Modeling of a flat plate membrane-distillation system for liquid desiccant regeneration in air-conditioning applications

A thermally driven flat plate air gap membrane distillation liquid desiccant regenerator for lithium chloride in dehumidification applications is modeled. Operating conditions and device geometry are optimized, and it is found that membrane materials have little influence on regenerator performance. It is shown that radiation heat transfer across the air gap cannot be neglected. The regenerator removes 11.4 g min^?1 cm^?3 of moisture with a COP of 0.372 for an inlet solution concentration of 0.38, solution flow rate of 50 ml min^?1, and heated solution temperature of 135 °C. This design has negligible desiccant carry-over losses and operates without a blower.     

Effects of meteorological variables on exergetic efficiency of wind turbine power plants

This present paper deals with exergy efficiency results of the Wind Turbine Power Plants (WTPPs). Effects of meteorological variables such as air density, pressure difference between state points, humidity, and ambient temperature on exergy efficiency are discussed in a satisfactory way. Some key parameters are given monthly for the three turbines. Exergy efficiency differs from 0.23 to 0.27 while temperature is changing from 268.15 K to 308.15 K with air density 1.368–1.146 (kg/m³). While pressure difference (ΔP) between inlet and outlet of the turbine differs from 100 to 1100 (Pa), exergy efficiency decreases fairly for different wind speeds. While specific humidity is changing from 0.001 to 0.015 (kg_water/kg_{dry air}), exergy efficiency decreases gently. Generally these meteorological variables are neglected while planning WTPPs, but this neglect can cause important errors in calculations and energy plans. Obtained results indicate that while planning WTPPs meteorological variables must be taken into account.     

The effects of operating conditions on emissions from masonry heaters and sauna stoves

Emissions from masonry heaters and sauna stoves were studied. In the sauna stove the production of organic gaseous carbon (OGC) at 10 gC kg^?1 (per kilogram of fuel), carbon monoxide (CO) at 55 g kg^?1, fine particle mass (PM₁) at 5 g kg^?1 and number emissions (N) at 1.8 × 10¹⁵ kg^?1 was higher than in other measured appliances. In a modern technology masonry heater with a unique grate, the emissions were very low: 0.4 gC kg^?1 OGC, 14 g kg^?1 CO and 0.7 g kg^?1 PM₁. Conventional masonry heaters, using small logs, clearly produced higher emissions when compared to using large logs. Doubling the fuel load caused emission factors to increase by up to 4- times (OGC), except for the number emission, which decreased from 4.0 × 10¹⁴ to 2.0 × 10¹⁴ kg^?1. From the conventional masonry heater 90% of the PM was emitted during the firing phase. Its combustion process is different to that in stoves or conventional open fireplaces. The insufficient supply of air, due to too fast pyrolysis, and increased ash release, due to the high combustion temperature, are the main parameters which cause high particle and gas emissions in masonry heaters and sauna stoves.     

Experimental investigation of mixed convection heat transfer in a rectangular channel with discrete heat sources at the top and at the bottom

Mixed convection heat transfer in a top and bottom heated rectangular channel with discrete heat sources has been investigated experimentally for air. The lower and upper surfaces of the channel were equipped with 8 × 4 flush-mounted heat sources subjected to uniform heat flux. Sidewalls, the lower and upper walls were insulated and adiabatic. The experimental study was made for an aspect ratio of AR = 6, Reynolds numbers 955 ≤ Re_Dh ≤ 2220 and modified Grashof numbers Gr* = 1.7 × 10⁷ to 6.7 × 10⁷. From experimental measurements, surface temperature and Nusselt number distributions of the discrete heat sources were obtained for different Grashof numbers. Furthermore, Nusselt number distributions were calculated for different Reynolds numbers. Results show that surface temperatures increase with increasing Grashof number. The row-averaged Nusselt numbers first decrease with the row number and then, due to the increase in the buoyancy affected secondary flow and the onset of instability, they show an increase towards the exit as a result of heat transfer enhancement.     

Electrochemical behavior of polyamides with cyclic disulfide structure and their application to positive active material for lithium secondary battery

Polyamides (DTA-I, DTA-II, and DTA-III) containing cyclic disulfide structure were prepared by condensation between 1,2-dithiane-3,6-dicarboxylic acid (DTA) and alkyl diamine, NH₂–(CH₂)_n–NH₂ (DTA-I; n=4, DTA-II; n=6, DTA-III; n=8) and their application to positive active material for lithium secondary batteries was investigated. Cyclic voltammetry (CV) measurements under slow sweep rate (0.5 mV s⁻¹) with a carbon paste electrode containing the polyamide (DTA-I, DTA-II, or DTA-III) were performed. The results indicated that the polyamides were electroactive in the organic electrolyte solution (propylene carbonate (PC)-1,2-dimethoxyethane (DME), 1:1 by volume containing lithium salt, such as LiClO₄). The responses based on the redox of the disulfide bonds in the polyamide were observed.Test cells, Li/PC-DME (1:1. by volume) with 1 mol dm⁻³ LiClO₄/the polyamide cathode, were constructed and their performance was tested under constant current charge/discharge condition. The average capacity of the test cells with the DTA-III cathode was 64.3 Ah kg⁻¹ of cathode (135 Wh kg⁻¹ of cathode, capacity (Ah kg⁻¹) of the cathode×average cell voltage (2.10 V)). Performance of the cell with linear polyamide containing disulfide bond (–CO–(CH₂)₂–S–S–(CH₂)₂–CONH–(CH₂)₈–NH–, GTA-III) was also investigated and the average capacity was 56.8 Ah kg⁻¹ of cathode (100 Wh kg⁻¹ of cathode, capacity (Ah kg⁻¹) of the cathode×average cell voltage (1.76 V)). Cycle efficiency of the test cell with the DTA-III cathode was higher than that with the GTA-III cathode.     

A rechargeable Zn- poly(aniline-co-m-aminophenol) battery

Based on the cyclic voltammograms and impedance spectra of poly(aniline-co-m-aminophenol) in the electrolyte solution containing ZnCl₂ and NH₄Cl, a solution consisting of 2.0 M ZnCl₂ and 3.0 M NH₄Cl with pH 4.70 was employed as an electrolyte solution of a Zn-poly(aniline-co-m-aminophenol) battery. The battery was charged and discharged between 0.75 and 1.45 V at different current densities. The average charge voltage is about 1.15 V and the average discharge voltage is about 1.05 V, slightly depending on the charge–discharge current density. The capacity and energy densities of poly(aniline-co-m-aminophenol) are 137.5 A h kg⁻¹ and 152.5 W h kg⁻¹ for discharge process, respectively, which are much better than those of polyaniline at the same solution. After the test of the charge–discharge at different current densities, the battery was successively charged and discharged for 120 cycles. At one-hundred and twentieth cycle, the coulombic efficiency is 100% and the energy density of poly(aniline-co-m-aminophenol) only decreases by 9.2%, compared with the first cycle of the successive charge–discharge processes.     

Assessment of nitrogen fertilization for the CO2 balance during the production of poplar and rye

This study was designed to consider all nitrogen fertilizer-related effects on crop production and emission of greenhouse gases on loamy sandy soils in Germany over a period of nine years (1999–2007). In order to set up a CO₂ balance for the production of energy crops, different nitrogen pathways were investigated, such as direct N₂O emissions from the soil and indirect emissions related to NO₃ leaching and fertilizer production. Fluxes of N₂O were measured in an experimental field using closed chambers. Poplar (Populus maximowiczii × P. nigra) and rye (Secale cereale L.) as one perennial and one annual crop were fertilized at rates of 0 kg N ha^?1 yr^?1, 75 kg N ha^?1 yr^?1 and 150 kg N ha^?1 yr^?1. The mean N₂O emissions from the soil ranged between 0.5 kg N ha^?1 yr^?1 and 2.5 kg N ha^?1 yr^?1 depending on fertilization rate, crop variety and year. The CO₂ fixed in the biomass of energy crops is reduced by up to 16% if direct N₂O emissions from soil and indirect N₂O emissions from NO₃ leaching and fertilizer production are included. Taking into account the main greenhouse gas emissions, which derive from the production and the use of N fertilizer, the growth of poplar and rye may replace the global warming potential of fossil fuels by up to 17.7 t CO₂ ha^?1 yr^?1 and 12.1 t CO₂ ha^?1 yr^?1, respectively.     

Net carbon dioxide emissions from alternative firewood-production systems in Australia

The use of firewood for domestic heating has the potential to reduce fossil-fuel use and associated CO₂ emissions. The level of possible reductions depends upon the extent to which firewood off-sets the use of fossil fuels, the efficiency with which wood is burnt, and use of fossil fuels for collection and transport of firewood. Plantations grown for firewood also have a cost of emissions associated with their establishment. Applying the FullCAM model and additional calculations, these factors were examined for various management scenarios under three contrasting firewood production systems (native woodland, sustainably managed native forest, and newly established plantations) in low-medium rainfall (600–800 mm) regions of south-eastern Australia. Estimates of carbon dioxide emissions per unit of heat energy produced for all scenarios were lower than for non-renewable energy sources (which generally emit about 0.3–1.0 kg CO₂ kWh⁻¹). Amongst the scenarios, emissions were greatest when wood was periodically collected from dead wood in woodlands (0.11 kg CO₂ kWh⁻¹), and was much lower when obtained from harvest residues and dead wood in native forests (<0.03 kg CO₂ kWh⁻¹). When wood was obtained from plantations established on previously cleared agricultural land, use of firewood led to carbon sequestration equivalent to −0.06 kg CO₂ kWh⁻¹ for firewood obtained from a coppiced plantation, and −0.17 kg CO₂ kWh⁻¹ for firewood collected from thinnings, slash and other residue in a plantation grown for sawlog production. An uncertainty analysis, where inputs and assumptions were varied in relation to a plausible range of management practices, identified the most important influencing factors and an expected range in predicted net amount of CO₂ emitted per unit of heat energy produced from burning firewood.     

Experimental study of natural convection in PV roof solar collector

The aim of this paper is to propose the PV roof solar collector (PV-RSC) to investigate the natural convection heat transfer and estimated the convective heat transfer coefficient in the channel. The experimental set-up was composed of a PV panel on the upper layer and the lower layer is aluminum plate of the channel. The inclination angle and air gap of channel were fixed at 30° and 15 cm, respectively. The channel width is 0.7 m, and length is 1.2 m. The data analysis were confirmed the effect of radiative exchange influent to natural convection within the channel. On the basis of the experimental results, an empirical formula is found; the Nu as a function of Ra_s sin30, that is Nu_s = 0.3282 (Ra_s sin30)^0.2249. The correlation obtained to range 3 × 10⁸ < Ra_s sin30 < 7 × 10⁸. A comparison between PV-RSC and normal PV panel, it was confirmed that the PV-RSC could be generated electric power than that normal PV panel by about 30 W; and also the percentage of power generation increase was rising about 25% throughout the day.     

Performance assessment of a direct expansion air conditioner working with R407C as an R22 alternative

This paper presents an experimental investigation of a direct expansion air conditioner working with R407C as an R22 alternative. Experiments are conducted on a vapor compression refrigeration system using air as a secondary fluid through both the evaporator and the condenser. The influences of the evaporator air inlet temperature (20–32 °C), the evaporator air flow rate (250–700 m³/h) and the evaporator air humidity ratio (9 and 14.5 g_wv/kg_a) at the condenser air temperature and volume flow rate of 35 °C and 850 m³/h, respectively on the system performance are investigated. Experimental results revealed that the evaporator air inlet temperature has pronounced effects on the air exit temperatures, pressures of the evaporator and the condenser, cooling capacity, condenser heat load, compressor pressure ratio and the COP of both refrigerants at humidity ratios of 9 and 14.5 g_wv/kg_a. Significant effects of the evaporator air flow rate are also gathered on the preceding parameters at the same values of mentioned-humidity ratios. The best performance, in terms of operating parameters as well as COP, can be accomplished using R22 compared to R407C. The inlet humidity ratio affects dramatically the performance of vapor compression system using R22 and R407C. The raising up humidity ratio from 9 to 14.5 g_wv/kg_a leads to an augmentation in the average cooling capacity by 29.4% and 38.5% and an enhancement in the average COP by 30% and 24.1% for R22 and R407C, respectively.     

Development of high energy density small flat spiral cells and battery pack based on lithium/carbon monofluoride (Li/CFx)

Small spiral-wound lithium–carbon monofluoride (Li/CF_x) cells, which were discharged at the C/40 rate, had a nominal capacity of 300 mAh and a gravimetric energy density of about 464 Wh kg⁻¹. These cells delivered pulse current loads (>22 mA) with good capacity (>200 mAh) if they were subjected to a pre-discharge step. A 17 V, 2.2 kW battery based on Li/CF_x flat cell technology has also been fabricated and tested. The battery had gravimetric and volumetric energy densities of 360 Wh kg⁻¹ and 700 Wh dm⁻³, respectively. This compares with a value of 330 Wh kg⁻¹ and 522 Wh dm⁻³ for an equivalent battery based on Li/SOCl₂.     

Performance evaluation of a solar-powered flat-plate multichannel liquid desiccant air conditioning system

There has been a limited application of liquid desiccant (LD) dehumidification systems in space air conditioning until now. The key elements responsible for this restricted implementation are leakage of desiccant solution, corrosion of components, and solution carryover along with the processed air to the space to be conditioned. To remove these problems, an evacuated tube solar heat collector-driven multichannel liquid desiccant air conditioning system has been proposed and experimentally investigated. In this study, dehumidification and regeneration rate, their effectiveness, cooling effect of the dehumidifier, and indirect evaporative cooling unit have been analyzed. The results obtained indicate that the process air has been dehumidified and cooled by 6.32 g kg⁻¹ and 5.26°C, respectively. The regeneration rate and effectiveness have been obtained to be 0.26 g s⁻¹ and 0.31, respectively. In terms of the cooling effect, the system output of 0.703 and 0.130 kW has been obtained from the dehumidifier and indirect evaporative cooling unit of the system, respectively. The proposed system validates the possibility of the novel solar-powered liquid desiccant air conditioning system concept and provides growth and development of the LD air conditioning technology for space air conditioning.     

Experimental study of an ammonia–water bubble absorber using a plate heat exchanger for absorption refrigeration machines

The development of absorption chillers activated by renewable heat sources has increased due mainly to the increase in primary energy consumption that causes problems such as greenhouse gases and air pollution among others. These machines, which could be a good substitute for compression systems, could be used in the residential and food sectors which require a great variety of refrigeration conditions. Nevertheless, the low efficiency of these machines makes it necessary to enhance heat and mass transfer processes in the critical components, mainly the absorber, in order to reduce their large size.This study used ammonia–water as the working fluid to look at how absorption takes place in a plate heat exchanger operating under typical conditions of absorption chillers, driven by low temperature heat sources. Experiments were carried out using a corrugated plate heat exchanger model NB51, with three channels, where ammonia vapor was injected in bubble mode into the solution in the central channel. The results achieved for the absorption flux were in the range of 0.0025–0.0063 kg m^?2 s^?1, the solution heat transfer coefficient varied between 2.7 and 5.4 kW m^?2 K^?1, the absorber thermal load from 0.5 to 1.3 kW. In addition, the effect of the absorber operating conditions on the most significant efficiency parameters was analyzed. The increase in pressure, solution and cooling flow rates positively affect the absorber performance, on the other hand an increase in the concentration, cooling, and solution temperature negatively affects the absorber performance.     

Implementation of an UASB anaerobic digester at bagasse-based pulp and paper industry

Upflow anaerobic sludge blanket (UASB) reactor was installed to replace the conventional anaerobic lagoon treating bagasse wash wastewater from agro-based pulp and paper mill, to generate bio-energy and to reduce greenhouse gas emissions. The plant was designed to treat 12 ML d⁻¹ of wastewater having two 5 ML capacity reactors, 5.75 kg COD m⁻³ d⁻¹ organic loading rate and 20 h hydraulic retention time. In the plant 80–85% COD reduction was achieved with biogas production factor of 520 L kg⁻¹ COD reduced. In 11 months 4.4 million m³ of biogas was generated from bagasse wash wastewater utilizing UASB process. Utilization of the biogas in the Lime Kiln saved 2.14 ML of furnace oil in 9 months. Besides significant economic benefits, furnace oil saving reduced 6.4 Gg CO₂ emission from fossil fuel and conversion of the anaerobic lagoon into anaerobic reactor reduced 2.1 Gg methane emission which is equal to 43.8 Gg of CO₂.     

Anaerobic digestion of by-products of sugar beet and starch potato processing

Anaerobic digestion (AD) is a promising option for the environmentally friendly recycling of agricultural by-products. However, overloading of the digester with sugar, starch or protein might cause inhibition of the anaerobic processes. The aim of the present project was to investigate the AD of sugar beet, starch potato by-products and effect of pre-treatment by steam on methane yield of potatoes pulp. The investigated by-products have been: sugar beet pulp silage (SBP), sugar beet tail silage (SBT), potato pulp (PP), potato peel pulp (PPP) and potato fruit water (PFW). All by-products were digested in 1 l eudiometer-batch digesters at 37.5 °C during 28–38 days. The specific methane yields of SBP and SBT were 430 and 481 l_N kg^?1 volatile solids (VS), respectively. The specific methane yields of PP, PPP and PFW were 332, 377 and 323 l_N (kg VS)^?1. A steam pre-treatment significantly increased the specific methane yield of PP up to 373 l_N (kg VS)^?1.     

Experimental investigation of opposing mixed convection hear transfer in the vertical flat channel in a laminar–turbulent transition region

In this paper we present the results on experimental investigation of the local opposing mixed convection heat transfer in the vertical flat channel with symmetrical heating in a laminar–turbulent transition region. The experiments were performed in airflow (p = 0.1–1.0 MPa) in the range of Re from 1.5 × 10³ to 6.6 × 10⁴ and Gr_q up to 1 × 10¹¹ at the limiting condition q_w1 = q_w2 = const. The analysis of the results revealed significant increase in the heat transfer with increasing of air pressure (Gr number). Also sharp increase in heat transfer was noticed in the region with vortex flow in comparison with the turbulent flow region.     

Effects of inlet geometry on heat transfer and fluid flow of tangential micro-heat sink

The paper presents the geometric optimization of the micro-heat sink with straight circular microchannels with inner diameter of D_i = 900 μm. The inlet cross-section has a rectangular shape and positioned tangentially to the tube axis with the four different geometries. The fluid flow regime is laminar and water with variable fluid properties is used as a working fluid. The heat flux spread through the bottom sink surface is q = 100 W/cm². Thermal and hydrodynamic performances of the heat sink are compared with results obtained for conventional channel configuration with lateral inlet/outlet cross-section. Besides, the results are compared with the tangential micro-heat sink with D_i = 300 μm. For all the cases, the thermal and hydrodynamic results are compared on a fixed pumping power basis.     

Application of neural networks to predict the steady state performance of a Run-Around Membrane Energy Exchanger

Modeling the performance characteristics of thermal systems has been a research interest for many decades with moisture transfer systems experiencing a resurgence over the last decade, especially in heating, ventilating, and air conditioning (HVAC) applications. In this study, a neural network (NN) model is developed to predict the heat and moisture transfer performances (i.e., the sensible and latent effectivenesses) of a novel HVAC energy exchanger called the Run-Around Membrane Energy Exchanger (RAMEE) which is able to transfer both heat and moisture between exhaust and supply air streams. The training data set for the NN model covers a wide range of design and operating parameters and is produced using an experimentally validated finite difference (FD) model. Two separate NNs (one for sensible and one for latent energy transfer) each with five inputs and one output, are selected to represent the RAMEE. The results from NN models are numerically and experimentally validated. The root mean squared error (RMSE) between the FD and NN models are 0.05 °C and 2 × 10^?5 kg_v/kg_a, indicating satisfactory agreement for energy exchange calculations. The paper reports the weights and biases to make the results of this study reproducible. These NN models are very fast and easy to use therefore, they might be used for design and for estimating the annual energy savings in different buildings which use the RAMEE in their HVAC system. Additionally, the NN models can be used with optimization algorithms to maximize energy savings and minimize life-cycle costs for a given system.     

Experimental investigation of mixed convection heat transfer from longitudinal fins in a horizontal rectangular channel

Mixed convection heat transfer from longitudinal fins inside a horizontal channel has been investigated for a wide range of modified Rayleigh numbers and different fin heights and spacings. An experimental parametric study was made to investigate effects of fin spacing, fin height and magnitude of heat flux on mixed convection heat transfer from rectangular fin arrays heated from below in a horizontal channel. The optimum fin spacing to obtain maximum heat transfer has also been investigated. During the experiments constant heat flux boundary condition was realized and air was used as the working fluid. The velocity of fluid entering channel was kept nearly constant (0.15 ? w_in ? 0.16 m/s) using a flow rate control valve so that Reynolds number was always about Re = 1500. Experiments were conducted for modified Rayleigh numbers 3 × 10⁷ < Ra¹ < 8 × 10⁸ and Richardson number 0.4 < Ri < 5. Dimensionless fin spacing was varied from S/H = 0.04 to S/H = 0.018 and fin height was varied from H_f/H = 0.25 to H_f/H = 0.80. For mixed convection heat transfer, the results obtained from experimental study show that the optimum fin spacing which yields the maximum heat transfer is S = 8–9 mm and optimum fin spacing depends on the value of Ra¹.     

Nonlinear flow and heat transfer dynamics of impinging jets onto slightly-curved surfaces

The nonlinear flow and heat transfer characteristics for a slot-jet impinging on slightly-curved surfaces are experimentally studied here. The effects of curved surface geometry and jet Reynolds number on the jet velocity distribution and circumferential Nusselt numbers are examined. Two different slightly-curved surface geometries of convex and concave are used as target surfaces. The nozzle geometry is a rectangular slot, and the dimensionless nozzle-to-surface distance equals to L¹ = 8. The constant heat fluxes are accordingly applied to the surfaces to obtain an impingement cooling by the air jet at ambient temperature. The measurements are made for the jet Reynolds numbers of Re = 8617, Re = 13 350 and Re = 15 415 for both curved surfaces. The velocity distributions of issuing jet from the nozzle exit to the target surface are obtained by a highly sensitive hot-wire anemometer. The T-type thermocouples are used to measure local temperatures of both the air jet and the plates. Two-dimensional velocity measurements show that the surfaces are remained out of the potential core region for all Re tested here. New correlations for local, stagnation point, and average Nusselt numbers as a function of jet Reynolds number and dimensionless circumferential distance are reported. The correlations reveal that the impinging cooling rate is higher with the concave surface and increase with increasing Re.