Production of biodiesel fuels from linseed oil using methanol and ethanol in non-catalytic SCF conditions

Methyl and ethyl esters as biodiesel fuels were prepared from linseed oil with transesterification reaction in non-catalytic supercritical fluids conditions. Biodiesel fuel is a renewable substitute fuel for petroleum diesel fuel made from vegetable or animal fats. Biodiesel fuel has better properties than that of petroleum diesel fuel such as renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. The purpose of the transesterification process is to lower the viscosity of the oil. The viscosity values of linseed oil methyl and ethyl esters highly decreases after transesterification process. The viscosity values of vegetable oils vary between 27.2 and 53.6 mm² s^?1, whereas those of vegetable oil methyl esters between 3.59 and 4.63 mm² s^?1. Compared with no. 2 diesel fuel, all of the vegetable oil methyl esters were slightly viscous. The flash point values of vegetable oil methyl esters are highly lower than those of vegetable oils. The transesterification of linseed oil in supercritical fluids such as methanol and ethanol has proved to be the most promising process. Methanol is the commonly used alcohol in this process, due in part to its low cost. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The most important variables affecting the methyl ester yield during the transesterification reaction are molar ratio of alcohol to vegetable oil and reaction temperature. Biodiesel has become more attractive recently because of its environmental benefits. Biodiesel is an environmentally friendly fuel that can be used in any diesel engine without modification.     

Effect of injection pressure on performance,emission and combustion characteristics of high linolenic linseed oil methyl ester in a DI diesel engine

Due to the increasing demand for fossil fuels and environmental threat, a number of renewable sources of energy have been studied worldwide. In the present investigation a high linolenic linseed oil methyl ester has been investigated in a constant speed, DI diesel engine with varied fuel injection pressures (200, 220 and 240 bar). The main objective of this study is to investigate the effect of injection pressures on performance, emissions and combustion characteristics of the engine. The test results show that the optimum fuel injection pressure is 240 bar with linseed methyl ester. At this optimized pressure the thermal efficiency is similar to diesel and a reduction in carbon monoxide, unburned hydrocarbon and smoke emissions with an increase in the oxides of nitrogen was noticed compared to diesel. The combustion analysis shows that, the ignition delay is lower at higher injection pressures compared to diesel and the peak pressure is also higher at full load. The combustion duration was almost same at all the injection pressures. It is concluded that linseed methyl ester at 240 bar injection pressure is more efficient than 200 and 220 bar, except for nitrogen oxides emission.     

Transesterified Hingan (Balanites) oil as a fuel for compression ignition engines

The study endeavor to utilize esters of Balanites aegyptiaca (L.) Del(Balanites) as a fuel for diesel engine. Ester developed from balanites oil by the transesterification process is investigated for its properties and the engine performance. A single stage alkali-catalyzed esterification process by using 1.25% KOH, methyl alcohol 8:1 molar ratio with respect to balanites oil, gives the maximum ester yield of 95%. The performance and emission characteristics of the engine are analyzed using balanites oil methyl esters and diesel as fuel. The viscosity of balanites oil is found to be decreased by 89% after esterification, and the calorific value of balanites oil methyl esters is nearly 94% of the diesel fuel. The engine performance with balanites oil methyl ester as a fuel resembles to that of conventional diesel fuel, while the exhaust gas emissions are reduced with the use of balanites oil methyl esters.     

Effects of blending alcohols with poultry fat methyl esters on cold flow properties

The low temperature operability, kinematic viscosity, and acid value of poultry fat methyl esters were improved with addition of ethanol, isopropanol, and butanol with increasing alcohol content. The flash point decreased and moisture content increased upon addition of alcohols to poultry fat methyl esters. The alcohol type did not result in a statistically significant difference in low temperature performance at similar blend ratios in poultry fat methyl esters. In addition, blends of ethanol in poultry fat methyl esters afforded the least viscous mixtures, whereas isopropanol and butanol blends were progressively more viscous, but still within specifications contained in ASTM D6751 and EN 14214. Blends of alcohols in poultry fat methyl esters resulted in failure of the flash point specifications found in ASTM D6751 and EN 14214. Flash points of butanol blends were superior to those of isopropanol and ethanol blends, with the 5 vol.% butanol blend exhibiting a flash point (57 °C) superior to that of No. 2 diesel fuel (52 °C). Blends of alcohols in poultry fat methyl esters resulted in an improvement in acid value with increasing content of alcohol. An increase in moisture content of biodiesel was observed with increasing alcohol content, with the effect being more pronounced in ethanol blends versus isopropanol and butanol blends. Finally, none of the alcohol–methyl ester samples exhibited a phase separation at sub-ambient temperatures.     

The effects of turbocharger on the performance and exhaust emissions of a diesel engine fuelled with biodiesel

This paper investigates the effects of turbocharger on the performance of a diesel engine using diesel fuel and biodiesel in terms of brake power, torque, brake specific consumption and thermal efficiency, as well as CO and NO_x emissions. For this aim, a naturally aspirated four-stroke direct injection diesel engine was tested with diesel fuel and neat biodiesel, which is rapeseed oil methyl ester, at full load conditions at the speeds between 1200 and 2400 rpm with intervals of 200 rpm. Then, a turbocharger system was installed on the engine and the tests were repeated for both fuel cases. The evaluation of experimental data showed that the brake thermal efficiency of biodiesel was slightly higher than that of diesel fuel in both naturally aspirated and turbocharged conditions, while biodiesel yielded slightly lower brake power and torque along with higher fuel consumption values. It was also observed that emissions of CO in the operations with biodiesel were lower than those in the operations with diesel fuel, whereas NO_x emission in biodiesel operation was higher. This study reveals that the use of biodiesel improves the performance parameters and decreases CO emissions of the turbocharged engine compared to diesel fuel.     

Methyl ester of peanut (Arachis hypogea L.) seed oil as a potential feedstock for biodiesel production

The peanut (Arachis hypogea L.) seed oil was extracted from the seeds of the peanut that grows in SE Anatolia of Turkey. Oil was obtained in 50 wt/wt.%, by solvent extraction. Peanut (A. hypogea L.) seed oil was investigated as an alternative feedstock for the production of a biodiesel fuel. Biodiesel was prepared from peanut by transesterification of the crude oil with methanol in the presence of NaOH as catalyst. A maximum oil to ester conversion was 89%. The viscosity of biodiesel oil is nearer to that of petroleum diesel and the calorific value is about 6% less than that of diesel. Peanut seed oil have about 8.3% less heating value than that of diesel oil due to the oxygen content in their molecules. The quality of biodiesel is most important for engine part of view and various standards have been specified to check the quality. The important properties of peanut oil and its methyl ester (biodiesel) such as density, kinematic viscosity, flash point, iodine number, neutralization number, pour point, cloud point, cetane number are found out and compared to those of no. 2 petroleum diesel, ASTM and EN biodiesel standards. The comparison shows that the methyl ester has relatively closer fuel properties to diesel than that of raw peanut seed oil.     

Effects of ethylene glycol ethers on diesel fuel properties and emissions in a diesel engine

The effect of ethylene glycol ethers on both the diesel fuel characteristics and the exhaust emissions (CO, NO_x, smoke and hydrocarbons) from a diesel engine was studied. The ethers used were monoethylene glycol ethyl ether (EGEE), monoethylene glycol butyl ether (EGBE), diethylene glycol ethyl ether (DEGEE). The above effect was studied in two forms: first by determining the modification of base diesel fuel properties by using blends with oxygen concentration around 4 wt.%, and second by determining the emission reductions for blends with low oxygen content (1 wt.%) and with 2.5 wt.% of oxygen content. The addition of DEGEE enhances base diesel fuel cetane number, but EGEE and EGBE decrease it. For concentrations of ?4 wt.% of oxygen, EGEE and diesel fuel can show immiscibility problems at low temperatures (?0 °C). Also, every oxygenated compound, according to its boiling point, modifies the distillation curve at low temperatures and the distillate percentage increases. These compounds have a positive effect on diesel fuel lubricity, and slightly decrease its viscosity. Blends with 1 and 2.5 wt.% oxygen concentrations were used in order to determine their influence on emissions at both full and medium loads and different engine speeds. Generally, all compounds help to reduce CO, and hydrocarbon emissions, but not smoke. The best results were obtained for blends with 2.5 wt.% of oxygen. At this concentration, the additive efficiency in decreasing order was EGEE > DEGEE > EGBE for CO emissions and DGEE > EGEE > EGBE for hydrocarbon emissions. For NO_x, both its behaviour and the sequence are opposite to that of CO.     

Potential of bioethanol production from agricultural wastes in Iran

The production of bioethanol from agricultural residues such as wheat, barley, sugar cane, corn and rice in Iran is investigated in this paper. In Iran, agricultural residues are not commonly used for energy application. This paper aims to cover several perspectives on the size of the bioethanol feedstock resource in Iran. Crop residues and sugar cane bagasse are included in feedstock for production of bioethanol. There are approximately 17.86 MT of wasted crops in Iran that can potentially produce 4.91 GL of bioethanol per year. Wheat, sugar cane bagasse, rice, barely and corn are the most favourable bioethanol production source in Iran. Agricultural waste materials can be used for production of bioethanol fuel. Bioethanol can be considered as the optimum alternative fuel for gasoline. Bioethanol is an environmentally friendly fuel and has the potential to provide comparable engine performance results.     

Experimental investigation of the effect of compression ratio and injection pressure in a direct injection diesel engine running on Jatropha methyl ester

Being a fuel of different origin, the standard design parameters of a diesel engine may not be suitable for Jatropha methyl ester (JME). This study targets at finding the effects of the engine design parameters viz. compression ratio (CR) and fuel injection pressure (IP) jointly on the performance with regard to fuel consumption (BSFC), brake thermal efficiency (BTHE) and emissions of CO, CO₂, HC, NO_x and Smoke opacity with JME as fuel. Comparison of performance and emission was done for different values of compression ratio along with injection pressure to find best possible combination for operating engine with JME. It is found that the combined increase of compression ratio and injection pressure increases the BTHE and reduces BSFC while having lower emissions. For small sized direct injection constant speed engines used for agricultural applications (3.5 kW), the optimum combination was found as CR of 18 with IP of 250 bar.     

6BTA 5.9 G2-1 Cummins engine performance and emission tests using methyl ester mahua (Madhuca indica) oil/diesel blends

Neat mahua oil poses some problems when subjected to prolonged usage in CI engine. The transesterification of mahua oil can reduce these problems. The use of biodiesel fuel as substitute for conventional petroleum fuel in heavy-duty diesel engine is receiving an increasing amount of attention. This interest is based on the properties of bio-diesel including the fact that it is produced from a renewable resource, its biodegradability and potential to exhaust emissions. A Cummins 6BTA 5.9 G2- 1, 158 HP rated power, turbocharged, DI, water cooled diesel engine was run on diesel, methyl ester of mahua oil and its blends at constant speed of 1500 rpm under variable load conditions. The volumetric blending ratios of biodiesel with conventional diesel fuel were set at 0, 20, 40, 60, and 100. Engine performance (brake specific fuel consumption, brake specific energy consumption, thermal efficiency and exhaust gas temperature) and emissions (CO, HC and NOx) were measured to evaluate and compute the behavior of the diesel engine running on biodiesel. The results indicate that with the increase of biodiesel in the blends CO, HC reduces significantly, fuel consumption and NOx emission of biodiesel increases slightly compared with diesel. Brake specific energy consumption decreases and thermal efficiency of engine slightly increases when operating on 20% biodiesel than that operating on diesel.     

Comparative performance studies of a 4-stroke CI engine operated on dual fuel mode with producer gas and Honge oil and its methyl ester (HOME) with and without carburetor

In order to meet the energy requirements, there has been growing interest in alternative fuels like biodiesels, methyl alcohol, ethyl alcohol, biogas, hydrogen and producer gas to provide a suitable diesel oil substitute for internal combustion engines. Biomass is basically composed of carbon, hydrogen and oxygen. A proximate analysis of biomass indicates the volatile matter to be between 60–80% and 20–25% carbon and the rest, ash. The first part of sub-stoichiometric oxidation leads to the loss of volatiles from biomass and is exothermic; it results in peak temperatures of 1400–1500 K and generation of gaseous products like carbon monoxide, hydrogen in some proportions and carbon dioxide and water vapor, which in turn are reduced in part to carbon monoxide and hydrogen by the hot bed of charcoal generated during the process of gasification. Therefore, solid biomass can be converted into a mixture of combustible gases, and subsequently utilized for combustion in a CI engine. Producer gas, if used in dual fuel mode, is an excellent substitute for reducing the amount of diesel consumed by the CI engine. Downdraft moving bed gasifiers coupled with an IC engine are a good choice for moderate quantities of available biomass, up to 500 kW of electric power. Vegetable oils present a very promising alternative to diesel oil since they are renewable and have similar properties. Vegetable oils offer almost the same power output with slightly lower thermal efficiency when used in diesel engines [1], [2], [3], [4], [5], [6], [7]. Research in this direction with edible oils have yielded encouraging results, but their use as fuel for diesel engines has limited applications due to higher domestic requirement [8], [9], [10]. In view of this, Honge oil (Pongamia Pinnata Linn) is selected and its viscosity is reduced by the transesterification process to obtain Honge oil methyl ester (HOME). Since vegetable oils produce higher smoke emissions, dual fuel operation could be adopted in order to improve their performance. A gas carburetor was suitably designed to maximize the engine performance in dual fuel mode with Honge oil–producer gas and HOME–producer gas respectively. Thus bio-derived gas and vegetable oil, when used in a dual fuel mode with carburetor, resulted in better performance with reduced emissions.     

Biodiesel production from waste chicken fat based sources and evaluation with Mg based additive in a diesel engine

In this study, chicken fat biodiesel with synthetic Mg additive was studied in a single-cylinder, direct injection (DI) diesel engine and its effects on engine performance and exhaust emissions were studied. A two-step catalytic process was chosen for the synthesis of the biodiesel. Methanol, sulphuric acid and sodium hydroxide catalyst were used in the reaction. To determine their effects on viscosity and flash point of the biodiesel, reaction temperature, methanol ratio, type and amount of catalyst were varied as independent parameters. Organic based synthetic magnesium additive was doped into the biodiesel blend by 12 μmol Mg. Engine tests were run with diesel fuel (EN 590) and a blend of 10% chicken fat biodiesel and diesel fuel (B10) at full load operating conditions and different engine speeds from 1800 to 3000 rpm. The results showed that, the engine torque was not changed significantly with the addition of 10% chicken fat biodiesel, while the specific fuel consumption increased by 5.2% due to the lower heating value of biodiesel. In-cylinder peak pressure slightly rose and the start of combustion was earlier. CO and smoke emissions decreased by 13% and 9% respectively, but NO_x emission increased by 5%.     

Effect of injection timing on the exhaust emissions of a diesel engine using diesel–methanol blends

Environmental concerns and limited resource of petroleum fuels have caused interests in the development of alternative fuels for internal combustion (IC) engines. For diesel engines, alcohols are receiving increasing attention because they are oxygenated and renewable fuels. Therefore, in this study, the effect of injection timing on the exhaust emissions of a single cylinder, naturally aspirated, four-stroke, direct injection diesel engine has been experimentally investigated by using methanol-blended diesel fuel from 0% to 15% with an increment of 5%. The tests were conducted for three different injection timings (15°, 20° and 25 °CA BTDC) at four different engine loads (5 Nm, 10 Nm, 15 Nm, 20 Nm) at 2200 rpm. The experimental test results showed that Bsfc, NO_x and CO₂ emissions increased as BTE, smoke opacity, CO and UHC emissions decreased with increasing amount of methanol in the fuel mixture. When compared the results to those of original injection timing, NO_x and CO₂ emissions decreased, smoke opacity, UHC and CO emissions increased for the retarded injection timing (15 °CA BTDC). On the other hand, with the advanced injection timing (25 °CA BTDC), decreasing smoke opacity, UHC and CO emissions diminished, and NO_x and CO₂ emissions boosted at all test conditions. In terms of Bsfc and BTE, retarded and advanced injection timings gave negative results for all fuel blends in all engine loads.     

Performance and emission characteristics of a diesel engine using isobutanol–diesel fuel blends

The aim of this study is to investigate the suitability of isobutanol–diesel fuel blends as an alternative fuel for the diesel engine, and experimentally determine their effects on the engine performance and exhaust emissions, namely break power, break specific fuel consumption (BSFC), break thermal efficiency (BTE) and emissions of CO, HC and NO_x. For this purpose, four different isobutanol–diesel fuel blends containing 5, 10, 15 and 20% isobutanol were prepared in volume basis and tested in a naturally aspirated four stroke direct injection diesel engine at full -load conditions at the speeds between 1200 and 2800 rpm with intervals of 200 rpm. The results obtained with the blends were compared to those with the diesel fuel as baseline. The test results indicate that the break power slightly decreases with the blends containing up to 10% isobutanol, whereas it significantly decreases with the blends containing 15 and 20% isobutanol. There is an increase in the BSFC in proportional to the isobutanol content in the blends. Although diesel fuel yields the highest BTE, the blend containing 10% isobutanol results in a slight improvement in BTE at high engine speeds. The results also reveal that, compared to diesel fuel, CO and NO_x emissions decrease with the use of the blends, while HC emissions increase considerably.     

Assessment of flash-boiling for pulse detonation engines

Liquid-fueled pulse detonation engines must complete the process of feeding, mixing, and purging in milliseconds. Such an engine is extremely sensitive to the Sauter mean diameter (SMD – must be less than 10 μm) and particle size distribution of the fuel, requirements which are difficult if impossible for most fuel injectors to achieve. This study selected an injector from a direct injection engine and used the aviation fuel JP-8. Utilizing a wide range of operation pressure and duration time, the injection timing and equivalence ratio could be accurately controlled with good response time. The results of the experiment indicate that an SMD of less than 10 μm can be achieved with a fuel pressure greater than 8 MPa. This condition, however, resulted in an overly long injection penetration. This study further incorporated the concept of flash boiling to derive a smaller SMD. However, this causes carbon deposition to occur due to cracking or thermal reaction. To circumvent this phenomenon, this study established a deoxygenation device to mitigate oxidization, further investigating the influence of heating temperature on the generation of deposition. The results of spray distribution indicated that when the fuel is heated to 100 °C, only 6 MPa is necessary for achieving fuel droplet characteristics favorable for detonation. Regarding deoxygenation, the results were most significant in fuel heated to 500 °C.     

Performance of low-temperature differential Stirling engines

In this paper, two single-acting, twin power piston and four power pistons, gamma-configuration, low-temperature differential Stirling engine are designed and constructed. The engine performance is tested with air at atmospheric pressure by using a gas burner as a heat source. The engine is tested with various heat inputs. Variations of engine torque, shaft power and brake thermal efficiency at various heat inputs with engine speed and engine performance are presented. The Beale number obtained from testing of the engines is also investigated. The results indicate that, for twin power piston engine, at a maximum actual heat input of 2355 J/s with a heater temperature of 589 K, the engine produces a maximum torque of 1.222 N m at 67.7 rpm, a maximum shaft power of 11.8 W at 133 rpm, and a maximum brake thermal efficiency of 0.494% at 133 rpm, approximately. For the four power pistons engine, the results indicate that at the maximum actual heat input of 4041 J/s with the heater temperature of 771 K, the engine produces a maximum torque of 10.55 N m at 28.5 rpm, a maximum shaft power of 32.7 W at 42.1 rpm, and a maximum brake thermal efficiency of 0.809% at 42.1 rpm, approximately.     

An experimental investigation of a household size trigeneration

A household size trigeneration based on a small-scale diesel engine generator set is designed and realized in laboratory. Experimental tests are carried out to evaluate the performance and emissions of the original single generation (diesel engine generator); and the performances of the whole trigeneration including the diesel generator within the trigeneration system, the heat exchangers which are used to recover heat from engine exhaust, the absorption refrigerator which is driven by the exhaust heat; and the emissions from the whole trigeneration.Comparisons of the test results of two generations are also performed. The test results show that the total thermal efficiency of trigeneration reaches to 67.3% at the engine full load, comparing to that of the original single generation 22.1% only. Within the range of engine loads tested, the total thermal efficiencies of trigeneration are from 205% to 438% higher than that of the thermal efficiency of single generation.The CO₂ emission per unit (kW h) of useful energy output from trigeneration is 0.401 kg CO₂/kW h at the engine full load, compared to that of 1.22 kg CO₂/kW h from single generation at the same engine load. Within the range of engine loads tested, the reductions of CO₂ emission per unit (kW h) of trigeneration output are from 67.2% to 81.4% compared to those of single generation.The experimental results show that the idea of realizing a household size trigeneration is feasible; the design and the set-up of the trigeneration is successful. The experimental results show that the innovative small-scale trigeneration is able to generate electricity, produce heat and drive a refrigeration system, simultaneously from a single fuel (diesel) input.     

Application of exhaust gas fuel reforming in diesel and homogeneous charge compression ignition (HCCI) engines fuelled with biofuels

This paper documents the application of exhaust gas fuel reforming of two alternative fuels, biodiesel and bioethanol, in internal combustion engines. The exhaust gas fuel reforming process is a method of on-board production of hydrogen-rich gas by catalytic reaction of fuel and engine exhaust gas. The benefits of exhaust gas fuel reforming have been demonstrated by adding simulated reformed gas to a diesel engine fuelled by a mixture of 50% ultra low sulphur diesel (ULSD) and 50% rapeseed methyl ester (RME) as well as to a homogeneous charge compression ignition (HCCI) engine fuelled by bioethanol. In the case of the biodiesel fuelled engine, a reduction of NO_x emissions was achieved without considerable smoke increase. In the case of the bioethanol fuelled HCCI engine, the engine tolerance to exhaust gas recirculation (EGR) was extended and hence the typically high pressure rise rates of HCCI engines, associated with intense combustion noise, were reduced.     

Comparison of biodiesel production from crude Jatropha oil and Krating oil by supercritical methanol transesterification

This work compared the production of biodiesel from two different non-edible oils with relatively high acid values (Jatropha oil and Krating oil). Using non-catalytic supercritical methanol transesterification, high methyl ester yield (85–90%) can be obtained in a very short time (5–10 min). However, the dependence of fatty acid methyl ester yield on reaction conditions (i.e., temperature and pressure) and the optimum conditions were different by the source of oils and were correlated to the amount of free fatty acids (FFAs) and unsaturated fatty acid content in oils. Krating oil, which has higher FFAs and unsaturated fatty acid content, gave higher fatty acid methyl ester yield of 90.4% at 260 °C, 16 MPa, and 10 min whereas biodiesel from Jatropha oil gave fatty acid methyl ester yield of 84.6% at 320 °C, 15 MPa and 5 min using the same molar ratio of methanol to oil 40:1. The product quality from crude Krating oil met the biodiesel standard. Pre-processing steps such as degumming or oil purification are not necessary.     

Combustion analysis of preheated crude sunflower oil in an IDI diesel engine

In this study, preheated crude sunflower oil (PCSO) was tested for combustion and emission properties against petroleum based diesel fuel (PBDF) in a naturally aspirated, indirect injection (IDI) engine. The cylinder gas pressure and heat release curves for PCSO at 75 °C were similar to those of PBDF. The ignition delays for the PCSO were longer and the start of injection timing was earlier than for PBDF. The difference in the average brake torque was a decrease of 1.36% for PCSO though this was statistically insignificant. The brake specific fuel consumption increased by almost 5% more or less in proportion to the difference in calorific value, so that the 1.06% increase in thermal efficiency was again statistically insignificant.The emission test results showed that the decreases in CO₂ emissions and smoke opacity 2.05% and 4.66%, respectively; however, this was not statistically significant, though in line with the apparent increase in thermal efficiency. There was a significant 34% improvement in the emissions of unburnt hydrocarbons. Carbon monoxide increased by 1.77% again the result was not statistically significant given the small number of repeat tests.The use of PCSO does not have any negative effects on the engine performance and emissions in short duration engine testing.