共查询到18条相似文献,搜索用时 93 毫秒
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竹炭对碱性品红的吸附性能研究 总被引:2,自引:1,他引:1
研究了竹炭对碱性品红染料的吸附性能,考察了竹炭用量、竹炭粒径、吸附时间、pH值、温度和染料浓度等因素对吸附效果的影响。实验结果表明,脱色率随着竹炭用量的增加而增大,竹炭粒径的减小而增加,用200~300目竹炭处理25 mg/L的碱性品红溶液,当加入量为4 g/L时,吸附平衡时间为10 h,脱色率为90.1%;在不改变碱性品红结构的pH范围内(pH<9),脱色率均大于74%;溶液温度升高,脱色率增大,但随着染料浓度增加,温度对脱色率的影响越来越小;Langmuir等温方程比Freundlich等温方程更适合于描述竹炭对碱性品红的吸附行为。 相似文献
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环糊精聚合物对碱性品红的吸附 总被引:6,自引:0,他引:6
以β-环糊精及氯乙酸为起始原料,环氧氯丙烷为交联剂,合成了具有不同取代度和不同交联度的羧甲基-β-环糊精交联聚合物(PCM--βCD)。研究了吸附时间(振荡时间)、溶液酸度、温度、碱性品红初始浓度等吸附条件对吸附性能的影响,考察了不同取代度和不同交联度的PCM-β-CD对碱性品红的吸附能力。实验结果表明:室温条件下振荡2 h即可达到吸附平衡;pH值为5~6时吸附效果较好。PCM-β-CD对碱性品红的吸附量与碱性品红溶液初始浓度有关。随着碱性品红溶液质量浓度增加,PCM-β-CD的QA也逐渐增加;QA随取代度的增大而降低,而交联度对QA则无明显影响;用IR和XRD表征了PCM-β-CD的结构。 相似文献
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以自制海藻酸纤维为吸附剂,考察了吸附剂用量、溶液温度、吸附时间和溶液pH值等因素对海藻酸纤维吸附碱性品红的吸附效果的影响。结果表明:脱色率随海藻酸纤维加入量的增加而提高,随着溶液温度升高而迅速下降;加酸或加碱都不利于海藻酸纤维对碱性品红的吸附;对于40 mg/L的碱性品红溶液,当海藻酸纤维的加入量为5 g/L,室温下振荡40 min既能达到吸附平衡,脱色率可达96%;Freundlich等温方程能很好地描述海藻酸纤维对碱性品红的吸附,其吸附行为是物理吸附,吸附过程为熵减过程;海藻酸纤维经过8次再生后,对碱性品红的脱色率仍可达到93%以上,可重复利用。 相似文献
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改性钢渣处理碱性品红染料废水研究 总被引:7,自引:0,他引:7
通过对钢渣的改性,大大提高了钢渣处理碱性品红染料废水的能力,考察了改性钢渣与钢渣吸附性能的比较、改性钢渣颗粒度大小、溶液pH、固液比等因素对吸附的影响以及吸附等温曲线.结果表明:改性吸附剂有更好的吸附能力,脱色率达98.89%,吸附量可达到71.9mg/g,吸附剂的再生简单易行。 相似文献
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《分离科学与技术》2012,47(7):1038-1043
To prepare a novel biosorbent, we modified waste beer yeast with citric acid using NaH2PO4 as catalyst in N,N-dimethylformamide. We characterized the absorbent using Fourier transform infrared and X-ray photoelectron spectroscopy. We examined the factors of pH, temperature, adsorption time, initial lysozyme concentration, and NaCl ionic strength on the adsorption capacity. Based on the Langmuir isotherm, the adsorption capacity of lysozyme was 909.09 mg · g?1, 11.06-fold higher than that of the unmodified. When it was eluted by 1.0 mol · L?1 NaCl, the desorption efficiency reached 84.8%. We then used the modified waste beer yeast to separate and purify the lysozyme from egg white, and the lysozyme could be purified in 27.5-fold in a single step with a total enzyme activity recovery of 71.3%. In addition, the regenerated biomass could be used again with little loss of the adsorption capacity. We found that the Langmuir model fitted the lysozyme adsorption isotherm better. Taken together, the modified waste beer yeast can purify lysozyme from chicken egg white in a rapid and cost-efficient way. 相似文献
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H. M. Asfour O. A. Fadali M. M. Nassar M. S. El-Geundi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(1):21-27
Equilibrium conditions of adsorption of a basic dye on hardwood sawdust were studied using the Langmuir and Freundlich isotherms. Two sets of experiments were carried out at different particle sizes and temperatures. The adsorption of the basic dye on hardwood was found to conform with the two isotherms. The capacity of hardwood for the adsorption of basic dye was found to increase by decreasing the particle size and increasing the temperature. The cost of hardwood adsorbent is only 8.4% that of activated carbon. 相似文献
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Gautham Madenoor Ramapriya Mohit Tawarmalani Rakesh Agrawal 《American Institute of Chemical Engineers》2014,60(3):1091-1097
Basic distillation configurations have been well studied, comprising of energy efficient (n ? 1)‐column configurations that can be used to separate an n‐component nonazeotropic feed mixture into its components. In this article, we present new (n ? 1)‐column configurations which differ from the conventional basic configurations due to the introduction of extra intermediate sections and the additional transfer‐streams associated with submixtures of these sections. We demonstrate using four‐component examples that these small differences lead to some interesting nonintuitive physical effects in the new configurations, resulting in large energy savings compared to the basic configurations. The proposed configurations offer more operable and energy efficient options for onsite implementation than the corresponding optimally operated basic configurations. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1091–1097, 2014 相似文献
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研究了利用游离酵母细胞转化葡萄糖为果糖1,6-二磷酸(FDP)的反应条件。采用甲苯进行细胞透性化处理获得优化效果。合适的反应条件为:温度35~40℃、pH6.0、葡萄糖浓度大于0.1mol/L和无机磷浓度小于0.2mol/L。在该条件下,于补料分批式反应中,FDP积累浓度达到0.399mol/L(135.65g/L),对糖收率达到28.2%。 相似文献
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Stephen J. Allen Gordon McKay K. Y. H. Khader 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1989,45(4):291-302
The adsorption of two basic dyes in aqueous solutions onto lignite is reported. The adsorption equilibrium isotherms are recorded for the dyes in single component solution. The isotherms are plotted to obtain the Freundlich constants, the Langmuir constants, and the Redlich-Peterson constants. 相似文献
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利用碱式碳酸镁的催化功能及易分解特性,实现间苯二酚、甲醛的快速凝胶,炭化得到孔隙发达的整体式多孔炭(MCM-Mg),其轴向抗压强度达9.4 MPa。与普通碳酸盐催化的样品相比,MCM-Mg孔隙更为发达。273 K下该系列样品的静态CO2吸附量可达3.49~4.50 mmol·g-1 (0.1 MPa),0.015 MPa最高可达1.87 mmol·g-1。研究发现,微孔对材料吸附性能起主导作用;MCM-Mg的单位微孔比表面积可吸附7.15 μmol CO2,超过了大部分活化法制备的炭材料。多组分动态穿透实验表明,该系列材料可实现CO2/N2的完全分离;材料具有良好的耐水汽性能和循环吸附-脱附性能,室温下经惰性气体吹扫即可实现再生。 相似文献