基于正交试验的水泥砂浆开裂敏感性研究

选取比表面积、SO3含量、碱含量、水灰比及养护温度5种因素,采用正交设计理论,通过水泥砂浆的圆环约束试验,分析讨论各因素对砂浆开裂敏感性影响的显著程度,为水泥的生产如何适应混凝土的质量要求以及如何在配合比设计和施工中提高混凝土的抗裂性提供参考.结果表明:各因素对水泥砂浆开裂敏感性的影响程度为比表面积水灰比养护温度碱含量SO3含量,水灰比、比表面积和养护温度对水泥砂浆开裂有显著影响.水灰比降低、比表面积增大和养护温度提高都会引起水泥砂浆开裂趋势的增大,显著降低水泥砂浆的抗裂性能,应引起足够的重视.     

废旧橡胶颗粒改性对水泥砂浆性能的影响研究

经氢氧化钠(NaOH),四氯化碳(CCl4),聚乙烯醇(PVA)三种溶液改性后的橡胶颗粒加入到水泥砂浆中可改善橡胶颗粒与水泥基体的界面,使橡胶颗粒在水泥砂浆中达到较好的使用效果.试验研究表明,CCl4溶液改性的效果较好,其次是NaOH饱和溶液.综合考虑压折比、抗冲击性能和经济性等因素,在工程中建议使用NaOH饱和溶液对橡胶颗粒进行改性.NaOH饱和溶液改性的40目橡胶颗粒掺量为20％时橡胶集料水泥砂浆的力学性能最好.     

聚合物改性水泥砂浆基础研究

通过相应的实验，对聚合物改性水泥砂浆作出一定研究，采用氯丁胶乳、聚乙烯醇溶液、乙烯一醋酸乙烯共聚乳液EVA三种不同聚合物作为改性剂，分析最佳配比及工艺参数，根据实验数据探讨力学性能及改性效果，分析微观结构，探讨其改性机理，给出研究聚合物改性水泥砂浆的一般方法。     

ACR的组成对PVC性能的影响

通过种子乳液聚合方法合成聚丙烯酸丁酯胶乳和丙烯酸丁酯与苯乙烯共聚胶乳,然后采用乳液聚合法接枝苯乙烯和甲基丙烯酸甲酯,制备出具有核-壳结构的丙烯酸酯类抗冲改性剂(ACR).以ACR作为聚氯乙烯(PVC)的抗冲击改性剂,考察了具有不同组成的ACR对改性后的PVC性能的影响.     

PVAC和ABR-60水泥混凝土的研究

着重研究了聚合物水泥混凝土的配比及性能。聚合物为PVAC和ABR-60,先选择对某一胶乳合适的助剂或进一步处理胶乳,使之对无机胶结料和机械作用具有稳定性。然后,分别按不同掺量加入水泥砂浆中,适当养护。结果表明,制得的混凝土许多性能得到明显的改善。     

改性芳纶纤维/水泥砂浆复合材料的力学性能

采用化学法、等离子体法、紫外线法处理芳纶纤维,考察改性纤维对水泥砂浆力学性能的影响.实验结果表明,化学法改性的芳纶纤维在芳纶纤维/水泥砂浆复合材料中能够形成良好的界面结合,使其力学性能得到显著改善.利用扫描电镜对试样进行了微观分析,初步探讨了改性芳纶纤维在水泥砂浆中的作用机理.     

表面改性丙纶增强水泥砂浆制品的研究

研究了表面改性丙纶对水泥砂浆制品的增强作用。结果表明 ,在水泥砂浆制品中混入表面改性丙纶可提高水泥砂浆制品的固化速率 ,减小水泥砂浆制品的龟裂 ,提高水泥砂浆制品的抗冲击强度和抗折强度 ,当纤维加入量为 1.6kg/m3 时 ,抗冲击强度和抗折强度有最大值     

表面改性丙纶增强水泥砂浆制品的研究

研究了表面改性丙纶对水泥砂浆制品的增强作用，结果表明，在水泥砂浆制品中混入表面改性丙纶可提高水泥砂浆制品的固化速率，减小水泥砂浆制品的龟裂，提高水泥砂浆制品的抗冲击强度和抗折强度，当纤维加入量为1.6kg/m^3时，抗冲击强度和抗折强度有最大值。     

聚丙烯纤维/聚合物乳液对砂浆干缩开裂的影响

针对水泥砂浆容易干缩开裂的问题,采用聚丙烯纤维和聚合物乳液对水泥砂浆进行改性,并对改性的水泥砂浆抗干缩开裂性能进行了实验研究.实验结果表明:在本实验条件下,掺加适量的聚丙烯纤维和聚合物乳液,可以有效地提高水泥砂浆抗干缩开裂性能.该研究是对聚丙烯纤维聚合物乳液改性水泥砂浆机理的初步探讨.     

环氧树脂-玻璃纤维对水泥改性膨胀土的加固机理试验研究

以膨胀土与水泥的重量比为指标,研究环氧树脂、玻璃纤维和水泥对膨胀土力学性质和微观结构的影响.结果 表明,环氧树脂与水泥改性膨胀土的最小配比为0.3,最佳配比为0.6.在此范围内,试样的抗压强度为水泥改性膨胀土的17.01倍,抗弯强度为水泥改性膨胀土的3.09倍.在最佳树脂/固体质量比条件下(玻璃纤维和玻璃纤维粉含量分别...     

聚合物乳液改性水泥砂浆基本性能研究

为开发高性能的表面修补材料,选用2种聚合物乳液对水泥砂浆进行改性,并对聚合物乳液改性水泥砂浆进行了室内抗压强度、抗折强度、黏结抗折强度、吸水率和孔结构分析等试验.结果表明,聚合物乳液的使用明显提高了砂浆与原混凝土的黏结抗折强度、降低了砂浆的吸水率,改善了砂浆的孔结构分布形态.     

Effect of Waterborne Epoxy on Performances of Cement Asphalt Mortar

The waterborne epoxy modified cement asphalt mortars were prepared with varying content waterborne epoxy and a constant fluidity. The effects of waterborne epoxy emulsion on water/cement ratio,compressive and flexural strength,tensile bond strength,freezing and thawing damage,corrosion resistance of cement asphalt mortar cured for 7 and 28 d have been investigated. The results show that waterborne epoxy is very beneficial to the improvement of mechianical properties and durability of cement asphalt mortar. Waterborne epoxy can improve the flowing ability of cement asphalt mortar. With the increasing of waterborne epoxy content,compressive strength,flexural strength and bond strength all have increased obviously. The modified mortar shows higher resistance to corrosion and the freezing and thawing compared with control mortar.     

Synthesis and Application of Sodium-carboxymethylcellulose Type Superplasticizer in Cement Mortars

The polymeric admixture, the sodium-carboxymethylcellulose(CMC)/poly sodium p-styrene sulfonate(PSS)/poly vinyl acetate(PVAc) was synthesized and applied in cement mortars. The polymer was tested by FTIR and SEM, and the results indicate that the ideal molecular structure is synthesized. The effect of addition amount of polymeric admixture and water-to-cement ratio on mechanical properties of cement mortars was studied. The polymer-modified mortars under the optimum water cement ratio and optimum polymer cement ratio, the flexural strength of polymer-modified mortars are 1.45, 1.21, and 1.17 times higher than the plain cement mortar at age of 3, 7, and 28 d, respectively. The compressive strength of polymer-modified mortars at age of 3, 7, and 28 d are 1.55, 1.40, and 1.2941 times higher than that of the plain cement mortar,respectively. Scanning electron microscope(SEM), FTIR and TG were used to analyze the effect of polymer emulsion on cement hydration reaction. The results show that the polymer emulsion can promote the hydration reaction of cement.     

粉煤灰对砂浆强度影响的实验研究

探讨了高烧失量粉煤灰对砂浆强度的影响。用不同掺量的粉煤灰做了两组实验，测试结果表明：粉煤灰砂浆的用水量随着粉煤灰掺量的增加而增加；在蒸养后，粉煤灰砂浆试块的抗压和抗折强度比无粉煤灰试块有较大的提高；当粉煤灰掺量占水泥量的３０％时，其抗压和抗折强度最高；在标差２８ｄ后，粉煤灰掺量大于３０％的砂浆试块抗压和抗折强度比无粉煤灰试块有所降低。     

Properties of cementitious rendering mortar prepared with recycled fine aggregates

The results of an experimental study on investigating the properties of cementitious rendering mortars prepared with a recycled fine aggregate (RA) were presented. The RA was obtained from a recycling plant in which mixed demolition wastes were processed by mechanical crushing, sieving and sorting operations. Two series of rendering mortar mixes were prepared with a constant water/cement and a constant aggregate/cement ratios of 0.55 and 3 respectively. River sand and natural crushed rock fine were originally used in the two series separately, and they were consistently replaced by 25%, 50%, 75% and 100% by the recycled aggregate. The experimental results showed that mechanical properties, such as compressive strength, flexural strength and modulus of elasticity of the mortars prepared with the RA were lower than the mortars made with the natural aggregates. Nevertheless, the bond strength at the interface between the mortar and masonry bricks determined by the Triplet test was found to be higher for the mortars prepared with the RA.     

Effect of Sand Content on Strength and Pore Structure of Cement Mortar

The effects of four sand contents on the compressive, flexural and splitting-tensile strength of cement mortars were evaluated. Moreover, we experimentally investigated the pore structure of cement mortar brought about by changing the sand content and water/cement ratio. The changes in the pore structure were quantified by measuring the porosity and pore size distribution obtained by using mercury intrusion porosimetry(MIP) technique. The test results show that the strengths of cement mortar increase with increasing sand content. It is also suggested that the traditional water/cement ratio law can be applied to cement mortar with different sand contents, provided that a slight modification is introduced. Sand content is an important parameter influencing the pore structure of cement mortar. Moreover, there is a good relationship between the pore structure and strength of cement mortar.     

水泥掺量对纤维改性聚合物树脂混凝土力学性能的影响

利用抗压试验、抗折试验、扫描电镜等方法,探讨了水泥掺量对聚合物砂浆性能的影响.试验结果表明：当水泥掺量为115%时与水泥掺量0%时相比,聚合物砂浆的抗折强度提高95%,抗压强度提高74%,折压比也相应有所提高.但加入量高于115%时,导致水泥比表面积过大,抗折强度和抗压强度均有所下降.     

Influences of polypropylene fiber and SBR polymer latex on abrasion resistance of cement mortar

Influences of polypropylene (PP) fiber and styrene-butadiene rubber (SBR) polymer latex on the strength performance, abrasion resistance of cement mortar were studied. The experimental results show that the flexural strength, brittleness index (σ_F/σ_C) and abrasion resistance can be improved significantly by the addition of PP fiber and SBR polymer latex. The relationship between the flexural strength and abrasion resistance was analyzed, showing a good linear relationship between them. The reinforced mechanism of PP fiber and SBR polymer latex on cement mortar was analyzed by some microscopic tests. The test results show that the addition of SBR polymer latex has no significant influence on the cement hydration after 7 d curing. Adding SBR polymer latex into cement mortar can form a polymer transition layer in the interfaces of PP fiber and cement hydrates, which improves the bonding properties between the PP fiber and cement mortar matrix effectively.     

Effects of carbon nanotubes on mechanical and 2D-3D microstructure properties of cement mortar

To study the influence of multi-wall carbon nanotubes （MWCNTs） on the mechanical and microstructural properties of cementitious composites, 0.00, 0.02, 0.08, 0.10, and 0.20 wt% of multi-wall carbon nanotubes were added into cement mortar, in which the cement-sand ratio was 1：1.5. The flexural and compressive strengths of cement mortar at the age of 3, 7, 28 and 90 d and the fracture performance at the age of 28 d were determined, its 2D micrograph was tested by means of SEM, and the 3D defects distribution was firstly determined with or without CNTs by means of XCT （X-ray computerized tomography）. The results showed that 0.08 wt% of CNTs improved the compressive strength and flexural strength by 18% and 19~A, respectively, and a significant improvement of its fracture property was observed. Moreover lower addition of carbon nanotubes to cement mortars can improve its microstructure and decrease the defects significantly compared to the cement mortar without CNTs. With the increase of the content of CNTs, the mechanical properties of cement mortars presented to be declined largely due to the agglomeration of CNTs.     

聚丙烯酸酯乳液改性砂浆微观结构与改性机理

为了研究聚丙烯酸酯乳液（PA）改性砂浆硬化过程中微观结构的形成过程及改性机理,分析PA聚合物乳液在新拌水泥砂浆中的吸附特性,并模拟孔隙溶液和PA乳液之间相互作用.同时采用扫描电子显微镜（SEM）和能谱分析（EDX）法表征了PA改性砂浆微观结构的演化过程.试验结果表明,PA颗粒将与孔隙溶液中的钙离子发生化学反应,PA聚合物将以不同的形态吸附在水泥砂浆的局部部位.在此基础上,考虑PA聚合物改性乳液与水泥基材料的反应,提出一种改进的聚合物改性与微观结构形成模型.这对研究聚合物改性水泥基材料的力学性能与推广聚合物改性水泥基材料在工程中的应用具有重要意义.