Emergy analysis of cassava-based fuel ethanol in China

Emergy analysis considers both energy quality and energy used in the past, and compensates for the inability of money to value non-market inputs in an objective manner. Its common unit allows all resources to be compared on a fair basis. As feedstock for fuel ethanol, cassava has some advantages over other feedstocks. The production system of cassava-based fuel ethanol (CFE) was evaluated by emergy analysis. The emergy indices for the system of cassava-based fuel ethanol (CFE) are as follows: transformity is 1.10 E + 5 sej/J, EYR is 1.07, ELR is 2.55, RER is 0.28, and ESI is 0.42. Compared with the emergy indices of wheat ethanol and corn ethanol, CFE is the most sustainable. CFE is a good alternative to substitute for oil in China. Non-renewable purchased emergy accounts for 71.15% of the whole input emergy. The dependence on non-renewable energy increases environmental degradation, making the system less sustainable relative to systems more dependent on renewable energies. For sustainable development, it is vital to reduce the consumption of non-renewable energy in the production of CFE.     

A key review on emergy analysis and assessment of biomass resources for a sustainable future

The present study comprehensively reviews emergy analysis and performance evaluation of biomass energy. Biomass resources utilization technologies include (a) bioethanol production, (b) biomass for bio-oil, (c) biodiesel production, (d) straw as fuel in district heating plants, (e) electricity from Municipal Solid Waste (MSW) incineration power plant, (f) electricity from waste landfill gas. Systems diagrams of biomass, which are to conduct a critical inventory of processes, storage, and flows that are important to the system under consideration and are therefore necessary to evaluate, for biomasses are given. Emergy indicators, such as percent renewable (PR), emergy yield ratio (EYR), environmental load ratio (ELR) and environmental sustainability index (ESI) are shown to evaluate the environmental load and local sustainability of the biomass energy. The emergy indicators show that bio-fuels from crop are not sustainable and waste management for fuels provides an emergy recovery even lower than mining fossil fuel.     

Techno‐economic analysis of an integrated biorefinery system for poly‐generation of power,heat, pellet and bioethanol

Bioethanol is an alternative to fossil fuels in the transportation sector. The use of pellet for heating is also an efficient way to mitigate greenhouse gas emissions. This paper evaluates the techno‐economic performance of a biorefinery system in which an existing combined heat and power (CHP) plant is integrated with the production of bioethanol and pellet using straw as feedstock. A two‐stage acid hydrolysis process is used for bioethanol production, and two different drying technologies are applied to dry hydrolysis solid residues. A sensitivity analysis is performed on critical parameters such as the bioethanol selling price and feedstock price. The bioethanol production cost is also calculated for two cases with either 10 year or 15 year payback times. The results show that the second case is currently a more feasible economic configuration and reduces production costs by 36.4%–77.3% compared to other types of poly‐generation plants that are not integrated into existing CHP plants. Copyright © 2013 John Wiley & Sons, Ltd.     

Assessing the sustainability of Brazilian oleaginous crops – possible raw material to produce biodiesel

The aim of this paper is to make an emergy assessment of oleaginous crops cultivated in Brazil, available to produce biodiesel, in order to determine which crop is the most sustainable. This study evaluates conventional agro-chemical farms that produce rapeseed (canola), oil palm, soybean, sunflower and cotton. Rapeseed (canola) crop uses 40.41% of renewable energy and it is the most sustainable conventional oil crop; on the other hand, it is not widely produced in Brazil, probably due to climate restrictions or low market demand. The oil palm emergy indicators are contradictory: its emergy exchange ratio (EER) value is the lower, showing the possibility of fair exchange, and the low transformity value indicates high efficiency; however, it also has low renewability (28.31%), indicating a high dependency on agro-chemicals (basically fertilizers). Oil palm is a potential energy source due to its high agricultural productivity, but appropriate management is necessary to increase its sustainability and reduce the use of non-renewable resources.     

Second generation bioethanol (SGB) production potential in Turkey

Energy demand is increasing by the years. Population's needs and technological investments bring the new approach about generating energy. It is considered that fossil fuels will not be able to respond to all energy requirements after approximately 150 years. Turkey imports nearly all of its petroleum and so this causes major economic problems. Turkey, as a major cereal producer, has a huge potential to grow energy crops and other cellulosic biomaterials and can obtain plant's residues, which are suitable to produce second generation bioethanol (SGB). With domestic production, bioethanol can reduce the dependence of petroleum for Turkey, and greenhouse gas emissions can be decreased. Taking into account Turkey's situation in fuel–oil consumption, costliness of gasoline and environmentally hazardous specification of fossil fuels, bioethanol gains more importance and increases in value. Especially, SGB production is rising. Foodstuffs are valuable, and producing ethanol from directly those materials can cause a crisis in Turkey because lignocellulosic bioethanol is becoming prominent. In this regard, bioethanol production in Turkey becomes a major alternative to petroleum and may be a key to new and clean energy source. Copyright © 2013 John Wiley & Sons, Ltd.     

Efficiency analysis of a combined PEFC and bioethanol‐solar‐reforming system for individual houses

In this research, the development of a bioethanol reforming system for fuel cells (FBSR: fuel cell with bioethanol steam reforming) using sunlight as a heat source was investigated. The system was investigated using the experimental result of catalyst performance, and numerical analysis. If ethanol purity is high, the production method of the bioethanol used for the proposal system will not be limited. The overall efficiency of the production of electricity and heat power of this system was determined by examining its thermal output characteristic. The FBSR was introduced into standard individual houses in Sapporo, Japan, for analysis. The amount of hydrogen production, the production‐of‐electricity characteristic, and the thermal output characteristic were examined using meteorological data on representative days in March and August. Compared with the representative day in March (28.0 MJ day⁻¹), the solar radiation of the representative day in August (37.0 MJ day⁻¹) is large. However, the amount of solar radiation fluctuation of the representative day in August in this analysis is large compared with the representative day in March. It depends for the overall efficiency of the system on the amount of solar radiation fluctuation rather than the amount of solar radiation. As a result, the overall efficiency of the system, defined as the rate of power and heat output compared with the amount of solar heat collected, was calculated to be 47.4 and 41.9% on the representative days in March and August, respectively. Copyright © 2009 John Wiley & Sons, Ltd.     

Optimizing ethanol and bioelectricity production in sugarcane biorefineries in Brazil

In sugarcane biorefineries, the lignocellulosic portion of the sugarcane biomass (i.e. bagasse and cane trash) can be used as fuel for electricity production and/or feedstock for second generation (2G) ethanol. This study presents a techno-economic analysis of upgraded sugarcane biorefineries in Brazil, aiming at utilizing surplus bagasse and cane trash for electricity and/or ethanol production. The study investigates the trade-off on sugarcane biomass use for energy production: bioelectricity versus 2G ethanol production. The BeWhere mixed integer and spatially explicit model is used for evaluating the choice of technological options. Different scenarios are developed to find the optimal utilization of sugarcane biomass. The study finds that energy prices, type of electricity substituted, biofuel support and carbon tax, investment costs, and conversion efficiencies are the major factors influencing the technological choice. At the existing market and technological conditions applied in the upgraded biorefineries, 300 PJ y⁻¹ 2G ethanol could be optimally produced and exported to the EU, which corresponds to 2.5% of total transport fuel demand in the EU. This study provides a methodological framework on how to optimize the alternative use of agricultural residues and industrial co-products for energy production in agro-industries considering biomass supply chains, the pattern of domestic energy demand, and biofuel trade.     

Sugar beet for bioethanol production: An approach based on environmental agricultural outputs

The EU imports both bioethanol and the raw material needed to produce it. Thirty percent of bioethanol is produced from sugar beets in the EU. However, sugar beet cultivated area and yields have fallen due to the 2006 sugar regime reform. Given the potential uncertainty about the future for sugar beet farmers, biofuels may represent an alternative market. This paper analyses potential contribution to the efficiency, in terms of environmental output, of the sugar beet crop both when production is oriented toward bioethanol and regarding the use of input.An empirical application is performed in Spain by Data Envelopment Analysis (DEA). The results show that 4% of farms have full technical efficiency, while the rest have an average efficiency of 55.9%. The figures show that inputs can be reduced over 40%, and also show the low average level of input-use efficiency. In addition, it cannot be said that there is a relationship between efficiency and farm scale. The consideration of aspects such as the environmental advantages of using sugar beet production for bioethanol can open new lines of action to support this crop in the EU. In addition, boosting sugar beet production may reduce potential dependency on importation.     

Comparison of entrapment and biofilm mode of immobilisation for bioethanol production from oilseed rape straw using Saccharomyces cerevisiae cells

Cell immobilisation provides the opportunity to reduce the cost of producing bioethanol from lignocellulosic biomass such as oilseed rape (OSR) straw, in addition to enhancing operational stability. Bioethanol fermentation of OSR straw hydrolysate by free and immobilised Saccharomyces cerevisiae was studied. Cells were either entrapped in alginate beads or Lentikat^® discs or immobilised as a biofilm on spent grains, Leca, or reticulated foam. The overall aims of the research were to compare bioethanol yields produced from free and immobilised systems, and to identify the most suitable immobilisation technique in terms of bioethanol yield and longevity of the immobilised cell system. Cell entrapment in alginate beads and Lentikat^® discs resulted in significantly higher bioethanol yields compared to when cells were free in suspension or immobilised as a biofilm on a support material. The maximum amount of bioethanol produced by cells immobilised in alginate beads and Lentikat^® discs were 169.26 ± 0.24 and 165.13 ± 0.67 g bioethanol kg⁻¹ OSR straw after 3 h and 7 h of fermentation, respectively. Due to the high mechanical stability and bioethanol yield, immobilisation of S. cerevisiae in Lentikat^® discs was considered the most appropriate immobilisation technique for bioethanol production.     

Spatially explicit modelling of biofuel crops in Europe

This paper describes a methodology to explore the (future) spatial distribution of biofuel crops in Europe. Two main types of biofuel crops are distinguished: biofuel crops used for the production of biodiesel or bioethanol, and second-generation biofuel crops. A multi-scale, multi-model approach is used in which biofuel crops are allocated over the period 2000-2030. The area of biofuel crops at the national level is determined by a macro-economic model. A spatially explicit land use model is used to allocate the biofuel crops within the countries. Four scenarios have been prepared based on storylines influencing the extent and spatial distribution of biofuel crop cultivation. The allocation algorithm consists of two steps. In the first step, processing plants are allocated based on location factors that are dependent on the type of biofuel crop processed and scenario conditions. In the second step, biofuel crops are allocated accounting for the transportation costs to the processing plants. Both types of biofuel crops are allocated separately based on different location factors. Despite differences between the scenarios, mostly the same areas are showing growth in biofuel crop cultivation in all scenarios. These areas stand out because they have a combination of well-developed infrastructural and industrial facilities and large areas of suitable arable land. The spatially explicit results allow an assessment of the potential consequences of large-scale biofuel crop cultivation for ecology and environment.     

Hydrogen as a transportation fuel produced from thermal gasification of municipal solid waste: an examination of two integrated technologies

Innovative technologies are required to offset increasing consumption and declining stocks of non-renewable resources. This study examines a possible enhancement of waste management and transportation by integrating two emerging technologies: municipal solid waste (MSW) gasification and fuel cell vehicles (FCVs), by fueling FCVs with hydrogen produced from gasified MSW. Material and energy flows were modeled in four MSW management scenarios (incineration, landfill, gasification, gasification with recycling) and four transportation scenarios (hybrid gasoline-electric, methanol FCVs, hydrogen FCVs using hydrogen from natural gas or municipal solid waste). Technological performance deemed feasible within 2010–2020 was assumed. Greenhouse gas emissions and non-renewable energy use were used to assess overall system performance. Gasification with hydrogen production performs as efficiently as incineration, but is advantageous compared to landfilling. Taking into account additional environmental criteria, the model suggests that hydrogen from MSW gasification for FCVs may provide benefits over conventional MSW treatment and transportation systems.     

How to improve the economy of bioethanol production in Serbia

Bioethanol accounts for the majority of biofuel use worldwide, either as a fuel or a gasoline enhancer. In Serbia, the industrial production of bioethanol still relies on conventional feedstocks containing starch and sugar such as corn, wheat and molasses. In order to improve the economy of bioethanol production and to avoid the competition of the feedstock utilization for food and energy, several production approaches based on crop selection, process integration and waste utilization were considered in this paper. Particular attention was put on utilization of non conventional crops such as triticale and damaged crops not appropriate for food consumption. Potential of lignocellulosic biomass for the production of second generation ethanol in Serbia was also considered as well as the utilization of stillage as a main by-product. The investigated approaches can significantly improve the economy of bioethanol production and contribute to solve serious environmental problems.     

Integrated energy,environmental and financial analysis of ethanol production from cellulosic switchgrass

Ethanol production from cellulosic sources such as switchgrass (Panicum virgatum L.) requires the use of natural resources, fossil fuels, electricity, and human-derived goods and services. We used emergy accounting to integrate the ultimate amount of environmental, fossil fuel, and human-derived energy required to produce ethanol from switchgrass. Emergy is the total amount of energy of one form required directly and indirectly to make another form of energy. Forty-four percent of required emergy came from the environment either directly or embodied in purchased goods, 30% came from fossil fuels either directly or embodied in purchased goods, and 25% came from human-derived services indirectly. Ethanol production per petroleum use (emergy/emergy) was 4.0-to-1 under our Baseline Scenario, but dropped to 0.5-to-1 under a scenario that assumed higher input prices, lower conversion efficiencies and less waste recycling. At least 75% of total emergy was from non-renewable sources. Energy ‘hidden’ in indirect paths such as goods and services was 65% of the total. Cellulosic-ethanol is not a primary fuel source that substitutes for petroleum because its production relies heavily on non-renewable energy and purchased inputs. It is a means for converting natural resources to liquid fuel.     

Sustainable ethanol production from lignocellulosic biomass - Application of exergy analysis

The sustainability of the second-generation biofuels requests to confirm that the energy produced from lignocellulosic biomass is significantly greater than the energy consumed in the process. As lignocellulosic biomass does not affect the food supply, sugarcane bagasse was analyzed as a raw material for second-generation biofuels production. Exergy analysis serves as a unified and effective tool to evaluate the global process efficiency. Exergy analysis evaluates the performance of sugarcane bagasse and its sustainability in the bioethanol production process. In this work, four ethanol production topologies using the typical daily amount of residual biomass produced by the sugar industry were compared. The exergy analysis concept is effective in screening design alternatives with the lowest environmental impact for second-generation bioethanol fuel production from renewable resources. This study was executed by the use of the Aspen Plus^® program and other software developed by the authors.     

Review of China’s bioethanol development and a case study of fuel supply, demand and distribution of bioethanol expansion by national application of E10

The increasing dependence on imported oil and tremendous greenhouse gases (GHG) emission is making the diversification of primary fuel such as petroleum a critical vital energy and environmental issue in China. China is promoting bioethanol by mandatory use in nine provinces and the expansion is on agenda. This paper first reviews China’s bioethanol development. Next, suitable feedstock crops for expanded ethanol production are discussed. Particularly, bioethanol expansion by national application of E10 is investigated from perspectives of potential in bioethanol supply, projected ethanol demand, and the possible cost-effective bioethanol distribution system. It is calculated that by making use of un-used land for feedstock planting and introduction of improved feedstock varieties, potential bioethanol production capacity in China will be up to 25.33 million tons per year. Ethanol demand for national application of E10 is projected to be around 7 million tons per year. A linear optimization model is used to consider the economic costs of distributing bioethanol in China. The optimization result suggests that development of bioethanol industry may focus on Henan, Jilin, Anhui, Jiangxi and Sichuan basin. It also estimates 53.79 RMB per ton of bioethanol for downstream rail or truck transportation remain a relatively small fraction of total fuel cost. Thanks to the well developed railway network in China, more bioethanol can be distributed at a relatively modest premium distribution costs and with low environmental influences.     

Sustainability accounting for the construction and operation of a plant‐scale solar‐biogas heating system based on emergy analysis

Domestic heating systems have long been playing a significant role in China's energy structure. The sustainability of a hybrid solar‐biogas heating system (SBHS) under various feedstock fermentation scenarios was evaluated using emergy analysis. Representative emergy indices such as transformities, emergy yield ratio (EYR), environmental loading ratio (ELR), emergy sustainability index (ESI), ratio of waste treatment (%W), feedback yield ratio (FYR), and emission mitigation intensity (EMI; g/10¹⁰ sej) were selected to evaluate the sustainability performance of different feedstock scenarios including cow dung (CD), swine manure (SM), and poultry manure (PM). The results showed that PM fermentation scenario had greater market competitiveness, lower environmental pressure, better sustainability, and self‐organizing ability than the other two options. However, both the emergy efficiency and the CO₂ emissions mitigation intensity of PM scenario were worse than that of the SM and CD. Moreover, compared with other biogas systems and traditional agricultural systems, the hybrid SBHS was proved to be a promising mode for the treatment of rural manure waste with favorable economic benefits and environmental sustainability.     

Biofuel production potentials in Europe: Sustainable use of cultivated land and pastures,Part II: Land use scenarios

Europe's agricultural land (including Ukraine) comprise of 164 million hectares of cultivated land and 76 million hectares of permanent pasture. A “food first” paradigm was applied in the estimations of land potentially available for the production of biofuel feedstocks, without putting at risk food supply or nature conservation.Three land conversion scenarios were formulated: (i) A base scenario, that reflects developments under current policy settings and respects current trends in nature conservation and organic farming practices, by assuming moderate overall yield increases; (ii) an environment oriented scenario with higher emphasis on sustainable farming practices and maintenance of biodiversity; and (iii) an energy oriented scenario considering more substantial land use conversions including the use of pasture land.By 2030 some 44–53 million hectares of cultivated land could be used for bioenergy feedstock production. The energy oriented scenario includes an extra 19 million hectares pasture land for feedstocks for second-generation biofuel production chains. Available land is foremost to be found in Eastern Europe, where substantial cultivated areas can be freed up through sustainable gains in yield in the food and feed sector.Agricultural residues of food and feed crops may provide an additional source for biofuel production. When assuming that up to 50% of crop residues can be used without risks for agricultural sustainability, we estimate that up to 246 Mt agricultural residues could be available for biofuel production, comparable to feedstock plantations of some 15–20 million hectares.     

Efficient sugar production from sugarcane bagasse by microwave assisted acid and alkali pretreatment

Sugarcane bagasse represents one of the best potential feedstocks for the production of second generation bioethanol. The most efficient method to produce fermentable sugars is by enzymatic hydrolysis, assisted by thermochemical pretreatments. Previous research was focused on conventional heating pretreatment and the pretreated biomass residue characteristics. In this work, microwave energy is applied to facilitate sodium hydroxide (NaOH) and sulphuric acid (H₂SO₄) pretreatments on sugarcane bagasse and the efficiency of sugar production was evaluated on the soluble sugars released during pretreatment. The results show that microwave assisted pretreatment was more efficient than conventional heating pretreatment and it gave rise to 4 times higher reducing sugar release by using 5.7 times less pretreatment time. It is highlighted that enrichment of xylose and glucose can be tuned by changing pretreatment media (NaOH/H₂SO₄) and holding time. SEM study shows significant delignification effect of NaOH pretreatment, suggesting a possible improved enzymatic hydrolysis process. However, severe acid conditions should be avoided (long holding time or high acid concentration) under microwave heating conditions. It led to biomass carbonization, reducing sugar production and forming ‘humins’. Overall, in comparison with conventional pretreatment, microwave assisted pretreatment removed significant amount of hemicellulose and lignin and led to high amount of sugar production during pretreatment process, suggesting microwave heating pretreatment is an effective and efficient pretreatment method.     

Improving the energy balance of bioethanol production from winter cereals: the effect of crop production intensity

Energy balances were calculated on the basis of biennial field trials conducted at two locations in southwest Germany. Winter cereals (rye cultivar ‘Farino’, triticale cv. ‘Modus’, wheat cv. ‘Batis') were grown under different crop production conditions (and intensities) optimized for ethanol production. To minimize the use of fossil energy, previous legume crops (pea, grass–clover) or stillage were substituted for mineral nitrogen. Stillage is a liquid processing residue from bioethanol processing that contains nitrogen in organic form. Along with the grain, straw, and bioethanol yields per hectare, both the cultivation and conversion processes were considered. The net energy gains (GJ ha⁻¹) and output/input ratios were computed either with or without by-product stillage and straw. As crop production intensity increased, both the energy output and the net energy gain per ha rose. However, the output/input ratios fell. Peak net energy gains (max. 56.4 GJ ha⁻¹) and highest output/input ratios (max. 3.07) without by-product consideration occurred after a previous pea crop. In stillage manuring, the net energy gains remained minor in comparison to mineral nitrogen fertilization because of poor cereal yield. Hence, the entire replacement of mineral nitrogen with stillage could not be approved unreservedly. Replacing basic nutrients (i.e. P₂O₅, K₂O) appears more feasible instead.     

Harvest index and straw yield of five classes of wheat

Wheat straw is a potential cellulosic feedstock for bioethanol. This study was conducted to evaluate straw yield potential and its relationship with grain yield for wheat (Triticum spp.) grown in the United States. The specific objective was to determine if differences in straw yield and harvest index (HI) exist between and within regions and/or wheat classes. Using on-going variety performance trials in eight states, a total of 255 varietal trial entriess from five classes of wheat were surveyed for above-ground biomass. Averaged over all wheat classes and regions the HI was 0.45. Soft red winter wheat in Kentucky had, on average, the highest HI and lowest straw yield among regions and wheat classes. Soft white winter wheat under irrigation in the Pacific Northwest produced the highest straw yield. Hard red winter wheat in the southern plain states of Texas and Oklahoma had, on average, the lowest HI. Differences in the amount of precipitation and cultivars were the major contributors to the variation detected within wheat classes. The amount of wheat straw available as cellulosic feedstock in a state or wheat class can be estimated using the grain yield estimates provided by the National Agricultural Statistics Service and the class specific HI.