1):38-40
依据新型高效沼气池特点与先进性,通过具体分析山区与沿海畜禽场推广该工艺沼气运行效果与成本效益,推广该工艺沼气工程能解决畜牧业发展带来严重环境污染问题。 相似文献
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本文通过对浙江省东阳市农村生活污水治理现状及重点、难点问题开展分析,从治理模式、治理措施和设施运维等方面探讨农村生活污水治理建设方式和规划实施中应重点关注的问题。农村生活污水治理工作主要采用纳管、相对集中治理和管控治理等三种模式;采用纳厂、提升改造、撤并和保留四类措施。规划实施过程中应重点关注规划实施顺序、资金筹措、工艺技术、治污降碳,协同增效、运维管理及监管机制等问题。 相似文献
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Vinod Kumar Manisha Nanda Sanjay Kumar Pankaj K. Chauhan 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2018,40(7):787-793
The effect of UV light on growth, biomass, lipid accumulation and biodiesel properties of microalgae was studied. A Microalgae strain Chlorella sorokiniana UUIND6 was cultivated for 14 days as under LED light (Control) and microalgae were exposed to UV light (280–320 nm) in the middle of the photoperiod for 3 days. The growth rate of microalgae was analyzed by spectrophotometer and cell counting, while oil accumulation was analyzed by improved Nile red method. Results showed that microalgae under UV light treated algal cells showed less growth. FAMEs profile of UV treated algal cells mainly contains hexadecanoic acid (C16), stearic acid (C18) fatty acids. PUFA found in very less amount in UV treated cells as compared to control. 相似文献
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Qing Shu Lei Qin Zhenhong Yuan Shunni Zhu Jin Xu Zhongbin Xu 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2018,40(7):751-758
This study is concerned with comparing raw dairy wastewater (DWW) with blue-green medium (BG11 medium) for biofuel production. Three microalgae strains (Chlorella sp., Scenedesmus sp., and Chlorella zofingiensis) were cultured in tubular bubble column photobioreactors with two media separately. After 8 days of cultivation, DWW was demonstrated to be more suitable medium for microalgae biomass and lipid production than BG11 medium. The biomass and lipid produced within wastewater provided suitable feedstocks for anaerobic digestion and biodiesel conversion. Nutrients in wastewater were efficiently removed (>90% total nitrogen removal, approximately 100% ammonia removal, and >85% total phosphorus removal) during this process. 相似文献
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Weizheng Zhou Zhongming Wang Shunni Zhu Shuhao Huo Zhenhong Yuan Jun Xie 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2016,38(5):670-679
Microalgae have been considered as the most promising sources of alternative bioenergy. For the purpose of saving costs, the present work focused on the potential use of microalgae in the meliorative municipal wastewater, which contains 90% municipal wastewater and 10% dairy wash wastewater. Four microalgal species, Palmellococcus miniatus, Neochloris oleoabundans, Scenedesmus quadricanda #507, and Chlorella zofingiensis, were cultured in pure municipal wastewater and meliorative municipal wastewater, respectively, for 5 days. Their biomass accumulation and removal rates of nitrogen and phosphate were measured. Results showed that the growth rates of Neochloris oleoabundans, Palmellococcus miniatus, and Chlorella zofingiensis in meliorative municipal wastewater (>0.8 g·L–1·d–1) were significantly higher than that in municipal wastewater (2.6 g·L–1·d–1), while there was no significant difference between the growth rates of Scenedesmus quadricanda #507 in meliorative municipal wastewater and in municipal wastewater. Neochloris oleoabundans exhibited the highest growth rate (0.86 g·L–1·d–1) and relatively high nutrient removal capacity. Scenedesmus quadricanda #507 had the highest P removal rate of over 94%. The four species have a similar N removal rate at about 90%. The results showed that the highest average removal rate of N and P were about 23.1 mg·L–1·d–1 and 7.1 mg·L–1·d–1. Furthermore, the content of lipid or carbohydrates increased and a different profile of fatty acids were found compared to those in municipal wastewater. Cellular components changes of microalgae in meliorative municipal wastewater were favorable as raw materials for bioethanol and biodiesel production. Cultivation with meliorative municipal wastewater is a win-win culture mode that facilitates the biomass production, lipid and carbohydrate accumulation, and wastewater purification. 相似文献
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In order to reduce the cost of the production of microalgae for biodiesel, the feasibility of using the mixture of seawater and municipal wastewater as culture medium and CO2 from flue gas for the cultivation of marine microalgae was investigated in this study. Effects of different ratios of municipal wastewater and 15% CO2 aeration on the growth of Nannochloropsis sp. were examined, and lipid accumulation of microalgae was also studied under nitrogen starvation and high light. It was found that optimal growth of microalgae occurred in 50% municipal wastewater, and the growth was further significantly enhanced by aeration with 15% CO2. When Nannochloropsis sp. cells were transferred from the first growth phase to the second lipid accumulation phase under the combination of nitrogen deprivation and high light, both biomass and lipid production of Nannochloropsis sp. were significantly increased. After 12 days of the second-phase cultivation, the biomass concentration and total lipid content increased from 0.71 to 2.23 g L−1 and 33.8–59.9%, respectively. This study suggests that it is possible to utilize municipal wastewater to replace nutrients in seawater medium and use flue gas to provide CO2 in the cultivation of oil-bearing marine microalgae for biodiesel. 相似文献
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Na DENG Dongyan LI Qiang ZHANG Awen ZHANG Rongchang CAI Biting ZHANG 《Frontiers in Energy》2019,13(1):64
To predict and analyze the municipal solid waste (MSW) pyrolysis and gasification process in an up-draft fixed bed more veritably and appropriately, numerical modeling based on Gibbs energy minimization was executed using the Aspen plus software. The RYield module was combined with the RGibbs module to describe the pyrolysis section, while the RGibbs module was used for the gasification section individually. The proposed model was used to forecast and analyze the target performance parameters including syngas composition, lower heating value (LHV) and carbon conversion rate under different conditions of the gasification temperatures, and ratios and types of gasifying agents. The results indicate that there is a good agreement between the experimental data and the simulated data obtained using this model. The predicted optimum gasification temperature is approximately 750°C, and the best ratio of water vapor as gasifying agent is around 0.4. The mixture of flue gas and water vapor has an economical and recycled prospect among four commonly used gasifying agents. 相似文献
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为了提高微藻的固碳效率和产脂速率,在模拟的微重力条件下,利用CO2培养蛋白核小球藻。实验结果表明:微重力条件和CO2对蛋白核小球藻的生长具有协同促进作用;与普通条件下通入空气培养蛋白核小球藻相比,在微重力条件下通入浓度为10%的CO2培养蛋白核小球藻120 h后,蛋白核小球藻的生物量浓度提高了178%;在普通条件下,蛋白核小球藻的固碳效率为2.64±0.41 mg/(L·h),在微重力条件下,蛋白核小球藻的固碳效率为17.28±0.42 mg/(L·h);在普通条件下通入CO2后,蛋白核小球藻细胞中的不饱和脂肪酸含量升高,而在微重力条件下通入CO2后,蛋白核小球藻细胞中的不饱和脂肪酸含量会下降。 相似文献
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城市固体废弃物热重分析及热解动力学研究 总被引:1,自引:0,他引:1
对城市垃圾典型组分(塑料、橡胶、果皮、织物、纸板等)进行热重分析及热解动力学研究。热重分析结果表明,塑料组分开始分解的温度较高,但分解速率最快;橡胶组分开始分解反应的温度相对较低,且分解速率相对较慢。果皮、织物和纸板类以纤维和木质类物质为主要成分,其热解特性较为相似。热解动力学研究表明,橡胶的热解活化能最高,最难分解,且热解符合二维扩散机理;塑料的热解相对较容易,符合一维扩散机理。而果皮、织物和纸板类的活化能较低,它们的热解符合体积缩小机理。 相似文献
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X.-P. Zhou L. Xia D. Zhang 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2016,38(1):82-87
Microalgae are considered as an alternative feedstock for producing biodiesel. In this study, six oil-producing algae were cultivated with natural sunlight outdoors. The highest lipid content, biomass productivity, and lipid productivity were 29.99%, 208.42 mg/l/d, and 69.84 ml/d, respectively. In addition, the photosynthetic efficiency of PS II (Fv/Fm) was kept high during the cultivation and the preferred fatty acids (C16–C18) for producing biodiesel were more than 95% of total fatty acids for all of the strains. 相似文献
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《International Journal of Hydrogen Energy》2020,45(39):20240-20249
Hydrogen is usually locked in energy-rich organic compounds and there is almost no pure hydrogen in nature. Organic compounds produced in reservoirs of hydrogen and carbon are an important source of hydrogen production. Understanding the productivity characteristics reservoirs of hydrogen and carbon is the important step to ensure adequate hydrogen energy. This study analyzes the production of hydraulically fractured organic reservoir of hydrogen and carbon. First, based on the diffusion mechanism in reservoir matrix, a multi-scale dual-porosity medium model of reservoir of hydrogen and carbon is established. Then, the mathematical model is solved and verified through a historical matching of field gas production data. Finally, parameter analysis was performed to determine the key parameters to improve the recovery efficiency in organic reservoir of hydrogen and carbon. Results show that improving fracture permeability can improve gas recovery efficiency of hydrocarbon reservoirs. The matrix desorption can develop natural gas production for a long period. Long sizes of hydraulic fractures have large contact surfaces for gas diffusion and increase gas generation and cumulative gas production. The proposed model can predict and analyze the production performance of reservoirs of hydrogen and carbon. 相似文献