聚四氟乙烯工程材料的摩擦磨损性能研究

用MPV-200型摩擦磨损试验机研究了干摩擦条件下磨损时间、滑动速度、载荷、填料等对聚四氟乙烯(PTFE)工程塑料摩擦磨损性能的影响，结果表明：PTFE材料的摩擦因数和磨损率先随速度的增大而减小，然后又随着速度的增大而增大；随磨损时间的增长而降低，最后趋于稳定值；另外，摩擦因数大体上随载荷的增大而减小，磨损量则随载荷的增大而增加；填料可将PTFE的磨损量降低2个数量级，其中石墨使PTFE的摩擦因数降低，玻璃纤维和碳纤维则增大了PTFE的摩擦因数，而MoS2对PTFE摩擦因数的影响较小。对PTFE工程塑料的摩擦磨损特性进行系统分析，为优化设计提供理论基础。     

偶件表面粗糙度对PTFE材料摩擦磨损性能的影响

为了研究干摩擦条件下偶件表面粗糙度对聚四氟乙烯(PTFE)密封材料摩擦磨损性能的影响,利用MMW-1立式万能摩擦磨损试验机,在不同载荷和转速下研究由PTFE材料制作的试验环分别与316L不锈钢和45#钢配副时的摩擦磨损性能,并利用粒形分析仪对PTFE试验环试验前后端面的形貌进行观测;利用触针式轮廓仪对摩擦配副钢环的端面粗糙度进行精确测量,分析表面粗糙度对PTFE试验环摩擦磨损性能的影响。试验结果表明:在干摩擦条件下,摩擦配副钢环的表面粗糙度过高或者过低都会引起PTFE试验环磨损量的增加;定载荷时,PTFE试验环磨损量随摩擦配副钢环表面粗糙度的增大先减小后增大,随转速的增大而增大;定转速时,PTFE试验环摩擦因数随摩擦配副钢环表面粗糙度的增大稍减小后而后增大,随载荷的增大先减小后增大;在相同工况下,316L不锈钢对PTFE试验环的切削和犁沟作用比45#钢更加明显。     

添加聚四氟乙烯微粉后聚醚醚酮复合材料的摩擦学性能

采用常温机械共混+高温模压方法制备了添加不同含量聚四氟乙烯(PTFE)微粉聚醚醚酮复合材料,研究了其力学性能、摩擦磨损性能及磨损形貌,并探讨了其摩擦磨损机理。结果表明:随PTFE微粉含量的增加,复合材料的洛氏硬度和压缩强度均降低,干摩擦条件下的摩擦因数减小,体积磨损量先降后升,当PTFE微粉质量分数5%时,体积磨损量最低;在油润滑和水润滑条件下复合材料的摩擦因数和体积磨损量均小于干摩擦条件下的,且随PTFE微粉含量的增加,油润滑条件下的体积磨损量下降,而水润滑条件下的增大;在干摩擦条件下复合材料的磨损机制以磨粒磨损为主,并伴有疲劳磨损,在油润滑条件下复合材料表面存在少量片状PTFE磨屑和碳纤维富集,在水润滑条件下复合材料表面被PTFE微片层覆盖,局部存在微裂纹和孔洞。     

铜碲硒铁合金的干摩擦磨损性能

利用环-盘式摩擦磨损试验机研究了铜碲硒铁合金的干摩擦磨损行为,分析了载荷和摩擦速度等参数对该合金摩擦磨损性能的影响,并用扫描电子显微镜对磨损形貌进行了观察.结果表明:铜碲硒铁合金的摩擦因数随载荷的增加变化不大,但随摩擦速度的增加而明显增大;合金的磨损率随载荷和摩擦速度的增加均增大;在轻载低速条件下,合金的磨损机制以犁削磨损和粘着磨损为主;在重载高速条件下,磨粒磨损和粘着磨损加剧.     

38CrSi自配副的摩擦磨损性能

采用自制的销盘式摩擦磨损试验机研究了38CrSi自配副干滑动时的摩擦因数、磨损率随滑动速度和载荷的变化规律;利用SEM观察了磨损面的微观形貌,分析了摩擦磨损机理。结果表明：其摩擦因数随着载荷和速度的增加而减小;磨损率随着载荷的增加而增大,随着速度的增加先增大后减小,和常用材料的磨损率随速度增加而增大的规律不同;磨损机理为磨粒磨损和粘着磨损。     

38CrSi自配副的摩擦磨损性能

采用自制的销盘式摩擦磨损试验机研究了38CrSi自配副干滑动时的摩擦因数、磨损率随滑动速度和载荷的变化规律;利用SEM观察了磨损面的微观形貌,分析了摩擦磨损机理。结果表明:其摩擦因数随着载荷和速度的增加而减小;磨损率随着载荷的增加而增大,随着速度的增加先增大后减小,和常用材料的磨损率随速度增加而增大的规律不同;磨损机理为磨粒磨损和粘着磨损。     

旋耕机旱地刀的摩擦磨损性能试验研究

利用HSR-2M高速式往复摩擦磨损试验机,试验干态条件下,往复速度、法向载荷和往复行程等对旋耕机旱地刀的摩擦因数和磨损量的影响,通过磨痕形貌分析其磨损机制。试验结果表明：摩擦因数均随往复速度和法向载荷的增大而减小;磨损量则随往复速度的增大先减小后增大,且随法向载荷和往复行程的增大而增大;干态条件下,磨损机制主要以磨粒磨损为主。     

高速条件下PTFE编织复合材料的摩擦磨损性能

将PTFE编织复合材料与9Cr18Mo钢组成摩擦副,在高速压摆摩擦磨损试验机上进行干摩擦磨损试验,研究了循环次数和摩擦温度对摩擦因数的影响,用扫描电镜观察了不同阶段摩擦表面及磨屑的形貌,并分析了PTFE编织复合材料的磨损机理。结果表明:PTFE复合材料的摩擦因数随着循环次数的增加先迅速降低,后在一定范围内达到动态平衡,随着摩擦的继续进行,摩擦因数急剧上升,PTFE复合材料发生磨损失效;摩擦温度是影响PTFE复合材料摩擦磨损机制一个重要因素,摩擦温度的急剧升高将加剧PTFE复合材料的磨损;随着磨损的加剧,磨屑也表现为相应的恶化趋势;磨损机理以疲劳磨损为主。     

泥沙条件下改性复合材料减振降噪性能研究

为了改善水润滑轴承材料热塑性聚氨酯（TPU）的减振降噪性能,以TPU为基体、聚四氟乙烯（PTFE）为添加剂,通过物理共混的方式制备PTFE/TPU改性复合材料。在RTEC摩擦磨损实验机上模拟泥沙工况,对复合材料进行不同速度和载荷下的摩擦学试验,通过分析复合材料的力学性能、摩擦因数、表面形貌以及振动噪声行为,探讨其摩擦磨损规律与减振降噪性能。结果表明：复合材料的拉伸强度和邵氏硬度均随着PTFE含量的增加而先增加后降低,质量分数8%PTFE改性TPU复合材料表现出最好的力学性能;随着速度与载荷的增大,复合材料的摩擦因数逐渐增大,材料表面损伤、变形、剥落等严重损伤逐渐增多;与纯TPU相比,改性复合材料的摩擦磨损剧烈程度更低,摩擦因数的变化幅度较小且摩擦因数曲线相对光滑,材料微观表面的损伤更少;随着速度与载荷的增大,复合材料的振动响应与辐射噪声现象增大,振动与噪声信号的平均强度增大,频域上的频率分量增多,幅值分量增大,主频向高频转移;PTFE能够改善TPU的摩擦学性能,降低摩擦因数,同时赋予复合材料一定的减振降噪性能,并且效果在高速、高载荷下更为明显。     

碳纤维增强杂萘联苯聚醚砜酮复合材料的摩擦学性能研究

利用MRH-03型环-块摩擦磨损试验机研究不同碳纤维含量的聚醚砜酮(PPESK)基复合材料的摩擦磨损性能,讨论载荷、速度及润滑介质对质量分数10%碳纤维增强复合材料摩擦磨损性能的影响,并用SEM观察材料的断面形貌和磨损表面形貌。结果表明：适量碳纤维的加入可以明显提高材料的摩擦磨损性能,并使得复合材料干摩擦条件下的磨损机制由严重的磨粒磨损和黏着磨损转变为黏着磨损和轻微的磨粒磨损。以质量分数10%碳纤维增强的复合材料为例,随着载荷的增加复合材料在干摩擦条件下的摩擦因数降低,而磨损率先降低后增加,在高滑动速度下复合材料的摩擦因数降低而磨损率增加;而海水润滑介质的加入大大降低了材料的摩擦因数和磨损率,并使得复合材料的磨损机制由干摩擦条件下的黏着磨损和轻微的磨粒磨损转变为轻微的磨粒磨损。     

干摩擦工况下Si3N4/PTFE配副材料摩擦磨损特性与转移膜形成分析

为使全陶瓷轴承在干摩擦工况下可靠运转,选用四氟乙烯(PTFE)材质的保持架为全陶瓷轴承提供润滑.利用Rtec销/盘摩擦磨损试验机,以PTFE盘与氮化硅(Si3 N4)销为摩擦副,研究Si3 N4/PTFE在不同载荷和转速条件下的摩擦磨损性能,通过SEM对Si3 N4表面的转移膜形貌进行观察,分析转移膜形成原因.结果表明...     

聚四氟乙烯复合材料的摩擦学二次转移行为研究

采用冷压成型、自由烧结工艺分别制备了青铜粉、聚酰亚胺、二硫化钼和石墨填充改性的聚四氟乙烯复合材料,在改装的M-2000型摩擦磨损试验机上考察了材料的二次转移摩擦学性能;用扫描电子显微镜对磨损表面进行观察和分析。结果表明:增加载荷有利于提高转移膜与基底的结合强度;填料种类对PTFE复合材料二次转移膜的摩擦学性能有影响,在本实验条件下(干摩擦、室温、滑动速度为0.42m/s、接触载荷为30N),以PTFE复合材料作为润滑剂提供源使用时,PTFE/MoS2、PTFE/Graphite复合材料形成的二次转移膜最好,PTFE/Bronze复合材料二次转移膜次之,PTFE/PI复合材料形成二次转移膜的能力最差。     

聚四氟乙烯及其石墨和MoS2填充复合材料的摩擦学性能研究

利用往复式摩擦磨损实验机,对聚四氟乙烯(PTFE)及石墨和MoS2填充的PTFE复合材料的摩擦磨损性能进行了实验,考察了载荷、速度以及对摩时间的影响,并利用光学显微镜对PTFE复合材料的摩擦磨损表面进行了观察。结果表明,填加了石墨和MoS2的PTFE,由于石墨和MoS2一方面起到了润滑作用,另一方面阻止了PTFE带状大面积破坏,因而使得PTFE的摩擦因数降低,耐磨性提高。加入石墨和MoS2后PTFE的磨损机制由以犁沟效应和粘着磨损为主变为以磨粒磨损为主。     

Dry sliding wear behaviour of PTFE filled with glass and bronze particles

Abstract

The wear behaviour of polytetrafluroethylene (PTFE) filled with 25% glass and 40% bronze particles was studied on a pin on disc test rig. Solid lubricant composite materials were prepared by compression moulding technique. The wear parameters considered for the study were applied load, sliding speed and sliding distance. The experimental results indicate that the weight loss increases with increasing load, sliding speed and sliding distance, as expected. Sliding distance has more effect on weight loss followed by applied load. The 40% bronze+PTFE composite exhibits better wear resistance compared to other types. The dominant interactive wear mechanisms during sliding of PTFE and its composites are discussed in this paper.     

Dry sliding friction and casing wear behavior of PCD reinforced WC matrix composites

The friction and casing wear properties of PCD reinforced WC matrix composites were investigated using a cylinder-on-ring wear-testing machine against N80 casing steel counterface under dry sliding conditions. The results indicate that the friction and casing wear rate of PCD reinforced WC matrix composites are the lowest among the materials. As the applied load and sliding speed steadily increase, the friction coefficients of PCD reinforced WC matrix composites decrease. In addition, the casing wear rates increase with increasing load, but decline with sliding velocity. The dominant wear mechanism of the PCD composite is the micro-cutting wear, accompanied by adhesive wear.     

不同工况下软质丁苯橡胶轮表面磨损颗粒的产生量及磨损机理

采用自行设计的摩擦磨损试验机,研究了磨损时间、载荷、滚动速度、相对湿度对软质丁苯橡胶轮表面产生的磨损颗粒数量和橡胶轮温度的影响,分析了不同工况下的磨损机理;采用正交试验分析了各因素的影响程度.结果表明:磨损颗粒随磨损时间和载荷的增加而增多,随滚动速度和相对湿度的增大而减少;粒径为2.5μm的磨损颗粒数量和橡胶轮温度随各...     

聚甲醛复合材料在不同载荷和转速下的摩擦学特性

为了考察外界条件对聚甲醛复合材料摩擦学特性的影响,用摩擦磨损实验对模压法制备的Ekonol/POM和Ekonol/G/MoS2/POM复合材料在不同载荷和转速下的摩擦学性能进行了研究,并用扫描电镜(SEM)对磨损表面进行了观察和分析,在此基础上探讨了复合材料在不同条件下的磨损机制。结果表明:随着载荷或转速的增加,聚甲醛(POM)及其复合材料的摩擦因数呈先增大后减小的趋势,而材料的磨损量则随着载荷或转速的增加而增大;随着载荷或转速的提高,ZOGM20的磨损机制发生了由粘着磨损到疲劳磨损再向塑性流动的转变。     

Tribo-investigation on PTFE lubricated PEEK in harsh operating conditions

A series of blends with Polytetrafluroethylene (PTFE) powder and Polyetheretherketone (PEEK) was developed by varying the PTFE contents in steps of 5 wt.% from 0 to 20 wt.%. The composites were evaluated for their friction and wear properties at room temperature as well as high temperature in low amplitude oscillating wear (LAOW) mode against steel (100 Cr 6) ball against polymer plate. The same blends were also evaluated in abrasive wear mode to study the influence of harsh operating conditions on wear and friction performance. Incorporation of PTFE benefited PEEK in various ways such as it increased the tribo-utility of the latter by increasing its limiting load value, removing its stick-slip tendency, lowering coefficient of friction and specific wear rate significantly. With increase in PTFE content, benefits to the wear performance increased regularly. This was not the case for friction coefficient. Lowest μ was recorded for 15% PTFE contents. The enhancement in wear and friction performance, however, was at the cost of strength properties which decreased substantially with increase in PTFE content. At 100 °C, friction coefficient and wear rates of all blends increased marginally. In abrasive wear mode, on the other hand, PTFE filled PEEK showed poorer wear resistance than neat PEEK. This was correlated with strength properties and it was observed that these blends closely followed the predictions of Ratner–Lancaster plot. SEM was used to examine the micro-structural features of worn surfaces.     

Friction and wear properties of metal powder filled PTFE composites under oil lubricated conditions

Four kinds of polytetrafluoroethylene (PTFE)-based composite, pure PTFE, PTFE+30vol.%Cu, PTFE+30vol.%Pb and PTFE+30vol.%Ni composite, were prepared. The friction and wear properties of these metal powder filled PTFE composites sliding against GCr15 bearing steel under both dry and lubricated conditions were studied using an MHK-500 ring-block wear tester. The worn surfaces of the PTFE composites and the transfer films formed on the surface of GCr15 bearing steel were examined using scanning electron microscopy (SEM) and optical microscopy respectively. Experimental results show that the friction and wear properties of the PTFE composites can be greatly improved by liquid paraffin lubrication. The wear of these PTFE composites can be decreased by at least 1 to 2 orders of magnitude compared with that under dry friction conditions, while the friction coefficients can be decreased by 1 order of magnitude, SEM and optical microscopy investigations of the rubbing surfaces show that metal fillers of Cu, Pb and Ni not only raise the load carrying capacity of the PTFE composites, but also promote transfer of the PTFE composites onto the counterfaces, so they greatly reduce the wear of the PTFE composites. However, the transfer of these PTFE composites onto the counterfaces can be greatly reduced by liquid paraffin lubrication, but transfer still takes place.     

Tribological Properties of PTFE and PTFE Composites at Different Temperatures

The friction and wear properties of polytetrafluoroethylene (PTFE) and its composites with fillers such as bronze, glass fiber, carbon fiber, carbon, graphite, and polymer were studied at ambient temperature and high temperature. The wear resistance and hardness were enhanced by the fillers. Results showed that the wear resistance of all composites was much higher than that of pure PTFE. Pure PTFE has the lowest friction coefficient at ambient temperature (temperature: 23 ± 2°C, humidity: 50 ± 10%) but highest friction coefficient at high temperature (above 100°C). The PTFE composite filled with bronze showed the best wear resistance at ambient temperature but the poorest wear resistance at high temperature. The carbon-graphite- or polymer-filled PTFE composite showed a lower friction coefficient and moderate wear resistance at both ambient and high temperature.