共查询到20条相似文献,搜索用时 125 毫秒
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WO3作为新型的气敏材料和光催化剂具有广阔的应用前景,通过贵金属纳米簇修饰后的WO3复合纳米晶比WO3基体材料在性能上大幅提高。本文综述了贵金属修饰对WO3基体气敏和光催化性能的影响,其中气敏性能以不同敏感气体(如NOx、H2S、H2等)为分类依据,而光催化性能以不同贵金属(Au、Ag、Pt等)添加剂为分类依据,系统综述了贵金属/WO3复合纳米晶的气敏和光催化性能研究最新进展,并总结了常见贵金属/WO3的气敏和光催化机理模型,提出了贵金属/WO3在气敏和光催化应用过程中存在的问题及前景展望。 相似文献
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Char particles from pyrolyzed biomass vary in particle size and shape. On average, the particles are more elongated the larger their size. The average size‐specific elongation is almost alike for all investigated samples, i.e. independent from their source material and process. The particle collectives cannot be characterized accurately with classical particle size distributions, which assume spherical particle shape. Accounting for their shape, they can be described more accurately with particle size distributions that are based on an ellipsoid model. The high bulk porosity is mainly attributed to the spaces between particles. 相似文献
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《Journal of aerosol science》2006,37(10):1303-1325
A new instrument capable of measuring aerosol size distribution with high time and size resolution, and high signal-to-noise ratios is described. The instrument, referred to as Fast Integrated Mobility Spectrometer (FIMS), separates charged particles based on their electrical mobility into different trajectories in a uniform electric field. The particles are then grown into super-micrometer droplets, and their locations on the trajectories are recorded by a fast charge-coupled device (CCD) imaging system. Images captured by the CCD reveal mobility-dependent particle positions and their numbers, which are then used to derive a particle size distribution spectrum. By eliminating the need to scan over a range of voltages, FIMS significantly improves the measurement speed and counting statistics. A theoretical framework has been developed to quantify the measurement range, mobility resolution, and transfer function of FIMS. It is shown that FIMS is capable of measuring aerosol size distributions with high-time and size resolution. 相似文献
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Thermomechanical properties of polymer blends seem to depend on their morphology on microscales and in particular on the size of the dispersed phase particles and/or their distances (ligament thickness). Precise characterization of morphologies by few simple geometrical parameters is often a quite delicate task, in particular because of the strong polydispersity of these systems. We present here a simple method based on image analysis of transmission electron micrographs (TEM) to estimate both distributions in particle size and ligament thickness. We first reconstruct three-dimensional distributions in particle size from two-dimensional measurements and show in particular that corrections from section thickness become significant when thickness is comparable to particle size. Knowing the distribution in particle size, we extend the model initially proposed by Wu to estimate the distribution in ligament thickness. This method provides a more detailed relation between the distribution in particle size and the distribution in ligament thickness. Advantages and limitations of the method are illustrated by practical examples on polyamide-12 systems filled with various particle dispersions. 相似文献
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Tiainen M Pusenius J Julkunen-Tiitto R Roininen H 《Journal of chemical ecology》2006,32(10):2287-2301
We studied the effects of the intensity of intraspecific competition, as indicated by seedling density, and competitive success within populations, as indicated by seedling size, on the secondary chemistry of the stems of silver birch seedlings and their palatability to field voles. We found that the size of seedlings and their total phenolic concentrations were inversely related to stand density. Voles, however, did not discriminate between seedlings grown at the densities studied. Variation in competitive success was associated with several phenomena. Seedling size was positively related to the concentrations of several secondary compounds and to vole preferences, but negatively related to nitrogen concentration. We suggest that the ecological consequences of variation in seedling size cannot be predicted without knowledge of the mechanism behind the variation. 相似文献
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Some interesting properties of metals confined in time and nanometer space of different shapes 总被引:2,自引:0,他引:2
El-Sayed MA 《Accounts of chemical research》2001,34(4):257-264
The properties of a material depend on the type of motion its electrons can execute, which depends on the space available for them (i.e., on the degree of their spatial confinement). Thus, the properties of each material are characterized by a specific length scale, usually on the nanometer dimension. If the physical size of the material is reduced below this length scale, its properties change and become sensitive to its size and shape. In this Account we describe some of the observed new chemical, optical, and thermal properties of metallic nanocrystals when their size is confined to the nanometer length scale and their dynamical processes are observed on the femto- to picosecond time scale. 相似文献
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《Ceramics International》2022,48(7):8960-8971
The demand for separation and purification applications under harsh conditions has grown strongly in recent years. Silicon carbide (SiC) ceramic membranes have broad prospects in this aspect due to their unique characteristics, but its pore size control is a crucial problem. Therefore, it is of great significance to develop simple and feasible methods for precise control of the pore size of SiC membranes to improve membrane selectivity and expand their application range. This review describes the pore formation process in the preparation of SiC membranes, focusing on the selection of SiC particles, sintering temperature, sacrificial template, sintering aids, oxidation process and other factors affecting the pore size and analysis. Finally, the control of SiC membrane pore size is summarized and the outlook is proposed. 相似文献
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The chemical reactivity of metal nanoclusters is determined mainly by their size and their oxidation state. The control of metal particle size is essential in order to manipulate their reactivity and interfacial behavior. Uniformity of size and spatial distribution of the metal nanoclusters is essential in the study of their properties and can be achieved primarily by conducting their synthesis in the presence of stabilizers. These materials, such as surfactants or polymers, adsorb onto the surfaces of growing clusters and create a “shielding effect,” a chemical barrier that prevents the effects of van der Waals interactions between particles, thus inhibiting particle aggregation. Polymers are frequently used as stabilizers for metal clusters because they are transparent, permeable, and nonconductive, and as such, do not interfere with and/or mask the potential optical, electrical, and catalytic properties of these clusters. When the concentration of the polymer in the reaction solution is above its critical coil overlap, entanglements occur, and hence the polymer may be viewed as a dynamically cross-linked network. Since the metal precursors can interact with the polymer via weak polar interactions, the metal cluster formation will therefore occur within the confines of these closed polymeric domains. In this work we will show, both theoretically and experimentally, the consequences of these interactions in the confines of the polymeric domains on metal particle size and particle size distribution. 相似文献
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Measurement of characteristics of particles in suspensions without dilution has a practical interest in formulation, mineral processing, material sciences and environmental technologies.These characteristics are the size, shape, and surface properties of the primary particles, and also the size, structure and the number of primary particles in the agglomerates.In this work, the multiple light-scattering model through the optical analyzer, Turbiscan MA 2000 is used to determine the mean settling velocities of monodisperse glass beads and two polydisperse samples of powders, kaolin D and alumina, differing by their particle size distribution, their shape and their surface properties.Beyond the experimental validation of theoretical and empirical predictions, the nonlinear adjustment of experimental settling data gives the number of primary particles per agglomerate and the agglomerate size. These two characteristics lead to the determination of the fractal dimension of the agglomerates. The latter was found in the range of 2.5-2.7 for all suspensions examined. The calculation of permeability and spherical factor reveals the nonspherical impermeable agglomerates. 相似文献