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1.
利用共沉淀法制备了CMS@Fe3O4磁性纳米颗粒。利用扫描电子显微镜、红外光谱、Zeta电位分析仪以及振动样品磁强计表征了纳米颗粒的形态以及性质。磁性纳米颗粒类似于球状,平均直径为(35±10)nm。结果表明,在较高的pH范围内粒子有较高的负电顺磁性。30 d后考察了CMS@Fe3O4磁性纳米颗粒的稳定性,CMS@Fe3O4磁性纳米颗粒在pH值为11时保持较好的稳定性。 相似文献
2.
Tseng‐Yeong Wang Raymond Chien‐Chao Tsiang Jin‐Shang Liou James Wu Hun‐Chang Sheu 《应用聚合物科学杂志》2001,79(10):1838-1846
A saturated star‐shaped polystyrene‐b‐poly(ethylene‐co‐propylene) block copolymer, (SEP)star, was synthesized for use as a viscosity index improver in lubricants. Polystyrene‐b‐polyisoprene arms were first made anionically, followed by a linking reaction at the optimum temperature of 60°C with divinylbenzene. The resulting star‐shaped (SI)star was hydrogenated to eliminate the double bonds on the polyisoprene segment, thus forming the star‐shaped (SEP)star. The number of arms on each molecule increased with an increase in the mol ratio of divinylbenzene to n‐butyllithium. Increasing the arm length adversely affected the linking efficiency but caused a slight increase in the degree of branching. The Tg of the poly(ethylene‐co‐propylene) block was 13°C higher than that of the original polyisoprene block. Compared with (SI)star, (SEP)star has a thermal decomposition temperature 50°C higher but independent of the arm length or the degree of branching. Viscosity measurements for (SEP)star revealed that intrinsic viscosity depends only on the arm length, but not on the degree of branching. Adding 1 wt % of (SEP)star markedly increased the viscosity index of a HN base oil. With a fixed arm length, a (SEP)star having a higher degree of branching increased the viscosity index more than that having a lower degree of branching. On the other hand, the viscosity index increased with an increase in the arm length when the degree of branching was fixed. The addition of 1wt % of (SEP)star increased the vioscosity index up to a number between 111 and 166, with the exact number depending upon its arm length and degree of branching. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 79: 1838–1846, 2001 相似文献
3.
Preparation and characterization of a type of ladder‐like poly(phenyl silsesquioxane) based hybrid star‐shaped copolymer of ε‐caprolactone
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Xiongfa Yang Cheng Cao Zhonghong Chen Jia Liu Alan R. Bassindale Guoqiao Lai 《应用聚合物科学杂志》2015,132(31)
Combination of the organic–inorganic hybrid such as silsesquioxane with ε‐caprolactone will lead to materials expected to be environmentally friendly and applicable to biomedical usages. A ladder‐like poly(phenyl silsesquioxane) based hybrid star‐shaped copolymer of ε‐caprolactone was prepared by ring opening polymerization of ε‐caprolactone catalyzed by Sn(Oct)2 with hydroxyl terminated ladder‐like poly(phenyl silsesquioxane) as initiator. The copolymers were characterized by proton nuclear magnetic resonance (1H‐NMR), silicon nuclear magnetic resonance (29Si‐NMR), Fourier‐transform infrared spectrometer (FT‐IR), size exclusion chromatography (SEC), thermo gravimetric analysis (TGA), and differential scanning calorimetry (DSC) in detail. Furthermore, the enzymatic degradation property of the copolymers was also investigated. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42335. 相似文献
4.
The ordinary flocculants rely on gravity settling for solid-liquid separation, it is difficult to meet the requirements of wastewater treatment in short flocculation settling time, few sludge production and low moisture content. A new type of flocculant is required to solve these difficulties. Magnetic materials are given more attention because of the magnetism in magnetic field. It is significant to prepare magnetic composite flocculant to realize solid-liquid separation with the combined effects of both gravity and external magnetic field. The gelatin-based magnetic flocculant consisted of poly (acrylamide-co-acryloyloxyethyl thimethylammonium chloride) grafted gelatin-coated Fe3O4 [magnetic poly (AM-co-DAC)-g-gelatin] was prepared in this article. A Box-Behnken design for determination of optimal plan with three-level and three-variable was designed. The best conditions of preparing magnetic poly (AM-co-DAC)-g-gelatin were determined. The structure of magnetic poly (AM-co-DAC)-g-gelatin was studied by infrared spectrum and its magnetic properties were characterized by magnetic hysteresis loop. The flocculation of magnetic poly (AM-co-DAC)-g-gelatin was compared with conventional flocculant. The flocculation experiment results showed that the magnetic poly (AM-co-DAC)-g-gelatin was effective for removal of turbidity and significantly reduced the settling time of flocs, compared to conventional flocculants. 相似文献
5.
Markus P
K Turunen Harri Korhonen Jukka Tuominen Jukka V Seppl 《Polymer International》2002,51(1):92-100
Star‐shaped low molecular weight poly(ε‐caprolactone)s (PCLs) were synthesized and functionalized with crosslinkable terminal groups for subsequent crosslinking. The ε‐caprolactone (CL) prepolymers were polymerized by ring‐opening in the presence of polyglycerine (PGL) as an initiator (1, 3 and 5 mol%) and Sn(II)2‐ethylhexanoate as a catalyst. Characterization of the prepolymer by 13C/1H nuclear magnetic resonance (NMR) spectroscopy, size exclusion chromatography (SEC), differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR) revealed a six‐armed star‐shaped structure for the prepolymer with the molecular weight controlled by the ratio of PGL and CL. Functionalization of the hydroxyl‐terminated prepolymer was carried out with maleic or itaconic anhydride. In both cases, the characterization of the functionalized prepolymer showed that the hydroxyl groups were completely substituted. The functionalized PCLs were successfully crosslinked through the reaction of double bonds. The crosslinking was induced either thermally with organic peroxide or photochemically with a photosensitive initiator. Characterization of the crosslinked PCLs by Soxhlet extraction, DSC and FTIR showed that the itaconic double bond was much more reactive in thermal crosslinking than the maleic double bond. Thus, the crosslinked prepolymers that were functionalized with itaconic double bonds achieved a gel content of about 90%. A gel content of 100% was achieved with several compositions where crosslinking agents were employed. © 2002 Society of Chemical Industry 相似文献
6.
To understand the molecular architectures of styrene‐butadiene four‐arm star (SBS) copolymers, a size exclusion chromatography combined with laser light scattering (SEC‐LLS) has been used to determine their weight‐average molecular weight (Mw) and radius of gyration (〈S2〉1/2), and a new method for the establishment of the Mark‐Houwink equation from one sample has been developed. Based on the Flory viscosity theory, we successfully have reduced the 〈S2〉1/2 values of numberless fractions estimated from many experimental points in the SEC chromatogram to intrinsic viscosities ([η]). For the first time, the dependences of 〈S2〉1/2 and [η] on Mw for the four‐arm star SBS in tetrahydrofuran at 25°C were found, respectively, to be 〈S2〉1/2 = 2.62 × 10?2 M (nm) and [η] = 3.68 × 10?2 M (mL/g) in the Mw range from 1.4 × 105 to 3.0 × 105. From data of [η] and 〈S2〉1/2 for linear and star SBS, we have obtained the information about the branching, namely, the ratios (g and g′) of 〈S2〉 and [η] for star SBS to that of the linear SBS of the same molecular weight, which agree with theoretical predictions. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 961–965, 2005 相似文献
7.
在超声辅助无惰性气体保护的条件下,采用氧化共沉淀和化学共沉淀相结合的方法成功制备了四氧化三铁纳米粒子。通过XRD、FTIR、SEM和TEM等对其进行表征,结果表明,制备的四氧化三铁纳米粒子具有较好的晶形结构,粒径约为7 nm。通过正交实验证明了超声时间是影响四氧化三铁纳米粒子粒径的主要因素;而Fe2+与Fe3+的摩尔比是影响四氧化三铁纳米粒子粒径的次要因素。用柠檬酸对四氧化三铁进行表面改性,制备了环境友好型水基磁流体;磁性结果显示,其矫顽力及剩磁均很低,表现出较好的超顺磁性。 相似文献
8.
Synthesis,self‐assembly,and drug release behavior of star‐shaped poly(ε‐caprolactone)‐b‐poly(ethylene oxide) block copolymer with porphyrin core
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Zhao Feng Wang Zhi‐Ming Huang Ya‐Fei Dai Xiao‐Hui Ge Yan‐Ru Pan Jian‐Ming Yan Yong‐Sheng Lin Sun 《应用聚合物科学杂志》2014,131(21)
A serial of star‐shaped poly(ε‐caprolactone)‐b‐poly(ethylene oxide) (SPPCL‐b‐PEO) block copolymers with porphyrin core were successfully synthesized from ring‐opening polymerization (ROP) of ε‐caprolactone (CL) initiated with porphyrin core, followed by coupling reaction with a hydrophilic polymer poly(ethylene oxide) (PEO) shell. The structure of this novel copolymer were synthesized and thoroughly characterized by Nuclear Magnetic Resonance (NMR), Gel Permeation Chromatography (GPC), Fourier Transform Infrared Spectroscopy (FTIR). Notably, the as‐prepared porphyrin‐cored star‐shaped copolymer could self‐assembly into different structures determined by transmission electron microscopy (TEM) and dynamic lighting scattering (DLS), which provides the great potential of using this well‐defined photodynamic therapy material for drug delivery system. Particularly, the doxorubicin‐loaded SPPCL‐b‐PEO nanosphere exhibits property of pH‐induced drug release. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40996. 相似文献
9.
Fe3O4/poly(styrene‐co‐maleic anhydride) core–shell composite microspheres, suitable for binding enzymes, were prepared using magnetite particles as seeds by copolymerization of styrene and maleic anhydride. The magnetite particles were encapsulated by polyethylene glycol, which improved the affinity between the magnetite particles and the monomers, thus showing that the size of the microspheres, the amount of the surface anhydrides, and the magnetite content in the composite are highly dependent on magnetite particles, comonomer ratio, and dispersion medium used in the polymerization. The composite microspheres, having 0.08–0.8 μm diameter and containing 100–800 μg magnetite/g microspheres and 0–18 mmol surface‐anhydride groups/g microsphere, were obtained. Free α‐amylase was immobilized on the microspheres containing reactive surface‐anhydride groups by covalent binding. The effects of immobilization on the properties of the immobilized α‐amylase [magnetic immobilized enzyme (MIE)] were studied. The activity of MIE and protein binding capacity reached 113,800 U and 544.3 mg/g dry microspheres, respectively. The activity recovery was 47.2%. The MIE had higher optimum temperature and pH compared with those of free α‐amylase and showed excellent thermal, storage, pH, and operational stability. Furthermore, it can be easily separated in a magnetic field and reused repeatedly. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 328–335, 2005 相似文献
10.
Yan Jiang Hongyan Shi Min Cai Yuan Liang Bin Li Hongwen Zhang Renguo Song 《应用聚合物科学杂志》2013,129(1):247-252
A series of polystyrene‐b‐poly(dimethylsiloxane)‐b‐polystyrene (PS/PDMS/PS) triblock copolymers had been synthesized by atom transfer radical polymerization (ATRP). The products had been characterized by Fourier transform infrared, gel permeation chromatography, differential scanning calorimetry, thermogravimetric analysis, contact angle, and scanning electron microscope. The results indicate that the PS chains have been successfully blocked onto the PDMS back bone, and the PS‐b‐PDMS‐b‐PS triblock copolymers have low‐surface tension, good thermal stability, and microphase separation configuration. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
11.
Synthesis,characterization, and photo‐responsive properties of Y‐shaped amphiphilic azo triblock copolymer
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In this study, we report the synthesis, characterization, and photo‐responsive properties of a new Y‐shaped amphiphilic azo triblock copolymer composed of two isotropic polyethylene glycol (PEG) blocks and an azobenzene liquid crystalline block. The azo block, with two ending groups suitable for the azo coupling reaction, is polymerized by atom transfer radical polymerization with a synthesized initiator containing two functional terminal groups. The macromolecular diazonium salts are prepared by the diazotization of PEG terminated with an amino group. The triblock copolymer is obtained by the azo coupling reaction between the azo block and macromolecular diazonium salts in DMF under mild condition. The intermediates and the obtained triblock copolymer are characterized by 1H NMR, FT‐IR, GPC, POM, DSC, TEM, and UV‐vis. The photoinduced isomerization behavior of the azo copolymer is investigated by UV‐vis. With the addition of water into the solution of the triblock copolymer, spherical aggregates with an average diameter of about 400 nm can be easily obtained. The aggregates are elongated when irradiated with polarized 365 nm UV light. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43695. 相似文献
12.
H. V. Vijayanand L. Arunkumar P. M. Gurubasawaraj P. M. Veeresha Sharma S. Basavaraja A. Saleem A. Venkataraman Anil Ghanwat N. N. Maldar 《应用聚合物科学杂志》2007,103(2):834-840
Novel polyimide‐γ‐Fe2O3 hybrid nanocomposite films (PI/γ‐Fe2O3) has been developed from the poly(amic acid) salt of oxydianiline with different weight percentages (5, 10, 15 wt %) of γ‐Fe2O3 using tetrahydrofuran (THF) and N,N‐dimethylacetamide (DMAc) as aprotic solvents. The prepared polyimide‐γ‐Fe2O3 nanocomposite films were characterized for their structure, morphology, and thermal behavior employing Fourier transform infrared spectroscopy (FTIR), scanning electron micrograph (SEM), transmission electron micrograph (TEM), X‐ray diffraction (XRD), 13C‐NMR, and thermal analysis (TGA/DSC) techniques. These studies showed the homogenous dispersion of γ‐Fe2O3 in the polyimide matrix with an increase in the thermal stability of the composite films on γ‐Fe2O3 loadings. Magnetization measurements (magnetic hysteresis traces) have shown very high values of coercive force indicating their possible use in memory devices and in other related applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 834–840, 2007 相似文献
13.
具有良好的化学稳定性、生物相容性、磁响应性的单分散磁性Fe3O4纳米粒子,在药学、催化化学、医学和光电磁记录材料等方面都有很大的使用前景;而具有自组装光子晶体现象的Fe3O4磁性纳米粒子在包装、印刷、防伪等领域的应用中更展现出巨大的潜力。本文在对单分散磁性Fe3O4纳米粒子的制备方法进行了总结回顾,并对单分散磁性Fe3O4纳米粒子的光学应用领域做了简略的介绍,并对单分散磁性Fe3O4纳米粒子的发展趋向进行了展望,并总结分析现阶段大多数Fe3O4纳米粒子的合成方法在非极性溶液中分散性差,使其在实际应用中受到很大的限制,未来Fe3O4纳米粒子表面进行修饰将成为该领域的研究热点之一。 相似文献
14.
Four‐arm star‐shaped polymers and copolymers were obtained by transition metal‐catalyzed atom‐transfer radical polymerization (ATRP). The polymers were characterized by FTIR and 1H‐NMR spectroscopy. Gel permeation chromatography results indicated the formation of polystyrene and polystyrene‐block‐poly(methyl methacrylate) (PS‐b‐PMMA) arms with controlled molecular weights. In dilute solution, the linear polymers had higher inherent viscosities than star‐shaped ones. Thermogravimetric analysis showed a similar degradation mechanism for linear and star‐shaped polymers. Differential scanning calorimetry indicated the successful formation of diblock star‐shaped copolymers. Copyright © 2006 Society of Chemical Industry 相似文献
15.
Preparation of new dendrimer‐like star‐shaped amphiphilic poly(ethylene glycol)–poly(ϵ‐caprolactone) copolymers for biocompatible and high‐efficiency curcumin delivery
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Novel amphiphilic star‐shaped terpolymers comprised of hydrophobic poly(?‐caprolactone), pH‐sensitive polyaminoester block and hydrophilic poly(ethylene glycol) (Mn = 1100, 2000 g mol?1) were synthesized using symmetric pentaerythritol as the core initiator for ring‐opening polymerization (ROP) reaction of ?‐caprolactone functionalized with amino ester dendrimer structure at all chain ends. Subsequently, a second ROP reaction was performed by means of four‐arm star‐shaped poly(?‐caprolactone) macromer with eight ‐OH end groups as the macro‐initiator followed by the attachment of a poly(ethylene glycol) block at the end of each chain via a macromolecular coupling reaction. The molecular structures were verified using Fourier transform infrared and 1H NMR spectroscopies and gel permeation chromatography. The terpolymers easily formed core–shell structural nanoparticles as micelles in aqueous solution which enhanced drug solubility. The hydrodynamic diameter of these agglomerates was found to be 91–104 nm, as measured using dynamic light scattering. The hydrophobic anticancer drug curcumin was loaded effectively into the polymeric micelles. The drug‐loaded nanoparticles were characterized for drug loading content, encapsulation efficiency, drug–polymer interaction and in vitro drug release profiles. Drug release studies showed an initial burst followed by a sustained release of the entrapped drug over a period of 7days at pH = 7.4 and 5.5. The release behaviours from the obtained drug‐loaded nanoparticles indicated that the rate of drug release could be effectively controlled by pH value. Altogether, these results demonstrate that the designed nanoparticles have great potential as hydrophobic drug delivery carriers for cancer therapy. © 2015 Society of Chemical Industry 相似文献
16.
Jianguo Deng Yuxing Peng Chuanlan He Xingping Long Pei Li Albert S C Chan 《Polymer International》2003,52(7):1182-1187
Magnetic and conducting Fe3O4–polypyrrole nanoparticles with core‐shell structure were prepared in the presence of Fe3O4 magnetic fluid in aqueous solution containing sodium dodecylbenzenesulfonate (NaDS) as a surfactant and dopant. Both the conductivity and magnetization of the composites depend strongly on the Fe3O4 content and the doping degree. With increase of Fe3O4 content in the composite, the conductivity at room temperature decreases, but the saturated magnetization and coercive force increase. Transmission electron microscopy (TEM) images of Fe3O4 and Fe3O4–polypyrrole particles show almost spherical particles with diameters ranging from 20 to 30 and 30 to 40 nm, respectively. The thermal stability of Fe3O4–polypyrrole composites is higher than that of pure polypyrrole. Studies of IR, UV–visible and X‐ray photoelectron spectroscopy (XPS) spectra suggest that the increased thermal stability may be due to interactions between Fe3O4 particles and polypyrrole backbone. Copyright © 2003 Society of Chemical Industry 相似文献
17.
Jiangang Jia Tieming Guo Shufang Ren Jinjun Lu Qin Ma 《International Journal of Applied Ceramic Technology》2013,10(6):900-907
Phase evolution and morphology of Fe3O4‐Si‐Al powder mixtures during ball milling from 30 min to 20 h were investigated. A 3‐h critical milling was necessary for the occurrence of mechanically activated combustion reaction. The reaction results in the formation of Fe (Si), Fe3Si, and α‐Al2O3. During ball milling from 3 to 20 h, Fe (Si) and Fe3Si were combined into disordered Fe3Si intermetallic and Fe3Si‐Al2O3 composite powder was formed. The presence of in situ formed alumina leads to a decrease in crystallite and particle sizes. The Fe3Si‐Al2O3 particles after milling for 20 h had a crystalline size of 10~12 nm. 相似文献
18.
A series of new amphiphilic poly[methyl(3,3,3‐trifluoropropyl) siloxane]‐b‐poly(ethyleneoxide) (PMTFPS‐b‐PEO) diblock copolymers with different ratio of hydrophobic segment to hydrophilic segment were prepared by coupling reactions of end‐functional PMTFPS and PEO homopolymers. PMTFPS‐b‐PEO diblock copolymers synthesized were shown to be well defined and narrow molecular weight distributed by characterizations such as NMR, GPC, and FTIR. Additionally, the solution properties of these diblock copolymers were investigated using tensiometry and transmission electron microscopy. Interestingly, the critical micellization concentration increases with increasing length of hydrophobic chain. Transmission electron microscopy studies showed that PMTFPS‐b‐PEO diblock copolymers in water preferentially aggregated into vesicles. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
19.
Guoliang Wu Songjun Zeng Encai Ou Puren Yu Yuanqin Xiong Weijian Xu 《应用聚合物科学杂志》2011,120(2):1162-1169
Acrylic acid was crosslinked with N,N′‐methylenebisacrylamide and converted to bioactive hydrogels by neutralization with different amino containing compounds. Several amino containing compounds were used such as 2‐aminopyridine, triethanol amine, hexamethylenetetramine (HMTA), pyridine, and imidazole. The best crosslinker ratio was determined in addition to the maximum absorbed water in different mediums. The antibacterial activity of the prepared gels were examined against examples of Gram‐positive (Staphylococcus aureus) and Gram‐negative bacteria (Escherichia coli) using agar plate method. The study was extended by evaluating one of prepared gels in columns as models for water filters. All prepared gels showed antibacterial action in agar plate method against both bacterium and the column method using one of the prepared gels showed excellent filtration and biocidal action. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
20.
Well‐defined side‐chain liquid crystalline star‐shaped polymers were synthesized with a combination of the “core‐first” method and atom transfer radical polymerization (ATRP). Firstly, the functionalized macroinitiator based on the α‐Cyclodextrins (α‐CD) bearing functional bromide groups was synthesized, confirmed by 1H‐NMR, MALDI‐TOF, and FTIR analysis. Secondly, the side‐chain liquid crystalline arms poly[6‐(4‐methoxy‐4‐oxy‐azobenzene) hexyl methacrylate] (PMMAzo) were prepared by ATRP. The characterization of the star polymers were performed with 1H‐NMR, gel permeation chromatography (GPC), differential scanning calorimetry (DSC) and thermal polarized optical microscopy (POM). It was found that the liquid crystalline behavior of the star polymer α‐CD‐PMMAzon was similar to that of the linear homopolymer. The phase‐transition temperatures from the smectic to nematic phase and from the nematic to isotropic phase increased as the molecular weight increased for most of these samples. All star‐shaped polymers show photoresponsive isomerization under the irradiation with Ultraviolet light. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献