EDTA excess Zn(II) back-titration in the presence of 4-(2-pyridylazo)-resorcinol indicator and naphthol green beta as inert dye for determining Cr(III) as Cr(III)/EDTA complex: application of the method to a leather industry wastewater

The colour changes of 4-(2-pyridylazo)-resorcinol and naphthol green beta as new screening metallochromic indicator in back-titration of EDTA excess with Zn(II) to determine Cr(III)/EDTA complex was investigated with the help of tristimulus colorimetry. Specific colour discrimination (SCD) and L*, a*, b* 1976 parameters were successfully applied to evaluate the quality of colour transition at the end-point in non-alkaline media and in the presence of Zn(II) and Ca(II) which resulted in non-interfering species at 1x10(-3) M and 2x10(-3) M, respectively. The above concentrations are comparable with those used for Cr(III). Validation of the fast and accurate reported method was performed by atomic absorption spectroscopy. Moreover, the method was applied for determining Cr as Cr(III) in a wastewater effluent deriving from a leather industry.     

A DDC-based capacity controller of a direct expansion (DX) air conditioning (A/C) unit for simultaneous indoor air temperature and humidity control – Part II: Further development of the controller to improve control sensitivity

The development of the novel direct digital control (DDC)-based capacity controller for a direct expansion (DX) air conditioning (A/C) unit having variable-speed compressor and supply fan to simultaneously control indoor air temperature and relative humidity (RH) in a conditioned space served by the DX A/C unit has been reported in Part I of the two-part series. The results of preliminary controllability tests for the novel capacity controller presented in Part I, however, suggested that the controller developed was operational, with acceptable control accuracy but rooms for improvement with respect to control sensitivity. This paper, the second part of the two-part series, reports on the further development of the controller to improve its control sensitivity and the associated controllability test results. Both control accuracy and reasonable control sensitivity were achieved by incorporating a traditional Proportional–integral (PI) controller into the DDC-based capacity controller.