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介绍了等离子的定义,简要描述了等离子处理技术的原理及其在纤维表面改性的应用,综述了近年来国内外等离子处理技术在处理复合材料待胶接表面的研究进展,阐述了等离子处理技术在处理过程中需要重点考虑的几个关键因素,如功率、时间、气体种类和气压等,同时阐述了表征处理结果的方法,如平均表面粗糙度、接触角(水),以及胶接完成后的剪切强度、破坏模式。最后,指出国内开展等离子体处理复合材料胶接表面研究存在的问题。 相似文献
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为了实现聚苯乙烯材料长效亲水改性,利用氨气等离子体对聚苯乙烯材料表面进行可控亲水改性。通过调整功率、处理时间和氨气气体流量等工艺参数,调节聚苯乙烯材料表面亲水改性程度。利用X射线光电子能谱(XPS)和原子力显微镜(AFM)对材料表面化学成分和表面形貌进行分析。监测等离子处理后材料表面接触角以评估亲水改性效果。结果表明:相比气体流量,氨气等离子处理时间和功率对聚苯乙烯材料表面接触角的影响更明显。在功率为400 W,处理时间为120 s,气体流量为200 mL/min条件下,等离子处理后材料表面接触角约(50±1.9)°。等离子处理后材料表面成功引入N元素和O元素,O和N元素原子数比例分别提高至17.27%和12.98%,O/C和N/C含量比分别增至0.25和0.19。等离子处理前后材料表面形貌无明显变化。接触角监测结果表明亲水改性效果至少可维持360 d。氨气等离子处理可有效实现聚苯乙烯材料表面可控亲水改性,且改性效果具有良好的长期稳定性。 相似文献
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聚四氟乙烯改性技术的研究 总被引:1,自引:0,他引:1
从聚四氟乙烯的结构和特性方面阐明了其改性的必要性,并根据聚四氟乙烯改性技术研究进展,对其表面改性、填充改性及共混改性进行了详细介绍,最后对聚四氟乙烯改性技术提出了一些建议。 相似文献
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简介了超高相对分子质量聚乙烯纤维的性能与应用,重点阐述了低温等离子处理法、辐照接枝改性法、化学氧化法和电晕放电法4种常用的对超高相对分子质量聚乙烯纤维改性方法的研究情况。综述表明,无论采用以上任何一种改性方法,都能相应有效改善纤维的表面性能,提高纤维与其它材质间的粘接性。 相似文献
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IM7 carbon fibers were surface treated in methane, ethylene, trifluoromethane and tetrafluoromethane plasmas. The surface chemical composition of the fibers was determined by X-ray photoelectron spectroscopy (XPS). The adhesion between as-received and plasma-treated carbon fibers and polyethersulfone (PES) and an epoxy resin was measured by the microbond pull-out test. XPS showed that the methane and ethylene plasmas deposited a thin layer of hydrocarbon on the fiber surface. The trifluoromethane plasma deposited a layer of fluorocarbon on the surface of the fibers. The tetrafluoromethane plasma etched the fibers and introduced a significant amount of fluorine on the surface. The microbond pull-out test results indicated that an etching plasma, such as the tetrafluoromethane plasma, improved the adhesion between carbon fibers and PES. These results are consistent with earlier work performed with ammonia plasma. The adhesion is believed to be due primarily to the differential thermal shrinkage between the fiber and the matrix. It was shown that in the case of a reactive matrix such as an epoxy resin, the fiber chemical composition plays a role in the fiber-matrix adhesion. However, this chemical effect is secondary to the cleaning effect of the surface treatment. 相似文献
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一种新型玉米淀粉粘合剂的研制 总被引:6,自引:0,他引:6
本文叙述了玉米淀粉经0氧化,酯化处理,糊化后添加聚乙烯酸缩甲醛合成淀粉粘合剂新工艺,该粘合剂具有流动性好,粘合力大,贮存期长的优点,可广泛用于涂料,粘合剂等领域. 相似文献
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The present study describes the modification of long oil palm stearin based alkyd resin through blending it with a commercially available ketone resin to improve its coating characteristics. The effects of blending on air drying time, hardness, adhesion, gloss, impact strength, chemical resistance and thermal behavior of dried films of blends were investigated and compared to virgin alkyds. It was found that blending results in modifying coating characteristics of palm stearin based alkyd resins, significantly. Best result was observed for weight ratio 70:30 of alkyd and ketone resins. 相似文献
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DC cathodic polymerizations of trimethylsilane (TMS) were carried out in a bell-jar reactor without using an anode assembly, i.e., under the conditions similar to ion vapor deposition (IVD) operation. In order to initiate the DC glow discharge, a negative potential was applied to IVD Al-coated aluminum panels, the cathode, and grounded reactor wall, the anode. TMS plasma coatings obtained under such operation was studied in terms of refractive indices, linear polarization resistance, and adhesion performance to subsequent spray paint primers. Experimental results indicated that the TMS plasma coatings obtained without anode assembly have similar coating characteristics to those obtained by anode magnetron plasmas as used in Part I of this series, which showed excellent corrosion protection of IVD Al-coated aluminum alloys. As a result, the plasma interface engineered coating systems of IVD/plasma polymer/non-chromated primer obtained under such operation showed excellent corrosion protection of IVD Al-coated aluminum alloys, which outperformed the chromate conversion-coated IVD controls after 4 weeks of SO2 and 12 weeks prohesion salt spray tests. 相似文献
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K. Rose S. Dzyadevych R. Fernández-Lafuente N. Jaffrezic G. Kuncová V. Matějec P. Scully 《Journal of Coatings Technology and Research》2008,5(4):491-496
Sensitive coatings are described for a novel enzyme-based optical sensor for in-situ continuous monitoring of reactants, such
as glucose, in biotechnological production processes. Glucose oxidase, incorporated into suitable coating materials that are
applied on lenses or optical fibers, is used to catalyze oxidization of glucose to gluconic acid in the presence of oxygen.
The presence and consumption of oxygen is determined by measuring the fluorescence signal of incorporated metal organic ruthenium
complexes, which is quenched by oxygen. Inorganic–organic hybrid polymers, synthesized via sol-gel processing, were used as
coating material. Due to the hybrid character of the coating, good adhesion is achieved on both glass and polymer surfaces.
Good compatibility is also given with enzymes and ruthenium complexes. The sensitive optical coating was built up as double-layer
and single-layer structures. The double layer comprised a primary coating containing the oxygen-sensitive ruthenium complex,
and a secondary coating containing the enzyme. The single layer comprised a single coating containing both the ruthenium complex
and the enzyme. 相似文献
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《Journal of Adhesion Science and Technology》2013,27(15-16):1783-1797
SIS (styrene-isoprene-styrene)-based pressure sensitive adhesives (PSAs) were prepared by melt- or solution-blending. In the coating process, two methods were used: solution coating and melt coating. The performances of the PSAs were found to be different, depending on which of these two blending or coating methods was used. In this study, we investigated the relationship between the viscoelastic properties and the performances of the SIS-based PSAs using different blending and coating methods. Three methods were used: (1) melt-blending and melt-coating, (2) melt-blending and solution-coating and (3) solution-blending and solution-coating. PSAs applied using melt-blending/melt-coating (M—M) have higher peel strength and probe tack than PSAs applied using melt-blending/solution-coating (M—S) and solution blending/solution coating (S—S). However, PSAs applied using M—M blends have lower holding power and SAFT (Shear adhesion failure temperature) than PSAs applied using M—S and S—S blends. The viscoelastic properties and GPC curves of M—S blends were similar to M-M blends, while the peel strength and tack of M—S blends were similar to S—S blends. Therefore, it was concluded that the blending process had more effect on the viscoelastic properties and shear creep of PSAs than the coating process. 相似文献
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《Journal of Adhesion Science and Technology》2013,27(5):575-596
The effect of the bulk modification of the EPDM rubber compound on the adhesion performance with polyurethane coating (PU) was studied. Ethylene propylene diene monomer (EPDM) was bulk modified using maleated EPDM, polynorbornene (PNR) or different curatives to improve adhesion to polyurethane coating. The coating–rubber composite adhesion performance was examined by peel, crack and abrasion tests followed by microscopic investigation of fracture surfaces and their chemical nature. The adhesion between the coating and the rubber substrate was improved using maleated EPDM or PNR, as well as different curing systems. The crack stress for the delamination of the polyurethane coating from the flexible bulk-modified rubber surface follows the trend: maleated EPDM > PNR > different curing systems > control. 相似文献
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A. Montarsolo A. Varesano R. Mossotti F. Rombaldoni M. Periolatto G. Mazzuchetti C. Tonin 《应用聚合物科学杂志》2012,126(4):1385-1393
In recent years, there has been growing attention on intrinsically conducting polymers, such as polypyrrole (PPy) because of the wide range of possible applications. Adhesion to other materials is a pending problem that could be tackled by enhancing the chemical affinity of the surface toward PPy coating. In this work, low‐temperature plasma pretreatments were used for improving adhesion of PPy on polyester (PET) fabrics by changing the surface chemistry and generating a microscopically rough surface. Oxygen and argon plasmas were used to treat both sides of PET fabrics before PPy deposition by in situ chemical polymerization. Moreover, PPy depositions were performed 1 h, 1 week, and 1 month after the plasma treatments to study possible ageing effects. Different chemical/physical characterizations (contact angle, surface energy, atomic force microscopy, and X‐ray photoelectron spectroscopy) showed the efficacy of plasma pretreatments in inducing wettability on PET fabrics and promoting adhesion of the PPy layer. The enhanced adhesion was confirmed by abrasion tests and subsequent surface resistivity and color measurements. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献