Utilization of moringa oleifera and nanofiltration membrane to treat palm oil mill effluent (POME)

The palm oil mill effluent imposes environmental issues because of natural and supplement substance. This waste has a significant amount of biological oxygen demand, total suspended solids, chemical oxygen demand, and turbidity. Moringa oleifera seeds′ performance analysis as natural coagulants during the pretreatment stage of palm oil mill effluent before it is filtered through commercial nanofiltration membrane is the focus of the current study. The untreated palm oil mill effluent has 2,410 mg/L biological oxygen demand, 3,900 mg/L chemical oxygen demand, 865 NTU turbidity, 41,900 mg/L total suspended solids, and 4.61 pH. The significant reduction occurred in the feed parameters viz., 91.7 % for biological oxygen demand, 83.0 % for chemical oxygen demand, 67.7 % for total dissolved solids, and 72.8 % for turbidity after the pretreatment; however, the pH increased to 4.88. Design expert® was used to design the experiments and optimize the palm oil mill effluent pretreatment process via a one-factor experimental design. The optimized solution has a 0.994 desirability index. Finally, it was concluded that with ever-tightening environmental standards, moringa oleifera could provide a cheap, green, and potential natural alternative to the existing coagulants employed to treat the palm oil mill effluent.     

Pretreatment of palm oil mill effluent (POME) using Moringa oleifera seeds as natural coagulant

Moringa oleifera seeds, an environmental friendly and natural coagulant are reported for the pretreatment of palm oil mill effluent (POME). In coagulation-flocculation process, the M. oleifera seeds after oil extraction (MOAE) are an effective coagulant with the removal of 95% suspended solids and 52.2% reduction in the chemical oxygen demand (COD). The combination of MOAE with flocculant (NALCO 7751), the suspended solids removal increased to 99.3% and COD reduction was 52.5%. The coagulation-flocculation process at the temperature of 30 degrees C resulted in better suspended solids removal and COD reduction compared to the temperature of 40, 55 and 70 degrees C. The MOAE combined with flocculant (NALCO 7751) reduced the sludge volume index (SVI) to 210mL/g with higher recovery of dry mass of sludge (87.25%) and water (50.3%).     

Review of microalgae growth in palm oil mill effluent for lipid production

Wastewater treatment using microalgae is an eco-friendly process without secondary pollution. During the process, the wastewater produced is reused, which allows efficient nutrient recycling. This review provides constructive information to enable progress of competent technology for microalgae based productions in palm oil mill effluent (POME). The characteristics of POME that will be described in this paper would be a source of pollution in water if discharged directly. Since microalgae have great potential to be isolated and cultivated in POME, previous studies to improve POME based culture media are still limited. Microalgae are highly competent in diminishing CO₂ emissions and reducing the organic components in POME. In conclusion, biological treatments by using microalgae discussed in this paper and the lipid production from microalgae biomass can be used as an alternative for energy production. The POME treatment with microalgae may meet the standards or limits before being discharged into the water body.     

Modern mill technology and centralised processing system,an alternative for improving performance of palm oil mills in Abia State,Nigeria

An assessment of palm fruit processing technologies in Abia State palm oil industry was carried out in this study. About 95% of the mills were in the small scale category with capacities in the range 0.2–3.0 t/hr. Majority (80–90%) of the mills still utilized local drums for sterilisation of fruit and clarification of oil. Palm fruit digestion and oil extraction operations have been mechanised to some extent with about 90% of the mills having one device or the other to handle the operations. Hand-operated screw press was predominant (80%) in most of the mill as a device for palm oil extraction. Fruit stripping was manually carried out. Nut/fibre separation by mechanical method is adopted by small group (40%) of the mills and 90% of the mills utilize nut cracker to crack their nuts. Most of the machines being utilized are sourced locally. Maintenance of the machines was being carried out mainly when they develop faults. More than 50% of the mills have abandoned one machine or the other with breakdown of machines being the predominant reason. Most of the mills sourced fruit by purchase or served as processing centre. The extraction rate of the mills was very low and was in the range of 7–13%. Cost of production was very high when compared with other West African palm oil producing countries. Introduction of a large scale mill utilising modern technology (and centralised processing system) in form of Public Private Partnership is being proposed. Such system will have to be backed up a palm oil act as well as adequate mobilization of the farmers in order to facilitate the adoption of the system by farmers. A modern mill of 5 t/hr capacity is being planned to serve a group of farmers in a catchment area as a model. This system will make available prompt returns to the farmers to strengthen their palm fruit production capacity and guarantee high quality oil that can be exported.     

Characterization of raw materials and manufactured binderless particleboard from oil palm biomass

The objective of this study was to examine the extractive, holocellulose, alpha cellulose, lignin, starch, and sugar contents of oil palm biomass and to evaluate its suitability in binderless particleboard production. In this study, bark, leaves, fronds, mid-parts and core-parts of the trunks were used to produce experimental binderless particleboard panels. Binderless particleboard panels were made with a target density of 0.80 g/cm³ at a temperature of 180 °C and a pressure of 12 MPa in a computer controlled hot press. The modulus of rupture, the internal bond strength, the thickness swelling and the water absorption of the panels were evaluated. Fourier transform infrared spectroscopy and field emission scanning electron microscopy were used to characterize the properties of the raw materials and the manufactured panels. The chemical composition of the oil palm biomass consisted of high holocellulose, lignin, starch and sugar contents that have been found to aid in the production of binderless particleboard. The core-part of the trunk contained the highest amount of starch and total sugar. Samples made from the core-parts and fronds had sufficient modulus of rupture and internal bond strength to meet the Japanese Industrial Standard. The internal bond strength of the mid-part panels also met the standard. However, binderless board prepared from bark and leaves showed poor modulus of rupture and internal bond strength. Samples from the core-parts had the lowest thickness swell and water absorption but did not meet the above standard. The Fourier transform infrared spectroscopy spectra did not show any substantial difference between the raw materials and the manufactured panels. Field emission scanning electron microscopy indicated that the compressed cells varied between raw material types and showed the presence of compressed cells with some starch granules that facilitated adhesion. Based on the findings of this study, oil palm has the potential to be used to manufacture binderless panel products, and further study is required to improve its dimensional stability.     

Development of empirical models for performance evaluation of UASB reactors treating poultry manure wastewater under different operational conditions

A nonlinear modeling study was carried out to evaluate the performance of UASB reactors treating poultry manure wastewater under different organic and hydraulic loading conditions. Two identical pilot scale up-flow anaerobic sludge blanket (UASB) reactors (15.7 L) were run at mesophilic conditions (30-35 degrees C) in a temperature-controlled environment with three hydraulic retention times (theta) of 15.7, 12 and 8.0 days. Imposed volumetric organic loading rates (L(V)) ranged from 0.65 to 4.257 kg COD/(m(3) day). The pH of the feed varied between 6.68 and 7.82. The hydraulic loading rates (L(H)) were controlled between 0.105 and 0.21 m(3)/(m(2)day). The daily biogas production rates ranged between 4.2 and 29.4 L/day. High volumetric COD removal rates (R(V)) ranging from 0.546 to 3.779 kg COD(removed)/(m(3)day) were achieved. On the basis of experimental results, two empirical models having a satisfactory correlation coefficient of about 0.9954 and 0.9416 were developed to predict daily biogas production (Q(g)) and effluent COD concentration (S(e)), respectively. Findings of this modeling study showed that optimal COD removals ranging from 86.3% to 90.6% were predicted with HRTs of 7.9, 9.5, 11.2, 12.6, 13.7 and 14.3 days, and L(V) of 1.27, 1.58, 1.78, 1.99, 2.20 and 2.45 kg COD/(m(3)day) for the corresponding influent substrate concentrations (S(i)) of 10,000, 15,000, 20,000, 25,000, 30,000 and 35,000 mg/L, respectively.     

Comparative performance of anaerobic reactors for treatment of sago industry wastewater

For a country like India where energy continues to be precious, with oil prices continuing to rise unlike in the West, anaerobic digestion has far greater relevance than it has to many other regions of the world. The cassava starch production in our country is mainly concentrated in small to medium scale factories, which generates 30,000–40,000 l of effluent per ton of sago produced. The effluent is acidic and highly organic in nature having chemical oxygen demand (COD) of 5,000–7,000 mg l^?1 during the season and 1,000–5,000 during the off-season. These effluents pose a serious threat to the environment and quality of life in the rural area. Since the treatment of cassava starch factory effluents through the normal biogas plants with 30–55 days retention period is very costly, attempts have been made to treat them through high-rate hybrid reactor with several hours of retention period. In Random-Packed Anaerobic Filter, the maximum COD reduction was observed (84.4 %) at 10 h hydraulic retention time (HRT). At 4 h HRT only 46.3 % COD was removed. Even though higher COD removal was achieved at 20 h, the better HRT was at 10 h as the difference between the 20 and 10 h HRT in only 0.2 %. In Up-flow Anaerobic Sludge Blanket reactor, the maximum COD removal (90 %) and total solid (TS) removal (82 %) were observed in a HRT of 30 h, whereas low COD (67 %) and TSs (64 %) removal was observed at 5 h HRT. The treatment of sago industry effluent in a hybrid reactor was studied and the HRT employed was 10, 24, 32, and 40 h. The COD removal rates were 86, 93, 94, and 95 %, and the TSs removal was 79, 85, 86, and 89 %. When the results of all these three reactors were compared, the hybrid reactor seems to be better with an optimum HRT range of 10–20 h. Hence, the anaerobic digestion has proved to be an effective method of treating the sago industry wastewater with simultaneous production of energy in the form of methane.     

Mechanical characteristics of oil palm fiber reinforced thermoplastics as filament for fused deposition modeling (FDM)

Fibers are increasingly in demand for a wide range of polymer composite materials. This study's purpose was the development of oil palm fiber (OPF) mixed with the thermoplastic material acrylonitrile butadiene styrene (ABS) as a composite filament for fused deposition modeling (FDM). The mechanical properties of this composite filament were then analyzed. OPF is a fiber extracted from empty fruit bunches, which has proved to be an excellent raw material for biocomposites. The cellulose content of OPF is 43%-65%, and the lignin content is 13%-25%. The composite filament consists of OPF (5%, mass fraction) in the ABS matrix. The fabrication procedure included alkalinizing, drying, and crushing the OPF to develop the composite. The OPF/ABS materials were prepared and completely blended to acquire a mix of 250 g of the material for the composition. Next, the FLD25 filament extrusion machine was used to form the OPF/ABS composite into a wire. This composite filament then was used in an FDM-based 3D printer to print the specimens. Finally, the printed specimens were tested for mechanical properties such as tensile and flexural strength. The results show that the presence of OPF had increased the tensile strength and modulus elasticity by approximately 1.9% and 1.05%, respectively. However, the flexural strength of the OPF/ABS composite had decreased by 90.6% compared with the virgin ABS. Lastly, the most significant outcome of the OPF/ABS composite was its suitability for printing using the FDM method.The full text can be downloaded at https://link.springer.com/content/pdf/10.1007%2Fs40436-019-00287-w.pdf     

Removal of chromium (VI) from aqueous solution using treated oil palm fibre

This study proposed an oil palm by-product as a low-cost adsorbent for the removal of hexavalent chromium [Cr (VI)] from aqueous solution. Adsorption of Cr (VI) by sulphuric acid and heat-treated oil palm fibre was conducted using batch tests. The influence of pH, contact time, initial chromium concentration and adsorbent dosage on the removal of Cr (VI) from the solutions was investigated. The optimum initial pH for maximum uptake of Cr (VI) from aqueous solution was found to be 1.5. The removal efficiency was found to correlate with the initial Cr (VI) concentration, adsorbent dosage as well as the contact time between Cr (VI) and the adsorbent. The adsorption kinetics tested with pseudo first order and pseudo second order models yielded high R(2) values from 0.9254 to 0.9870 and from 0.9936 to 0.9998, respectively. The analysis of variance (ANOVA) showed significant difference between the R(2) values of the two models at 99% confidence level. The Freundlich isotherm (R(2)=0.8778) described Cr (VI) adsorption slightly better than the Langmuir isotherm (R(2)=0.8715). Difficulty in desorption of Cr (VI) suggests the suitability of treated oil palm fibre as a single-use adsorbent for Cr (VI) removal from aqueous solution.     

Effects of heat treatment on oil palm shell coarse aggregates for high strength lightweight concrete

In this study, the effects of heat treatment on oil palm shell (OPS) coarse aggregates are evaluated for high strength lightweight concrete (HSLWC). OPS coarse aggregates are subjected to heat treatment at two temperature settings (60 and 150 °C) and duration of heat treatment (0.5 and 1 h). The reduction in density is found to be within the range of HSLWC when heat-treated OPS aggregates are added into the oil palm shell concrete (OPSC). The results reveal that workability of the OPSC increases with an increase in temperature and duration of heat treatment of the OPS aggregates. It is found that the maximum achievable 28-days and 90-days compressive strength is 49 and 52 MPa, respectively. Furthermore, the ultrasonic pulse velocity (UPV) is examined and the results showed that a good condition is achieved for the OPS HSLWC at the age of 3 days. The average modulus of elasticity (i.e. (E) value), is found to be 15.9 GPa for all mixes, which is higher than that reported in previous studies and is within the range of normal weight concrete. Hence, the findings of this study are of primary importance as they reveal that the selection of a suitable temperature and duration of heat treatment for OPS aggregates can be used as a new eco-friendly alternative method to enhance HSLWC.     

Design of alternate solvent for recovery of residual palm oil: simultaneous optimization of process performance with environmental,health and safety aspects

In this work, a computer-aided molecular design (CAMD)-based approach has been developed to design alternative solvents for extracting palm oil from palm pressed fibre (PPF). PPF is a by-product from palm oil milling process produced during the extraction of crude palm oil from fresh fruit bunches. It is noted that the oil that found in PPF consists of high concentration of carotenoids; therefore, palm oil industries are trying to recover the residual oil in PPF. Hexane is conventionally used as a solvent to extract PPF. However, hexane has high boiling point which leads to significant degradation of carotene during solvent recovery. Besides, hexane is considered as a toxic chemical; thus, the extracted oil cannot be used in food applications. In order to overcome the limitations of hexane, this work presents a systematic approach to generate alternative solvents with desirable attributes for PPF oil extraction via CAMD with the integration of safety and health aspects. In this work, diffusivity is defined as a key parameter to evaluate the solvent functionality because the solvent must diffuse through the fibrous matrix to solubilize trapped oil. The safety and health aspects were assessed by implementing disjunctive programming to discretize the properties for allocation of subindex scores. The developed algorithm can trade-off the process and environmental, health and safety (EHS) performances and identify alternative solvents which improve EHS performance compare with hexane.     

Fluidization of palm kernel shell,palm oil fronds,and empty fruit bunches in a swirling fluidized bed gasifier

The increased biomass utilization has triggered the use of palm oil waste as fuel for gasification in Malaysia. In this study, pioneering work was conducted on three types of palm oil wastes namely palm kernel shell (PKS), palm oil fronds (POF), and empty fruit bunches (EFB). Minimum air velocity (U_mf) required for fluidization of the tested biomass was determined experimentally in a swirling fluidized bed, by considering the effect of bed weight, density, particle size, fluidized bed height, pressure drop, and bed voidage. It was revealed that higher the particle size the smaller will be the voidage, which consequently affects the minimum fluidization velocity. U_mf was increased with a decrease in voidage size. However, a direct relationship was found between particle size and U_mf. Overall highest U_mf was determined for EFB followed by POF and PKS. Fluidized bed height was increased by decreasing the particle size regardless of the biomass type. Highest unsettled bed height was obtained with PKS on account of its low density among all the test fuels. It was concluded that optimization of the fluidized bed for each type of biomass, particle size, and density is explicitly required for a low-cost energy conversion process.     

Optimum manufacturing parameters for compressed lumber from oil palm (Elaeis guineensis) trunks: Respond surface approach

The objective of this investigation was to evaluate optimum manufacturing parameters to produce compressed lumber from oil palm (Elaeis guineensis) trunks. Experimental samples were made using steaming time, pressure, pressure time and temperature ranging from 2 to 4 h, from 5 to 12 MPa, from 20 min to 60 min and from 100 °C to 200 °C, respectively. Compression and recovery ratios of the specimens were determined employing Response Surface Methodology (RSM) approach within the scope of Central Composite Design (CCD) computer program. Experimental and calculated values were compared to each other. Based on the results of the work, the specimens steamed for 2 h before they were compressed using a pressure of 11.16 MPa at a temperature of 200 °C for 60 min resulted in optimum conditions. Measured and calculated compression and recovery ratios of the samples showed 0.70 and 0.83 correlation coefficient values, respectively.     

Evaluation of the energy saving opportunities for palm oil refining process: Sahabat Oil Products (SOP) in Lahad Datu,Malaysia

Palm Oil industry is one of the major contributors to Malaysia’s economic activity. Accounting for 39 % of the world palm oil production and 44 % of world exports, Malaysia holds an important niche in fulfiling the growing global needs for oils and fats sustainably. This industry has high potential for further improvements especially in terms of energy saving as a major contributor to cost and emission reduction. An analysis of the refining process of palm oil in Sahabat Oil Products, Lahad Datu has been performed and presented in this paper for scoping potential energy and cost savings using heat integration. A first stage optimisation of the minimum temperature difference, ?T _min, of a heat exchanger network (HEN) has been performed. The goal has been to evaluate the maximal possible heat recovery as well as the appropriate placement of utilities. The HEN design is presented in both grid diagram and shifted retrofit thermodynamic grid diagram (SRTGD). SRTGD representation has been illustrated in this paper as a useful tool for guiding eventual future retrofit. The capital-energy trade-off of the heat recovery targets indicates optimum ?T _min of 12.3 °C. The hot and cold utility targets at ?T _min = 12.3 °C are 1419 and 1649 kW, indicating potential saving of 3.5 and 3.1 % as compared to the existing utility consumption and emissions. Future work could proceed further to seek potentially viable retrofit of the existing heat recovery network.     

Optimization of coagulation-flocculation process for pulp and paper mill effluent by response surface methodological analysis

Coagulation-flocculation is a proven technique for the treatment of high suspended solids wastewater. In this study, the central composite face-centered design (CCFD) and response surface methodology (RSM) have been applied to optimize two most important operating variables: coagulant dosage and pH, in the coagulation-flocculation process of pulp and paper mill wastewater treatment. The treated wastewater with high total suspended solids (TSS) removal, low SVI (sludge volume index) and high water recovery are the main objectives to be achieved through the coagulation-flocculation process. The effect of interactions between coagulant dosage and pH on the TSS removal and SVI are significant, whereas there is no interaction between coagulant dosage and water recovery. Quadratic models have been developed for the response variables, i.e. TSS removal, SVI and water recovery based on the high coefficient of determination (R(2)) value of >0.99 obtained from the analysis of variances (ANOVA). The optimum conditions for coagulant dosage and pH are 1045mgL(-1) and 6.75, respectively, where 99% of TSS removal, SVI of 37mLg(-1) and 82% of water recovery can be obtained.     

Development and characterisation of gelatine/palm wax/lemongrass essential oil (GPL)-coated paper for active food packaging

This research focused on the enhancement of paper through the incorporation of a biodegradable and hydrophobic film coating with antioxidant properties. The effects of different lemongrass essential oil (LEO) concentrations (0–12%) on the physical, mechanical, microstructural, water-resistance, antioxidant and biodegradable properties of gelatine/palm wax/lemongrass essential oil (GPL)-coated paper were analysed. Uncoated paper was used as a control. The GPL-coated papers were heat sealable and had significantly (p < 0.05) higher tensile strength and stretchability but lower stiffness than those of the control paper. The GPL-coated paper incorporated with higher LEO concentrations showed a significant (p < 0.05) increase in the initial contact angle while also demonstrating significant (p < 0.05) reductions in the Cobb value and water vapour permeability. The GC–MS analysis revealed that LEO was highly dominated by monoterpenes, sesquiterpenes, and their oxygenated derivatives, supporting that all GPL-coated papers have a good amount of total phenolic compounds and free radical scavenging activities, which improved significantly (p < 0.05) with higher LEO concentrations. In conclusion, the GPL film coating was capable of improving the physical, mechanical and functional properties of Kraft paper and has the potential to be applied for food products.     

Integrated treatment of olive mill wastewater (OMW) by the combination of Fenton's reaction and anaerobic treatment

The use of an integrated treatment scheme consisting of wet hydrogen peroxide catalytic oxidation (WHPCO) followed by two-stage upflow anaerobic sludge blanket (UASB) reactor (10l each) for the treatment of olive mill wastewater was the subject of this study. The diluted wastewater (1:1) was pre-treated using Fenton's reaction. Optimum operating conditions namely, pH, H(2)O(2) dose, Fe(+2), COD:H(2)O(2) ratio and Fe(+2):H(2)O(2) ratio were determined. The UASB reactor was fed continuously with the pre-treated wastewater. The hydraulic retention time was kept constant at 48h (24h for each stage). The conventional parameters such as COD, BOD, TOC, TKN, TP, TSS, oil and grease, and total phenols were determined. The concentrations of polyphenolic compounds in raw wastewater and effluents of each treatment step were measured using HPLC. The results indicated a good quality final effluent. Residual concentrations of individual organic compounds ranged from 0.432 mg l(-1) for rho-hydroxy-benzaldhyde to 3.273 mg l(-1) for cinnamic acid.     

Comparative life cycle assessment (LCA) of bio-oil production from fast pyrolysis and hydrothermal liquefaction of oil palm empty fruit bunch (EFB)

This paper presents a life cycle assessment of two alternative processes for the production of bio-oil from Malaysian oil palm empty fruit bunch (EFB), namely, fast pyrolysis and hydrothermal liquefaction, in which limited studies have been reported in the literature. In this study, both processes were evaluated and compared in terms of their impacts to the environment, specifically based on the selected impact categories: global warming potential (GWP), acidification, eutrophication, toxicity, and photochemical-oxidant formation. The results indicated that fast pyrolysis process of EFB caused more severe impact on the environment compared to hydrothermal liquefaction process. Fast pyrolysis process caused almost 50 % more GWP impact compared to hydrothermal liquefaction process, due to both high energy demand in the drying process and high-temperature operation of fast pyrolysis. Other than that, the assessment on other environmental impacts indicated that hydrothermal liquefaction operation is more environmentally benign compared to fast pyrolysis due to the reduced energy consumption. Lastly, sensitivity analysis involving three scenarios (change in bio-oil yield, thermal efficiency of boilers, and thermal efficiency of dryers), respectively, were constructed and presented.     

Effects of treatment with low molecular weight phenol formaldehyde resin on the surface characteristics of oil palm (Elaeis quineensis) stem veneer

Even though oil palm (Elaeis quineensis) stem (OPS) is highly potential as an alternative raw material in wood industry, it possesses some inferior characteristics. One of the critical weaknesses is a high degree of veneer surface roughness that resulted in high resin consumption during plywood manufacture. The objective of this study was to investigate effects of treatment with low molecular weight phenol formaldehyde (LMWPF) resin on the wettability and surface roughness of OPS veneer. OPS veneers were segregated into two categories namely outer and inner layer veneer, prior to soaking in LMWPF resin solution to obtain weight percent gain of 16–20%. The wettability of OPS veneers was assessed with contact angle measurement according to the sessile drop method. The veneer surface roughness was evaluated by determining the average roughness (R_a), mean peak-to-valley height (R_z), and maximum roughness (R_max) using a stylus profilometer in accordance with DIN standard 4768. The results show that the effect of LMWPF resin treatment on the surface roughness of the veneers is statistically significant. The technique used in the study was able to enhance the surface properties as well as improved the physical and mechanical properties of OPS plywood.     

Enhanced performance of a submerged membrane bioreactor with powdered activated carbon addition for municipal secondary effluent treatment

The aim of this study was to investigate the feasibility of PAC-MBR process treating municipal secondary effluent. Two laboratory-scale submerged MBRs (SMBR) with and without PAC addition were continuously operated in parallel for secondary effluent treatment. Approximately 63%TOC, 95% NH₄⁺-N and 98% turbidity in secondary effluent were removed by the PAC-MBR process. Most organics in the secondary effluent were found to be low molecular weight (MW) substances, which could be retained in the reactor and then removed to some extent by using PAC-MBR process. Parallel experiments showed that the addition of PAC significantly increased organic removal and responsible for the largest fraction of organic removal. Membrane fouling analysis showed the enhanced membrane performance in terms of sustainable operational time and filtration resistances by PAC addition. Based on these results, the PAC-MBR process was considered as an attractive option for the reduction of pollutants in secondary effluent.