Application of thermochromic colorants on textiles: temperature dependence of colorimetric properties

Commercial thermochromic colorants were applied to a conductive cotton fabric prepared by using nichrome/cotton core‐spun yarns in weft and 100% cotton in warp. The fabrics were pretreated and coloured with thermochromic pigments in isolation, in combination with each other, or in a mixture with a non‐thermochromic pigment. The weft yarns were joined to allow passage of current through the fabric to enable ohmic heat generation to increase fabric temperature. The heat generation and temperature rise could be controlled by monitoring the voltage applied. The colour of the samples changed gradually with an increase in temperature, and significantly so when the temperature of the fabric rose beyond the activation temperature of the thermochromic colorant. The temperature‐dependent properties of commercial thermochromic colorants were determined using a spectrophotometer. Wash fastness of the samples was found to be fair in all cases except with the yellow colorant. Predetermined colour effects, such as camouflage or novel design, can be produced by combining thermochromic colorants with conventional pigments or thermochromic colorants with different activation temperatures.     

An unsupervised method for dominant colour region segmentation in yarn‐dyed fabrics

This paper presents a novel unsupervised approach to detect dominant colour regions standing out conspicuously in yarn‐dyed fabric images. For a dominant colour region of a yarn‐dyed fabric, measured by an imaging system, its individual yarn has an irregular three‐dimensional shape resulting in significant colour difference among pixels of the yarn. This difference leads to difficulty in segmenting yarns into dominant colour regions. A probabilistic model is proposed in this study to associate the colour of a dominant colour region with the colours of its yarns. Based on this model, the colour histograms of a dominant colour region are first estimated from those of yarns in a yarn‐dyed fabric image. Then, a hierarchical segmentation structure is devised to detect dominant colour regions in the image. Experimental results show that the proposed approach achieves satisfactory performance for dominant colour region segmentation in yarn‐dyed fabric images, with high computational efficiency.     

A novel method for weft and warp yarn segmentation in multicolour yarn‐dyed fabric images

This paper proposes a novel method for segmentation of weft and warp yarns in multicolour yarn‐dyed fabric images. A multicolour yarn‐dyed fabric is cross‐woven by weft and warp yarns with different colours. When a multispectral imaging system is used to measure the colour of a multicolour yarn‐dyed fabric image, its weft and warp yarns need to be detected before analysing their colours. Detection of interstices between weft and warp yarns is firstly conducted. A modified K‐means clustering approach is then utilised to separate weft and warp yarns. The number of clusters is fixed to 2. The metric to measure the distance between a pixel and the mean of a cluster is the CIELAB colour difference. The initial means are determined by the expected values of fitted Gaussian distributions to CIExyY colour histograms. Experimental results show that the proposed method is promising for the segmentation of weft and warp yarns in multicolour yarn‐dyed fabrics, with an improved segmentation accuracy and much faster processing speed than K‐means clustering in CIEXYZ and CIELAB spaces.     

Comparison of tensile,thermal, and thermo‐mechanical properties of polyester filaments having different cross‐sectional shape

One of the most important morphological features of fibers is their cross‐sectional shape. Nowadays, the circular fiber cross‐section is the most common shape of melt‐spun man‐made fibers. Other shapes are beginning to emerge for a variety of reasons such as performance, comfort, pilling propensity, bulkiness, tactility, processing etc. The filaments' cross‐section can be easily varied by changing the spinneret hole shape. Synthetic fibers that are predominantly spun by the melt spinning method with spinnerets having the noncircular hole geometry are called profiled or noncircular fibers. Modifications of the fiber cross‐section allow designing surface properties in yarn and fabric. However, the effect of profiled fibers on yarn properties has not been well documented yet. In this article, the influence of different filament cross‐section geometry on fiber properties was studied. PET (polyethylene terephthalate) filament yarns having two different cross‐sectional shaped filaments, circular and cruciform, were manufactured by melt spinning. Differences in tensile properties of filament yarn and as well as of individual filament depending on the cross‐sectional type were studied and revealed. More over, thermal and thermomechanical properties of filament yarn of both the cross‐sections were studied and revealed by DSC and TMA method, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Analysis of spinning process parameters on development of spun‐dyed PET yarn using the Taguchi method

The yarn tenacity of a spun‐dyed yarn is predicted from the spinning conditions and other properties of the yarn are analyzed through the defined parameters using the Taguchi method. To develop a spun‐dyed yarn using the Taguchi method, four factors that can largely influence the yarn properties are selected. From the experimental design based on four factors, the processes are executed to produce the specific yarns whose properties are measured to analyze the relationship between the process conditions and their results. The target properties of a spun‐dyed yarn may be obtained through adjusting the spinning parameters that are related to the yarn properties by the Taguchi tool. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:1419–1427, 2006     

14．8tex麻浆纤维赛络纺纱实践

通过对14．8tex纯纺麻浆纤维赛络纺纱的实践,探讨了赛络纺麻浆纤维各工序工艺配置及应注意的问题。结果表明：开清棉、梳棉、并条、粗纱、细纱和络简工序的工艺优化配置,赛络纺纺出纱线的成纱质量远优于环锭纱的成纱质量,用其织成的面料抗起球性能高,抗摩擦性能好,手感柔软,服用性能佳。     

Properties of cotton yarns after slack swelling and stretching in presence or absence of alkali. II

An investigation on the properties of solution‐stretched ring spun and rotor spun cotton yarns at regular time intervals was made. Significant changes in the properties of these yarns are observed. The changes in fine structure are evaluated by means of infra red spectroscopy and X‐ray diffraction methods. Ring spun cotton yarns exhibit better abrasion resistance than do rotor spun yarns. Abrasion resistance of NS‐ring and rotor spun yarns is higher than their counter parts. WS‐ring spun yarns are characterized by higher compression values, explaining the softness produced by the stretching treatment. The dyeability of the treated yarns is also studied with reactive dye, and the color values are found to be significantly greater for WS‐ring and rotor spun yarns. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Determining the dependence of colour values on yarn structure

The colour values of knitted cotton fabrics made from single and plied ring and compact yarns were investigated before and after dyeing. The fabric samples were knitted under the same constructional properties and then dyed with direct and reactive dyes. It was found that fabrics with ring yarns had high lightness and low chroma and colour strength values compared with fabrics with compact yarns. Also colour strength and colour difference values of dyed fabrics were assessed after increasing abrasion cycles (2500, 5000, 7500 and 10 000). The main changes in colour strength values were observed at 2500 abrasion cycles. The effect of abrasion on colour difference values of fabrics having ring yarns was more obvious than fabrics having compact yarns.     

氨纶包芯纱的纺制、结构性能及应用研究

氨纶包芯纱织物因其芯丝优良的弹性及外包纤维不同风格的表面特性,一直受到消费者的青睐。文章以环锭纺为例对氨纶包芯纱的纺纱原理、结构特点、力学性能及应用进行了研究探讨。     

Structure development of poly(L‐lactic acid) fibers processed at various spinning conditions

Poly(L ‐lactic acid) (PLA) filaments were spun by melt‐spinning at 500 and 1850 mm^?1, and further drawn and heat‐set to modify the morphology of these PLA filaments. PLA yarns were characterized by wide‐angle X‐ray diffraction (WAXD) and sonic method. WAXD reveals that PLA yarns spun at 500 mm^?1 are almost amorphous while the PLA filaments spun at 1850 mm^?1 have about 6% crystallinity. This is different from PET filaments spun at the same speed that have almost no crystallinity. Both drawn‐ and heat‐set PLA filaments showed much higher crystallinity (60%) than do as‐spun fibers produced at 500 and 1850 mm^?1 speed, which is also higher than the usual heat‐set PET yarns. It appears that crystalline orientation rapidly reaches a value in the order of 0.95 at 1850 mm^?1 and that drawn‐ and heat‐set yarns have almost the same crystalline orientation values. Molecular orientation is relatively low for as‐spun PLA yarn, and molecular orientation increased to ～0.5 after drawing or heat–setting or both. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1210–1216, 2006     

Novel hydrolysable azo disperse dyes based on N‐ester‐1,8‐naphthalimide: dyeing of polyester–cotton blends

The dyeing of polyester–cotton blends with new alkali‐hydrolysable azo disperse dyes based on N‐ester‐1,8‐naphthalimide was investigated. Polyester–cotton blend fabrics were dyed using both one‐ and two‐bath methods. Dyes 3 and 4 offered lower colour yield on polyester using the one‐bath method. For the rest of the dyes, employing either the one‐ or two‐bath method resulted in a similar colour yield on polyester fabric. The results for fastness properties and colour yield of the dyeings showed that the dyes were suitable for dyeing polyester–cotton blends using the one‐bath method. The kinetic study of hydrolysis of the dyes in alkali media obeyed the pseudo first‐order reaction rate.     

Crosslinking of poly(N‐vinyl‐2‐pyrrolidone) in the coating of cotton yarn

Coating of cotton yarn is employed in the textile industry to increase the mechanical resistance of the yarns and resistance to vibration, friction, impact, and elongation, which are some of the forces to which the yarn is subjected during the weaving process. The main objective of this study is to investigate the usage of a synthetic hydrophilic polymer, poly(N‐vinyl‐2‐pyrrolidone) (PVP), to coat 100% cotton textile yarn, aiming to give the yarn a temporary mechanical resistance. For the improvement of the mechanical resistance of the yarn, the following crosslinking processes of PVP were investigated: UV‐C (ultraviolet) radiation, the Fenton and photo‐Fenton reactions, and sensitized UV‐C radiation. The influence of each crosslinking process was determined through tensile testing of the coated yarns. The results indicated that the best crosslinking process employed was UV‐C radiation; increasing the mechanical resistance of the yarn up to 44% if compared with the pure cotton yarn, that is, without polymeric coating and crosslinking. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers.     

Optimal yarn colour combination for full‐colour fabric design and mixed‐colour chromaticity coordinates based on CIE chromaticity diagram analysis

It is challenging for textile designers to achieve full‐colour effects in woven fabric using a limited set of coloured yarns. The common problems encountered during full‐colour fabric design include an insufficient number of colours and a failure to match the fabric colour with the desired colour. Using the theories of primary colours and optical colour mixing, we examine the mixed‐colour distribution of primary colour yarns on the basis of the CIE 1976 chromaticity diagram (CIE u′v′). In our experiment, dope‐dyed polyester filament yarns were selected as raw materials. Eight kinds of gradually varied weave structures and four types of primary colour combination were adopted in order to make different types of full‐colour fabric colour chart. Spectrophotometer and DigiEye colour measurement systems were selected to measure the reflectance and colour value of the fabric samples. By comparing the colour distribution of mixed fabrics in the CIE u′v′ diagram, the relationship between the primary colour combinations and the colour distribution of mixed fabrics is discussed. Of RGB, CMY, NCS, and RGBCMY combinations, only RGBCMY resulted in a relatively complete and large colour gamut. Moreover, the colour positions of mixed fabrics in the CIE u′v′ diagram were almost all distributed on or near the connecting line of the primary colour coordinates. The specific colour position of mixed fabrics in the CIE u′v′ diagram were mainly determined by the proportion of primary colours on the fabric surface. In this way, a new method for computing colour position in the CIE u′v′ diagram is introduced.     

Automatic detection of layout of color yarns of yarn‐dyed fabric. Part 3: Double‐system‐Mélange color fabrics

Automat layout detection of color yarns is necessary for weaving and producing processes of yarn‐dyed fabrics. This study presents a novel approach to inspect the layout of color yarns of double‐system‐mélange color fabrics automatically, which is Part III of the series of studies to develop a computer vision‐based system for automatic inspection of color yarn layout for yarn‐dyed fabrics. The inspection of single‐system‐mélange color fabrics has been realized in Part I of the series of studies. Integrating the projection‐based region segmentation method proposed in Part I and the FCM‐based stepwise classification method proposed in Part II, the proposed approach is composed of three steps: (1) fabric region segmentation, (2) fabric region selection, and (3) layout of color yarns recognition. In the first step, the fabric regions are segmented by the projection‐based region segmentation method. In the second step, the reasonable fabric regions are selected by analyzing their color histograms and comparing their weft color's frequency. In the third step, the layout of color yarn is recognized by the FCM‐based stepwise classification method, and the precise layouts of color warps and wefts are produced. The experimental analysis proved that the proposed method can recognize the layout of color yarns of double‐system‐mélange color fabrics correctly by testing four different color fabrics and three pieces of same yarn‐dyed fabrics. © 2016 Wiley Periodicals, Inc. Col Res Appl, 42, 250–260, 2017     

An efficient method for solid‐colour and multicolour region segmentation in real yarn‐dyed fabric images

This paper presents an efficient approach to solid‐colour and multicolour region segmentation in real yarn‐dyed fabric images. The approach is based on a novel model describing the spectral response of a multispectral imaging system to yarn‐dyed fabrics. The model indicates that solid‐colour regions cannot be distinguished from multicolour regions in terms of reflectance, tristimulus, or CIELAB values owing to a geometric term representing the influence of fabric surface condition on measured colours. The geometric term makes it difficult to determine the segmentation thresholds of CIEXYZ and CIELAB colour histograms. However, solid‐colour and multicolour regions can be detected in CIExyY space because chromaticity coordinates are impervious to the geometric term. The CIExyY histograms of a solid‐colour region accord with one Gaussian distribution, but those of a multicolour region accord with a combination of two Gaussian distributions. The CIEXYZ, CIELAB, and CIExyY colour distributions of both solid‐colour and multicolour yarn‐dyed fabrics were analysed in detail in simulation and real experiments. Experimental results show that solid‐colour yarn‐dyed regions can be distinguished from multicolour yarn‐dyed fabric regions by the shapes of CIExyY histograms, but cannot be distinguished by the shapes of CIEXYZ or CIELAB histograms.     

热塑性树脂基复合材料用摩擦纺混纤纱

对连续纤维增强热塑性树脂基复合材料，增强纤维和热塑性树脂的结合是这类复合材料加工的难点。从９０年代起，Ｗｕｌｆｈｏｒｓｔ等探索性地研究了用摩擦纺方法将增强纤维和树脂纤维一起加工成热塑性复合材料用混纤纱。本文对这种摩擦纺混纤纱加工方法进行一步讨论，纺制了进一步讨论，纺制了几种混纤纱并通过扫描电镜和纱线均匀度测试仪研究了其结构。     

Electrospun self‐assembled nanofiber yarns

A technique for making self‐assembled electrospun (E‐spun) nanofiber yarns from poly(acrylonitrile) in a single step is described. The process involved formation of the nanofiber yarn directly within the electrospinning zone and its removal before it can reach the counter‐electrode. The yarn is presumably formed due to splitting of the main jet into numerous nanojets and their reassembly into a single entity midway between the two electrodes. The process was found to occur at a particular field strength, which varied considerably with the concentration of the polymer dope. The gross morphology of yarns and the alignment of nanofibers in the yarn were evaluated by scanning electron microscopy (SEM). The rationale behind the formation of the yarn like structure has been explained. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Fabrication of continuous nanofiber yarn using novel multi‐nozzle bubble electrospinning

A novel multi‐nozzle bubble electrospinning apparatus, including spinning unit, metering pump, constant flow pump, metal funnel and yarn winder, was designed for the preparation of continuous twisted polyacrylonitrile nanofiber yarns, and the principle of nanofiber yarn spinning was studied. An innovative spinning unit consisting of nozzle and air chamber was used to improve the production of nanofibers. Double conjugate electrospinning was developed using two pairs of oppositely charged spinning units to neutralize the charges. The effects of applied voltage, air flow rate, overall solution flow rate and funnel rotary speed on the fiber diameter, production rate and mechanical properties of the nanofiber yarns were analyzed. Nanofibers could be aggregated stably and bundled continuously, then twisted into nanofiber yarns uniformly at an applied voltage of 34 kV, air flow rate of 1200 mL min^?1 and overall solution flow rate of 32 mL h^?1. With an increase in the funnel rotary speed, the twist angle of the nanofiber yarns gradually increased when the take‐up speed was constant. The yarn tensile strength and elongation at break showed an increasing trend with increasing twist angle. Nanofiber yarns obtained using this novel method could be produced at a rate from 2.189 to 3.227 g h^?1 with yarn diameters ranging from 200 to 386 µm. Nanofiber yarns with a twist angle of 49.7° showed a tensile strength of 0.592 cN dtex^?1 and an elongation at break of 65.7%. © 2013 Society of Chemical Industry     

Melt spinning and drawing of 2‐methyl‐1,3‐propanediol‐substituted poly(ethylene terephthalate)

The structure and properties of fibers prepared from copolymers of poly(ethylene terephthalate) (PET) in which 2‐methyl‐1,3‐propanediol (MPDiol® Glycol is a registered trademark of Lyondell Chemical Company) at 4, 7, 10, and 25 mol% was substituted for ethylene glycol were studied and compared with those of PET homopolymer. Filaments were melt spun over a range of spinning conditions, and some filaments that were spun at relatively low spinning speeds were subjected to hot drawing. The filaments were characterized by measurements of birefringence, differential scanning calorimetry (DSC) crystallinity, melting point, glass transition temperature, wide‐angle X‐ray diffraction patterns, boiling water shrinkage, tenacity, and elongation to break. Filaments containing 25 mol% MPDiol did not crystallize in the spinline at any spinning speed investigated, whereas the other resins did crystallize in the spinline at high spinning speeds. However, compared with PET homopolymer, increasing substitution of MPDiol reduced the rate at which the crystallinity of the melt spun filaments increased with spinning speed and reduced the ultimate crystallinity that could be achieved by high‐speed spinning. The rate of development of molecular orientation, as measured by birefringence, also decreased somewhat with increasing MPDiol content. Shrinkage in boiling water decreased at high spinning speeds as the amount of crystallinity increased; however, the shrinkage decreased more slowly with increase in spinning speed as MPDiol content increased. Tenacity also decreased slightly at any given spinning speed as MPDiol content increased, but there was no significant effect on elongation to break. The addition of MPDiol in amounts up to 7 mol% increased the maximum take‐up velocity that could be achieved at a given mass throughput. This result indicates that the use of higher spinning speeds could potentially increase the productivity of melt spun yarns. Copolymer filaments spun at low speeds were readily drawn to produce highly oriented fibers with slightly less birefringence, crystallinity, and tenacity than similarly processed PET homopolymer. Preliminary dyeing experiments showed that the incorporation of MPDiol improved the dyeability of the filaments. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2598–2606, 2003     

Colour gamut of natural dyes on cotton yarns

Cotton fibres were dyed using various natural dyes alone and in combination to yield six basic shades: blue, yellow, red, black, green and fawn. These dyed fibres were then blended in various proportions along with undyed cotton fibres and spun on a rotor-spinning machine to produce 204 coloured yarns. The fastness properties of the six basic shades were determined. The L * a * b * and L * C * h values of the yarns having 50% dyed fibre and 50% undyed cotton fibre was also determined. The values were plotted to obtain the colour gamut of natural dyes on cotton yarns.