Investigating the effect of production process of ball mill refiner on some physical quality parameters of compound chocolate: response surface methodology approach

Chocolate compound was produced using ball mill refiner, and the effect of agitator shaft speed and refining time on the physical quality parameters (particle size, colour and steady‐state rheology) of compound chocolate was determined using response surface methodology. The shaft speed and refining time range were selected between 40–60 r.p.m. and 10–30 min, respectively. Determination coefficient of the models established for particle size, Newtonian viscosity and colour parameters (brightness, chroma and hue angle) were found to be very close to unity. Increasing shaft speed and time induced a reduction in particle size and an increase in viscosity of the samples. Temperature sweep test was also performed, and the obtained data were successfully fitted to Arrhenius equation to calculate the corresponding parameters representing temperature dependency of the compounds. The results highlighted that the establishment of such models can provide essential information in terms of optimisation of production processes regarding usage purpose of the compound chocolate.     

Effect of roasting parameters on soy‐butter product quality

Effect of roasting temperature and time on the hardness, moisture content and colour of whole‐kernel of soybean was studied using response surface method (RSM). Colour of reference soy‐butter (RSB) was used to indicate the time and temperature suitable for roasting soybean kernels to prepare soy‐butter (SB). Temperature (160 °C) and time (90 min) for roasting were identified, soybean kernels were roasted, subsequently made into SB and compared with RSB on the basis of nutrient content, particle size, colour and rheology. SB contained 45 g% protein and 34 g% fat on dry matter basis. There was a significant difference (P < 0.05) between RSB and SB on the basis of L* values, D_3,2 and D_4,3. Rheology showed that SB samples behaved like a viscoelastic material. The mean apparent viscosity was significantly different (P < 0.0001) between SB (7.18 Pa.s) and RSB (4.72 Pa.s) which may be due to the significant difference in the particle size distribution (PSD). The Herschel‐Bulkley model could successfully explain the rheological behaviour of SB.     

Effect of crystal promoters on viscosity and melting characteristics of compound chocolate

The effects of the addition of crystal promoting additives to compound chocolate viscosity and melting characteristics were evaluated in this study. Three types of crystal promoters, namely CP1, CP2, and CP3, were added at varying concentrations (0.25, 0.5, 0.75, and 1.0%). The compound chocolate with no added crystal promoters served as a control. Increase in viscosity with increasing additive concentration was observed among all samples regardless of additive type. Addition of CP1 resulted in significant changes in dimensions and shape deformation after incubation at 40°C for 24 h except at 0.25% concentration. Samples with CP2 and CP3 were fairly stable at 40°C with only CP3 0.25% melting. Crystal promoter type influenced the melting properties of the samples, as determined through differential scanning calorimetry, particularly in terms of T_index and ΔH_M. The ΔH_M of all the samples decreased, while the addition of CP1 decreased T_index values, and adding CP2 and CP3 increased the T_index. Additive type had limited effects on T_peak, T_onset, and T_endset. Results suggest that crystal promoters added to compound chocolate affect their viscosity and thermal behavior.     

Effect of reduction of lactose in yogurts by addition of β‐galactosidase enzyme on volatile compound profile and quality parameters

A comparative study between reduced‐lactose yogurts made with added β‐galactosidase (E yogurts) and controls (C yogurts) was performed. The evolution of lactose content, pH, acidity and volatile compounds was measured during fermentation and storage at 5 °C. The hydrolysis percentages of lactose ranged from 75% to 78% in E yogurts and from 10% to 13% in C yogurts at the end of manufacture and stayed without changes throughout storage. There were no significant differences in pH and titratable acidity values among yogurts. A total of 22 volatile compounds were identified. The change in lactose level by the action of β‐galactosidase influenced the production of some volatile compounds derived from this sugar. At the end of fermentation, minor differences in volatile composition were recorded among yogurt samples. During storage, acetaldehyde and diketone levels were always higher in hydrolysed yogurts than their respective controls.     

Effects of ball‐milling on the glass transition of wheat flour constituents

BACKGROUND: Starch and gluten, the major components of wheat flour, greatly influence the structural characteristics of food products made with wheat flour. The effects of ball‐milling on the change in the semicrystalline structure of starch granules to the amorphous state have been reported. However, the effects of ball‐milling of native wheat flour on physicochemical changes in wheat flour constituents have not been elucidated. Therefore in this study the effects of ball‐milling on the glass transition of wheat flour constituents were investigated. RESULTS: Crude gluten, non‐gluten proteins and separated starch were obtained from wheat flour ball‐milled for 0–10 h, and the glass transition temperature (T_g) of these constituents was evaluated. The T_g of all wheat flour constituents decreased with increasing ball‐milling time. Sodium dodecyl sulfate polyacrylamide gel electrophoresis revealed that changes in band position and intensity did not occur for gluten but did occur for non‐gluten proteins. X‐ray diffraction revealed decreased crystallinity and greater plasticisation by water in separated starch as the ball‐milling time was prolonged. CONCLUSION: The results showed that the ball‐milling process decreased the T_g of wheat flour constituents as a function of milling time. The decrease in T_g was probably due to changes in conformation of protein subunits in gluten and depolymerisation of the non‐gluten protein fraction. The information obtained here about the physical alteration of wheat flour constituents may enhance the ability to successfully use ball‐milled wheat flour in food applications. Copyright © 2008 Society of Chemical Industry     

Effect of soaking process on nutritional quality and protein solubility of some legume seeds

Legume seeds (soy bean, lupin and bean seeds) were soaked in 0.5% sodium bicarbonate in attempt to evaluate their nutritional quality and protein solubility index. Soaking process led to an increase in the hydration coefficient, seed weight, total protein, ash, fat, fiber, while non protein nitrogen, total carbohydrates, starch, stachyose, raffinose, reducing sugars, and minerals (except Na) were decreased. All antinutritional factors such as phytic acid, tannin, trypsin inhibitor and hemagglutinin activity were decreased during soaking in 0.5% sodium bicarbonate; it was the same for the protein solubility in different solutions, while the in-vitro protein digestibility and available lysine were increased.     

A comparison of antioxidant properties between artisan‐made and factory‐produced chocolate

The antioxidant capacities and the total phenolic content in cocoa liquor directly manufactured chocolate from an artisan manufacturer were measured using different in vitro methods (BR, TEAC, and Folin–Ciocalteu Reagent). These parameters were then compared with those of a chocolate made by a leading manufacturing company producing chocolate and cocoa‐containing products. A statistical analysis of the collected data showed that the antioxidant properties of the artisan‐made chocolate are significantly better than those of the factory‐produced one. These results were ascribed to the fact that all the bioactive components in the cocoa beans are better preserved in the artisan‐made chocolate.     

Effect of pH and distillate volume on monitoring aroma quality of bittersweet chocolate

A central composite rotatable design (CCRD) was applied to study the response pattern for monitoring aroma quality of sweet chocolate bars. The two parameters varied were pH adjustment before distillation of chocolate and the distillate volume obtained after steam distillation. Aroma was qualitatively evaluated in three commercial chocolates and in their distilled extracts. Based on the responses for UV absorption, number of peaks on chromatograms and sensorial aroma values, response surface methodology (RSM) revealed that higher scores were obtained for each of these responses at a lower range (1.5–3) of pH and distilled volume (5–10 ml). It was also possible to distinguish between products of different manufacturers when a pH of 2.5 was adjusted for distillation and a distillate of 10 ml used. These conditions are considered optimum for monitoring the over-all aroma quality in cocoa products.     

Fractionation and characterization of ball‐milled and enzyme lignins from abaca fibre

An Erratum has been published for this article in Journal of the Science of Food and Agriculture 79(15) 1999, 2122. Ball‐milled and enzyme lignins were produced from abaca fibre via ball milling for 6 days followed by cellulase treatment for 3 days. The crude lignin preparations were fractionated into milled lignin (ML), enzyme lignin (EL), hemicellulose‐rich milled lignin (HRML), and lignin‐rich enzyme lignin (LREL) fractions using a two‐step precipitation method instead of a traditional ether precipitation procedure. The yield and chemical composition of the resulting lignin samples are reported. The ML and EL fractions contained low amounts of associated neutral sugars (2.0–3.3%) and uronic acids (1.4–1.5%), and showed relatively low average molecular weights (2500–2660), while the LREL and HRML fractions contained large amounts of bound polysaccharides (35.6–38.3%), and showed high molecular weights (8800–25000). The four lignin fractions are composed of a large proportion of syringyl units with fewer guaiacyl and p‐hydroxyphenyl units. The ML is mainly composed of β–O–4 ether bonds between the lignin structural units. The less common β–β, β–5 and 5–5′ carbon–carbon linkages are also present in the lignin molecules. It was found that uronic acids and 41–63% of p‐coumaric acids are esterified to lignin in the three lignin‐rich fractions of ML, EL and LREL. This level increased to over 90% in the hemicellulose‐rich fraction of HRML. For ferulic acids, 92–97% were found to be etherified to lignin in the three lignin‐rich fractions of ML, EL and LREL, while in the hemicellulose‐rich fraction of HRML this reduced to only 13%, suggesting that a majority of the ferulic acids are esterified to hemicelluloses or lignin in this fraction. © 1999 Society of Chemical Industry     

Effect of spray‐drying parameters on the solubility and the bulk density of camel milk powder: A response surface methodology approach

Response surface methodology coupled with a Box–Behnken experimental design was used to investigate the effect of the air inlet drying temperature, the feed rate, and the fat content on the solubility and the bulk density of spray‐dried camel and cow milk powders. The response surface methodology analysis highlighted that milk fat content and feed rate were the most effective parameters affecting the solubility and the bulk density of cow and camel milk powders. Importantly, there was no significant interaction between the studied drying parameters and camel milk powder solubility or bulk density. Overall, camel milk powder exhibited a comparable solubility to that of cow milk powder with a higher bulk density.     

真空和面工艺对面条质量的影响及参数优化

采用三元二次回归正交旋转组合设计,探讨真空度、加水量、和面时间等真空和面工艺参数对生鲜面条、冷藏面条感官和烹调特性的影响,依据生鲜面和冷藏面的评价结果确定最佳工艺条件。结果表明,真空和面能显著提升生鲜面、冷藏面的感官质量,降低烹调损失。和面最优真空度为0.06 MPa,过高的真空度会导致面条质量下降。加水量对面条的硬度、光滑性及感官总评分有显著影响;适当提高加水量可以显著改善面条质量;而过高的加水量会导致面条过软、咀嚼性降低。真空条件下,5~9 min和面时间对面条质量无显著影响。生鲜面的色泽和弹性主要受真空度影响;表观、硬度和光滑性主要受加水量影响。面条冷藏后,真空度对其表观、硬度和黏性的影响及加水量对弹性的影响均增大。真空和面对于延长生鲜面的保质期、保证产品质量稳定有重要作用;提高真空度可以减缓面条在冷藏过程中的质量劣变。真空和面最佳工艺条件为:真空度0.06 MPa,加水量35.3%,和面时间7.2 min。