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固相微萃取(SPME)的演变和现状 总被引:13,自引:0,他引:13
固相微萃取(SPME)是一种广泛使用的样品前处理技术,它是集萃取、浓缩、解吸、进样于一体的样品前处理新技术,它以固相萃取(SPE)为基础,保留了SPE的全部优点,排除了需要柱填充物和使用有机溶剂进行解吸的缺点.SPME是以涂渍在石英玻璃纤维上的固定相(高分子涂层或吸附剂)作为吸收(吸附)介质,对目标分析物进行萃取和浓缩,并在气相色谱仪进样口中进行分析,这一技术适合于很多技术领域的样品处理和分析.对SPME的演变和进展做了简要讨论. 相似文献
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固相微萃取(SPME)是基于固相萃取(SPE)技术发展起来的一种集萃取、浓缩、解吸、进样等功能于一体的样品前处理方法。碳纳米管CNTs是一维碳基纳米材料,具有独特的管状结构、良好的化学稳定性、热稳定性和高比表面积。本文将碳纳米材料作为固相微萃取的纤维涂层材料,进而介绍了两种纤维涂层的制备方法—物理涂覆法和化学涂覆法,并对其在水样分析中的应用做一综述。 相似文献
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分别采用溶剂萃取法(SE)、固相微萃取法(SPME)和微波辅助-固相微萃取(MAE-SPME)联用技术等前处理方法提取草莓果实中香气物质,通过气相色谱-质谱(GC-MS)联用仪对挥发性成分进行了分离鉴定。结果表明,不同的前处理方法所得结果相差甚远,MAE-SPME联用技术前处理方法提取后,可鉴定到85种化合物,其中酯类53种,其他依次是醛类、酮类、醇类、酸类、醚类、烯烃、芳香烃和杂环化合物等;而用SE法、SPME法提取,分别仅鉴定到26种和16种香气物质。说明微波辅助-固相微萃取两种技术联用,是一种能较好地提取果蔬中香气物质的样品前处理技术。 相似文献
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Chia Chun Loi Huey Chern Boo Abdulkarim Sabo Mohamed Abdul Azis Ariffin 《Journal of the American Oil Chemists' Society》2010,87(6):607-613
Processing of vegetative material containing pentoses has been shown to result in the formation of furfural. Furfural exhibits
a spectrophotometric absorption peak at 518 nm when complexed with aniline acetate. Headspace solid-phase microextraction
(HS-SPME) method has been successfully used to confirm the presence of furfural in crude palm oil (CPO). Solid phase microextraction
(SPME) fiber composed of divinylbenzene/Carboxen/polydimethylsiloxane (DVB/PDMS/CAR) was used to absorb the volatiles in the
headspace of the oil. The isolated compounds from the fiber was desorbed and separated on a capillary polar column of a gas
chromatograph. Response surface methodology (RSM) was used to optimize the SPME fiber condition for maximum absorption of
furfural from CPO. The optimized temperature and time for furfural extraction onto the SPME fiber are 70 °C for 40 min. Oils
obtained from the mill were found to contain between 2 and 13% furfural. 相似文献
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Solid‐phase microextraction (SPME) in combination with GG‐MS was applied to quality control polyamide 6.6 collected for recycling and to study the long‐term properties and degradation of nitrile rubber, polyethylene, and polyamide 6.6. The migration of plasticizer and other additives reduces the service‐life and changes the properties of the material. It is also a possible health hazard, for example, legislation against the use of brominated flame retardants in plastic materials, is under discussion, and fast and reliable methods are required to detect such compounds in plastic materials collected for recycling. SPME rapidly and effectively extracted several brominated compounds from in‐plant collected polyamide 6.6. Migration of tris(2‐butoxyethyl)phosphate plasticizer and its degradation products from nitrile rubber during long‐term thermal ageing at 60 and 80°C was shown by SPME‐GC‐MS, while the plasticizer was not volatile enough to be detected by traditional HS‐GC‐MS. In accordance the number of degradation products extracted from thermo‐oxidized PE by HS‐SPME was three times larger than the number detected after HS‐GC‐MS analysis. SPME‐GC‐MS could also detect early signs of degradation in thermo‐oxidized virgin and in‐plant recycled polyamide 6.6 before any signs of degradation were observed by, for example, tensile testing or FTIR. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 867–873, 2003 相似文献
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Sodeif Azadmard-Damirchi Mahboob Nemati Javad Hesari Masoud Ansarin Bahram Fathi-Achachlouei 《Journal of the American Oil Chemists' Society》2010,87(10):1155-1159
Phytosterols are separated into three classes: 4-desmethylsterols, 4-monomethylsterols and 4,4′-dimethylsterols. 4,4′-Dimethylsterols
are used to detect vegetable oil adulteration and some compounds from this class can have anti-inflammatory and anticancer
properties. There are methods such as thin layer chromatography (TLC) and solid phase extraction (SPE) used to separate phytosterol
classes from each other. However, in some cases, separation of all three classes is not required. In addition, TLC has some
drawbacks such as low recovery and it is time consuming. An SPE method has previously been used, but it was necessary to use
high volume of solvents with this method to avoid coelution of phytosterol classes. In this study, an SPE (silica, 1 g) method
was developed to separate and enrich only 4,4′-dimethylsterols from unsaponifiables of vegetable oil samples using 25 mL n-hexane and diethyl ether (95:5, v:v). This method was applied to hazelnut and olive oils and results were compared with those
of TLC and the previously developed SPE method. Recovery of 4,4′-dimethylsterols was two times higher with the new SPE method
compared with the TLC method. The newly developed SPE method generally gave a similar recovery compared with the previously
developed SPE method. Moreover, the SPE method developed in this study has the advantage of using a 3.5 times lower volume
of solvent than previously developed SPE methods. Because the newly developed SPE method has a single step requiring a low
volume of solvents, it is rapid and simple, and can easily be used to detect olive oil adulteration with hazelnut oil and
to analyze and quantify effective nutritional compounds in the 4,4′-dimethylsterols class. 相似文献
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Wenlin Huang Christopher J. Smith Charisse J. Walcott James Grainger Donald G. Patterson Jr. 《Polycyclic Aromatic Compounds》2013,33(3-4):339-351
Sample preparation techniques using solid-phase extraction (SPE) and solid-phase microextraction (SPME) are compared for the analysis of monohydroxy polycyclic aromatic hydrocarbons (OHPAH) in human urine. Urine samples spiked with five carbon-13 labeled internal standards are first enzymatically hydrolyzed. Sixteen OHPAH from eight parent compounds (naphthalene, fluorene, phenanthrene, fluoranthene, pyrene, chrysene, benzo[ c ]phenanthrene, and benz[ a ]anthracene) are then extracted along with the internal standards by these two different techniques. The analytes are derivatized by a silylating reagent before final analysis. Final separation and detection are performed by temperature-programmed capillary gas chromatography (GC) and high-resolution mass spectrometry (HRMS). The two extraction techniques are compared for sample preparation time, cost, throughput, reinjection possibility, frequency of outliers, matrix interference, signal linearity, and method detection limit. SPE demonstrates major advantages over SPME for most of these aspects. 相似文献
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研究了黑龙江产芫荽籽的香气成分.采用两种固相微萃取柱萃取芫荽籽香气成分,并用GC-MS分析,还与水蒸气蒸馏法获取的芫荽籽精油的成分进行了比较.用DVB/CAR on PDMS萃取柱时,检出24个成分,解析出占总成分的85.391%的17种物质,主要成分芳樟醇相对含量44.666%;用CAR on PDMS萃取柱时,检测出19种成分,解析出占总成分98.443%的18种成分,主要成分芳樟醇相对含量为32.578%;水蒸气蒸馏法获取的芫荽籽精油得油率为0.50%,检测出31个成分,解析出占精油总成分的99.727%的29种成分,芳樟醇相对含量为73.614%. 相似文献
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《塑料、橡胶和复合材料》2013,42(10):497-501
AbstractSolid phase extraction (SPE) was used to separate pyrolysates of rubber blends. Then each rubber polymer in rubber blends was identified, based on interpreting infrared spectrum of separated pyrolysates. By using this method, nature–ethylene–propylene, ethylene–propylene–silicone, butyl–styrene–butadiene and ethylene–propylene–butadiene–acrylonitrile rubber blends were analysed. The analytical results show that each characteristic pyrolysate of polymer in rubber blend pyrolysate can be separated by SPE. The method for identification of rubber polymers in rubber blends by infrared coupled with SPE is flexible, rapid and low cost, compared with the method by pyrolysis gas chromatography coupled with infrared spectroscopy or mass spectroscopy. 相似文献