共查询到19条相似文献,搜索用时 859 毫秒
1.
2.
综述了国内外新型无毒增塑剂在儿童玩具和食品包装行业应用现状及发展趋势。欧盟对工业增塑剂安全政策法规的进程、国外新开发及正在推广的无毒增塑剂的现状,以及美国、德国、韩国等开发的无毒增塑剂的品种。我国无毒环保增塑剂的现状及国内企业的生产概况,柠檬酸酯无毒增塑剂产品质量指标,也指出了国内无毒环保增塑剂发展方向的存在的技术问题。 相似文献
3.
4.
5.
6.
7.
柠檬酸酯是环保型塑料增塑剂,可以取代限用的邻苯二甲酸酯类增塑剂。本文介绍了柠檬酸三正丁酯及其乙酰化的新的合成工艺。为合成研究提供了实验数据。 相似文献
9.
10.
介绍了国内外新型增塑剂品种及其在工业塑料制品中的应用。天然多元醇增塑剂、无毒、生物可降级增塑剂柠檬酸酯、降解新型增塑剂Benzoflex 2888、新型偏苯三酸三酯类增塑剂、均苯四酸四酯、聚酯等助剂的应用性能;介绍了上述增塑剂产品新应用及在制品的配方组成,特别是对卫生、无毒性等要求高的塑料制品及民用塑料及高科技特种塑料制品中的应用。 相似文献
11.
12.
The effect of modified flax fibers by plasticizer absorption in poly(L‐lactic acid) composites was investigated. The plasticizes chosen were triethyl citrate (TEC), tributyl citrate (TBC) and glycerol triacetate (GTA), which were derived from natural sources. Characterization was performed by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). The morphology was examined from scanning electron microscopy (SEM) and optical microscopy (OM). The results showed that the plasticizer caused a marked increase in the storage modulus of the composites, which could be due to an improvement in the morphology of the matrix and a smoother surface coverage of the fibers by the matrix. The thermal properties were also affected, in which the glass transition temperature (Tg), the crystallization temperature (Tc) and the crystallinity (Xc) were reduced depending on the plasticizer. The citrate esters revealed to be the most effective plasticizers of those tested. 相似文献
13.
Plasticizers play a key role in the formulation of polymers and in determining their physical properties and processability. This study examines the effects of citrate esters, triethylcitrate, and triacetine as plasticizers on the thermal and mechanical properties of poly(methyl methacrylate). The samples were characterized by differential scanning calorimetry, dynamical mechanical analysis, and mechanical testing under different plasticizer contents. Both citrate esters proved to be effective as plasticizers, DSC data for the triacetine additive fits with Fox equation. Microstructure and relaxation properties were studied by dynamic mechanical analysis where loss modulus shows clearly that absorbed plasticizer shifts the α‐transition to lower temperature and β‐relaxations associated to ester side groups are unchanged even up to 30 wt % plasticizer. Mechanical properties were evaluated with an Instron testing machine. Both additives produced (1) an initial plasticization, with a decrease in tensile strength and modulus; (2) an antiplasticization, reflected as an increase in tensile strength; and modulus and (3) a final plasticization, with a notable decrease in tensile strength and modulus and an increase in elongation where a 35 wt % of triethylcitrate added to the poly(methyl methacrylate) increased in 200% its elongation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
14.
Imelda Harte Colin Birkinshaw Eric Jones James Kennedy Eamonn DeBarra 《应用聚合物科学杂志》2013,127(3):1997-2003
Citrate esters triethyl citrate, tributyl citrate, and acetyl tributyl citrate were used as plasticizers for amorphous poly(D,L ‐lactide) (PDLLA). The resultant compositions were analyzed by means of differential scanning calorimetry (DSC), dynamic mechanical thermal analysis, and tensile testing to investigate the properties of the blends. Glass transition temperatures (Tgs) obtained by DSC were also compared to theoretically calculated Tgs. Increasing plasticizer content decreased the resultant Tg of the blend with plasticizer efficiency enhanced as the molecular weight of the citrate ester increased. However, in blends with high plasticizer content, a lack of miscibility also occurred with increased molecular weight. Theoretical results were comparable with those obtained experimentally at compositions, which were miscible. Increasing plasticizer content increased the ductility and decreased the strength of the polymer. The addition of 10 wt % plasticizer to PDLLA decreased tensile strength by over 50% with the deterioration larger at higher concentrations of plasticizer. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
15.
16.
Ye Yuan Zeyu Hu Xiaowei Fu Liang Jiang Yao Xiao Kai Hu Peiyao Yan Jinxin Lei 《应用聚合物科学杂志》2016,133(21)
The esterification of glycerol with lactic acid was carried out to synthesize glyceryl lactate, which was used as a as a plasticizer with different contents and blended with poly(lactic acid) (PLA) to get a completely biodegradable material with potential applications because of its biodegradability. The structural, morphological, thermal, and mechanical properties of the plasticized PLA were studied to evaluate the plasticizing effects. The results show that the PLA plasticized with glyceryl lactate had a lower glass‐transition temperature and a better ductility. With increasing plasticizer content, the crystallinity of PLA increased. The elongation at break reached 380%, and the impact strength was 1.7 times that of neat PLA. Simultaneously, the migration rate measurements showed that glyceryl lactate presented relatively low migration toward the surface compared with glycerol and citrate esters. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43460. 相似文献
17.
《国际聚合物材料杂志》2012,61(2):121-130
Abstract The synthesis of epoxy esters of 3-pentadecenyl phenol a low cost indigeneous raw material is described. These epoxy esters have further been evaluated as secondary plasticizers for PVC. Epoxidized 3-pentadecenyl-phenyl linoleate seems to be an attractive candidate as a secondary plasticizer amongst the epoxy esters evaluated. 相似文献
18.
This work examines the properties of starch esters for their possible application as environmentally degradable thermoplastics. The rheological, thermal, and mechanical properties of a series of fatty-acid esters of high-amylose starch (as well as the effects of adding plasticizer on some selected properties) were evaluated. The ester group acts like an internal plasticizer, with an increase in the size of the fatty-acid chain, resulting in greater internal plasticization. This is reflected in the rheological and thermal measurements as well as in the mechanical properties. Overall, larger ester groups and the addition of external plasticizer make these starch-based materials more processable and more ductile. However, comparing their properties and cost to commodity thermoplastics leads us to believe that their commercial applications are likely to be limited, at least in the near future. © 1995 John Wiley & Sons, Inc. 相似文献
19.
Citrate esters were used as plasticizers with poly(lactic acid) (PLA). Films were extruded using a single-screw extruder with plasticizer contents of 10, 20, and 30% by weight. All of the citrate esters investigated were found to be effective in reducing the glass transition temperature and improving the elongation at break. It was observed that the plasticizing efficiency was higher for the intermediate-molecular-weight plasticizers. Hydrolytic and enzymatic degradation tests were conducted on these films. It was found that the lower-molecular-weight citrates increased the enzymatic degradation rate of PLA and the higher-molecular-weight citrates decreased the degradation rate as compared with that of unplasticized PLA. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 1507–1513, 1997 相似文献