The possibility of increasingTc in oxide high-Tc superconductor films: Interaction with elastic fields of defects

The influence onT _c of dilatation centers (DC) as elastic defects near the surface or in thin films of oxide high-T_c superconductors is considered. The distribution function ofT _c in this case was obtained. This is the Lorentzian with center shifted to largerT _c values. The half width of theT _c distribution n (n is the concentration of DC) is larger than its center shift and corresponds to the increase ofT _c fluctuations near the surface. As a result, a continuum percolation behavior with increasing critical temperature percolation levelT ^(c) near the surface appears. The inequalityn>T ^(c)>T _c ^initial is fulfilled. ForT>T ^(c) the quasi-2D Josephson media takes place where a finite superconductive domain withT _c ^local >T ^(c) exists. The influence of DC considerably increases for strong DC such as off-center impurity ions.     

Anomalous photoemission threshold in high-T c oxide superconductor with Cs and K submonolayers

The photoemission threshold and photocurrent spectra were investigated for Bi₂Sr₂CaCu₂O₈ crystals with K or Cs submonolayer films. The different films of K or Cs were deposited on the Bi-O surface in the temperature range 80–250 K. We observed an appreciable (up to 0.3 eV) energy shift of the threshold and a strong modification of the photocurrent spectra for different temperatures and submonolayer coverages. The appropriate model of such a phenomena is based on a quasimetallic K or Cs clusters effect and additional 2D-polaronic effect.     

Preparation of high-T c oxide films via flaming solvent spray

Thick films of the high-temperature superconductors YBa₂Cu₃O_7?x and Bi_1.7Pb_0.3Sr₂Ca₂Cu₃O₁₀ have been prepared by spraying an ignited ethanol, ethylene glycol, or liquid ammonia solution of stoichiometric amounts of the metal nitrates (or acetates) onto polycrystalline MgO. The flaming spray is mechanically forced to traverse a region directly in front of the substrates. This new method is simple and inexpensive, and eliminates the problem of substrate cooling encountered in normal spray pyrolysis methods. Since decomposition of the solvent and metal salts occurs before deposition, the resulting films are relatively free of craters and nonuniformities common with spray methods. The method can be adapted to coat large areas and irregular or nonplanar shapes (i.e., cylinders), which could have useful magnetic shielding properties. The films were characterized by XRD and show single-phase material with preferredc-axis orientation. For YBa₂Cu₃O_7?x , resistance vs. temperature measurements show aT _c onset at 90 K and aT _c 0 at 76 K. Silver nitrate has been added to some of the solutions in an attempt to improve contact among individual grains.     

Crystal engineering of high-T c and related oxide films for future electronics

Advanced technology and future prospect of oxide-based electronic materials are described with a focus on the significance of atomically controlled epitaxy of high-T _c superconductors and related oxide films. Problems in suitably forming the oxides whose power is potentially superior to silicon’s are discussed to stimulate technology development for engineering oxide film growth on an atomic scale. Our experimental results on controlled epitaxial growth of oxide films are presented with respect to pulsed laser deposition of YBa₂Cu₃O_{7 −δ} films as well as laser MBE growth of SrTiO₃ homoepitaxy and CeO₂ heteroepitaxy on Si substrates.     

Analysis of specific heat anomalies of high-T c superconductors based on a two-carrier high-T c superconductor model

We investigate the specific heat properties of a high-T _c superconductor model, the “two-carrier model” which includes an electron-phonon interaction driven by lattice defects such as oxygen deficiencies in the otherwise conventional BCS superconductor. The normal state is identified as a two-carrier model system which is composed of two groups of charge carriers: the normal and the renormalized Bloch carriers. An enhanced normal-state electronic specific heat is obtained, and there is good agreement between theoretical predictions about the specific heat anomalies at and aboveT _c and experimental data.     

Effect of precursor history on synthesis of high-T c BPSCCO superconductor

High-T _c lead-doped BSCCO superconductors (BPSCCO) were prepared from precursors of three different histories. The method, which combined three kinds of calcined powders, decreased the total sintering time for the formation of high-T _c BPSCCO superconductor phases relative to other methods based on one type of powder. The proportion of secondary phase, such as Ca₂2CuO₃ was also reduced. As a result, the transition temperature,T _c, from the current method is higher than for the latter fabrication methods. Thec-axis parameters of BSCCO superconductors from different precursors were compared. The average X-ray particle size of each phase in the bulk sample was calculated from the Scherrer formula. Finally, the surface morphology and composition of BPSCCO were examined by SEM and energy dispersive spectrometry.     

Preparation and analysis of high-T c Nb-Ge films

The dependence of T_c on sputtering conditions, chemical composition, and phase structure for Nb-Ge films has been studied. It was found that T_c varied with composition, but was not dependent on exact stoichiometry of the film; the Nb/Ge ratio was <3 for very high T_c 23 K films and 4 for films with T_c 20 K. X-ray results showed that the films with T_c 23 K contained a certain amount of tetragonal Nb₅Ge₃ with a lattice parameter of A15 phase 5.14 Å. The depth profile of very high T_c films showed no increase of oxygen concentration at the film-substrate interface; no correlation of high T_c and impurities was found.     

Statics and dynamics in the system of high-T c superconductor and permanent magnet

Equilibrium and small oscillations in the system of high-T _c superconductor (SC) and permanent magnet (PM) are considered. A phenomenological theory based on the observed magnetization curves for SC is given. The measured forces and oscillation frequencies in the system of YBa₂Cu₃O₇ superconductor and SmCo₅ permanent magnet are compared with the theoretical predictions. Conclusions are made as to the possible applications for studying the SC properties of materials.     

Specific heat of the high-T c oxide superconductors

We review the specific heat measurements on La₂CuO₄, La_2?xM_xCuO₄ (M = Ca, Sr, and Ba), YBa₂Cu₃O₇, and the Bi-Ca-Sr-Cu-O and Tl-Ca-Ba-Cu-O systems. Tables of properties derived from the data are presented. Results on RBa₂Cu₃O₇ (R=rare earth elements other than Y) are summarized, as are results on YBa₂(Cu_3?xM_x)O₇ (M=Zn, Cr, Fe, or Ni). The difficulties of analyzing the specific heat data, and specifically the separation of the contributions associated with magnetic impurities, are discussed. It is tentatively concluded that the data nearT _c are consistent with BCS theory, although they show evidence of fluctuation effects. It is also concluded that the low-temperature zero-field data on a majority of the high-T _c oxide superconductors provide evidence of anintrinsic term that is proportional toT, a result that is inconsistent with a gap in the electronic density of states.     

Surface structure of high-T c Nb3Ge films

We have studied the surface structure of rf-sputtered Nb₃Ge films by means of reflection electron diffraction and Auger electron spectroscopy. It is found that a tetragonal Nb₅Ge₃ phase exists, being partly disordered, at the surface of high-T _c films, whereas A15 phase is predominant in the body of the film as proved by x-ray diffraction. The tetragonal surface phase is replaced by an amorphous phase in thin films of <1000 Å, where reducedT _c 's as compared with those of thick films are found. Single A15 phase occurs at the surface of Ge-deficient films which have lowT _c 's. Auger analysis has shown a pronounced Ge-rich layer with a depth of 60–100 Å, depending on film composition and thickness. At the top of the surface layer, Ge is enriched beyond a composition corresponding to Nb₅Ge₃. It is inferred that the Ge-rich layer is responsible for formation of the tetragonal phase.Work supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture of Japan.     

Electrostatic bonding of high-T c superconducting films to any substrate

Complete integration of high-T _c thin-film superconducting technology with other electronic technologies requires hybrid structures with both technologies on the same substrate. This is difficult to do with direct growth of the superconductor on certain substrates (GaAs, InP) because of the high temperatures required for formation of the superconductor. A method is proposed to circumvent this problem by using electrostatic forces and appropriate thin-film materials to bond superconducting films to any substrate at 300°C. The same principle can be applied to the bonding of other devices on other substrates.     

Video detection of microwaves using high-T c Y-Ba-Cu-O thin films

Microwave video detection (demodulation) studies were carried out on high-T _c thin films at 64 K. The amplitudes of the video detection signal varies linearly with incident microwave power. The microwave response shows a peak at an optimum bias current. The shape analysis of the demodulated signal indicates the nonbolometric nature of the detector.     

CO2 laser annealing of plasma-deposited high-T c superconducting thick films

Recent advances in the fabrication of high-T _c superconducting thick films demand processing techniques which can eliminate film/substrate interdifiusion that occurs during subsequent post-annealing heat treatment after the film is deposited, thereby limiting the application of the thick films for devices. The present study evaluates laser annealing techniques for plasma-deposited Y-Ba-Cu-O thick films using a high-energy CO₂ laser (10.6Μm) in a continuous wave mode. The results are compared with those obtained by conventional furnace annealing techniques necessary for post-heat treatment of as-deposited superconducting thick films. The high-T _c superconducting phase is recovered by cationic diffusion during subsequent post-annealing heat treatment. Crystallographic phases and microstructural characterization have been performed using XRD, SEM, and EPMA analytical techniques. The significance of the technology lies in the elimination of film/substrate interdiffusion problems, thereby resulting in high-quality superconducting thick films. The technology will significantly reduce the post-annealing times usually required by conventional furnace annealing techniques.     

The flux-line lattice in high-T c superconductors

The flux-line lattice in type-II superconductors has unusual nonlocal elastic properties which make it soft for short wavelengths of distortion. This softening is particularly pronounced in the highly anisotropic high-T _c superconductors (HTSC) where it leads to large thermal fluctuations and to thermally activated depinning of the Abrikosov vortices. Numerous transitions are predicted for these layered HTSC when the temperatureT, magnetic inductionB, or current densityJ are changed. In particular, the flux lines are now chains of two-dimensional (2D) “pancake vortices” which may “evaporate” by thermal fluctuations or may depin individually. At sufficiently highT, ohmic resistivityρ(T, B) is observed down toJ → 0. This indicates that the flux lines are in a “liquid state” with no shear stiffness and with small depinning energy or that the 2D vortices can move independently. At lowerT, ρ(T, B, J) is nonlinear since the pinning energy of an elastic vortex lattice or “vortex glass” increases with decreasingJ as predicted by theories of collective pinning and by “vortex glass” scaling.     

Low-field magnetic properties of high-T c GdxY1−xBa2Cu3Oy superconductor

The magnetization of Gd_0.85Y_0.15Ba₂Cu₃O _y high-T _c superconductor was measured at low fields (<100 Oe) and at a constant temperature of 77 K. The magnetization curves deviate from linearity at 25 Oe, causing the destruction of the weak couplings of the superconducting grains. The hysteresis due to granular superconductivity was also observed.     

Effect of Bi/Pb ratio and annealing temperature onT c and formation of high-T c phase in Bi-Pb-Sr-Ca-Cu-O superconductor

We studied the effect of Bi/Pb ratio and annealing temperature onT _c and formation of the high-T _c ; phase in Bi-Pb-Sr-Ca-Cu-O superconductor by the three-step reaction process. The optimum Bi/Pb ratio is about 1.8∶0.3 and the optimum annealing temperature is about 845–855°C. It is found that a variate high-T _c phase existed at the higher annealing temperature. The zero-resistance temperature of the variate high-T _c phase decreased when the annealing temperature increased, although the phase is isostructural with the 110 K phase.     

Statistics of normal-phase clusters and magnetic-flux trapping in films of high-T c superconductors

The morphological properties of YBCO superconducting films and their relationship to magnetic and transport phenomena are considered. A geometric probability analysis of the principal statistical characteristics of normal-phase clusters is performed, and their influence on the dynamics of trapped magnetic flux under the action of a pulsed transport current is revealed. The superconducting film is treated as a percolation system. It is found that the critical currents have a statistical distribution, which is specified by the morphology of the material being studied. The critical current for passage of the film into the resistive state is found. Pis’ma Zh. Tekh. Fiz. 25, 30–36 (June 26, 1999)     

Electrochemical processing of high-T c Bi(Pb)-Sr-Ca-CuO thin films

Superconducting thin films of Bi(Pb)-Sr-Ca-CuO system were prepared by depositing the film onto silver substrate by d.c. electrodeposition technique with dimethyl sulphoxide bath in order to examine the effect of Pb addition to the BSCCO system. The films were deposited at the potential of -0.8 V vs saturated calomel electrode (SCE) onto the silver substrate. The different preparative parameters such as deposition potential, deposition time were studied and optimized. These films were then oxidized electro-chemically at room temperature in an alkaline (1 N KOH) solution, and also at 600°C temperature in an oxygen atmosphere. The films showed the superconducting behaviour, with T_c values ranging between 85 K and 96 K, respectively.