Characterisation of the cross-linking process in an E-glass fibre/epoxy composite using evanescent wave spectroscopy

The term “self-sensing composites” is sometimes used to describe the case where the reinforcing glass fibres in advanced fibre-reinforced composites are used as the sensors for chemical process-monitoring (cure monitoring). This paper presents conclusive evidence to demonstrate that reinforcing E-glass fibres can be used for in situ cure monitoring. The cure behaviour of an epoxy/amine resin system was compared using evanescent wave spectroscopy via the reinforcing E-glass fibres and conventional transmission Fourier transform infrared spectroscopy. This paper also reports for the first time that evanescent wave spectroscopy via E-glass fibres can be used to detect the presence of silane coupling agents. Preliminary results indicated that the cure kinetics on the E-glass fibre surface, as observed using evanescent wave spectroscopy, were influenced by the silane coupling agent.     

Analytical prediction of damage due to large mass impact on thin ply composites

This article presents analytical models for predicting large mass impact response and damage in thin-ply composite laminates. Existing models for large mass impact (quasi-static) response are presented and extended to account for damage phenomena observed in thin-ply composites. The most important addition is a set of criteria for initiation and growth of bending induced compressive fibre failure, which has been observed to be extensive in thin ply laminates, while it is rarely observed in conventional laminates. The model predictions are compared to results from previous tests on CFRP laminates with a plain weave made from thin spread tow bands. The experiments seem to confirm the model predictions, but also highlight the need to include the effects of widespread bending induced fibre failure into the structural model.     

Fatigue strength of CFRP strengthened welded joints with corrugated steel plates

This paper presents an experimental and numerical research on the carbon fibre reinforced polymer (CFRP) strengthened welded joints with corrugated plates. The effectiveness of the strengthening in the improvement of fatigue strength has been examined experimentally on the test joints through varying the number and the layout of the CFRP laminates. The test results show that the joints with transition curvature region reinforcement and single side reinforcement produce slightly lower rigidity but longer fatigue life in contrast to those with full width reinforcement on the double side of the main plate. Furthermore, a simplified two dimensional analytical model which allows for the geometric characteristics of the joint has been proposed to investigate the stress intensity factor of mode I. The proposed analytical model has been simulated by finite element technique and its solution result is compared with previously reported theoretical calculation. Parametric studies have been performed to investigate the effects of the number of CFRP layers and the moduli of carbon fibre & adhesive on the stress intensity factor. The combined influence of the corrugation angle and crack depth has also been considered. It has been found that these effects on the stress intensity factor are more significant for the joints with smaller corrugation angle.     

Experimental study of bond behaviour between concrete and FRP bars using a pull-out test

This paper presents the results of an experimental programme concerning 88 concrete pull-out specimens prepared according to ACI 440.3R-04 and CSA S806-02 standards. Rebars (reinforcing bars) made of carbon-fibre and glass-fibre reinforced polymer (CFRP and GFRP), as well as steel rebars, with a constant embedment length of five times the rebar diameter were used. The influence of the rebar surface, rebar diameter and concrete strength on the bond–slip curves obtained is analysed. In addition, analytical models suggested in the literature are used to describe the ascending branch of the bond–slip curves. To calibrate the analytical models, new equations that account for the dependence on rebar diameter are presented.     

Quantification of flexural fatigue life and 3D damage in carbon fibre reinforced polymer laminates

Carbon fibre reinforced polymer (CFRP) laminated composites have become attractive in the application of wind turbine blade structures. The cyclic load in the blades necessitates the investigation on the flexural fatigue behaviour of CFRP laminates. In this study, the flexural fatigue life of the [+45/−45/0]_2s CFRP laminates was determined and then analysed statistically. X-ray microtomography was conducted to quantitatively characterise the 3D fatigue damage. It was found that the fatigue life data can be well represented by the two-parameter Weibull distribution; the life can be reliably predicted as a function of applied deflections by the combined Weibull and Sigmodal models. The delamination at the interfaces in the 1st ply group is the major failure mode for the flexural fatigue damage in the CFRP laminate. The calculated delamination area is larger at the interfaces adjacent to the 0 ply. The delamination propagation mechanism is primarily matrix/fibre debonding and secondarily matrix cracking.     

Prediction of material property parameter of FRP composites using ultrasonic and acousto-ultrasonic techniques

A study has been made of the use of ultrasonic techniques and acousto-ultrasonic techniques to evaluate the material property parameter of the glass fibre reinforced plastic (GRP) and carbon fibre reinforced plastic (CFRP) composites. The theoretical results indicated that the ultimate tensile strength of GRP and CFRP composites can be related to the material property parameter of FRP composites.     

Analytical approach for the flexural analysis of RC beams strengthened with prestressed CFRP

The objective of this paper is to propose a simplified analytical approach to predict the flexural behavior of simply supported reinforced-concrete (RC) beams flexurally strengthened with prestressed carbon fiber reinforced polymer (CFRP) reinforcements using either externally bonded reinforcing (EBR) or near surface mounted (NSM) techniques. This design methodology also considers the ultimate flexural capacity of NSM CFRP strengthened beams when concrete cover delamination is the governing failure mode. A moment–curvature (M–χ) relationship formed by three linear branches corresponding to the precracking, postcracking, and postyielding stages is established by considering the four critical M–χ points that characterize the flexural behavior of CFRP strengthened beams. Two additional M–χ points, namely, concrete decompression and steel decompression, are also defined to assess the initial effects of the prestress force applied by the FRP reinforcement. The mid-span deflection of the beams is predicted based on the curvature approach, assuming a linear curvature variation between the critical points along the beam length. The good predictive performance of the analytical model is appraised by simulating the force–deflection response registered in experimental programs composed of RC beams strengthened with prestressed NSM CFRP reinforcements.     

SiC晶须增韧陶瓷基复合材料及其分散研究

阐述了SiC晶须增韧陶瓷基复合材料的进展，指出晶须增韧过程中遇到的难题；综述了近年来对SiC晶须分散摘要并认为化学键合理论在SiC晶须的分散中是主性的研究及其效果，主要介绍了硅烷偶联剂的化学键合理论和物理作用理论，要的。     

Wood based PLA and PP composites: Effect of fibre type and matrix polymer on fibre morphology,dispersion and composite properties

This study presents a comparison of the effect of various wood fibre types in polylactic acid and polypropylene composites produced by melt processing. The study also reveals the reinforcing effect of pelletised wood fibres compared to conventionally used wood flour or refined fibres. Composites containing 30 wt.% of chemical pulps, thermomechanical pulp and wood flour were produced by compounding and injection moulding. Fibre morphologies were analysed before and after melt processing. The dispersion of the fibres and mechanical performance of the composites were also investigated. Fibre length was reduced during melt processing steps, reduction being higher with longer fibres. Wood fibres provided clearly higher plastic reinforcement than wood flour. Comparing the wood fibre types, TMP fibres provided the highest improvement in mechanical properties in polylactic acid composites with uniform fibre dispersion. In polypropylene composites, fibre selection is not as crucial.     

Natural-fibre-reinforced polyurethane microfoams

Polyurethane-based composites reinforced with woven flax and jute fabrics were prepared with an evenly distributed microvoid foam structure. The relationship between the resin-filled grade and the microvoid content and the density was described. The influence of the type of reinforcing fibre, fibre and microvoid content on the mechanical properties was studied. The investigation results for the static mechanical properties of the composites were described by approximate formulae. It was found that the specific data were only slightly dependent on microvoid content. Increasing the fibre content induces an increase in the shear modulus and impact strength. However, increasing the microvoid content in the matrix results in a decreased shear modulus and impact strength. The woven flax fibre results in composites with better mechanical strength than the woven jute fibre composites.     

Experimental observations of the strain distribution around a matrix crack bridged by reinforcing members and its effect on tensile fracture

Measurements have been made of the elastic strain distributions developed around matrix cracks of various lengths bridged orthogonally by reinforcing members. The experimental specimens consisted of aluminium sheets reinforced with stainless steel tubes. The strains were produced by tensile loads applied parallel to the alignment of the reinforcing members. Measurements were made on reinforced and unreinforced specimens. For both conditions good agreement was found between the experimental data and the strain field previously postulated as a means to calculate critical strains for unstable crack extension. A comparison is made between the failure processes predicted by the analytical model and those observed experimentally in fibre composites.     

Structural capacitor materials made from carbon fibre epoxy composites

In this paper, an approach towards realising novel multifunctional polymer composites is presented. A series of structural capacitor materials made from carbon fibre reinforced polymers have been developed, manufactured and tested. The structural capacitor materials were made from carbon fibre epoxy pre-preg woven laminae separated by a paper or polymer film dielectric separator. The structural capacitor multifunctional performance was characterised measuring capacitance, dielectric strength and interlaminar shear strength. The developed structural CFRP capacitor designs employing polymer film dielectrics (PA, PC and PET) offer remarkable multifunctional potential.     

A novel processing technique for thermoplastic manufacturing of unidirectional composites reinforced with jute yarns

This paper primarily investigates the fabrication process of long-fibre reinforced unidirectional thermoplastic composites made using jute yarns (both untreated and treated). Tubular braiding technique was used to produce an intermediate material called “microbraid yarn” (MBY) with jute yarn as the straightly inserted axial reinforcement fibre and polymer matrix fibre being braided around the reinforcing jute yarns. Microbraid yarns were then wound in a parallel configuration onto a metallic frame and compression molded to fabricate unidirectional composite specimens. In this study, two types of polymeric materials (biodegradable poly(lactic) acid and non-biodegradable homo-polypropylene) were used as matrix fibres. Basic static mechanical properties were evaluated from tensile and 3 point bending tests. Test results were analyzed to investigate the effects of molding temperature and pressure on the mechanical and interfacial behaviour. For the unidirectional jute fibre/poly(lactic) acid (PLA) composites, the results indicated that the molding condition at 175 °C and 2.7 MPa pressure was more suitable to obtain optimized properties. Improved wettability due to proper matrix fusion facilitated thorough impregnation, which contributed positively to the fibre/matrix interfacial interactions leading to effective stress transfer from matrix to fibre and improved reinforcing effects of jute yarns. For the jute/PP unidirectional composites, specimens with only 20% of jute fibre content have shown remarkable improvement in tensile and bending properties when compared to those of the virgin PP specimens. The improvements in the mechanical properties are broadly related to various factors, such as the wettability of resin melts into fibre bundles, interfacial adhesion, orientation and uniform distribution of matrix-fibres and the lack of fibre attrition and attenuation during tubular braiding process.     

Analysis of CFRP externally-reinforced steel CHS tubular beams

The reinforcing effect of externally bonded composite materials in the ultimate response of steel structures is introduced and the principal variables discussed. Composite beams of carbon fibre reinforced polymer (CFRP) sheets and steel circular hollow steel sections (CHS) are considered in this study. The investigation aims to quantify the contribution of the external reinforcing system to enhancing the strength characteristics of the thin walled steel section. An analysis of the ultimate bending strength of composite steel-CFRP CHS tubular beams which accounts for material properties and fibre orientation is outlined. The variations in the elastic and yielded regions around the section are examined. The provided results demonstrate that the ultimate load can be increased satisfactorily by adding high-strength fibre sheets to the steel sections and externally reinforcing them.     

碳纤维复合材料低温热导率分析计算模型

探讨了碳纤维复合材料（ＣＦＲＰ）低温传热机理及低温热导率的一般规律和影响因素；在分析讨论的基础上，建立了ＣＦＲＰ低温热导率的计算模型，并将计算结果与测试结果进行了比对。为设计、推算ＣＦＲＰ材料的低温热导率提供了一种简便、较准确的手段。     

Behavior of 3D orthogonal woven CFRP composites. Part II. FEA and analytical modeling approaches

In this paper, a 3D macro/micro finite element analysis (FEA) modeling approach and a 3D macro/micro analytical modeling approach are proposed for predicting the failure strengths of 3D orthogonal woven CFRP composites. These approaches include two different scale levels, macro- and micro-level. At the macro-level, a relatively coarse structural model is used to study the overall response of the structure. At the micro-level, the laminate block microstructure is modeled in detail for investigating the failure mechanisms of 3D orthogonal woven CFRP composites. The FEA and analytical models developed previously [Tan P, Tong L, Steven GP. Modeling approaches for 3D orthogonal woven composites, Journal of Reinforced Plastics and Composites, 1998:17;545–577] are employed to predict the mechanical properties of 3D orthogonal woven CFRP composites. All models presented in this paper are validated by comparing the relevant predictions with the experimental results, which were reported earlier in Part I of the paper [Tan P, Tong L, Steven GP. Behavior of 3D orthogonal woven CFRP composites. Part I. Experimental investigation, Composites, Part A: Applied Science and Manufacturing, 2000:31;259–71]. The comparison shows that there is a good agreement for the mechanical properties. An acceptable agreement exists for the failure strength in the x or stuffer yarn direction even though the FEA model gives a lower bound and the analytical model gives an upper bound. However, for the failure strength in the y or filler yarn direction, the difference between the predicted and experimental results is significant due to primarily ignoring of the waviness of filler yarn in the models. A curved beam model, which considers the waviness of the filler yarn, will be presented in Part III of the paper.     

Investigation of the effect of surface modifications on the mechanical properties of basalt fibre reinforced polymer composites

Unsaturated polyester-based polymer composites were developed by reinforcing basalt fabric into an unsaturated polyester matrix using the hand layup technique at room temperature. This study describes basalt fibre reinforced unsaturated polyester composites both with and without acid and alkali treatments of the fabrics. The objective of this investigation was to study the effect of surface modifications (NaOH & H₂SO₄) on mechanical properties, including tensile, shear and impact strengths. Variations in mechanical properties such as the tensile strength, the inter-laminar shear strength and the impact strength of various specimens were calculated using a computer-assisted universal testing machine and an Izod Impact testing machine. Scanning Electron Microscope (SEM) observations of the fracture surface of the composites showed surface modifications to the fibre and improved fibre–matrix adhesion. The result of the investigation shows that the mechanical properties of basalt fibre reinforced composites are superior to glass fibre reinforced composites. This work confirms the applicability of basalt fibre as a reinforcing agent in polymer composites.     

Reinforcement and quantitative description of inorganic particulate-filled polymer composites

Understanding the reinforcing mechanisms should be meaningful for preparation of new polymer composites. The reinforcing mechanisms of the inorganic particulate-filled polymer composites were analyzed and discussed in the present paper, and concluded several reinforcing theories on the basis of the previous studies, such as interfacial adhesion reinforcing theory, filler inducing crystallization reinforcing theory, filler frame reinforcing theory, and synergistic reinforcing effect theory. The reinforcing effects should be related closely to the filler shape and size, in addition to the filler concentration and dispersion in the matrix. Consequently, to describe accurately the reinforcing mechanisms of the composites, two or more reinforcing theories should be used for the actual composite system, and one of among them should be usually as the major reinforcing mechanism. Finally, the quantitative characterization of the reinforcement was described.     

Mechanical analysis and toughening mechanisms of a multiphase recycled CFRP

The mechanical response of a recycled CFRP is investigated experimentally. A complex multiscale microstructure is revealed, with both dispersed fibres (with fractured-sections) and fibre-bundles. The specific properties of the recyclate compare favourably with those of aluminium and glass–fibre composites. Micromechanical studies show that tensile failure follows the pre-existing fractured-sections on the dispersed-fibres, while compressive failure occurs by shear-banding. Fracture toughness measurements coupled with SEM evidence how bundles considerably toughen the composite by complex failure mechanisms. This analysis can guide the optimisation of recycling processes and support the development of design methods for recycled CFRP; it also provides insight on the mechanical response of other multiphase short-fibre reinforced materials.     

Recycling of shredded composites from wind turbine blades in new thermoset polymer composites

As the energy produced from wind increases every year, a concern has raised on the recycling of wind turbine blades made of glass fibre composites. In this context, the present study aims to characterize and understand the mechanical properties of polyester resin composites reinforced with shredded composites (SC), and to assess the potential of such recycling solution. A special manufacturing setup was developed to produce composites with a controlled content of SC. Results show that the SC in the composites was well distributed and impregnated. The composite stiffness was well predicted using an analytical model, and fibre orientation parameters for strength modelling were established. The stress-strain curves revealed composite failure at unusual low strain values, and micrographs of the fracture surface indicated poor adhesion between SC and matrix. To tackle this problem, chemical treatment of SC or use of an alternative resin, to improve bonding should be investigated.