Polyvinylpyrrolidone/polyaniline (PVP/PANI) with additives (TiO2, ZnO, NaCl and Na2SO4) was synthesized. To spread the electric and photoelectric applications of PVP/PANI, its photodegradation under UV irradiation was studied by Fourier transform infrared spectroscopy, diffuse reflectance spectroscopy, water uptake and scanning electron microscopy. Results show that ZnO, TiO2 and NaCl accelerate the photodegradation, respectively, but Na2SO4 stabilized PVP/PANI. The degradation rate of PVP/PANI/tert-butyl alcohol and PVP/PANI/ascorbic acid proved the radical role. Water uptake results show that the power of interactions is in this order: PVP/PANI/Na2SO4?>?PVP/PANI/TiO2?>?PVP/PANI/ZnO?>?PVP/PANI?>?PVP/PANI/NaCl?>?PVP/PANI/tert-butyl alcohol>PVP/PANI/ascorbic acid. 相似文献
Polyaniline (PANI) has been prepared by the oxidation of aniline with ammonium peroxydisulfate in the 0-4 M phosphoric acid. The maximum conductivity of PANI, 15.5 S cm−1, was found with PANI prepared in the presence of 1 M phosphoric acid. The mass loss after deprotonation with ammonium hydroxide revealed that relatively large amounts of phosphoric acid were associated with PANI if the polymerization had been carried out at higher acid concentration. This suggests the protonation of both the imine and amine nitrogens in PANI, the increased adsorption of phosphoric acid by PANI, or the presence of polyphosphate counter-ions. The increasing content of phosphoric acid is also reflected in the increase of sample density. FTIR spectra of ammonium salts collected after deprotonation proved that the counter-ions of the sulfate type, resulting from the decomposition of peroxydisulfate, always participated in the protonation of PANI. The proportion of sulfate to phosphate counter-ions was reduced as the concentration of phosphoric acid in the medium increased.Thin PANI films were produced in situ on glass surfaces immersed in the reaction mixture during the polymerization of aniline. Optical absorption has been used to assess their thickness, 70-140 nm, which was found to be virtually independent of the acid concentration. The film conductivity was comparable with the conductivity of the PANI powders produced at the same time. Colloidal dispersions were obtained when the reaction mixture contained poly(N-vinylpyrrolidone). The particle size, 200-260 nm, and polydispersity, determined by dynamic light scattering, were virtually independent of the concentration of phosphoric acid. The films produced on glass during the dispersion polymerization of aniline were thinner, 20-90 nm, compared with those grown in the precipitation polymerization. 相似文献
A new process for the synthesis of high conductivity polyaniline/Ag/graphite nanosheet (PANI/Ag/NanoG) composites was developed.
Graphite nanosheet was prepared by treating the expanded graphite in aqueous alcohol solution using sonication, and a uniform
silver film about 470 nm thick was obtained on graphite nanosheet surface via an improved electroless plating method. Then
PANI/Ag/NanoG composites were fabricated via in situ polymerization of aniline monomer in the presence of silver coated graphite
nanosheet through using ultrasonic technique. The sliver particles and composites were evidenced by scanning and transmission
electron microscopy examinations, the results showed that the silver coated graphite nanosheet particles played an important
role in forming conducting bridge in polyaniline matrix. According to the electrically test, the conductivity of the PANI/Ag/NanoG
composites was dramatically increased compared with pure PANI. From the thermogravimetric analysis, the PANI/Ag/NanoG composites
exhibited a beneficial effect on the thermal stability of pure PANI. 相似文献
Summary: The compatibilization of polyethylene/polyaniline (PE/PANI) blends and the preparation of plasticized PANI/camphorsulfonic acid (CSA) complexes suitable for melt blending were studied. Rheological properties of the components essentially affected the morphology of the blend and thereby the electrical conductivity. The hydrogen bonds between the PANI complex and the functionalized metallocene PE used as compatibilizer compensated the unfavorable viscosities of the components. Mechanical properties of PE/PANI blends were improved, and electrical conductivity of the blends remained the same or increased through addition of functionalized metallocene polyethylene. Plasticized PANI/CSA complex with good electrical conductivity was successfully prepared.
Compatibilization of PANI/CSA complex and OH‐functionalized polyethylene. 相似文献
PANI/SWCNT composites were prepared by electrochemical polymerisation of polyaniline onto SWCNTs and their capacitive performance was evaluated by means of cyclic voltammetry and charge-discharge cycling in 1 M H2SO4 electrolyte. The PANI/SWCNT composites single electrode showed much higher specific capacitance, specific energy and specific power than pure PANI and SWCNTs. The highest specific capacitance, specific power and specific energy values of 485 F/g, 228 W h/kg and 2250 W/kg were observed for 73 wt.% PANI deposited onto SWCNTs. PANI/SWCNT composites also showed long cyclic stability. Based upon the variations in the surface morphologies and specific capacitance of the composite, a mechanism is proposed to explain enhancement in the capacitive characteristics. The PANI/SWCNT composites have demonstrated the potential as excellent electrode materials for application in high performance supercapacitors. 相似文献