含偶氮苯侧链型聚酰亚胺的合成及光致变色性能

用5,5′-(六氟异丙基)-二-(2-氨基苯酚)(6FHP)、均苯四甲酸酐(PMDA)及分散红1(DR1)合成了具有光致变色性能的含偶氮苯侧链型聚酰亚胺。利用红外(IR)、紫外-可见(UV-Vis)、示差扫描量热(DSC)和热失重分析(TGA)等手段对该光致变色聚合物材料进行了结构和热性能表征。示差扫描量热分析测得其玻璃化转变温度为298℃,热重分析测得其热分解温度为365℃,表明具有非常好的热稳定性。研究了该材料的N-甲基-2-吡咯烷酮(NMP)溶液和聚合物薄膜在紫外光诱导下的光异构化及热回复异构化行为。结果表明,在一定波长(365 nm)紫外光诱导下均能发生光致变色现象,对于实现偶氮材料的永久光致双折射和永久光存储具有一定意义。     

侧链含偶氮苯发色团的聚酰亚胺的光致变色性能与非线性光学效应

利用对-硝基苯基重氮氟硼酸盐和聚酰胺酸进行重氮偶合反应,再经过酰亚胺化反应,合成了侧链含偶氮苯发色团的聚酰亚胺非线性光学材料(NLOPI).在室温下测试了NLOPI的光致变色性能,研究了激光作用时间和激光功率密度对光致变色性能的影响.研究发现,在波长为532 nm的YAG激光作用下,随着激光辐射时间的延长和激光功率密度的增大,NLOPI在360 nm处的吸收增强,而在500 nm处的吸收减弱.采用单光束Z-扫描技术,系统地研究了NLOPI三阶非线性光学特性.研究表明,侧链含偶氮苯发色团的聚酰亚胺为自散焦介质,其非线性折射率n2为-1.62×10-7 esu,非线性折射系数γ为-4.04×10-14 m2/W,非线性吸收系数β为3.98×10-8 m/W,三阶光学非线性极化率χ(3)为3.41×10-18 m2/W.     

手性偶氮苯衍生物的光致变色和全息存储特性研究

研究了手性偶氮分子N-[4-(4-十二烷氧基苯基偶氮)苯甲酰]-L-谷氨酸(C12-Azo—L-Glu)掺杂聚合物薄膜的光致变色特性。利用C12-Azo-L-Glu掺杂聚甲基丙烯酸甲酯(PMMA)薄膜的可逆光致异构过程．以线偏振的氩离子激光(488nm)作抽运光和写入光，线偏振氦氖激光(632．8nm)作再现光和读出光．探讨了光致双折射和全息光学存储过程中．衍射信号强度与氩离子激光功率的关系。实验结果表明C12-Azo-L-Glu具有响应时间快、可擦重写、耐疲劳度高的特点，可用作实时存储材料。     

偶氮材料的光致变色

探讨了光致变色的作用原理,从分子结构分析角度,研究了偶氮化合物材料的光致变色特性采用激光脉冲作为探测光对该材料的光致变色进行了实验和测量,得到了透过光强与时间的关系图并对有机光致变色介质在光信息存储领域的应用特点进行了说明.     

新型偶氮苯衍生物的制备及其光学性能

以4-(4′-硝基偶氮苯)-1-萘酚、4-氯正丁醇和3-噻吩乙酸为原料,通过脱氯化氢反应和酯化反应,制备了具有推拉电子结构的新型偶氮苯衍生物3-{4-[(4′-硝基苯偶氮基)萘氧基]丁基)噻吩基乙酸酯(ATh4).研究表明,ATh4的热稳定性较好,起始分解温度约为200℃;ATh4在不同的极性溶剂中产生明显的溶致变色效应,在550～750 nm范围内,ATh4在三氯甲烷和THF中没有出现明显的吸收带,而在DMSO、DMF和NMP中出现明显的吸收带,随着溶剂极性的增强,最大吸收峰强度不断增强,且最大吸收峰产生红移现象;ATh4具有良好的光致发光性能,在三氯甲烷中ATh4在550 nm处出现一个明显的荧光发射峰.     

偶氮苯聚合物掺杂液晶光栅的研究

将偶氮苯聚合物和向列相液晶以一定比例混合后注入液晶盒,用线性偏振光进行掩膜光照,引发偶氮苯聚合物发生顺反异构,诱导液晶产生光双折射现象,形成偶氮苯聚合物掺杂液晶光栅,样品通过光学显微镜和He-Ne激光器的检测,结果表明该光栅具有清晰的光栅结构,衍射效率高并具有电场可调谐性,更为重要的是驱动电压大幅降低,可与集成电路匹配。     

偶氮苯聚合物的光致双折射数学模型的优化

通过计算机模拟对含偶氮苯生色团的无定型共聚物的光致双折射进行研究,分析其光致双折射的写入、弛豫持性,对光致双折射的产生机制提出了一个新的数学模型。通过改变理论模型的参数,用穷举法求出具有不同参数的理论模型与实验数据之间误差的最小值,从而求出最理想数学模型的参数。     

掺杂偶氮苯聚合物薄膜光致双折射特性

通过改变激励光光强以及激励光偏振方向与探测光偏振方向的夹角θ,研究一种新的掺杂偶氮苯聚合物薄膜光致双折射的特性。实验结果表明该掺杂偶氮苯聚合物薄膜在低激励光强下具有良好的光信息储存性能,是一种很有潜力的光储存材料。对有关实验结果作出了定性的解释。     

偶氮苯聚合物薄膜光致表面调制效应研究

实验观测了偶氮苯聚合物薄膜在Ar^ 激光（488nm)激发下的光表面调制效应。给出了488nm激光激发条件下,含有不同偶氮苯侧基的聚合物的光表面调制效应的数值。分析比较了偶氮苯聚合物表面调制效应的强弱及其产生的原因。给出光表面调制效应与聚合物接枝率的关系。     

含偶氮苯弯曲液晶的光化学性质研究

研究了紫外光照和温度对偶氮弯曲液晶极化电流的影响。在365 nm紫外光照下,这种偶氮化合物的极化强度随紫外光照时间增加而变化直至为零;当温度从150^oC 升高到 175^oC时,弯曲液晶的极化电流随温度线性降低,用Landau-de Gennes理论解释了这一现象。其极化情况随紫外光照和温度而变化的实验规律表明：在紫外光照下偶氮弯曲液晶发生了光致异构化、光裂解和热裂解作用。     

Reversible photoinduced bi-state polymer solar cells based on fullerene derivatives with azobenzene groups

[6,6]-Phenyl-C61-butyric acid-4′-hydroxyl-azobenzene ester (PCBAb) was synthesized and used as the acceptor in the fabrication of reversible UV–VIS response bi-state polymer solar cells (PSCs) based on the photoinduced cis–trans isomerization of PCBAb. The device can be switched between “active” and “sleep” by the irradiation of UV and visible light, respectively. The active device has a PCE of 2.0%. With UV irradiation, the device goes to “sleep” with a lowered PCE (0.4%), and simultaneously decreased J_sc, V_oc and FF, while after visible light treatment, the device is made “active” again. The mechanism of the bi-state process involves the different electron mobilities of the isomers.     

环己烷类聚硅氧烷侧链液晶的合成与液晶行为研究

选用环己烷类液晶基元反式-4-乙烯基-反式-4’-丙基双环己烷(MA)和反式-4-丁烯基-反式-4’-丙基双环己烷(MB),通过硅氢加成反应将其接枝到柔性的聚硅氧烷主链上,合成了含有2种环己烷结构的聚硅氧烷侧链液晶P_(AB),产率为80.3%。采用傅立叶变换红外光谱法(FTIR)和氢核磁共振谱法(~1H-NMR)对其分子结构进行表征,说明其分子结构符合预期;采用热台偏光显微镜法(POM)和X射线衍射法(XRD)对其液晶相类型和液晶行为进行观察和分析,发现在升降温过程中所呈现出胆甾相油状条纹织构和小板块织构,揭示出因有序度不同所导致的不同织构特征;采用差示扫描量热法(DSC)和综合热分析法(TGA)对其热性能进行分析,确定其液晶区间为28.68K,T_(d(5wt%))为405.25℃,均高于液晶基元的液晶区间和热稳定性。     

Fabrication process and optical properties of perdeuterated graded-index polymer optical fiber

We proposed a graded-index polymer optical fiber (GI-POF) enabling greater-than-gigabit data transmission in a short reach network by applying a two-step interfacial-gel polymerization process to a perdeuterated polymer material. Using this process, it is possible to fabricate a nearly optimum refractive-index profile with good reproducibility. In this paper, the preparation of a perdeuterated polymethyl methacrylate (PMMA-d8)-based GI-POF utilizing a PMMA cladding is described. This means that the low-loss PMMA-d8 material is used only for the core. Because the cladding transmits only a small fraction of the optical power, a low-loss material is not necessarily required for the cladding. It was verified that the low attenuation of the PMMA-d8 was maintained even if the cladding was composed of hydrogenated PMMA. As a result, a gigabit data transmission over 300 m was achieved by the PMMA-d8-core and PMMA-cladding GI-POF, which was impossible by the conventional PMMA-based GI-POF.     

Fabrication and properties of polymer optical fibers containingNd-chelate

Graded-index poly(methyl methacrylate) optical fibers (GI POF) containing a Nd-chelate have been fabricated. The absorption spectrum of the fiber exhibited several strong bands in the visible and infrared regions. We have observed infrared fluorescence (0.90, 1.06, and 1.3 μm) of the Nd³⁺ ion of the fiber at room temperature when it was pumped with an Ar⁺-pumped dye laser at 580 nm     

基于聚合物光纤局域网系统的自由空间光通信

设计了与125 Mbps聚合物光纤局域网兼容的自由空间光通信系统,以实现楼宇间的数据通信,克服聚合物光纤传输距离较短的缺点.自由空间光通信包括发射和接收两个部分,发射部分由650 nm半导体激光器,驱动电路和准直扩束镜组成,接收部分由接收透镜和光电探测器组成.半导体激光器的调制发射功率为3 dBm,光电探测器的探测灵敏度为-27 dBm.分析了大气对光信号的衰减以及大气湍流造成的光斑抖动对通信的影响,记录了系统的信号传输波形和通信眼图.实验表明,自由空间光通信可以延长聚合物光纤局域网的通信距离,使其在实际工程中的应用更加灵活.     

Crosstalk-enhanced polymer digital optical switch based on aW-shape

A three branch digital optical switch in polymers with a crosstalk of -30 dB is presented. Its crosstalk is insensitive to increasing heat power, which is the main advantage to ordinary DOS     

Tunable attenuator based on polymer microstructured optical fibers

The polymer microstructured optical fiber is a kind of fiber whose core and cladding are composed of air holes and organic compornoleel by a certain rule. Similar with silica microstructured optical fibers (SMOF), according to the light guide mechanism PM…     

一种基于MZI的聚合物光波导加速度计

提出了一种基于马赫增德尔干涉仪（MZI）的聚合物光学波导加速度计。理论推导了MZI结构的传输函数,仿真分析了悬臂梁结构参数与器件灵敏度的关系,制备和测试了基于聚合物材料和柔性衬底的加速度传感芯片。制备得到了4 μm×4 μm单模传输芯层波导的传感芯片。搭建了集成光学加速度测试系统,采用比较校准法对探测器输出电压信号进行标定,实现了传感芯片因施加加速度后输出光强变化的测试,完成了加速度测量。该加速度传感芯片分辨率为10-2 g,动态范围为±2 g。     

Impact of polymer material properties on microstructured optical fibres

Polymer optical fibres (POFs) have historically been regarded as a poor relation to their silica counterparts because of their higher attenuation, but they also have a number of advantages, particularly when coupled with a range of properties that can be produced using micro-structures. In terms of their mechanical properties, they are lighter, remain flexible at large core sizes and can be stretched well beyond 30% without breakage. They are also biocompatible, they do not produce dangerous shards, and their low processing temperatures allow functionalized organic materials to be incorporated without decomposition. Other advantages for specific applications include better transmission properties (in the THz region) and the possibility of refractive indices that are close to that of water.