共查询到18条相似文献,搜索用时 62 毫秒
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Sn-Ag-Cu无铅焊料性能研究 总被引:2,自引:0,他引:2
环保和微电子器件高度集成化的发展驱动了高性能无铅焊料的研究和开发,Sn—Ag-Cu系无铅焊料由于具有良好的焊接性能和使用性能,已逐渐成为一种通用电子无铅焊料。文章通过实验的方法,研究了8种不同配比的Sn—Ag—Cu焊料中银、铜含量对合金性能(包括熔点、润湿性和剪切强度)的影响,并对焊料的显微组织进行对比与分析,得出低银焊料的可靠性比高银焊料好,同时Sn-2.9Ag—1.2Cu的合金具有较低的熔点且铺展性好,为确定综合性能最佳的该系焊料合金提供了依据。 相似文献
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Ce对SnAgCu系无铅焊锡力学性能的影响 总被引:6,自引:0,他引:6
通过向Sn-3Ag-2.8Cu钎料合金中添加微量稀土Ce,利用扫描电子显微镜(SEM)研究了不同稀土含量对Sn-3Ag-2.8Cu合金的力学性能的影响,同时对显微组织进行了分析.实验结果表明,微量的Ce稀土可以显著提高Sn-3Ag-2.8Cu钎料的延伸率、延长其焊接接头在室温下的蠕变断裂寿命,尤其是当稀土的质量分数为0.1%时,其蠕变断裂寿命可以达到Sn-3Ag-2.8Cu钎料的9倍以上,当稀土的质量分数超过0.1%时,接头的蠕变断裂寿命呈下降趋势.综合考虑,最佳的稀土质量分数为0.05%~0.10%. 相似文献
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Sn-Zn无铅焊料由于熔点接近Sn-Pb,价格低廉、无毒性、力学性能优良等特点,倍受人们的关注。然而由于Zn的表面活性高,在钎焊过程中焊料容易氧化,导致了润湿性能下降。本文综述合金元素对Sn-Zn无铅焊料氧化性能、润湿性的影响。并对Sn-Zn焊料今后的研究方向进行了简要分析。 相似文献
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Effects of Trace Amounts of Rare Earth Additions on Microstructure and Properties of Sn-Bi-Based Solder Alloy 总被引:3,自引:0,他引:3
Wenxing Dong Yaowu Shi Zhidong Xia Yongping Lei Fu Guo 《Journal of Electronic Materials》2008,37(7):982-991
The effect of trace amounts of rare earth additions on the microstructure and properties were studied for the Sn-58Bi and
Sn-58Bi-Ag solder alloys. At the same time, the intermetallic compounds (IMCs) in the solder alloys and intermetallic layer
(IML) thickness at the solder/Cu substrate interface were investigated, both as-reflowed and after high-temperature aging.
The results indicate that adding trace amounts of rare earth (RE) elements has little influence on the melting temperature
and microhardness of the solders investigated, but adding RE elements improves the wettability and shear strength of the Sn-58Bi
and Sn-58Bi-Ag solder alloys. In addition, it was found that the addition of RE elements not only refines the microstructure
and size of the IMC particles, but also decreases the IML thickness and shear strength of the Sn-58Bi solder joint after high-temperature
aging. Adding trace amounts of RE elements is superior to adding trace amounts of Ag for improving the properties of the Sn-58Bi
solder. The reason may be related to the modification of the microstructure of the solder alloys due to the addition of trace
amounts of RE elements. 相似文献
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微合金化对Sn-9Zn基无铅钎料润湿性能的影响 总被引:9,自引:2,他引:7
熔炼制备了纯的以及含微量Al、Mg、Ti、Bi、重稀土Y、混合轻稀土RE和一种富P非金属活性组元NM的Sn-9Zn基合金,通过测量这些合金以及商用Sn-37Pb焊料在铜基板上的铺展面积比较了它们对铜的润湿性能。结果表明Al、Ti和 Mg不利于提高合金在铜上的润湿性或附着力;Y的改善作用不大;而Bi、RE和NM则能明显改善Sn-9Zn合金对铜的润湿性。在此基础上进一步研究了RE和NM含量对Sn-9Zn润湿性能的影响。以铺展面积衡量,本研究所达到的最佳改善效果使Sn-9Zn合金对铜的润湿性由Sn-37Pb焊料润湿性水平的45.4%提高到了70.3%。 相似文献
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Zhanli Guo Nigel Saunders Peter Miodownik Jean-Philippe Schillé 《Journal of Electronic Materials》2008,37(1):23-31
A full set of physical and thermophysical properties for lead-free solder (LFS) alloys have been calculated, including liquidus/solidus
temperatures, fraction solid, density, coefficient of thermal expansion, thermal conductivity, Young’s modulus, viscosity,
and liquid surface tension, all as a function of composition and temperature (extending into the liquid state). The results
have been extensively validated against data available in the literature. A detailed comparison of the properties of two LFS
alloys Sn-20In-2.8Ag and Sn-5.5Zn-4.5In-3.5Bi with Sn-37Pb has been made to show the utility and need for calculations that
cover a wide range of properties, including the need to consider the effect of nonequilibrium cooling. The modeling of many
of these properties follows well-established procedures previously used in JMatPro software for a range of structural alloys.
This paper describes an additional procedure for the calculation of the liquid surface tension for multicomponent systems,
based on the Butler equation. Future software developments are reviewed, including the addition of mechanical properties,
but the present calculations can already make a useful contribution to the selection of appropriate new LFS alloys. 相似文献
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Ag对Sn-9Zn合金钎料组织及性能的影响 总被引:3,自引:0,他引:3
用莱卡显微镜、XRD研究添加元素Ag对Sn-9Zn钎料组织及性能的影响。结果表明:Ag与Zn形成AgZn3化合物,能抑制粗大针状富Zn相的形成,可使Sn-9Zn钎料合金的润湿性提高20%,并明显改善Sn-9Zn的耐蚀性。 相似文献
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Effect of SiC Nanoparticle Additions on Microstructure and Microhardness of Sn-Ag-Cu Solder Alloy 总被引:1,自引:0,他引:1
In this work, lead-free composite solders were produced by mechanically mixing nominal 20 nm moissanite SiC particles with
Sn-3.8Ag-0.7Cu solder paste. The effects of the amount of SiC addition on the melting behavior, microstructure, and microhardness
of as-solidified composite solders were systematically investigated. In comparison with solder without the addition of SiC
nanoparticles, the subgrain of β-Sn, the intermetallic compounds (IMCs) average grain size and distance decreased significantly
in the composite solder matrix. This was possibly ascribed to the strong adsorption effect and high surface free energy of
the SiC nanoparticles. Our results showed that 0.05 wt.% addition of SiC nanoparticles could improve the microhardness by
44% compared with the noncomposite and that the average grain size and distance changed from 0.5 μm to 0.2 μm and from 0.6 μm to 0.32 μm, respectively. The refined IMCs, acting as a strengthening phase in the solder matrix, enhanced the microhardness of the
composite solders, in good agreement with the prediction of the classic theory of dispersion strengthening. 相似文献
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提出了一种对微电子封装器件中焊点剪切强度进行测试的方法,可有效降低测试误差。利用该方法,对Sn—Ag—Cu无铅焊料分别在Cu基板和Ni-P基板上形成的焊点,经不同的热时效后的剪切强度进行了测量,并对断裂面的微观结构进行了研究。结果表明,新的剪切测试方法误差小,易于实施,焊点剪切强度、断裂面位置与焊料在不同基板界面上金属间化合物的形貌、成分有关。 相似文献
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通过成分设计形成了Sn-Zn-Bi-Ag系钎料合金。针对微电子产业的应用要求研究了钎料的物理性能,分析了Sn-Zn-Bi-Ag系钎料中合金元素对钎料物理性能的影响。发现:Sn-Zn-Bi-Ag系钎料的合金元素中Bi、Ag含量(质量分数)的增加会使钎料的密度增大,而Zn含量对钎料的密度影响不大。Zn含量5.0%~6.5%,Bi含量1.5%~3.0%,Ag含量0.5%~0.8%范围的Sn-Zn-Bi-Ag钎料具有较好的润湿性能。Sn-Zn-Bi-Ag系钎料中Bi含量不高时,钎料的电阻率均比传统Sn-37Pb钎料小。随着Bi含量的增加,钎料的电阻率有明显增大的趋势。 相似文献
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浅谈Sn-Ag-Cu无铅焊料的可靠性 总被引:3,自引:0,他引:3
随着电子组装技术的发展,电子产品在制造过程中使用的焊料也随之更新换代,由原来的使用锡铅焊料改为使用无铅焊料,特别是Sn-Ag-Cu焊料,以满足WEEE和RoHS指令以及其他方面的要求。然而,使用无铅焊料却带来了一系列的问题,这些问题自然影响到产品的可靠性和使用寿命,因此,成为业界最关注的热点问题。文章主要讨论了Sn-Ag-Cu焊料的可靠性等问题。 相似文献