Heavy metals in animals of Lake Balaton

Hg, Cd, Cu, Pb, Zn, Fe and Mn concentrations were measured in Chironomidae larvae, Crustacea plankton, as well as in various organs of mussels and fishes collected from the open water area of Lake Balaton. The values were comparatively low. However, there were significant differences in the metal concentrations of species and tissue.Most Cd was found in the gill of Unio pictorum L., most Pb, Zn and Mn in the gill of Anodonta cygnea L., most Cu in Crustacea plankton and in the liver of Abramis brama L., and most Hg and Fe in Chironomidae larvae. Low concentrations occurred in fishes, the lowest in the flesh of Stizostedion lucioperca L.Accumulation of metals in organs as compared with their concentration in the lake water was in the range of 3.4 × 10²−2.6 × 10³ for Hg; 7.0 × 10²−6.8 × 10³ for Cd; 3.3 × 10²−9.7 × 10³ for Cu; 6.9 × 10²−8.1 × 10³ for Zn; 1.5 × 10³−2.4 × 10⁴ for Pb; 3.5 × 10²−3.1 × 10⁴ for Fe; and 5.0 × 10¹−3.5 × 10⁵ for Mn.     

Mercury distribution and speciation in Lake Balaton, Hungary

The distribution and speciation of mercury in air, rain, lake water, sediment, and zooplankton in Lake Balaton (Hungary) were investigated between 1999 and 2002. In air, total gaseous mercury (TGM) ranged from 0.4 to 5.9 ng m(-3) and particulate phase mercury (PPM) from 0.01 to 0.39 ng m(-3). Higher concentrations of both TGM and PPM occurred during daytime. Higher concentrations of PPM occurred in winter. In rain and snow, total mercury ranged from 10.8 to 36.7 ng L(-1) in summer but levels up to 191 ng L(-1) in winter. Monomethylmercury (MMHg) concentrations ranged from 0.09 to 1.26 ng L(-1) and showed no seasonal variations. Total Hg in the unfiltered lake water varied spatially, with concentrations ranging from 1.4 to 6.5 ng L(-1). Approximately 70% of the total Hg is dissolved. MMHg levels ranged from 0.08 to 0.44 ng L(-1) as total and from 0.05 to 0.37 ng L(-1) in the dissolved form. Lower Hg concentrations in the water column occurred in winter. In suspended particulate matter and in sediment, total mercury ranged from 9 to 160 ng g(-1) dw, and MMHg ranged from 0.07 to 0.84 ng g(-1) dw. In zooplankton, an average mercury level of 31.0+/-6.8 ng g(-1) dw occurred, with MMHg accounting for approximately 17%. In sediments, suspended-matter- and zooplankton-high Hg and MMHg levels occurred at the mouth of the River Zala, but, in the lake, higher concentrations occurred on the Northern side, and an increasing trend from north-west to north-east was observed. In general, regarding Hg, Lake Balaton can be considered as a relatively uncontaminated site. The high-pH and well-oxygenated water as well as the low organic matter content of the sediment does not favour the methylation of Hg. In addition, bioconcentration and bioaccumulation factors are relatively low compared to other aquatic systems.     

湖泊富营养化评价方法研究

湖泊富营养化评价方法研究对于人们管理和认识湖泊富营养状态有着非常重要的作用,但是由于评价指标较多,以及不同方法所适用的湖泊条件各有不同,还没有形成较为成熟的评价方法。提出一种湖泊富营养化综合评价方法,通过主成分分析法确定影响湖泊水质的主要影响因子,构建湖泊富营养化评价标准体系,采用改进的模糊综合评价方法对湖泊水质进行评价。在上述算法的基础上,采用C语言编写算法,开发了湖泊富营养化评价系统,为水环境治理和修复提供了理论基础和技术支持。     

A mathematical model of a shallow and eutrophic lake (the Keszthely Basin, Lake Balaton) and simulation of restorative manipulations

Concern about the overall management of lakes has been growing, and a lake ecological model provides the guidelines necessary for such management. In this study, an ecological model describing the ecosystem of the Keszthely Basin, Lake Balaton, Hungary, one of the typical shallow and eutrophic lakes, was proposed. This model includes three types of zooplankton and two types of fish as well as two types of algae and nutrients. Parameters concerning the algae and fish were estimated based on observations in the basin between 1991 and 1995. The other parameters and the structure of the model were determined by our previous study. The parameters of the model were calibrated with the Monte Carlo technique, and its predictability was confirmed. The effects on the basin's ecosystem of three restorative manipulations, namely a biomanipulation, reduction of loading phosphorus, and dredging the sediment, were assessed by simulation studies using the proposed model. The simulation results indicated that a biomanipulation that removed 90% of the bream should suppress the growth of algae temporarily through bottom-up regulation; however, this effect seemed to not be perpetuated in this basin. The reduction of loading phosphorus seemed to be the most effective means to suppress algal growth, while dredging of sediment seemed to be the most desirable restoration method from the standpoint of the overall management of the lake, because it was expected to accelerate the growth of fish population as well as to suppress algal growth. Furthermore, the algal growth suppression mechanism of the dredging was discussed on the basis of the model calculations.     

Heavy metals in Lake Balaton: water column, suspended matter, sediment and biota

During the period 1999-2002, five sampling cruises have been carried out on Lake Balaton to assess trace metal distribution in the lake and to identify major sources. Eighteen elements, including Cr, Co, Ni, Cu, Zn, Cd, Pb (trace metals) and Al, Ba, Ca, Fe, K, Mg, Mn, Na, P, S, Sr (major metals), were determined in one or more of the lake's compartments. Lower trace metal concentrations in rainwater were observed in June and February 2000, while much higher levels were present in September 2001 (during a storm event) and in snow (February 2000). In the Northern and Western parts of the lake, especially at the inflow of river Zala and the locations of the yacht harbours, metal concentrations were higher in almost all compartments. Because the lake is very shallow, storm conditions also change significantly the metal distributions in the dissolved and particulate phases. The Kis-Balaton protection system located on Zala river functions very efficiently for retaining suspended particulate matter (SPM; 72% retention) and associated metals. Metal concentrations in surface sediments of the lake showed a high variability. After normalisation for the fine sediment fraction, only a few stations including Zala mouth appeared to be enriched in trace metals. In zooplankton, Zn seemed to be much more elevated compared to the other trace metals. Based on the molar ratios of the trace metals in the various compartments and input flows of the lake, several trends could be deduced. For example, molar ratios of the trace metals in the dissolved and solid (suspended particulate matter and sediments) phases in the lake are fairly similar to those in Zala River.     

Biological and chemical factors influencing shallow lake eutrophication: a long-term study

The focus of eutrophication research has tended to be upon short-term and experimental studies. However, given the range of factors that can influence eutrophication dynamics, and that these matter over a range of time scales, some discrete, some continuous, eutrophication dynamics may only be fully investigated when long-term, time-series data are available. The present study aims to evaluate the interacting effects of abiotic processes and biotic dynamics in explaining variations of phytoplankton biomass in a eutrophic shallow lake, Barton Broad (Norfolk, UK) using a long-term data set. Multivariate statistical analysis shows that the inter-relationships between phytoplankton variability, nutrient and grazing factors were highly sensitive to seasonal periodicity. In spring phytoplankton biomass was related to phosphorus, nitrogen and silicon. In summer phytoplankton biomass was associated with phosphorus, nitrogen and zooplankton. In autumn phytoplankton was related to phosphorus, nitrogen, silicon and zooplankton. In winter, no significant relationship could be established between phytoplankton and environmental variables. This paper improves our understanding of the governing role of nitrogen, phosphorus, silicon and zooplankton upon phytoplankton variability, and hence, improves management methods for eutrophic lakes.     

Seasonal variation of phosphorus release from the sediments of Shallow Lake Balaton (Hungary)

Phosphorus release was low from intact sediment cores of the mesotrophic area of the lake throughout the year, and amounted to 0.3 mg P m⁻² day⁻¹ during autumn in short-term incubations. In the hypertrophic area maximum release (2.8 mg Pm⁻² day⁻¹) was measured during summer.

Phosphorus release showed a rapid increase from long-term incubated intact sediment cores with the increasing pH of the overlying water. At the ecologically real maximum pH the release may amount to 0.8 and 4.0 mg P m⁻² day⁻¹ in the mesotrophic and hypertrophic areas, respectively. A release of 2.0–3.9 mg P m⁻² day⁻¹ was estimated from sediment suspensions of the hypertrophic area within a pH range of 8–9. These values are similar to the external phosphorus loadings of the respective areas.

The most important phosphorus mobilizing factors are pH and the decomposition of the organic matter in the sediments. Redox conditions may play a significant indirect role in the regulation of the internal loading.

A positive feedback is hypothesized between the internal phosphorus loading and primary production both processes being affected by the external loading in different ways.     

Sulfate reduction in Lake Agmon, Israel

Lake Agmon, a newly reflooded water body in the southern part of the Hula valley is characterized by a clear phase period in winter with almost no blooms of phytoplankton. Dense macrobenthos and algal blooms form in the lake during summer and autumn. High primary production and chlorophyll-a concentrations were measured in April and during the summer of 1997. Fresh organic matter in the sediments from the degradation and decomposition of the blooms together with high sulfate concentrations, allowed microbial sulfate reduction to occur. Sediment cores taken from different sites (peat and marl) during various seasons in 1997, showed high sulfate reduction rates in June in the marl region, and in September in the peat region (842 and 2834 nmol SO(4)2- reduced ml(-1) day(-1), respectively). In February, corresponding to the development and decline of macrophytes and algal blooms, lower rates of sulfate reduction were recorded (11 nmol SO(4)2- reduced ml(-1) day(-1)). Sulfate reduction is limited by the supply of organic matter and is one of the major processes contributing to the mineralization of organic matter in this lake.     

内外结合注浆在浅埋偏压隧道施工中的应用

针对宜万铁路齐家湾隧道DK156＋000～DK156＋040超浅埋段围岩软弱、浅埋偏压及山体开裂、下陷、滑移等地质条件,采用了地表和洞内外结合的注浆加固施工方案,保证了该段隧道施工安全和掘进速度。     

Thermo-hydro-chemical couplings considered in safety assessment of shallow tunnels subjected to fire load

Fire loading of concrete tunnel linings is characterized by various physical, chemical, and mechanical processes, resulting in spalling of near-surface concrete layers and degradation of strength and stiffness of the remaining tunnel lining. In this paper, the governing transport processes taking place in concrete at elevated temperatures are considered within a recently published fire-safety assessment tool [Savov K, Lackner R, Mang HA. Stability assessment of shallow tunnels subjected to fire load. Fire Safety J 2005; 40: 745–763] for underground structures. In contrast to consideration of heat transport only [Savov et al.], a coupled thermo-hydro-chemical analysis, simulating the heat and mass transport in concrete under fire loading, is performed, giving access to more realistic temperature distributions as well as gas-pressure distributions within the tunnel lining. These data serve as input for the structural safety assessment tool considering, in addition to the temperature dependence of mechanical properties, the effect of the gas pressure on the strength properties of the heated lining concrete. The combination of the two analysis tools (coupled analysis of governing transport processes and structural safety assessment) is illustrated by the fire-safety assessment of a cross-section of the Lainzer tunnel (Austria) characterized by low overburden (shallow tunnel).     

Peak load characteristics of Sydney office buildings and policy recommendations for peak load reduction

Growth in peak period electricity demand has driven the requirement for a significant expansion of Sydney's electricity network. Energy efficiency and demand management activities in office buildings may be an alternative to electricity network augmentation, with significant economic and environmental benefits. This paper identifies and characterises trends in electricity peak demand in Sydney's office buildings, comparing a range of high and low energy consuming buildings. The paper assesses the potential for energy efficiency and demand management strategies in office buildings to reduce peak loads and hence defer electricity network augmentation. Base building electricity load data was analysed for a sample of 25 Sydney office buildings, along with Sydney electricity substation and temperature data. Peak loads for buildings with best practice energy performance were found to be 26% lower than for buildings with average energy performance, while annual electricity consumption was 57% lower. With these findings, this paper has assessed the effectiveness of current energy efficiency policy for peak demand management and has recommended strengthening energy efficiency policies in order to capture coincidental peak load reductions, as well as new policies specifically targeting peak demand management. It was found that these measures could offer significant potential to defer network investment.     

应用荷载效应法画结构内力图

依照不同荷载使结构产生不同效应提出一种快速绘制内力图的简便方法——荷载效应法,简述了其计算方法,并通过实例说明该方法不仅适用于静定单跨梁,还适用于画静定多跨梁,实践证明值得推广应用。     

Phosphorus reduction in a shallow hypereutrophic reservoir by in-lake dosage of ferrous iron

In Bautzen Reservoir (Germany), a technique of internally dosing iron compounds in combination with a local water column destratification was developed in order to control Microcystis blooms. In this paper, experimental results concerning the phosphorus (P) precipitation by iron application are reported. First, preliminary studies were conducted serving the choice of an appropriate precipitant. Subsequently, a whole-lake experiment was carried out. Fe2+ salts displayed a delayed oxidation and flocculation behaviour when injected into an ascending water jet. Nevertheless, the efficiency of soluble reactive phosphorus (SRP) elimination was equal to experiments with Fe3 + compounds both in laboratory and field experiments. During Fe2+ application, a large P-binding potential remained during the horizontal spreading of the treated water, since the proportion of the dissolved iron fraction near the dosage point was still high. Thus, measurements at a greater distance from the dosage point revealed higher amounts of P eliminated by Fe2+ than by Fe3+ dosage. Compared to the preceding year 1995, during the treatment periods in May-August 1996 and 1997 the SRP contents in the whole water body dropped by 72% and 54%, respectively, while the total phosphorus contents dropped by 45% at each period. We conclude that in-lake dosage of Fe2+ is an appropriate method to reduce the P loading of hypereutrophic reservoirs.     

浅谈内部会计控制应注意的几个问题

对内部会计控制进行了介绍,深入探讨了内部会计控制应注意的几个问题,阐述了内部会计控制的实质及内部控制的思路,以加强企业内部控制,更好地发挥企业内部控制的作用。     

Cooling load reduction by using thermal mass and night ventilation

We provide a quantitative understanding of the relationship between thermal mass and cooling load, i.e. the effect of thermal mass on energy consumption of air-conditioning in office buildings. A simple office-building model with air-conditioning at daytime and free cooling at nighttime is analyzed in detail to quantify the hourly and overall variation of cooling load of air-conditioning. As an important parameter, an increase of time constant can effectively reduce the cooling load, by as much as more than 60% when the time constant is more than 400 h. However, when the time constant is larger than 1000 h, a further increase may slightly increase the cooling load, as a too large time constant may also postpone the heat release of thermal mass until the daytime. For the most effective reduction of cooling load, the interior and exterior convective heat transfer numbers need to be matched.     

钢筋混凝土偏压柱控制内力组合分析

从大偏压情况和小偏压情况两方面，分析了偏心率对对称配筋矩形和偏压柱截面配筋的影响，探讨了配筋量与偏心率的关系，结合具体算例加以说明偏心率与配筋量的关系，以保证截面设计安全。     

后注浆灌注桩静载特性研究

结合某工程的地质概况,采用人工堆载下慢速维持荷载法,对灌注桩进行了现场堆载试验,分析对比了桩端是否注浆对灌注桩承载性能的影响,得出了后注浆灌注桩承载特性和发挥机理。     

Contribution of natural ventilation in a double skin envelope to heating load reduction in winter

This study examined the contribution of a double skin envelope (DSE) to the heating energy savings brought about by natural ventilation in office buildings. A DSE was applied to the east- and west-facing walls on an actual three-floor building. Field measurements and computer simulations were performed in winter.     

Water quality modeling for load reduction under uncertainty: a Bayesian approach

A Bayesian approach was applied to river water quality modeling (WQM) for load and parameter estimation. A distributed-source model (DSM) was used as the basic model to support load reduction and effective water quality management in the Hun-Taizi River system, northeastern China. Water quality was surveyed at 18 sites weekly from 1995 to 2004; biological oxygen demand (BOD) and ammonia (NH(4)(+)) were selected as WQM variables. The first-order decay rate (k(i)) and load (L(i)) of the 16 river segments were estimated using the Bayesian approach. The maximum pollutant loading (L(m)) of NH(4)(+) and BOD for each river segment was determined based on DSM and the estimated parameters of k(i). The results showed that for most river segments, the historical loading was beyond the L(m) threshold; thus, reduction for organic matter and nitrogen is necessary to meet water quality goals. Then the effects of inflow pollutant concentration (C(i-1)) and water velocity (v(i)) on water quality standard compliance were used to demonstrate how the proposed model can be applied to water quality management. The results enable decision makers to decide load reductions and allocations among river segments under different C(i-1) and v(i) scenarios.     

Regression models for estimating storm runoff load and its application to Lake Kasumigaura

Regression models are proposed for accurate estimation of storm runoff load. Regression equations are obtained for the relationship between final cumulative load and flow during direct runoff by each storm event. The models are applied to estimate annual nutrients load by all influent rivers into the Lake Kasumigaura for a model year of average annual rainfall. The load in dry weather is calculated from observed data of all influent rivers. Total annual load for a year is the sum of loads in dry weather days and loads in wet weather days. The ratios of the load in a wet weather day to total annual loads are 29 percent for T‐N, 51 percent for T‐P, 53 percent for T‐COD, 22 percent for D‐N, 22 percent for D‐P and 30 percent for D‐COD.