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1.
Single-phase perovskites were formed in the (1−x)Ba(Zn1/3Nb2/3)O3-( x )La(Zn2/3Nb1/3)O3 system for compositions with 0.0≤ x ≤0.6. Although the stability of the trigonal "1:2" ordered structure of the Ba(Zn1/3Nb2/3)O3 end member is very limited (0.0≤ x ≤0.05), low levels of lanthanum induce a transformation to a cubic, "1:1" ordered structure that has a broad range of homogeneity (0.05≤ x ≤0.6). Samples with x > 0.6 were comprised of La3NbO7, ZnO, and a perovskite with x = 0.6. The cubic 1:1 phases were fully ordered and no evidence was found for a compositionally segregated microstructure. These observations could not be reconciled in terms of a "space-charge" model; rather, they supported a charge-balanced, "random-site" structure for the 1:1 cation-ordered Ba(β1/21/2")O3 phases.  相似文献   

2.
A narrow region of Zn-vacancy-containing cubic perovskites was formed in the (1− x )Ba3(ZnNb2)O9−( x )Ba3W2O9 system up to 2 mol% substitution ( x =0.02). The introduction of cation vacancies enhanced the stability of the 1:2 B-site ordered form of the structure, Ba(Zn1− x x )1/3(Nb1− x W x )2/3O3, which underwent an order–disorder transition at 1410°C, ∼35° higher than pure Ba(Zn1/3Nb2/3)O3. The Zn vacancies also accelerated the kinetics of the ordering reaction, and samples with x =0.006 comprised large ordered domains with a high lattice distortion ( c/a =1.226) after a 12 h anneal at 1300°C. The tungstate-containing solid solutions can be sintered to a high density at 1390°C, and the resultant ordered ceramics exhibit some of the highest microwave dielectric Q factors ( Q × f =1 18 000 at 8 GHz) reported for a niobate-based perovskite.  相似文献   

3.
Microstructures of ordered Ba(Cd1/3Ta2/3)O3 perovskite dielectric ceramics with and without a boron additive have been observed by atomic resolution transmission electron microscopy (TEM). The selected area electron diffraction and lattice image show a well-ordered structure with hexagonal symmetry (lattice constants of a ∼5.8 Å and c ∼7.1 Å) in the ordered Ba(Cd1/3Ta2/3)O3 with a boron additive, which is similar to those in ordered Ba(Zn1/3Ta2/3)O3 and Ba(Mg1/3Ta2/3)O3 ceramics. Ordered domains with a twin crystallographic relationship and high-density domain interfaces induced by ordering were observed in the ordered Ba(Cd1/3Ta2/3)O3 without a boron additive sintered at a relatively high temperature. Atomic resolution TEM further revealed the conservative twin boundaries along (001) and (110) planes and non-conservative antiphase boundaries with a projected displacement vector of the type [001] in the ordered Ba(Cd1/3Ta2/3)O3 without a boron additive. Finally, the energetics of different domain interfaces are discussed with the interfacial structures in ordered Ba(Cd1/3Ta2/3)O3 ceramics revealed by an electron microscope.  相似文献   

4.
The 1/3 <111>-type ordering of Ba(Zn1/3Ta2/3)O3 (BZT) can be transformed to 1/2 <111>–type ordering by substituting the La3+ cation into the A site. The 1/3 <111> ordering in BZT is shown to be reduced, discontinued, and then replaced by 1/2 <111> ordering, using X–ray diffraction, electron microscopy, and Raman spectroscopy. On the other hand, potassium–substituted BZT only displays a reduction in the degree of ordering.  相似文献   

5.
The microwave dielectric properties and crystal structure of Ba(Zn1/3Ta2/3)O3– (Sr,Ba)(Ga1/2Ta1/2)O3 ceramics were investigated in the present study. The Q value of Ba(Zn1/3Ta2/3)O3 was improved by adding 5 mol% Sr(Ga1/2Ta1/2)O3. The maximum Q value of Q × f = 162000 GHz was obtained at 0.95Ba(Zn1/3Ta2/3)O3. 0.05Sr(Ga1/2Ta1/2)O3. For this composition, a lattice super structure caused by hexagonal ordering was observed. A further improvement in the Q value was attained when some Sr was replaced with Ba, and 0.95Ba(Zn1/3Ta2/3)O3· 0.05(Sr0.25Ba0.75)(Ga1/2Ta1/2)O3 exhibited a maximum Q value such that Q × f = 210000 GHz. Despite the increased Q value with the replacement of Sr by Ba, the c/a value, which indicates the degree of lattice distortion, remained constant near 3/2. The Q value thus improved without lattice distortion in the system Ba(Zn1/3Ta2/3)O3-(Sr,Ba)(Ga1/2Ta1/2)O3, whereas the improvement of Q value increased with lattice distortion in the solid solution system with Ba(Zn1/3Ta2/3)O3 as an end member.  相似文献   

6.
The dielectric loss tangent at microwave frequencies for the complex perovskite Ba(Zn1/3Ta2/3)O3 was calculated with respect to the degree of structural disorder on B sites. Starting out from the equations of ion motion, dielectric loss was expressed in terms of the pair-correlation functions corresponding to the ordering of Zn and Ta ions on B sites. The characteristic length included in the pair-correlation functions corresponds to the average size of the region containing disorder in ion arrangements on B sites; thus the relation between the structural disorder on the B site and the dielectric loss tangent at microwave frequencies was clarified theoretically. The numerical results show that the microwave loss tangent values change their power from – 3 to – 6 with increasing degree of order on the B site, which agrees well with the experimental observations. Results obtained here confirm the physical origin of the microwave loss of complex perovskite Ba(Zn1/3Ta2/3)O3.  相似文献   

7.
Cation ordering and domain boundaries in perovskite Ca[(Mg1/3Ta2/3)1− x Ti x ]O3 ( x =0.1, 0.2, 0.3) microwave dielectric ceramics were investigated by high-resolution transmission electron microscopy (HRTEM) and Rietveld analysis. The variation of ordering structure with Ti substitution was revealed together with the formation mechanism of ordering domains. When x =0.1, the ceramics were composed of 1:2 and 1:1 ordered domains and a disordered matrix. The 1:2 cation ordering could still exist until x =0.2 but the 1:1 ordering disappeared. Neither 1:2 nor 1:1 cation ordering could exist at x =0.3. The space charge model was used to explain the cation ordering change from 1:2 to 1:1 and then to disorder. A comparison between the space charge model and random layer model was also conducted. HRTEM observations showed an antiphase boundary inclined to the (111) c plane with a projected displacement vector in the 〈001〉 c direction and ferroelastic domain boundaries parallel to the 〈100〉 c direction.  相似文献   

8.
Both 1:2 and 1:1 ordered structures form in the perovskite solid solutions of La-substituted BMT Ba1− x La x (Mg(1+ x )/3Ta(2− x )/3)O3, sintered at 1600°C. The 1:2 ordered structure exists in the composition range 0.0 ≤ x ≤ 0.12, while that of 1:1 ordered structure exists in a wider composition range 0.04 ≤ x ≤ 1.0. Two ordered phases coexist in 0.04 ≤ x ≤ 0.12. High-resolution micrographs indicate that 1:2 and 1:1 ordered domains coexist in one grain. The ordering parameter of 1:2 phase decreases with x , yet that of 1:1 phase increases with x . Both increase with soak time. Variations in ordering are discussed in terms of cation occupancy and crystal chemistry. The quality factor increases with x , reaches a maximum, then decreases with x . The dielectric constant increases with x first, and levels off.  相似文献   

9.
Sb2O5 were selected to substitute (Nb0.8Ta0.2)2O5 and the effects of Sb substitution on the dielectric properties of Ag(Nb0.8Ta0.2)O3 ceramics were studied. The perovskite Ag(Nb0.8Ta0.2)1− x Sb x O3 ceramics showed no obvious change with x value being no more than 0.08, and the pseudoperovskite unit cell parameters a = c , b and monoclinic angle β decrease with Sb concentration increasing. The dielectric properties of Ag(Nb0.8Ta0.2)1− x Sb x O3 ceramics were found to be affected greatly by the substitution of Sb for Nb/Ta. The ɛ value of Ag(Nb0.8Ta0.2)1− x Sb x O3 ceramics sintered at their densified temperature increased from 480 to 825 with x from 0 to 0.08, the tan δ value decreased sharply from 0.0065 to 0.0023 (at 1 MHz) with x increasing from 0 to 0.04, and then kept a stable lower tan δ value ∼0.0024 with x to 0.08. The temperature coefficient of capacitance values continuously decreased from a positive value of 1450 ppm/°C for x =0 to a negative value of −38.52 ppm/°C for x =0.08.  相似文献   

10.
A complete range of perovskite solid solutions can be formed in the (1 − x )Ba(Mg1/3Nb2/3)O3- x La(Mg2/3Nb1/3)O3 (BMN-LMN) pseudobinary system. While pure BMN adopts a 1:2 cation ordered structure, 1:1 ordered phases are stabilized for 0.05 ≤ x ≤ 1.0. Dark-field TEM images indicate that the La-doped solid solutions are comprised of large 1:1 ordered domains and no evidence was found for a phase-separated structure. This observation coupled with the systematic variations in the intensities of the supercell reflections supports a charge-balanced "random-site" model for the 1:1 ordering. The substitution of La also induces a transformation from a negative to positive temperature coefficient of capacitance in the region 0.25 ≤ x ≤ 0.5.  相似文献   

11.
The effect of ZrO2 on crystallographic order, microstructure, and microwave dielectric properties of Ba(Zn1/3Ta2/3)O3 (BZT) ceramics was investigated. A small amount of ZrO2 disturbed the 1:2 cation ordering. The average grain size of the BZT significantly increased with the addition of ZrO2, which was attributed to liquid-phase formation. The relative density increased with the addition of a small amount of ZrO2, but it decreased when the ZrO2 content was increased. Variation of the dielectric constant with ZrO2 addition ranged between 27 and 30, and the temperature coefficient of resonant frequency increased abruptly as the ZrO2 amount exceeded 2.0 mol%. The Q value of the BZT significantly improved with the addition of ZrO2, which could be explained by the increased relative density and grain size. The maximum Q × f value achieved in this investigation was ∼164 000 GHz for the BZT with 2.0 mol% ZrO2 sintered at 1550°C for 10 h.  相似文献   

12.
The crystal structure of lanthanum-modified lead magnesium niobates having composition (Pb1− x La x ) (Mg(1+ x )/3-Nb(2− x )/3)O3 with X = 0 to 1 was investigated by X-ray powder diffraction. It was found that the fundamental reflections from perovskite structure remain in the whole range of composition. The superlattice reflections from the A(B'1/2-B"1/2)O3 ordered structure are also well preserved for La content greater than 50 at.%; however, a series of extra peaks of mixing indices appears, with intensities gradually enhanced with the increase of La content. For the complete substitution of Pb by La, a splitting of some reflections can be observed in the diffraction pattern. The results indicate that the crystal structure evolves continuously with the La content, from disordered cubic perovskite of space group Pm 3 m for X = 0, to ordered cubic perovskite of space group Fm 3 m for X = 0.5, distorted cubic perovskite of space group Pa 3 for 0.5 < X < 0.9, and finally to a rhombohedral perovskite, possibly belonging to the space group R 3 , for X ≥ 0.9. In the evolution of structure, a linear reduction of the lattice constant of the perovskite cell from 4.048 to 3.964 Å was observed.  相似文献   

13.
The crystal structure and microwave dielectric properties of the (1 − x ) La(Zn1/2Ti1/2)O3· x SrTiO3 and (1 − x )La(Zn1/2Ti1/2)O3· x CaTiO3 system were investigated. X-ray powder diffraction showed that cation ordering disappeared at x > 0.3 for both systems. However, infrared spectra demonstrated that short-range cation ordering could exist at x = 0.4. Permittivity and the temperature coefficient of the resonant frequency (τf) of both systems exhibited nonmonotonic variations with composition. Both systems exhibited a τf of zero at the same composition of x = 0.5 although the τf of SrTiO3 was about two times larger than that of CaTiO3. The behavior of the permittivity and τf were described by the tilting of oxygen octahedra and cation ordering. The relation between τf and cation ordering of La(Zn1/2Ti1/2)O3 was discussed in conjunction with the experimental results on metal halides. It is suggested that cation ordering induced a negative τf and suppressed the increase of permittivity for compositions between x = 0 to x = 0.5 for (1 − x )La(Zn1/2Ti1/2)O3· x SrTiO3 and (1 − x )La(Zn1/2Ti1/2)O3· x CaTiO3 systems.  相似文献   

14.
Dielectric properties of A(B3+1/2B5+1/2)O3 (A = Ba, Ca, Sr; B3+= La, Nd, Sm, Yb; B5+= Nb, Ta) ceramics have been investigated at microwave frequencies. Sr(B3+1/2B5+1/2)O3 and Ca(B3+1/2B5+1/2)O3 ceramics have relative dielectric constants (ε r ) above 20 and negative temperature coefficients of resonant frequency (T f ). In the group of Ba(B3+1/2B5+1/2)O3 ceramics, T f changes from + 118 ppm/° to nearly zero according to the kinds of B-site ions. Among the ceramics investigated, Sr(Sm1/2Ta1/2)O3 ceramics have the highest Q values at microwave frequencies. For Sr(Sm1/2Ta1/2)O3 ceramics Q = 7000, ε r = 27.7, and T f =−62.5 ppm/° at 8.5 GHz. The microstructure of Sr(Sm1/2Ta1/2)O3 ceramics is composed of a matrix of the ternary compound (Sr-Sm-Ta-O system) and secondary phase grains of the binary compound (Sm-Ta-O system).  相似文献   

15.
The 1:2 ordering in Ba(Ni1/3Nb2/3)O ceramics sintered at 1350-1500°C has been investigated by using XRD and Raman spectroscopy. Both of the techniques show that the degree of the 1:2 ordering decreases as the sintering temperature increases. However, XRD discerns the 1:2 ordering only for the samples sintered at 1350-1400°C, whereas Raman spectroscopy discerns the 1:2 ordering for all the samples. Similar results have been obtained for Ba(Zn1/3Nb2/3)O3 ceramics, where only the temperature range is slightly different. It is demonstrated that Raman spectroscopy can be a useful tool for probing of the 1:2 ordering in the A(B'II1/3B"V2/3)O3-type complex perovskite compounds.  相似文献   

16.
The hexagonal perovskite, Ba8ZnTa6O24, was prepared in single-phase form and was found to be a stable secondary phase, formed as a result of the loss of ZnO from Ba(Zn1/3Ta2/3)O3 microwave dielectrics. The experimental and calculated X-ray patterns of Ba8ZnTa6O24 indicate it is isostructural with Ba8Ta6NiO24 with an 8H (cchc)2 close-packed BaO3 stacking sequence and the lattice parameters, a =10.0825(14), c =19.0587(38)Å. High-density ceramics of Ba8ZnTa6O24 could be prepared at temperatures considerably lower (1400°C) than those used to sinter pure Ba(Zn1/3Ta2/3)O3, and exhibit very good microwave dielectric properties with ɛ=30.5, Q f=62 300, and τf=+36 ppm/°C at 8.9 GHz.  相似文献   

17.
The sintering behavior and dielectric properties of perovskite Ag(Nb1− x Ta x )O3 (0 < x < 1) solid solutions and two-phase composite assemblages were explored. A small amount of CuO (1 wt%) was used for liquid-phase sintering and led to high densification at temperatures <950°C. The temperature coefficient of capacitance, TCC, was adjusted by varying the Nb:Ta ratio within the solid-solution series and by creating composite microstructures. Two-phase assemblages consisting of Ag(Nb3/4Ta1/4)O3 and Ag(Nb1/4Ta3/4)O3 were synthesized to achieve a temperature-stable dielectric material for high-frequency applications. The composite dielectric with CuO addition had an average dielectric constant of 390 and a Q × f factor of 410 GHz at 2 GHz, with a stable TCC (0 to −180 ppm/°C) in the temperature range from −20° to +60°C. In addition, process compatibility with a silver conductor was confirmed by high-frequency ring-resonator measurements and microstructural characterization. The Ag(Nb1− x Ta x )O3 solid solutions and composites are promising candidates as embedded capacitors for radio-frequency/microwave applications.  相似文献   

18.
The dielectric properties at microwave frequencies of Ba(Zn1/3Ta2/3)O3 ceramics prepared by sintering were investigated. These ceramics had lower density but higher loss quality than ceramics hot-pressed at 1400°C. Loss quality was greatly improved by prolonged sintering. The Q of the ceramics measured by the dielectric resonator method was 14 000 at 12 GHz. The ceramics were investigated by X-ray diffraction analysis. It was found that Q improvement corresponds with increased Zn and Ta ordered structures in the ceramics.  相似文献   

19.
20.
The sol–gel method has been developed for the preparation of pure Ba(Mg1/3Ta2/3)O3 ceramics. This involves the reaction of the heterometallic alkoxide Ta2Mg(OEt)12 with hydrated barium hydroxide Ba(OH)2·8H2O. Complete crystallization of the sol–gel-derived powder is achieved at 600°C, leading to a cubic perovskite type phase. After sintering at 1400°C (2–5 h), a trigonal cell arises from Mg–Ta ordering (the degree of order is greater than 0.9), and about 98.5% of the theoretical density is obtained. Preliminary microwave dielectric measurements show that the dielectric constant and the unloaded Q u of the ceramics are 24.2 and 6750, respectively, at 7.7 GHz.  相似文献   

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