采用R22、R134a两种制冷剂的毛细管特性对比研究

建立单相区和两相区毛细管模型,模型计算的毛细管质量流量与实验测量的质量流量差别小于(10%.研究了R134a代替R22后毛细管的质量流量随冷凝温度、过冷度、毛细管内直径和毛细管长度的变化规律,结果表明,两种制冷剂有相同的变化规律,但是在相同的条件下,R22的质量流量比R134a大,比如冷凝温度为45℃时,R22的质量流量比R134a高31.1%.     

R515B在中高温热泵系统中的性能研究

对低GWP制冷剂R515B在双螺杆单级蒸汽压缩式热泵系统中的性能进行了研究。通过实验对比研究R515B直接替换R134a时系统的性能变化,结果表明：R515B的制热量比R134a降低27%左右,消耗功率比R134a降低约28%,制热COP比R134a平均提高1%,排气温度降比R134a低约15℃。同时建立热泵系统仿真模型,预测R515B在较高冷凝器出水温度下热泵系统的性能,结果表明：R515B具有优良的热力学性能和循环性能,在采用单级蒸汽压缩循环的中高温热泵系统中可实现88℃以下的高冷凝器出水温度。     

R1234ze(E)在R134a离心式制冷压缩机中的直接替代研究

随着全球对环保要求的日益提高,以R1234yf、R1234ze(E)、R1233zd(E)等为代表的ODP为0且GWP较低的制冷剂得到广泛关注并应用。针对R134a离心式冷水机组,采用CFD数值方法,对采用R1234ze(E)直接替代的离心制冷压缩机进行了模拟,对机组性能进行了比较分析。结果表明：在同一转速下,当冷凝温度较小时,R1234ze(E)机组的制冷量和COP都小于R134a机组的,当冷凝温度较大时,R1234ze(E)机组的制冷量和COP都大于R134a机组的。当R134a机组与R1234ze(E)机组的蒸发温度、冷凝温度和制冷量都相同时,R1234ze(E)机组的COP比R134a机组的COP平均降低了约5.14%。     

R134a/CO2复叠制冷系统的实验研究

针对R134a/CO2复叠制冷系统搭建实验台,研究不同工况下系统性能参数的变化规律,考查了压缩机效率对系统性能的影响,并与传统R404a系统性能进行比较。研究表明：在高温级冷凝温度48℃,低温级蒸发温度-30℃,冷凝蒸发器传热温差为3℃的工况下,CO2冷凝温度为-2℃时系统COP出现最大值,并在最优值±5℃内系统性能变化不大;不同实验工况下,CO2压缩机绝热效率最大偏差不超过4%,影响系统制冷量的主要因素是压缩机的容积效率;相同工况下,R134a/CO2复叠制冷系统性能可比常规R404a系统性能高3%。     

改进的R23/R134a自复叠制冷系统实验研究

为了研究R23/R134a混合工质自复叠制冷系统在变工况下的运行性能,更深入地了解系统各部件对自复叠循环的影响,在已建成的自复叠循环系统实验台上进行实验研究.在冷凝温度较高的夏季,测试该自复叠实验装置所能达到的最低蒸发温度,并研究冷凝温度、工质充注质量分数及蒸发冷凝压力对该系统的影响.     

-60℃水冷自复叠制冷系统研究

提出一种新型水冷自复叠制冷循环方式,用冷凝分离器代替传统循环的冷凝器和相分离器,在冷凝分离器中同时完成了高沸点工质的冷凝及高沸点工质与低沸点工质的分离。对采用这种冷凝分离器的水冷自复叠制冷循环方式的R22/R23、R290/R170、R134a/R23、R134a/R170四种工质对进行了循环特性研究。在自行搭建的水冷自复叠制冷系统实验台上进行了R22/R23、R134a/R23两种工质对的实验研究。结果表明,在相同工况下,R22/R23自复叠制冷系统的COP要高于R134a/R23自复叠制冷系统;和传统的自复叠系统相比,采用冷凝分离器的水冷自复叠制冷循环COP明显提高,提升率达到60%~100%。     

R134a和R417A应用于热泵热水器灌注式替代R22的实验分析

在空气源热泵热水器中,对R22、R417A和R134a进行了理论计算及实验分析.结果表明,R417A的制热量和COP更接近于R22,并且排气温度比R22低25℃左右,排气压力也比R22平均低0.17MPa;尽管R134a也具有较低的排气温度和排气压力,但其制热量远远小于R22,低温工况下,吸气压力过低,而且需更换压缩机润滑油,因此,R417A比R134a更适合在空气源热泵热水器中对R22进行直接灌注式替代.     

水平光滑细管内R1234ze冷凝换热特性实验研究

对流体R1234ze在内径2 mm 的水平光滑圆管内的冷凝换热特性进行了实验研究,设定流体饱和温度为35 ℃、40 ℃,质量流量为100~400 kg/(m2?s),热流密度为4~22 kW/m2。实验获得了R1234ze在不同工况下的冷凝换热系数和摩擦压降。发现R1234ze的冷凝换热系数范围在1.5到8 kW/(m2?K)之间,且随干度的增加而增加,随质量流量的增大而增大,随饱和温度的升高而降低,比在相同工况下R134a 、R32的换热系数分别平均低约22%和31%。R1234ze的摩擦压降随质量流量增加而增大,随饱和温度的升高而降低,高于相同工况下R32的摩擦压降。并将本次实验值与其它经典换热模型和压降模型进行了对比分析,发现Baird等人的模型对本次实验的换热系数预测较好,对其它文献中的相似数据点预测也较好。Müller- Heck模型对摩擦压降预测最好。     

R1234yf和R134a制冷及制热性能实验研究

通过搭建实验台,对R1234yf的制冷及制热性能进行测试,并与R134a进行比较。测试结果表明,相同工况下,采用同一压缩机,R1234yf的排气温度更低,能在更大的工况范围内运行;R1234yf功耗比R134a高0.76%~5.18%;R1234yf的制冷量和制冷COPc与R134a相比因工况的不同而大小不同;R1234yf的制热量和制热COPh与R134a相比分别小0.75%~27.08%和1.50%~29.96%。     

R1234yf热泵技术综述与潜力分析

为了满足逐步严苛的环保法规要求,R1234yf成为车用热泵制冷剂R134a的热门替代制冷剂之一。本文对R1234yf热泵技术的研究进行了综述与分析,其GWP<1,各方面性质均符合车用热泵系统的工作需求。在传热效果上,R1234yf的沸腾传热性能略优于R134a,且冷凝过程压降比R134a低5%～10%,优于R134a系统。在诸多R1234yf和R134a系统的仿真和实验研究中,R1234yf热泵性能略低于R134a,但可以通过优化零部件、强化补气、改善工况等方式使其与R134a十分接近甚至超越。R1234yf低压饱和压力比R134a高约15%,可以适配更高的压缩机转速,低温下制热性能比R134a更好,且较低的压缩机排气温度使系统工作更为稳定,强化补气的效果也优于R134a。因此,R1234yf在车用热泵中具有较好的工作性能和发展前景,可以作为R134a的替代制冷剂。     

Viscosity of refrigerants R12, R113, and R114 and mixtures of R12 + R114 at high pressure

New viscosity measurements for the gaseous and supercritical state of the halogenated hydrocarbons R12, R113, and R114 and binary mixtures of R12 + R114 of different compositions are presented. The measurements were carried out at superheated and supercritical temperatures from 30 to 200° C and in the pressure range from 1 to 80 bar. Viscosity was measured with an oscillating-disk viscometer and the data obtained are relative to the viscosity of nitrogen. The estimated accuracy of the measured results is ±0.6%. The results obtained show that, at subcritical temperatures, the pressure effect on viscosity is negative. This anomalous behaviour is investigated in detail in this work. At atmospheric pressure the viscosity of gas mixtures is almost a linear function of their composition. At high pressure, the residual viscosities - ₀ of both the pure components and the mixtures were used to follow a single relationship versus the residual reduced density _r0.Paper presented at the Tenth Symposium on Thermophysical Properties, June 20–23, 1988, Gaithersburg, Maryland, U.S.A.     

R32/R134a和R407C用于变浓度热泵系统的实验

为了解决R32/R134a应用于变浓度热泵系统存在的排气温度过高问题,提出使用三元混合工质R407C用于该系统中.以R32/R134a和R407C作为工质在变浓度容量调节热泵系统中进行了吸气压力不变时的变浓度实验.实验结果表明,R407C在本系统中变浓度范围低于R32/R134a,但R407C的排气温度和耗功均低于R32/R134a,具有良好的变浓度调节潜力.     

Viscosity of Gaseous R404A, R407C, R410A, and R507

This paper presents new measurements of the viscosity of gaseous R404A (52 wt% R143a, 44 wt% R125, 4 wt% R134a), R407C (23 wt% R32, 25 wt% R125, 52 wt% R143a), R410A (50 wt% R32, 50 wt% R125), and R507 (50 wt% R143a, 50 wt% R125). These mixtures are recommended as substitutes for the refrigerants R22, R502, and R13B1. Measurements were carried out in an oscillating-disk viscometer. The obtained values of the viscosity are relative to the viscosity of nitrogen. The experiments were performed at atmospheric pressure over the temperature range 297 to 403 K. and near the saturation line up to pressures of 0.6 P _crit. The estimated uncertainty of the reported viscosities are ±0.5% for the viscosities at atmospheric pressure and ± 1% along the saturation line, being limited by the accuracy of the available vapor pressure and density data. The experimental viscosities at atmospheric pressure are employed to determine the intermolecular potential parameters, and , which provide the optimum representation of the data with the aid of the extended law of corresponding states developed by Kestin et al. A comparison of the experimental viscosity data with the values calculated by REFPROP, both at atmospheric pressure and along the saturation line, is presented.     

R32替代R22的可行性探讨

从理论热工性能分析、环保、安全以及性能测试试验对比等角度,讨论制冷剂 R32 替代 R22 的优势,认为R32替代R22是可行的.同时,分析R32替代R22时存在的高排气压力和高排气温度以及安全性问题.基于目前的制冷技术以及R32本身的热力特性,只要能够通过采取一系列技术手段和安全措施解决这些问题,R32可以作为R22良好的过渡或替代制冷剂.     

R290与R404A在水平管内沸腾换热的压降研究

将R22的两种新型替代工质R290和R404A在光管和内螺纹管中的沸腾换热压降实验结果与Lockhart ＆ Martinelli压降计算关联式预测结果进行了比较,并依据工质R290和R404A在内螺纹管中的实验压降值对Lockhart ＆ Marlinelli压降计算关联式进行了修正。结果表明Lockhart ＆ Martinelli关联式对R404A在光管和内螺纹管的沸腾换热摩擦压降,均有良好的预测精度,平均偏差分别为-11．52％和-17．86％。Lockhart ＆ Martinelli关联式可以较好的预测R290在光管内的沸腾换热摩擦压降,平均偏差为-21．68％;经修正后的Lockhart ＆ Martinelli关联式可以较好的预测R290在在内螺纹管中的沸腾换热摩擦压降,Lockhart ＆ Martinelli关联式乘上修正系数2．06后的修正值与实验值偏差较小,平均偏差为2．37％。研究结果对R290和R404A蒸发器的工程设计及优化具有一定参考意义。     

Viscosity of R134a, R32, And R125 at Saturation

This paper reports the results of the measurement of the viscosity of R134a close to the saturation line in the vapor phase. The new measurements were carried out in a vibrating-wire viscometer specially constructed for the purpose, and the results have an accuracy of ±2%. In addition, the opportunity is taken to present a reevaluation of earlier measurements along the saturation line of the viscosity of R32 and R125. Improved equations of state for these fluids are now available and can be employed to generate improved values for the viscosity.     

冷藏车层叠式蒸发器应用R404A与R22和R134a的比较

采用分布参数法对层叠式蒸发器建立数学模型，并对蒸发器采用R404A，R22和R134a时的换热和流动性能进行模拟比较。结果表明，在空调工况范围内，新型中低温混合制冷剂R404A具有R134a换热性能好和R22压降小的特点，能够很好地适用于冷藏车系统空调侧层叠式蒸发器。     

新型混合制冷剂R1270/R152a/R13I1的理论研究

针对制冷剂R22的替代问题,提出了一种适用于空调等制冷设备的环保型混合制冷剂R1270/R152a/R13I1。基于Refprop8.0,对R1270/R152a/R13I1的基本热物理性质和制冷系统循环性能进行了分析,研究表明:在标准工况下,R1270/R152a/R13I1混合制冷剂的COP和单位容积制冷量均与R22相当,非常有利于直接灌注式替代;在变工况下,R1270/R152a/R13I1的滑移温度较小,性能优于R407C,单位容积制冷量与R407C和R22相当,是一种优良的R22替代物。     

在家用／商用空调中用R32替代R22的探索

在R22的替代工作进入实质性阶段,但国内外成熟替代品又尚不明朗之际,本文在分析国内外R22替代物的现状、存在的问题以及国际上对环保工质要求的新趋向的前提下,探索提出在家用／商用空凋中使用R32替代R22的设想,并从其热物理性质、环保特性、安全性、热工性能、市场可获得性等几个方面,与现有的R22替代物R410A,R290和R1234yf等进行比较,认为R32是一种兼顾减排、安全、节能和市场诸方面要求的、很有前景的R22替代制冷剂。     

Measurements of the thermal conductivity of liquid R32, R124, R125, and R141b

This paper reports measurements of the thermal conductivity of refrigerants R32, R124, R125, and R141b in the liquid phase. The measurements, covering a temperature range from 253 to 334 K and pressure up to 20 MPa, have been performed in a transient hotwire instrument employing two anodized tantalum wires. The uncertainty of the present thermal-conductivity data is estimated to be ±0.5%. The experimental data have been represented by polynomial functions of temperature and pressure for the purposes of interpolation. A comparison with other recent measurements is also included.