Effects of rapid thermal annealing on ohmic contact of AIGaN/GaN HEMTs

Ohmic contacts with Ti/Al/Ti/Au source and drain electrodes on A1GaN/GaN high electron mobility transistors （HEMTs） were fabricated and subjected to rapid thermal annealing （RTA） in flowing N2. The wafer was divided into 5 parts and three of them were annealed for 30 s at 700, 750, and 800 ℃, respectively, the others were annealed at 750 ℃ for 25 and 40 s. Due to the RTA, a change from Schottky contact to Ohmic contact has been obtained between the electrode layer and the A1GaN/GaN heterojunction layer. We have achieved a low specific contact resistance of 7.41 × 10-6Ω cm2 and contact resistance of 0.54 Ω.mm measured by transmission line mode （TLM）, and good surface morphology and edge acuity are also desirable by annealing at 750 ℃ for 30 s. The experiments also indicate that the performance of ohmic contact is first improved, then it reaches a peak, finally degrading with annealing temperature or annealing time rising.     

关于石墨烯上Ge/Au/Ni/Au欧姆接触的对比研究

Superior graphene-metal contacts can improve the performance of graphene devices. We report on an experimental demonstration of Ge/Au/Ni/Au-based ohmic contact on graphene. The transfer length method （TLM） is adopted to measure the resistivity of graphene-metal contacts. We designed a process flow, which can avoid residual photoresist at the interface of metal and graphene. Additionally, rapid thermal annealing （RTA） at different temperatures as a post-processing method is studied to improve graphene-metal contact. The results reveal that the contact resistivity of graphene and Ge/Au/Ni/Au can reach 10^-5 Ω· cm^2 after RTA, and that 350 ℃ is optimum annealing temperature for the contact of graphene-Ge/Au/Ni/Au. This paper provides guidance for fabrication and applications of graphene devices.     

p-GaN Ni/Au 电极退火后NiO的除去

The Ni/Au contact was treated with oxalic acid after annealing in 02 ambient, and its 1-V characteristic showed the property of contact has been obviously improved. An Auger electron spectroscopy （AES） depth profile of the contact as-annealed showed that the top layer was highly resistive NiO, while an X-ray photo-electron spectroscopy （XPS） of oxalic acid treated samples indicated that the NiO has been removed effectively. A scanning electron microscope （SEM） was used to observe the surface morphology of the contacts, and it was found that the lacunaris surface right after annealing became quite smooth with lots of small Au exposed areas after oxalic acid treatment. When the test probe or the subsequently deposited Ti/Au was directly in contact with these small Au areas, they worked as low resistive current paths and thus decrease the specific contact resistance.     

Ti/WSi/Ni ohmic contact to n-type SiCN

Ti/WSi/Ni contact to n-type SiCN was investigated using the circular transmission line method. Current–voltage characteristics, X-ray diffraction and X-ray photoelectron spectroscopy were used to characterize the contacts before and after annealing. It is shown that the conducting behavior of the contacts is dependent on the annealing temperature. After annealing at 900 ℃ or above, ohmic contacts with specific contact resistivity were achieved. The 1000-℃-annealed contact exhibits the lowest specific contact of 3.07E-5 Ω? cm2. The formation of ohmic contact with low specific contact resistivity was discussed.     

Lateral diffusion effects in AuGe based source-drain contacts to AllnAs/InGaAs/InP doped channel MODFETs

We have investigated the formation of source-drain AuGe/Au and Ni/AuGe/Ni/Au alloyed ohmic contacts to AlInAs/InGaAs/InP doped channel MODFETs, and observed lateral diffusion of the contact system after the standard annealing procedure at the temperature range of 185 to 400°C. Auger depth profiling of contacts annealed at 250°C, revealed that Au(Ge) diffused through the top InGaAs and AlInAs layers into the active InGaAs layer, but had reduced penetration into the AlInAs buffer layer. This reduction in diffusion along the depth axis at the AlInAs buffer layer boundary is believed to result in enhanced lateral diffusion and the observed lateral encroachment of the contacts. Both Au and Ni containing contact systems showed similar behavior in terms of lateral diffusion with encroachment extending between 0.25 and 0.5 μm at the periphery of the contacts for annealing temperatures between 300 and 400°C. A controlled ramp-to-peak temperature annealing procedure is developed to suppress such lateral diffusion effects. Low temperature annealing (250°C) using this procedure resulted in equally low contact resistance values (∼0.1Θ-mm) and no lateral diffusion. It is concluded that in thin multilayered structures the modified annealing procedure presented here, is necessary for optimal ohmic contact formation.     

The behavior of Ni/Au contacts under rapid thermal annealing in GaN device structures

The effect of rapid thermal annealing (RTA) on Ni/Au contacts on P-type GaN was investigated in terms of surface morphology and diffusion depth of metallic species. Ni/Au contacts were evaporated on the P-type 0.5 μm thick top layer of a GaN P/N homojunction. Optical micrographs revealed that the contact morphology degrades when annealed above 800°C for 1 min. At the same time, both Ni and Au atoms strongly diffuse in the P-type layer and even can reach the junction for a 1 min long annealing at 900°C, therefore making the junction structure unoperable. This behavior was evidenced using the Auger voltage contrast (AVC) technique.     

Au/Pt/AuGe/Ni中Pt扩散阻挡层对n-GaAs欧姆接触的影响

The multi-layer metals of Ni/Au Ge/Pt/Au with a Pt diffusion barrier layer of ohmic contact to n-GaAs were studied. The surface morphology and ohmic contact resistivity of multi-layer metals were characterized, with and without the Pt diffusion barrier layer for comparison. The SEM and EDS measurements show the Pt diffusion barrier layer can block the interdiffusion of atoms in multi-layer metals, and improve the surface morphology.The TLM results show that the samples with a Pt diffusion barrier layer have uniform ohmic contact resistance,indicating that the Pt diffusion barrier layer can increase the repetition and uniformity of ohmic contact to n-GaAs,and improve the thermal stability and reliability of GaAs-based devices.     

Optimization of the base electrode for InGaAs/InP DHBT structures with a buried emitter-base junction

We have optimized the base electrode for InGaAs/InP based double heterojunction bipolar transistors with a buried emitter-base junction. For the buried emitter-base structure, the base metal is diffused through a thin graded quaternary region, which is doped lightly n-type, to make ohmic contact to the p⁺InGaAs base region. The metal diffusion depth must be controlled, or contact will also be made to the collector region. Several metal schemes were evaluated. An alloy of Pd/Pt/Au was the best choice for the base metal, since it had the lowest contact resistance and a sufficient diffusion depth after annealing. The Pd diffusion depth was easily controlled by limiting the thickness to 50?, and using ample Pt, at least 350?, as a barrier metal to the top layer of Au. Devices with a 500? base region show no degradation in dc characteristics after operation at an emitter current density of 90 kA/cm² and a collector bias, V_CE, of 2V at room temperature for over 500 h. Typical common emitter current gain was 120. An f_t of 95 GHz and f_max, of 131 GHz were achieved for 2×4 μm² emitter size devices.     

采用Ni/Ti/Ni多层金属在N型4H-SiC衬底改善粘附性和界面的欧姆接触

The Ni/Ti/Ni multilayer ohmic contact properties on a 4H-SiC substrate and improved adhesion with the Ti/Au overlayer have been investigated. The best specific contact resistivity of 3.16 × 10^-5 Ω.cm^2 was obtained at 1050 ℃. Compared with Ni/SiC ohmic contact, the adhesion between Ni/Ti/Ni/SiC and the Ti/Au overlayer was greatly improved and the physical mechanism under this behavior was analyzed by using Raman spectroscopy and X-ray energy dispersive spectroscopy （EDS） measurement. It is shown that a Ti-carbide and Ni-silicide compound exist at the surface and there is no graphitic carbon at the surface of the Ni/Ti/Ni structure by Raman spectroscopy, while a large amount of graphitic carbon appears at the surface of the Ni/SiC structure, which results in its bad adhesion. Moreover, the interface of the Ni/Ti/Ni/SiC is improved compared to the interface of Ni/SiC.     

Low ohmic contact AIN/GaN HEMTs grown by MOCVD

AlN/GaN high-electron-mobility transistors （HEMTs） on SiC substrates were fabricated by metalorganic chemical vapor deposition （MOCVD） and then characterized. An Si/Ti/Al/Ni/Au stack was used to reduce ohmic contact resistance （0.33 g2.mm） at a low annealing temperature. The fabricated devices exhibited a maximum drain current density of 1.07 A/mm （Vows = I V） and a maximum peak extrinsic transconductance of 340 mS/mm. The off-state breakdown voltage of the device was 64 V with a gate-drain distance of 1.9 μm. The current gain extrinsic cutoff frequency fT and the maximum oscillation frequency fmax were 36 and 80 GHz with a 0.25 μm gate length, respectively.     

Specific contact resistivity of InGaAs/InP p-isotype heterojunctions

The specific contact resistivity of lattice matched InGaAs/InP p-isotype heterojunction has been measured through the use of an interface transmission line model structure. The measured resistance values are comparable to or greater than those of the metal/semiconductor interface and depend heavily on the doping and the abrupt or graded nature of the interface.<>     

Current crowding on metal contacts to planar devices

A simple transmission line model is applied to the contact region between metal and diffusion layer in planar devices. Taking into account the sheet resistance of the diffusion layer and an ohmic specific contact resistance between metal and semiconductor the theoretical current distribution across the contact is calculated and compared with the results obtained with a model suggested by Kennedy and Murley. Experimental data are given that confirm the validity of the transmission line model.     

InP/InGaAs HBTs with n+-InP contacting layers grown byMOMBE using SiBr4

InP/InGaAs heterojunction bipolar transistors (HBTs) with low resistance, nonalloyed TiPtAu contacts on n⁺-InP emitter and collector contacting layers have been demonstrated with excellent DC characteristics. A specific contact resistance of 5.42×10^-8 Ω·cm², which, to the best of our knowledge, is the lowest reported for TiPtAu on n-InP, has been measured on InP doped n=6.0×10¹⁹ cm^-3 using SiBr₄. This low contact resistance makes TiPtAu contacts on n-InP viable for InP/InGaAs HBTs     

Large-signal computer simulations of the contact, circuit, and bias dependence of X-band transferred electron oscillators

We present a treatment synthesizing the roles of the contact and the circuit forX-band length transferred electron devices sustaining self-excited oscillations. The contact is modeled with specific cathode electric-field relations. The circuit is modeled with lumped elements. The scope of the simulation is relevant to both high-efficiency InP oscillations and the moderate-efficiency GaAs oscillations.     

一种高性能InP基谐振隧穿二极管的研制

设计并用分子束外延技术生长了InP基InGaAs/AlAs体系RTD材料,采用传统湿法腐蚀、光学接触式光刻、金属剥离、台面隔离和空气桥互连工艺,研制出了具有优良负阻特性和较高阻性截止频率的InP基RTD单管，器件正向PVCR为17.5,反向PVCR为28,峰值电流密度为56kA/cm^2,采用RNC电路模型进行数据拟合后得到阻性截止频率为82.8GHz，实验为今后更高性能RTD单管的研制,以及RTD与其他高速高频三端器件单片集成电路的设计与研制奠定了基础。     

In0.53Ga0.47As contact layer for 1.3 ?m light-emitting diodes

Measurements of the specific contact resistance on epitaxially grown layers of p-In1?xGaxAsyP1?y as a function of composition demonstrate the resistance minimum of 7×10?6 ?cm2 for In0.53Ga0.47As. Growth procedures for the preparation of InGaAsP/InP double-heterostructure LED wafers incorporating such a ternary InGaAs contact layer are described. This contacting technique allows fabrication of high-performance devices with reproducibly low series resistance.     

扶手椅型碳化硅纳米管的电子输运特性

采用结合密度泛函理论的非平衡格林函数法(4, 4)对扶手椅型碳化硅纳米管的电子输运特性进行了研究。碳化硅纳米管的平衡态透射谱的费米能级附近存在大约2.12 eV的透射谷,这表明碳化硅纳米管是宽带隙半导体材料,与第一性原理的计算结果是一致的;在非平衡态输运特性中,发现了微分负阻效应,该效应是偏压引起态密度变化的结果。论文的研究对碳化硅纳米管电子器件的建模与仿真具有较重要的意义。     

(8, 0) 碳/氮化硼纳米管的微分负阻效应

Using the method combined non-equilibrium Green’s function with density functional theory, the electronic transport properties of an (8, 0) carbon/boron nitride nanotube heterojunction coupled to Au electrodes were investigated. In the current voltage characteristic of the heterojunction, negative differential resistance was found under positive and negative bias, which is the variation of the localization for corresponding molecular orbital caused by the applied bias voltage. These results are meaningful to modeling and simulating of related electronic devices.     

Electronic transport properties of the armchair silicon carbide nanotube

The electronic transport properties of the armchair silicon carbide nanotube (SiCNT) are investigated by using the combined nonequilibrium Green's function method with density functional theory. In the equilibrium trans-mission spectrum of the nanotube, a transmission valley of about 2.12 eV is discovered around Fermi energy, which means that the nanotube is a wide band gap semiconductor and consistent with results of first principle calculations.More important, negative differential resistance is found in its current voltage characteristic. This phenomenon orig-inates from the variation of density of states caused by applied bias voltage. These investigations are meaningful to modeling and simulation in silicon carbide nanotube electronic devices.     

Obtaining the specific contact resistance from transmission line model measurements

In characterizing ohmic contacts using the transmission line model, it is necessary to make a measurement referred to as the contact end resistance, as a result of modification to the sheet resistance under the contact. In this article we show that this contact end resistance and the consequent specific contact resistance can be deduced from simple resistance measurements carried out between contacts on a standard, transmission line model test pattern.