Some aspects of risk reduction strategy by multiple recycling in fast burner reactors of the plutonium and minor actinide inventories

The paper shows the impact of recycling LWR-MOX fuel in a fast burner reactor on the plutonium (Pu) and minor actinide (MA) inventories and on the related radio activities. Reprocessing of the targets for multiple recycling will become increasingly difficult as the burn up increases. Multiple recycling of Pu + MA in fast reactors is a feasible option which has to be studied very carefully: the Pu (except the isotopes Pu-238 and Pu-240), Am and Np levels decrease as a function of the recycle number, while the Cm-244 level accumulates and gradually transforms into Cm-245. Long cooling times (10 + 2 years) are necessary with aqueous processing.The paper discusses the problems associated with multiple reprocessing of highly active fuel types and particularly the impact of Pu-238, Am-241 and Cm-244 on the fuel cycle operations. The calculations were performed with the zero-dimensional ORIGEN-2 code. The validity of the results depends on that of the code and its cross section library. The time span to reduce the initial inventory of Pu + MA by a factor of 10, amounts to 255 years when average burn ups are limited to 150 GWd t⁻¹.     

Neutronic and safety aspects of inert matrix fuel utilization in fast reactors for plutonium and minor actinides transmutation

The solving of ecological problems of future nuclear power is connected with the solving of long-lived radioactive waste utilization problems. It concerns primarily plutonium and minor actinides (MAs), accumulated in the spent fuel of nuclear reactors. One of the ways this can be solved is to use a fast reactor with uranium-free or inert matrix fuel (IMF). The physics of this type of reactor was widely investigated during last year for BN-800 reactors. The solution of the most important problems was: a decrease in non-uniformity of power distribution and an increase of the Doppler effect. The next stage of such core investigations is an evaluation of self-protection to beyond design accidents. Preliminary results show a high safety level of BN-800 reactors with IMF in the event of unprotected loss of coolant flow (ULOF) accident.     

Interpretation of actinide transmutation in thermal and fast reactors

The commonly used transmutation rate of minor actinides in nuclear reactors is decomposed into four components, overall fission rate, Pu production rate, MA production rate, and element production rate. The physical meanings of these factors are described. The transmutation rates of minor actinides in two types of highly-moderated PWRs, a MOX fueled Na cooled fast reactor, and a metal fueled Pb cooled fast reactor are interpreted using the four components. The metal fueled Pb cooled fast reactor can incinerate minor actinides most (79kg/GWth/year), and this amount is about 4 times larger than the thermal reactors. The thermal reactors have large relative overall fission rates for ²⁴¹Am and have a potential for the incineration of ²⁴¹Am.     

Short-term irradiation behavior of minor actinide doped uranium plutonium mixed oxide fuels irradiated in an experimental fast reactor

A fuel irradiation program is being conducted using the experimental fast reactor ‘Joyo’. Two short-term irradiation tests in the program were completed in 2006 using a uranium and plutonium mixed oxide fuel which contains minor actinides (MA-MOX fuel). The objective of the tests is the investigation of early thermal behavior of MA-MOX fuel such as fuel restructuring and redistribution of minor actinides. Three fuel pins which contained MA-MOX: 2% neptunium and 2% americium doped uranium plutonium mixed oxide (Am,Pu,Np,U)O_2−x fuel were supplied for testing. The first test was conducted with high-linear heating rate of approximately 430 W cm⁻¹ for only 10 min. After the first test, one fuel pin was removed for examinations. Then the second test was conducted with the remaining two pins at nearly the same linear power for 24 h. In these tests, two oxygen-to-metal molar ratios were used for fuel pellets as a test parameter. Non-destructive and destructive post-irradiation examinations results are discussed with early on the behavior of the fuel during irradiation.     

Extending FEAST-METAL for analysis of low content minor actinide bearing and zirconium rich metallic fuels for sodium fast reactors

Computational models in FEAST-METAL fuel behaviour code have been upgraded to simulate minor actinide bearing zirconium rich metallic fuels for use in sodium fast reactors. Increasing the zirconium content to 20-40 wt.% causes significant changes in fuel slug microstructure affecting thermal, mechanical, chemical, and fission gas behaviour. Inclusion of zirconium rich phase reduces the fission gas swelling rate significantly in early irradiation. Above the threshold fission gas swelling, formation of micro-cracks, and open pores increase material compliancy enhance diffusivity, leading to rapid fuel gas swelling, interconnected porosity development and release of the fission gases and helium. Production and release of helium was modelled empirically as a function of americium content and fission gas production, consistent with previous Idaho National Laboratory studies. Predicted fuel constituent redistribution is much smaller compared to typical U-Pu-10Zr fuel operated at EBR-II. Material properties such as fuel thermal conductivity, modulus of elasticity, and thermal expansion coefficient have been approximated using the available database. Creep rate and fission gas diffusivity of high zirconium fuel is lowered by an order of magnitude with respect to the reference low zirconium fuel based on limited database and in order to match experimental observations. The new code is benchmarked against the AFC-1F fuel assembly post irradiation examination results. Satisfactory match was obtained for fission gas release and swelling behaviour. Finally, the study considers a comparison of fuel behaviour between high zirconium content minor actinide bearing fuel and typical U-15Pu-6Zr fuel pins with 75% smear density. The new fuel has much higher fissile content, allowing for operating at lower neutron flux level compared to fuel with lower fissile density. This feature allows the designer to reach a much higher burnup before reaching the cladding dose limit. On the other hand, in order to accommodate solid fission product swelling and to control fuel clad mechanical interaction of the stiffer fuel, the fuel smear density is reduced to 70%. In addition, plenum height is increased to accommodate for fission gases.     

Use of nonuranium diluents for plutonium in large fast breeder reactors

The authors study the physical characteristics of fast breeder reactors with cylindrical and ringshaped cores, and also the characteristics of infinite lattices of heterogeneously-arranged large fuel cassettes distributed in the breeding-zone material.It is shown that there are certain reactors with optimum doubling period.Translated from Atomnaya Énergiya, Vol. 21, No. 2, pp. 84–92, August, 1966.     

CANDU reactor as minor actinide/thorium burner with uniform power density in the fuel bundle

A CANDU reactor fueled with a mixed fuel made of thoria (ThO₂) and nuclear waste actinides has been investigated. The mixed fuel composition has been varied in radial direction to achieve a uniform power distribution and fuel burn-up in the fuel bundle.     

Comparative study of minor actinide transmutation in sodium and lead-cooled fast reactor cores

This paper shows that lead-cooled and sodium-cooled fast reactors (LFRs and SFRs) can preferentially consume minor actinides without burning plutonium, both in homogeneous and in heterogeneous mode. The former approach consists of admixing about 5% of minor actinides (MAs) into uranium–plutonium fuels in the core and using a limited number of thermalising pins consisting of UZrH_1.6. These are needed to keep the negative Doppler feedback larger than the positive coolant reactivity coefficient. Our Monte Carlo burn-up calculations showed that a 600 MW_e LFR self-breeder without blankets can burn an average of around 67 kg annually of MAs with a reactivity swing of only about −0.7$ per year. The reactivity swing of a corresponding 600 MW_e SFR is more than three times larger due to the poorer breeding and half the critical mass in comparison to the LFR. However, when axial and radial blankets loaded with 10% MAs are added, the SFR burns 25% more MAs (131 kg/yr) and breeds 30% more Pu (150 kg/yr) than an equally sized LFR. When only the blankets are loaded with MAs, the SFR breeds 30% more Pu (198 kg/yr) and still burns about 60 kg a year of MAs. However, in terms of severe accident behaviour, the LFR, with its superior natural coolant circulation and larger heat capacity, has definite advantages.     

Pyrochemical conversion of weapons plutonium into plutonium mononitride,monocarbide and mixed uranium-plutonium fuel for fast reactors

The main directions and results of research on pyrochemical reprocessing of weapons plutonium in fuel for fast reactors are presented. It is shown that this technology is economical and ecologically validated, compact, fire and explosion safe, especially for reprocessing in carbide-nitride as well as oxide fuel for fast reactors. It satisfies the principle of nonproliferation. For reprocessing weapons plutonium in oxide fuel with deep removal of ²⁴¹Am and Ga, a combined process which combines pyrochemical conversion of plutonium into oxide or nitride powder, and dissolution in acids and extraction of impurities. It is shown that the fuel kernels made from nitride, carbide, and oxide powers both from individual PuN, PuC_0.86, and PuO₂ powders as well as mixed plutonium compounds with uranium are fabricated by means of the conventional regime and provide the required density and content of gallium of <0.001 wt. %.     

Influence of void fraction change on plutonium and minor actinides recycling in BWR with equilibrium burnup

A study on the influence of void fraction change on plutonium and minor actinides recycling in standard boiling water reactor (BWR) with equilibrium burnup model has been conducted. We considered the equilibrium burnup model since it is a simple time independent burnup method that can handle all possible produced nuclides in any nuclear system.

The uranium enrichment for the criticality of the reactor diminishes significantly for the plutonium and minor actinides recycling case compared to that of the once-through cycle of BWR case. This parameter decreases much lower with the increasing of the void fraction. A similar propensity was also shown in the required natural uranium per annum. The annual required natural uranium was calculated by assuming that the uranium concentration in the tail of the enrichment plant is 0.25 w%. The amount of loaded fuel reduces slightly with the increment of the void fraction for plutonium and minor recycling in BWR.     

Feasibility study of minor actinide transmutation in light water reactors with various Am/Cm separation efficiencies

A study was conducted to evaluate the feasibility of minor actinide (MA) transmutation in light water reactors (LWR). The purpose of this work was to provide a guide for future investigations into MA transmutation in LWR. This work considered the effects of various Am/Cm separation efficiencies as well as homogeneous and heterogeneous MA bearing fuel assemblies. The MA content was introduced into the reactor as mixed oxide plus minor actinide (MOX + MA) fuel. Three Am/Cm separation efficiencies were independently considered: 99.9%, 99.0%, and 90.0%. In order to evaluate the feasibility of MA transmutation, the fuel performance of the various assemblies and core designs, as well as their respective safety related parameters, were calculated. The reduction of the burden of high level waste (HLW) motivated the investigation of MA transmutation. It was found that the MA bearing fuel assemblies and their subsequent core designs were able to perform within the safety limits required as well as achieving similar burnups to a UO₂ core. The Am transmutation rates were ∼40% for the homogeneous assemblies and up to 68% for the MA targets in the heterogeneous assemblies after the described burnup, however, there was a significant amount of Cm produced during burnup. This Cm production was due to the more favorable neutron capture reaction over fission for Am in the thermal spectrum. Future work should examine the benefits of Am transmutation at the expense of large Cm production rates.     

Pyrochemical method of salvaging weapons plutonium in oxide for fabricating mixed fuel for fast reactors

Experimental results of investigations of pyrochemical conversion of weapons plutonium into plutonium oxide for fabricating fast-reactor fuel are presented. Weapons plutonium was hydrogenized by hydrogen at 220°C, after which the plutonium hydride obtained was acidified at 550–560°C with the formation of PuO₂. To increase fire and explosion safety of the process, a mixture of oxygen with nitrogen, helium, or argon was used or nitriding with nitrogen and oxidation of plutonium mononitride were introduced. The particle size of the plutonium oxide powders obtained was less than 15 μm. The powders showed poor flowability, but after granulation they were suitable for fabricating kernels with mixed fuel. The gallium was removed by reduction of Ga₂O₃ by hydrogen to Ga₂O, which was sublimated. The mixed-fuel kernels sintered at 1600–1700°C in a hydrogen atmosphere contained <0.001 wt.% gallium, and their density was 94–97% of the theoretical value.     

Studies of core disruptive accidents and licensing aspects of fast breeder reactors

This paper discusses the role of the core disruptive accident (CDA) in the safety evaluations and licensing of Liquid Metal Fast Breeder Reactors (LMFBR). Parametric studies of transient overpower (TOP) accidents based on calculations for SNR-300 using the HOPE computer code are presented. Major uncertainties in TOP analysis are identified and discussed with emphasis on the need for reliable fuel failure criteria. A series of calculations illustrating the possible behavior of the U.S. LMFBR demonstration plant following a loss-of-flow (LOF) accident without scram using the SAS-IIIA computer code are described. It is shown that for a beginning of life (BOL) core and end of equilibrium cycle (EOEC) core, the reactivity effects from sodium voiding and clad motion can lead to further sustained reactivity additions from subsequent fuel motion and FCI driven sodium voiding. In these calculations we have used the fuel enthalpy criterion which predicts clad failure around the core midplane. For the EOEC case these effects can add sufficient reactivity to take the system above prompt-critical (LOF driven TOP) and into hydrodynamic disassembly. For the BOL case the sodium void may not be sufficient to bring the system near sustained prompt-critical. However, clad motion appears to be effective in raising the reactivity to prompt-criticality. These results are based on clad failure dynamics modeling in SAS-IIIA. Further work is needed in the area of fuel-clad behavior under severe transients before definitive conclusions can be drawn regarding the applicability of current clad failure models at high clad temperatures (>1000°C). The potential significance of a new concept in CDA analysis called the “transition phase” is briefly mentioned.     

Some aspects of the use of ZrN as an inert matrix for actinide fuels

The sodium compatibility and the nitric acid dissolution of (Zr_0.80U_0.20)N, prepared by carbothermic reduction of the oxide, were determined. No interaction with liquid sodium (T=823 K) was observed. The material readily dissolved in nitric acid (T=378–383 K). From these results it is concluded that ZrN is an attractive inert matrix in fast reactor fuels for the incineration of plutonium and minor actinides.     

Physical studies of minor actinide transmutation in the accelerator-driven subcritical system

The accelerator-driven subcritical system(ADS)with a hard neutron energy spectrum was used to study transmutation of minor actinides(MAs). The aim of the study was to improve the efficiency of MA transmutation while ensuring that variations in the effective multiplication factor(k_(eff)) remained within safe margins during reactor operation. All calculations were completed using code COUPLE3.0. The subcritical reactor was operated at a thermal power level of 800 MW, and a mixture of mononitrides of MAs and plutonium(Pu) was used as fuel.Zirconium nitride(ZrN) was used as an inert matrix in the fuel elements. The initial mass composition in terms of weight percentages in the heavy metal component(IHM)was 30.6% Pu/IHM and 69.4% MA/IHM. To verify the feasibility of this MA loading scheme, variations in k_(eff), the amplification factor of the core, maximum power density and the content of MAs and Pu were calculated over six refueling cycles. Each cycle was of 600 days duration, and therefore, there were 3600 effective full power days.Results demonstrated that the effective transmutation support ratio of MAs was approximately 28, and the ADS was able to efficiently transmute MAs. The changes in other physical parameters were also within their normal ranges.It is concluded that the proposed MA transmutation scheme for an ADS core is reasonable.     

The reactivity risk in fast reactors and the related international experimental programmes CABRI and SCARABEE

CABRI and SCARABEE are two experimental reactors, located at Cadarache, France. During the last twenty years, they were operated by IPSN, together with other French and foreign research institutes, in order to conduct several experimental programmes to study the problems raised by the reactivity risk in fast reactors. Transient over-power tests were realized in CABRI, whereas in SCARABEE bundles with up to 37 pins were brought to melting and even boiling.

The results led to code developments and general engineering expertise, and helped to give a better understanding and prediction capability of different hypothetical accident scenarios, like core disruptions and subassembly blockages.

A new programme is underway to complement some important issues, mainly linked to other scenarios, like an accidental control rod withdrawal and the risk of recriticality of a molten core.