Shrinkage compensation approach proposed for ABS material in FDM process

Dimensional accuracy of parts manufactured by Fused Deposition Modelling (FDM) greatly suffers from the shrinkage problems of the available polymer materials. This paper proposes a constructive idea for resolving the shrinkage issues and explains how shrinkage could be managed by interior geometry of the artifacts fabricated on desktop 3D printers. The main principle for preventing the deterioration on dimensional accuracy of the holes/slots is to utilize the auxiliary lines located from the hole’s perimeter to the outer boundaries of the artifact. Thus, the shrinkage of these auxiliary line segments simply helps to pull the original hole backward, acting against the predicted contraction. In this paper, the proposed approach will be examined using a finite element analysis tool to predict the shrinkage behavior of the fabricated samples along with necessary measurements taken on the Coordinate Measuring Machine. Additionally, an analytical framework for modeling the shrinkage behavior of ABS is to be elaborated. The coherence of the simulations and the measurements are to be analyzed regarding the effect of the geometry and material color on the shrinkage behavior. The discussion involves the improvement on the dimensional accuracy of 3D printed features.     

Dynamic simulation of a single-effect ammonia–water absorption chiller

A lumped-parameter dynamic simulation of a single-effect ammonia–water absorption chiller is performed. Modeling is based on the continuity of species constituting the ammonia–water mixture and the conservation of energy for each component of the absorption chiller. Ordinary differential equations governing the response of each component and the algebraic equations describing the constitutive relation are solved in parallel by numerical integration. The model has been applied to a commercially available 10.5 kW absorption chiller to study the transients of temperature, pressure, concentration, and void fraction of each component during the start-up operation. The time constant of the absorption chiller is also investigated. The parameters considered are the bulk concentration of the ammonia–water solution, the mass of the solution filled, and the volumes of key components of the absorption chiller. In addition, the reduction of the time constant by a stepwise turn-up and turn-down of the flue gas flow rate during the primary stage of start-up period is demonstrated.     

Capturing Nitrosamines in Environment by Zeolite

To meet the requirement of environment protection, the adsorption of volatile nitrosamines, which are carcinogenic compounds in tobacco smoke, by zeolite is investigated in this article, along with the temperature programmed surface reaction of nitrosamines on zeolite to assess the catalytic capability of the porous material on the decomposition of the carcinogens. The actual function of zeolite to reduce the level of nitrosamines in cigarette smoke is also studied. The influences of zeolite pore's structure and the surface acid-basic properties of the adsorbent on the adsorption are explored in terms of geometric matching content and adsorbent-adsorbate interaction. Moreover, the role played by the cation of zeolite in the adsorption of volatile nitrosamines is discussed and the possible attracting range of the sodium cation in basic zeolite to pull the nitrosamine molecule is tentatively calculated. Owing to the specific ability of capturing nitrosamines, zeolite is proven to be the most effective additive encased within a cigarette as the functional additive for lowering the nitrosamines content of smoke to protect the environment and public health. Other porous oxides such as amorphous silica and alumina are also utilized in these experiments, and their actual functions to trap nitrosamines as well as their potential application as the candidates for cigarette additives are discussed and prospected, too.     

Corrosion Resistance of an electrodeposited Zinc Coating Containing CeO2 Nanoparticles

A Zinc coating containing CeO2 nanoparticles has been deposited by electrodeposition in a zinc plating bath.The content of CeO2 in the coating is 0.22 mass%. The results of weight loss experiments and electrochemistry tests show that corrosion resistance of the Zinc coating containing CeO2 nanoparticles is remarkably improved in contrast to the pure zinc coating in 0.5 M MgSO4 solution. The effects of CeO2 microparticles on the corrosion resistance of the zinc coating have been studied, the results show that CeO2 microparticles have no effect on the corrosion resistance of the zinc coating. SEM and XRD experiments suggest that the presence of CeO2 nanoparticles in the coating causes the modification of the surface morphology and preferential orientation of the crystal planes; therefore, the reason for the enhancement of corrosion resistance is mainly related to improvement of the structure of the coating.     

Archaeometallurgical contributions to a better understanding of the past

Archaeometallurgical investigations, and in particular those employing metallographic techniques, have greatly increased our understanding of the past, primarily by improving our knowledge of the histories of technological developments. However, these studies have potential for contributing to our comprehension of many more aspects of life in the past. The series of case studies presented here illustrate the application of metallography not only in elucidating the history of technology but also in areas such as the dating of objects, the determination of the spread of technologies and the nature and implications of the contact of cultures with the ‘outside’ world.     

Corrosion of reinforcement induced by environment containing chloride and carbon dioxide

Reinforced concrete structures during their exploitation may be exposed to the common action of carbonation and chlorides causing corrosion of steel reinforcement. Therefore, the related data seem to be interesting and important when the evaluation of the service life of the structures is the object of interest. This fact was a motivation for the present experimental study on the sequence of action of chloride solutions and carbonation of the embedding concrete. The results obtained show that carbonation of concrete foregoing the action of chloride solutions may intensify the process of corrosion of steel reinforcement in comparison to the converse sequence of the action of mentioned media. At the same time the natrium chloride solution has been shown as a more aggressive medium opposite to the calcium and magnesium chloride solutions.     

Modelling enthalpy and entropy of pure and mixed refrigerants with an innovative corresponding states method

In this work an original improvement of the Corresponding States technique is developed and a new model, based on a three parameters CS format, is proposed to predict the enthalpy and the entropy of the new generation halogenated alkanes fluids together with some alkanes. Limiting the analysis of the selected fluids to a specific thermodynamic property behaviour, an appropriate conformality approach can be deduced, which allows to set up a predictive model of high accuracy level on a wide range of the enthalpy and entropy surfaces. The fundamentals of the model are innovative scaling parameters deduced from the enthalpy of vaporization and from two dedicated equations, belonging to the selected family of fluids. This allows to set up innovative models following a CS format. Through the introduction of advanced mixing rules, the models can be simply extended to calculate the corresponding properties for mixtures. The proposed models allow also the calculation of VLE for systems of rather regular behaviour. The required inputs for a pure target fluid are an ideal gas isobaric heat capacity correlation, a single value of saturated liquid density and of vaporization enthalpy; if the last one is lacking, a single value of vapor pressure can be alternatively supplied. For non azeotropic mixtures the enthalpy and entropy models are predictive, whereas in case of azeotropy VLE calculations are possibly only applying regressed interaction coefficients. Due to the lack of accurate experimental enthalpy data and to the particular nature of the entropy function, the validation of the models is proposed against fundamental dedicated EoS available, both for pure and mixtures, for a significant number of the studied family of fluids. The predictive character of the proposed approach as well as the high performances reached, make these models particularly suitable for the new families of fluids regarding advanced technological applications.     

Ice crystal growth in supercooled solution

Study on the crystal growth of ice in water-ethyleneglycol solution was carried out, experimentally. The ice crystal, which was seeded on top of the capillary tube, propagated inside the tube slowly and began to grow freely at the tip of the tube in subcooled solution. The outer diameter of the tip of the capillary tube was less than 0.1 mm, which was much smaller than that of other researchers. Hence, considerable reduction of the influence of the existence of a capillary was accomplished and the initial growth of a single crystal was observed, precisely. Under the condition of subcooling of less than 8 K, the shape of the crystal was observed to be different from that of the one in pure water. The velocity of dendrite ice growth and the radius of the curvature of the tip were measured. It was found that after the dendrite ice developed to a certain size, the velocity of the dendritic growth and the radius of curvature were kept steady, and its values were dependent on the degree of subcooling and the concentration of the solution.     

Untersuchung von Schmelz‐ und Rekristallisationsprozessen sowie Riss‐, Oxid‐ und Porenbildung beim Schweißen

Investigation of melting and re‐crystallization processes and of crack, oxide and pore formation during welding In the paper some known investigation methods of the primary re‐crystallization and of the structure of the crystallization front are discussed. All these methods have disadvantages, in some cases they cause a limited validity or are expensive. The presented new method is based on the micrographic recording of the melting and solidifying metal surfaces. The method overcomes the above‐mentioned disadvantages. It is able to investigate in the welding seams not only the primary re‐crystallization processes but also the secondary ones including the formation of cracks and pores and the appearance of non‐metallic inclusions like oxides. The facilities of the method are demonstrated on some examples of use.     

对广电数字化运动的几点看法——兼谈对信息时代的数字技术标准化意义的反思

从信息革命的角度对于当前这场广电数字化运动做定位分析。对当前数字电视领域中的一些有争议的问题提出了看法。如,公共平台与收费平台的关系,服务平台的统一,整体平移,外来标准和自主标准,数字标准的统一等。提出了对标准化意义的反思。指出,在信息时代,给社会和技术带来进步的往往是追求标准化的过程,而不是标准建立的事实本身。近几年来,许多人已经开始意识到工业时代标准化的“旧瓶”,已经很难装下信息时代数字技术的“新酒”。标准化的工作要有一种新思维来适应信息社会的变化和特点。