Analysis of blended fuel properties and engine performance with palm biodiesel–diesel blended fuel

Depleting fossil fuel sources accompanied by continuously growing energy demands lead to increased interest in alternative energy sources. Blended biodiesel–diesel fuel has been approved as a commercial fuel at a low blending ratio. However, problems related to fuel properties are persistent at high blending ratios. Hence, in this study, the feasibility of biodiesel produced from palm oil was investigated. Characterization of blended fuel properties with increasing palm biodiesel ratio is conducted to evaluate engine performance test results. The qualifying of blended fuel properties was used to indicate the maximum blending ratio suitable for use in unmodified diesel engines according to the blended fuel standard ASTM D7467. The property test results revealed that blended fuel properties meet blended fuel standard requirements at up to 30% palm oil biodiesel. Furthermore, blending is efficient for reduction of the pour point from 14 °C for unblended biodiesel to less than 0 °C at a 30% biodiesel blending ratio. However, the energy content reduces by about 1.42% for each 10% increment of biodiesel. Engine test results demonstrated that there was no statistically significant difference for engine brake thermal efficiency among tested blended fuels compared to mineral diesel, and the lowest engine cyclic variation was achieved with blended fuel B30.     

Experimental investigation of the influence of blending on engine emissions of the diesel engine fueled by mahua biodiesel oil

The present article elaborates on the various emission characteristics of mahua oil with diesel fuel in a diesel engine at various blending conditions. Experimental investigation results are studied for various parameters such as exhaust emission of carbon monoxide (CO), hydrocarbon (HC), and oxides of nitrogen (NO) gases and exhaust gas temperature. Results show that residual oxygen, CO, HC, and NO emission were the lowest for mahua biodiesel compared with diesel. The experimental results proved that the use of mahua oil biodiesel as fuel in the diesel engine is a viable alternative to diesel fuel. Mahua biodiesel oil may be beneficial in decreasing greenhouse gas emissions without any engine modification. Mahua oil has the possibility of becoming a sustainable fuel source as biodiesel.     

降低酸化油生物柴油NOx和烟度排放的试验研究

本文主要针对降低柴油机燃用酸化油生物柴油及其混合燃料的NOx、烟度排放的方法进行了试验研究。采用乙醇/生物柴油混合燃料法和推迟供油提前角两种方法在R4105T型柴油机上进行了试验。结果表明,在不影响动力性前提下燃用添加5%的乙醇的混合柴油,NOx及碳烟的排放均有明显下降。推迟供油提前角能有效的降低NOx的排放,但碳烟排放量增加,功率下降,燃料经济性变差。     

Effect of MC–MA polymer pour point depressants on the flow properties of biodiesel

To generate efficient pour point depressants (PPDs) for biodiesel, this study prepared a series of MC–MA polymers and their cold flow properties on biodiesel were studied by determining their solid points (SPs) and cold filter plugging points (CFPPs). This study also investigated the performance mechanisms of these polymers through differential scanning calorimetry (DSC) and rheological mechanics to identify the low-temperature crystal morphology and crystallization behavior of the biodiesel samples. Results indicated that compared with other polymers, the synthesis of polymer PPD2 could satisfactorily improve the low-temperature flow properties of biodiesel without altering other important fuel properties.     

Mahua oil (Madhuca Indica seed oil) methyl ester as biodiesel-preparation and emission characterstics

There is an increasing interest in many countries to search for suitable alternative fuels that are environment friendly. Although straight vegetable oils can be used in diesel engines, their high viscosities, low volatilities and poor cold flow properties have led to the investigation of various derivatives. Biodiesel is a fatty acid alkyl ester, which can be derived from any vegetable oil by transesterification. Biodiesel is a renewable, biodegradable and non-toxic fuel. In this study, Mahua oil (Madhuca indica seed oil) was transesterified with methanol using sodium hydroxide as catalyst to obtain mahua oil methyl ester. This biodiesel was tested in a single cylinder, four stroke, direct injection, constant speed, compression ignition diesel engine (Kirloskar) to evaluate the performance and emissions.     

Effects of exhaust gas recirculation on emission characteristics of Mahua (Madhuca Indica) biodiesel using red mud as catalyst

In this work, Mahua vegetable oil in the presence of red mud as a catalyst for the preparation of bio-diesel is investigated. The cracking process is carried out in a reactor chamber maintained at a temperature of 65°C in order to obtain biodiesel. The product obtained after the cracking process is evaluated for physio-chemical properties such as flash point, fire point, calorific value, and specific gravity, and the obtained values were compared with neat diesel. The biodiesel is then blended with diesel fuel on volume basis such as B25, B50, B75, and B100. The experiment was carried out in a single cylinder, water cooled DI diesel engine to study the emission characteristics. The results revealed that the use of red mud as a catalyst increases the fuel property and reduces the effect of environmental pollution. This method of biodiesel preparation is very much cost effective and the use of red mud as a catalyst further decreases the cost of biodiesel compared to neat diesel.     

Exhaust emission study on neat biodiesel and alcohol blends fueled diesel engine

In this study, neat biodiesel with octanol additive was employed in a diesel engine and its effects on engine emission were studied. The five fuels evaluated were neat palm kernal oil biodiesel, octanol blended with biodiesel by 10%, 20%, and 30% volume, and diesel. All the emissions are reduced by the addition of octanol in biodiesel in all loads owing to the higher oxygen concentration of air/fuel mixtures and improved atomization. Hence, it is concluded that the neat biodiesel and octanol blends can be employed as an alternative fuel for existing unmodified diesel engines owing to its lesser emission characteristics.     

Emission and engine performance analysis of a diesel engine using hydrogen enriched pomegranate seed oil biodiesel

The aim of this study is to determine the availability of pomegranate seed oil biodiesel (POB) as an alternative fuel in diesel engines and evaluate engine performance and emission characteristics of pure hydrogen enriched POB using diesel engine. For this purpose, the intake manifold of the test engine was modified and hydrogen enriched intake air was supplied throughout the experiments. Physical properties of POB and its blend with diesel fuel were also determined. The results showed that measured physical properties of POB are comparable with diesel fuel. According to engine performance experiments, although POB utilization has slight undesirable effects on some engine performance parameters such as brake power output and specific fuel consumption, it can be used as alternative fuel in diesel engines, by this way CO emission can be improved. Finally, hydrogen enrichment experiments indicated that pure hydrogen addition causes a slight improvement in both engine performance and exhaust emissions.     

生物柴油-柴油混合燃料的理化特性研究

对生物柴油-柴油混合燃料直接影响发动机性能和燃料的使用、存储和运输的几种基本物理化学性质进行了研究。通过对不同比例（生物柴油含量分别为0％，20％，100％）的混合燃料的密度、粘度、表面张力、十六烷值、闪点、润滑性、硫含量、冷滤点、凝固点等理化性质的测试和研究，初步探讨了生物柴油含量对混合燃料物性参数的影响规律。     

降低小型柴油机排放的试验研究

从生物混合燃料成分、燃烧室结构和排气再循环等方面探索降低柴油机排放的方法。通过对柴油机排放性能的大量试验研究,结果表明:对于直喷式柴油机,生物混合燃料的NOx排放与柴油的排放基本相当,碳烟排放则比柴油有较大幅度的降低,而涡流室柴油机,NOx的排放量却有大幅度的降低,碳烟排放则比直喷式柴油机有更大幅度的降低,生物燃料的添加比例对NOx的排放影响不大。柴油机采用排气再循环技术后,混合燃料的碳烟排放仍比柴油少,混合燃料可以承载一定的EGR率而不增加碳烟排放。排气再循环可以大幅度地降低NOx排放且与EGR率有关,与燃料的性质关系不大。涡流室柴油机采用生物燃料和排气再循环,可以同时降低NOx和碳烟的排放,排放效果非常优良。     

代用燃料在柴油机中的应用研究

本文对植物油,生物柴油,乳化油,乙醇/柴油等的制备和理化特性进行了研究.通过柴油机台架试验,研究了柴油机燃用生物柴油、乙醇/柴油、微乳燃油的排放特性.对比试验表明:生物柴油CO,碳氢(HC)和颗粒物(PM)的比排放下降幅度分别为34.6％,40.2％和28.9％,但NOx比排放增加了6.63％;柴油机燃用乙醇/柴油时,...     

Effect of nanoparticles and hydrogen on combustion performance and exhaust emission of corn blended biodiesel in compression ignition engine with advanced timing

In this study, we have evaluated the influence of Zinc oxide and Titanium dioxide nanoparticles addition in hydrogen-corn blended biodiesel combustion performance and exhaust emission using a dual direct-injection compression-ignition engine. 5% of Zinc oxide and Titanium dioxide were mixed with corn-vegetable oil methyl ester under ultrasonication. Results revealed that the addition of nanoparticles improved the Brake power by 22% (Titanium dioxide) and 4% (Zinc oxide). Consequently, 18% and 15% reduction in brake specific fuel consumption indeed at 50% load compared to neat diesel. Furthermore, the addition of nanoparticles also resulted in a reduction of emission values of 37% and 26% in hydrocarbon, 26% and 36% for carbon monoxide, 19% and 15% in nitrogen oxide and followed by 13% and 8% of smoke opacity. Therefore, the results proved that hydrogen-corn biodiesel blended with nanoparticles additive reports a positive effect on compression-ignition diesel engines without major modifications in engine.     

Effect of induction on exhaust gas recirculation and hydrogen gas in compression ignition engine with simarouba oil in dual fuel mode

Biofuels extracted from non-edible oil is sustainable and can be used as an alternative fuel for internal combustion engines. This study presents the performance, emission and combustion characteristic analysis by using simarouba oil (obtained from Simarouba seed) as an alternative fuel along with hydrogen and exhaust gas recirculation (EGR) in a compression ignition (CI) engine operating on dual fuel mode. Simarouba biofuel blend (B20) was prepared on volumetric basis by mixing simarouba oil and diesel in the proportion of 20% and 80% (v/v), respectively. Hydrogen gas was introduced at the flow rate of 2.67 kg/min, and EGR concentration was maintained at 30% of total air introduction. Performance, combustion and emission characteristics analysis were examined with biodiesel (B20), biodiesel with hydrogen substitution and biodiesel, hydrogen with EGR and were compared with neat diesel operation. Results indicate that BTE of the engine operating with biodiesel B20 was decreased when compared to neat diesel operation. However, introducing hydrogen along with B20 blend into the combustion chamber shows a slight increase in the BTE by 1%. NO_x emission was increased to 18.13% with the introduction of hydrogen than that of base fuel (diesel) operation. With the introduction of EGR, there is a significant reduction in NO_x emission due to decrease in in-cylinder temperature by 19.07%. A significant reduction in CO, CO_2, and smoke emissions were also noted with the introduction of both hydrogen and EGR. The ignition delay and combustion duration were increased with the introduction of hydrogen, EGR with biodiesel than neat diesel operation. Hence, the proposed biodiesel B20 with H₂ and EGR combination can be applied as an alternative fuel in CI engines.     

Partial hydrogenation and hydrogen induction: A comparative study with B20 operation in a turbocharged CRDI diesel engine

Numerous studies explored the possibility and effective strategies for supplementing hydrogen along with fossil or biofuels on internal combustion engines. Hydrogen is also being employed for formulating fuels such as hydrogen compressed natural gas in the gaseous form and hydrogenated biofuels in the liquid form. The present study evaluates (i) hydrogen usage on the fuel formulation and (ii) investigates the engine operation of an automotive turbocharged diesel engine operated with karanja biodiesel blended diesel (B20) as a reference fuel. Existing literature outlines that biodiesel blends possess lower energy content and emit higher nitric oxide (NO) emission than fossil diesel. The present research paper partially hydrogenates karanja biodiesel using an autoclave reactor with a palladium catalyst to increase the saturation levels and mitigate the biodiesel-NO penalty. Besides, the drop in energy release of B20 is compensated through the provision of hydrogen induction along the intake manifold. The hydrogen flow rates to the turbocharged engine are maintained at a fixed energy share of 10%. Both biodiesel and hydrogenated biodiesel were blended on a volume basis (20%) with fossil diesel (80%) and are designated as B20 and HB20, respectively. The test results reveal that HB20 effectively mitigates the biodiesel-NO penalty with a maximum reduction of 29.8% compared to B20. Further, hydrogen induction yielded a significant improvement (23.7%) in fuel consumption with HB20 relative to B20 without hydrogen addition. The compounding effect of hydrogen usage on the engine operation and fuel formulation exhibited a better performance and emission trade-off at mid load conditions.     

Nozzle flow and atomization characteristics of ethanol blended biodiesel fuel

This study was conducted to investigate the injection and atomization characteristics of biodiesel–ethanol blended fuel. The injection performance of biodiesel–ethanol blended fuel was analyzed from the injection rate characteristics using the injection rate measuring system, and the effective injection velocity and effective spray diameter using the nozzle flow model. Moreover, the atomization characteristics, such as local and overall SMD distributions, overall axial velocity and droplet arrival time were analyzed and compared with these from diesel and biodiesel fuels to obtain the atomization characteristics of biodiesel–ethanol blended fuel.It was revealed that ethanol fuel affects the decrease of the peak injection rate and the shortening of the injection delay due to the decrease of fuel properties, such as fuel density and dynamic viscosity. In addition, the ethanol addition improved the atomization performance of biodiesel fuel, because the ethanol blended fuel has a low kinematic viscosity and surface tension, then that has more active interaction with the ambient gas, compared to BD100.     

生物柴油对直喷式柴油机燃烧和排放的影响

列举了生物柴油的基本物化特性。介绍了生物柴油对直喷式柴油机燃烧和排放的影响。相比普通柴油,燃用生物柴油可以减少CO、CO_2、SO_2、HC、微粒以及碳烟的排放且不会影响柴油机工作性能。采用EGR、乳化油、多次喷射及微粒捕捉器等措施可以进一步降低使用生物柴油的微粒和NOx排放。生物柴油作为一种可再生的替代能源,以其良好的环境效应受到越来越多的关注。     

Combustion of fat and vegetable oil derived fuels in diesel engines

In this article, the status of fat and oil derived diesel fuels with respect to fuel properties, engine performance, and emissions is reviewed. The fuels considered are primarily the methyl esters of fatty acids derived from a variety of vegetable oils and animal fats, and referred to as biodiesel. The major obstacle to widespread use of biodiesel is the high cost relative to petroleum. Economics of biodiesel production are discussed, and it is concluded that the price of the feedstock fat or oil is the major factor determining biodiesel price.Biodiesel is completely miscible with petroleum diesel fuel, and is generally tested as a blend. The use of biodiesel in neat or blended form has no effect on the energy based engine fuel economy. The lubricity of these fuels is superior to conventional diesel, and this property is imparted to blends at levels above 20 vol%. Emissions of PM can be reduced dramatically through use of biodiesel in engines that are not high lube oil emitters. Emissions of NO_x increase significantly for both neat and blended fuels in both two- and four-stroke engines. The increase may be lower in newer, lower NO_x emitting four-strokes, but additional data are needed to confirm this conclusion. A discussion of available data on unregulated air toxins is presented, and it is concluded that definitive studies have yet to be performed in this area. A detailed discussion of important biodiesel properties and recommendations for future research is presented. Among the most important recommendations is the need for all future studies to employ biodiesel of well-known composition and purity, and to report detailed analyses. The purity levels necessary for achieving adequate engine endurance, compatibility with coatings and elastomers, cold flow properties, stability, and emissions performance must be better defined.     

Determination of ecological efficiency in internal combustion engines: The use of biodiesel

This paper evaluates and quantifies the environmental impact from the use of some renewable fuels and fossils fuels in internal combustion engines. The following fuels are evaluated: gasoline blended with anhydrous ethyl alcohol (anhydrous ethanol), conventional diesel fuel, biodiesel in pure form and blended with diesel fuel, and natural gas. For the case of biodiesel, its complete life cycle and the closed carbon cycle (photosynthesis) were considered. The ecological efficiency concept depends on the environmental impact caused by CO₂, SO₂, NO_x and particulate material (PM) emissions. The exhaust gases from internal combustion engines, in the case of the gasoline (blended with alcohol), biodiesel and biodiesel blended with conventional diesel, are the less polluting; on the other hand, the most polluting are those related to conventional diesel. They can cause serious problems to the environment because of their dangerous components for the human, animal and vegetable life. The resultant pollution of each one of the mentioned fuels are analyzed, considering separately CO₂, SO₂, NO_x and particulate material (PM) emissions. As conclusion, it is possible to calculate an environmental factor that represents, qualitatively and quantitative, the emissions in internal combustion engines that are mostly used in urban transport. Biodiesel in pure form (B100) and blended with conventional diesel as fuel for engines pollute less than conventional diesel fuel. The ecological efficiency for pure biodiesel (B100) is 86.75%; for biodiesel blended with conventional diesel fuel (B20, 20% biodiesel and 80% diesel), it is 78.79%. Finally, the ecological efficiency for conventional diesel, when used in engines, is 77.34%; for gasoline, it is 82.52%, and for natural gas, it is 91.95%. All these figures considered a thermal efficiency of 30% for the internal combustion engine.     

Performance characteristics of a low heat rejection diesel engine operating with biodiesel

Vegetable oils are a promising alternative among the different diesel fuel alternatives. However, the high viscosity, poor volatility and cold flow characteristics of vegetable oils can cause some problems such as injector coking, severe engine deposits, filter gumming, piston ring sticking and thickening of lubrication oil from long-term use in diesel engines. These problems can be eliminated or minimized by transesterification of the vegetable oils to form monoesters. These monoesters are known as biodiesel. The important advantages of biodiesel are lower exhaust gas emissions and its biodegradability and renewability compared with petroleum-based diesel fuel. Although the transesterification improves the fuel properties of vegetable oil, the viscosity and volatility of biodiesel are still worse than that of petroleum diesel fuel. The energy of the biodiesel can be released more efficiently with the concept of low heat rejection (LHR) engine. The aim of this study is to apply LHR engine for improving engine performance when biodiesel is used as an alternative fuel. For this purpose, a turbocharged direct injection (DI) diesel engine was converted to a LHR engine and the effects of biodiesel (produced from sunflower oil) usage in the LHR engine on its performance characteristics have been investigated experimentally. The results showed that specific fuel consumption and the brake thermal efficiency were improved and exhaust gas temperature before the turbine inlet was increased for both fuels in the LHR engine.     

非直喷式增压柴油机燃用生物柴油的性能与排放特性

研究了非直喷式增压柴油机燃用柴油一生物柴油混合燃料的性能和排放特性。未对原机作任何调整和改动,研究了不同生物柴油掺混比例的混合燃料对功率、油耗、烟度和NOx排放的影响。结果表明：非直喷式柴油机燃用生物柴油后柴油机功率略有下降,油耗有所上升,烟度大幅下降,NOx排放增加明显。油耗、烟度和NOx的变化均与生物柴油掺混比例呈线性关系,合适的生物柴油掺混比例即可以保持柴油机的性能,又可有效地降低碳烟排放,且不引起NOx排放的显著变化。对于该增压柴油机,掺混生物柴油对外特性下的排放影响最大,影响最小的为标定转速下的负荷特性。不论是全负荷还是部分负荷,燃用生物柴油时低速下的烟度降低和NOx上升幅度均比高速时大,而同转速下高负荷时烟度降低和NOx上升更为明显。