热处理对7075铝合金应力腐蚀及断口形貌的影响

采用预裂纹双悬臂梁(DCB)试样研究了7075铝合金的应力腐蚀行为.结果表明,四种不同热处理状态合金的应力腐蚀敏感性由高向低的排列顺序为T6>G180>RRA>T7351.不同热处理状态的7075铝合金试样在干燥空气中的SSRT拉伸断口形貌都是由韧窝剪切台阶组成,属于韧窝型延性断裂.在3.5%NaCl溶液中,应力腐蚀敏感性较高的T6状态铝合金,其断口形貌是由塑性韧窝和腐蚀平坦区组成的,而应力腐蚀敏感性较轻微的7075-G180铝合金,属韧性断裂.     

7075铝合金应力腐蚀敏感性的SSRT和电化学测试研究

采用慢应变速率试验(SSRT)研究了7075铝合金的应力腐蚀行为。试验结果表明,外加阳极极化和阴极极化都能增加7075铝合金的应力腐蚀敏感性,即使在弱极化情况下也能显著增加合金的应力腐蚀敏感性。但是,外加极化对于不同热处理状态的7075铝合金,其应力腐蚀敏感性增加的程度不同。电极极化对T6状态合金的SCC敏感性的影响显著,而对RRA和T7351状态合金的影响较轻微。随着拉伸应力的增加,7075-RRA铝合金的阳极极化曲线略向正移,滞后环面积扩大,但并不显著。     

不同时效制度对7075铝合金组织及抗应力腐蚀性能的影响

结合回归再时效(RRA)以及分级时效两种方法,利用二者的优点,探究不同热处理制度对7075铝合金组织结构及其抗应力腐蚀性能的影响。采用光学显微镜、显微硬度仪以及扫描电镜等分析方法研究了不同时效热处理后7075铝合金组织的变化。按照ASTM G44-99应力腐蚀实验标准,对相同方法加工制造的7075铝合金螺母进行应力腐蚀实验。结果表明,经过"RRA+分级时效"的7075铝合金会获得更加均匀、细密的显微组织;而经过"回归+分级时效"处理的铝合金,在保持一定高强度的情况下,获得了更好的抗应力腐蚀性能。     

7075高强度铝合金多级时效处理及微观组织分析

以7075系高强度铝合金挤压材为研究对象,对比合金的力学性能(强度、韧性、断裂韧性)、微观组织,并重点研究了其固溶处理后的双级时效热处理工艺.结果表明,7075挤压材采用适宜的双级时效热处理工艺后具有良好的综合性能,其抗剥落腐蚀性能优于T6单级人工时效状态的性能,在保证强度满足设计要求的前提下,提高了7075型材的抗应力腐蚀性能.     

时效处理对7075合金晶界析出现象及化学性质的影响

工业用7075铝合金在其最大强7075度状态(T6)下,对应力腐蚀破裂的敏感性极强。过时效能减小应力腐蚀破裂的敏感性,但强度却下降了一些。虽然一些研究人员研究了晶界区对应力腐蚀破裂的作用,但对铝合金,特别是高强铝合金的应力腐蚀破裂根源与机理还未取     

7075铝合金预加热处理对自冲铆接质量的提升

针对7075铝合金延展率低从而造成SPR(Self-Piercing Riveting)自冲铆接过程中出现裂纹的问题,提出了对7075铝合金板材进行预加热处理的方法,使用厚度为2 mm的7075铝合金板件作为下层板与厚度为1.2 mm的RC5754铝合金板件作为上层板进行SPR铆接,对比7075铝板预加热处理前后的SPR铆接质量,并且对预加热处理前后的7075铝合金板件进行拉伸比较实验。实验结果表明:通过预加热处理,7075铝合金延展率得到提升。通过预加热处理,7075铝合金在SPR铆接过程中出现裂纹的问题得到了解决。     

7075铝合金汽车发动机摇臂的热处理工艺

通过对7075铝合金汽车发动机摇臂进行热处理工艺优化,并对3种时效状态下的7075铝合金汽车发动机摇臂的显微组织、力学性能及抗应力腐蚀性能进行了分析。结果表明,经过T6处理后,摇臂的强度达到了峰值,但电导率较低,即抗应力腐蚀性能较差;经过双级时效正交试验优化,合金强度稍有降低,电导率大幅提高,合金抗应力腐蚀性能得到改善的同时减少了生产时间及成本;该摇臂的最佳热处理制度为(460℃×1 h)固溶+(105℃×8 h+160℃×8 h)时效。     

应力作用下7075铝合金的腐蚀行为研究

本研究以7075铝合金为研究对象,采用SEM、TEM和EDAX研究了不同弹性应力和浸泡时间对7075-T6、7075-RRA铝合金在3．5wt％NaCl溶液中腐蚀行为的影响。结果表明：无应力作用下7075-T6与7075-RRA铝合金在3．5％NaCl溶液中均以点蚀为主,并伴有少量晶问腐蚀。7075-T6铝合金随着应力增加,点蚀大面积发展成片,同时晶间腐蚀向基体深入发展。而应力主要导致7075-RRA铝合金点蚀大面积发展,且随着应力增加,点蚀大面积发展,并表现为严重的均匀腐蚀。     

铝锂合金的晶间腐蚀和剥落腐蚀行为

高比强和高比模铝锂合金在航空和航天工业中具有广阔的应用前景。虽然铝锂合金对局部腐蚀极其敏感,但可通过选择适当的热处理工艺和改变环境化学条件来缓和。此外,铝锂合金的耐蚀性与合金成份和热处理工艺密切相关。本工作采用标准实验方法测试了五种铝锂合金的晶间和剥落腐蚀性能,并与常规铝合金进行了对比。结果表明,几种铝锂合金的抗晶     

热处理制度对2519铝合金板材力学性能和应力腐蚀敏感性的影响

选用3种不同的热处理工艺对2519铝合金板材进行处理，采用测定试样在腐蚀前后力学性能的变化即腐蚀的力学性能指标Kσ和Kδ来评定2519铝合金的应力腐蚀敏感性。结果表明：2519铝合金板材经先高温后低温的双级时效处理(180℃，3h 145℃，24h)后力学性能最好，抗应力腐蚀性能最差；而经形变热处理(20℃，100h 冷加工15％ 145℃，21h)后的力学性能较好，抗应力腐蚀性能最好；过时效状态(180℃，30h)下力学性能最差，抗应力腐蚀性能适中。     

An investigation of the reduction in tensile strength and fatigue life of pre-corroded 7075-T6 aluminum alloy

In aging aircraft, the synergetic interaction between corrosion and fatigue has been shown to reduce the life expectancy of aluminum alloys. The objective of this study was to quantify the effects of corrosion, in terms of mass loss per unit area, on the static strength and fatigue life of 7075-T6 aluminum alloy. This was an experimental study in which test specimens were corroded in a laboratory environment. The corrosion process was accelerated by use of a corrosion cell. Test specimens were cut from flat sheets of aluminum and covered with masking material to restrict corrosion to a confined area. After testing, the fatigue life, ultimate tensile strength (UTS), and hardness of the specimens were observed to drop significantly with small amounts of corrosion. After the initial decrease, the UTS was observed to decrease linearly with increasing corrosion levels. The fatigue life of the specimens decreased in an inverse exponential fashion as mass loss per unit area increased. The hardness values of the corroded surfaces were also observed to drop. The topology of the pits and the related subsurface damage produced areas of high stress concentration resulting in the immediate reduction of UTS and fatigue life of the specimens. Subsurface corrosion damage was responsible for the reduction in hardness.     

深冷处理对7075-T6铝合金高速切削亚表层微细观演变及腐蚀机理的影响研究

目的 探究切削速度对经深冷处理和未经深冷处理的7075-T6铝合金微观组织演变机理和耐腐性的影响。方法 选取经深冷处理(T6-C)和未经深冷处理(T6)的7075-T6铝合金进行切削加工,并在3.5%(质量分数)NaCl溶液中进行电化学腐蚀实验。通过透射电镜(TEM)、HRTEM、X射线衍射仪(XRD)、扫描电镜(SEM)和电化学分析,对微观组织演变、表面形貌和耐腐蚀性能进行研究。结果 在相同的切削参数下,相较于T6铝合金,T6-C铝合金表现出更小的晶粒尺寸,铝基体中存在更多的析出相——η相MgZn2,且位错密度以及析出相密度更大,无析出晶界带为断续分布。深冷处理和增大切削速度都显著提高了7075-T6铝合金的耐腐蚀性能,且腐蚀形貌存在显著的龟裂现象。通过电化学分析得知,当切削速度为1 500 m/min时,与未深冷处理相比,深冷处理后的7075-T6铝合金的电流密度减小了3.24×10⁻⁶ A/cm²,极化电阻增大了1.68×10⁵ Ω.cm²,在该参数下表现出较好的耐腐蚀性能。与此同时,随着切削速度的增大,容抗弧半径呈增大的变化趋势,且相较于T6铝合金,T6-C铝合金具有更大的容抗弧半径。结论 深冷处理可以有效细化7075-T6铝合金的晶粒结构,进而强化位错密度,从而显著提升该合金的耐腐蚀性能。     

两种包铝的高强铝合金受力状态下的大气腐蚀行为

采用U型弯曲加载和模拟大气加速腐蚀试验方法及扫 描电镜，研究了包铝的两种工业高强铝合金LY12和LC4在受力状态下的大气腐蚀行为.结果表明，两种铝合金基体在此模拟大气加速腐蚀试验环境中对晶间腐蚀和应力腐蚀裂开均敏感.晶间腐蚀从局部开始，逐渐向四周扩展.在发生晶间腐蚀部位出现垂直于受力方向的沿晶裂纹，并随试验时间延长裂纹也逐渐加长；合金板材表面具有约90μm厚的包铝层，除点蚀外，这层包铝层未出现其它形式的局部腐蚀，说明包铝层对铝合金基体起到了很好的保护作用.两种包铝高强铝合金板材在包铝层完好时均对晶间腐蚀和应力腐蚀裂开的敏感性差.     

Corrosion Evolution of High-Strength Aluminum Alloys in the Simulated Service Environment of Amphibious Aircraft in the Presence of Chloride and Bisulfite

The corrosion evolution of 2024-T351 and 7075-T651 aluminum alloys in the thin electrolyte layer (TEL) and wet-dry alter-nating cycle (WDAC) environment is studied in this work.The results show that in the TEL environment,the competitive effect between H+ that accelerates corrosion reactions and deposition of aluminum sulfate that impedes corrosion attacks exists during the corrosion exposure.The difference is that with increasing HSO3-,subsurface intergranular corrosion on 2024-T351 is promoted to form exfoliation corrosion eventually and the degree of exfoliation corrosion begins to decrease because the blocking effect of aluminum sulfate exceeds the expediting effect of H+.For 7075-T651,the corrosion area and the corrosion diameter decrease gradually,which is attributed to the HSO3-enhanced deposition of corrosion products and their blocking effect.In the WDAC environment,the corrosion processes of 2024-T351 and 7075-T651 are the acidic dissolution of the matrix during the soaking phase.When the HSO3-concentration is high enough (0.1 M),the inhibiting effect of aluminum sulfate becomes the dominant factor.     

Effect of aging time and temperature on exfoliation corrosion of aluminum alloys 2024‐T3 and 7075‐T6

Two types of aluminum alloys, 2024‐T3 and 7075‐T6, have been selected in this study to investigate the effect of metallurgical aspects on exfoliation corrosion. To determine and evaluate the metallurgical effects of heat treatments on corrosion behaviour of these alloys, G34 ASTM test was selected to investigate the exfoliation corrosion behaviour. The results showed that with increasing the aging time for the aluminum alloy type 2024‐T3 the susceptibility to exfoliation corrosion increases, while for type 7075‐T6 decreased. These results refer to precipitation of the intermetallic compound phases such as CuAl₂, and MgZn₂, in 2024‐T3 and 7075‐T6 respectively. The amount of these phases increases with increasing the aging time for both alloys. The investigations showed the phases that initiate in 2024‐T3 act as anode sites while in 7075‐T6 they act as cathode sites.     

SURFACE ANALYSIS OF ALUMINUM ALLOYS INFLUENCED BY SULFATE REDUCING BACTERIA

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Effect of high-temperature pre-precipitation on mechanical properties and stress corrosion cracking of Al-Zn-Mg alloys

1　INTRODUCTIONMediumandhighstrengthAl Zn Mgseriesaluminumalloysarethe primaryweldingstructurematerialsofaerocrafts ,transportationvehiclesandmilitaryequipments[1,2 ] ,duetoitsbetterweldabilityandexcellenttechnologicalproperty .Buttheexten siveutilizationofthesealloysishamperedbyitspoorstresscorrosioncracking (SCC)resistance[3,4 ] .Ac cordingly ,manystudieshavebeenconcernedwithsuchaproblemashowtoimprovestresscorrosionre sistanceofAl Zn Mgalloyswithnon deterioratedstrength[3,58] .Atpres…     

Study of the SCC Behavior of 7075 Aluminum Alloy After One-Step Aging at 163 °C

For the past many years, 7075 aluminum alloys have been widely used especially in those applications for which high mechanical performances are required. It is well known that the alloy in the T6 condition is characterized by the highest ultimate and yield strengths, but, at the same time, by poor stress corrosion cracking (SCC) resistance. For this reason, in the aeronautic applications, new heat treatments have been introduced to produce T7X conditions, which are characterized by lower mechanical strength, but very good SCC behavior, when compared with the T6 condition. The aim of this study is to study the tensile properties and the SCC behavior of 7075 thick plates when submitted to a single-step aging by varying the aging times. The tests were carried out according to the standards and the data obtained from the SCC tests were analyzed quantitatively using an image analysis software. The results show that, when compared with the T7X conditions, the single-step aging performed in the laboratory can produce acceptable tensile and SCC properties.     

Influence of Ultrasonic Rolling on Corrosion Resistance of 7075 Aluminum AlloyEI北大核心CSCD

表面纳米化处理是一种有效改善耐腐蚀性能的手段,但受表面粗糙度和残余应力等因素的影响,其相关机制并不清晰。 运用透射电镜(TEM)和扫描电镜(SEM)研究经超声表面滚压工艺(USRP)处理后 7075 铝合金的组织和性能。结果表明： 经 1 道次和 15 道次 USRP 处理后,7075 铝合金表面粗糙度减小并且引入了残余压应力。滚压 15 个道次的试样表面能获得平均晶粒尺寸为 52 nm 的纳米晶。相较于未处理试样,经 1 道次和 15 道次 USRP 处理后试样的耐腐蚀性能均显著提高。其中, 滚压 15 个道次试样的耐腐蚀性能提升更为显著。这主要是因为纳米晶可以使材料表面形成更加致密的钝化膜,导致其耐腐蚀性能显著提高,而表面粗糙度降低和引入残余压应力是提升耐腐蚀性能的次要因素。对比分析残余应力、表面粗糙度和表面纳米晶对 7075 铝合金耐腐蚀性能的影响,揭示了 7075 铝合金经表面纳米化处理后耐腐蚀性能提升的机制。