Mn对Fe3Al合金室温力学性能的影响

Ｆｅ３Ａｌ金属间化合物具有抗氧化耐腐蚀性良，比强度高和成本低等特点，从而具有可观的工程应用前景。对这种材料目前国内研究的热点之一是改善其室温塑性。改善Ｆｅ３Ａｌ合金室温塑性的一个重要途径是合金化，这是因为Ｆｅ３Ａｌ合金有序结构的成分变化范围较宽，适于通过合金化来改善其性能，有报道表明，在Ｆｅ３Ａｌ合金中加入Ｃｒ可有效地提高室温塑性，但会使屈服强度有所下降，本文在加Ｃｒ的研究基础上，研究了Ｍｎ对Ｆｅ     

电刷镀技术对Fe3Al基合金室温环境脆性的改善作用

运用电刷镀技术在Ｆｅ３Ａｌ基合金表面刷镀一层Ｃｕ或Ｎｉ可以适度抑制其室温环境脆性，合金的室温塑性提高近３倍。ＳＥＭ分析发现，刷镀后在合金和镀层之间形成了过渡层，并在断口上出现了表征延性断裂的韧窝。     

Zr对Ni3Al晶界及力学性能的影响

对不同Ｚｒ含量Ｎｉ３Ａｌ的力学性能及晶界的研究结果表明：随Ｚｒ含量的增加，合金的屈服强度和抗张强度不断提高；当Ｚｒ≤０．７ａｔ．－％时，塑性随Ｚｒ含量的增加而提高；但Ｚｒ含量达１．２ａｔ．－％时，Ｚｒ的增塑效果下降．Ａｕｇｅｒ能谱分析表明：Ｚｒ在晶界有偏聚，偏聚因子约为３．断口观察显示：不含Ｚｒ或Ｚｒ含量为１．２ａｔ．－％的Ｎｉ－２４．０Ａｌ合金均为沿晶断裂，其余含Ｚｒ合金的断裂方式为穿晶、沿晶混合断裂．这表明：含Ｚｒ的Ｎｉ３Ａｌ塑性和Ｚｒ在晶界的偏聚有密切关系．     

两种含硼Ni3Al合金的微观组织与力学性能

本文研究了两种不同硼含量Ｎｉ３Ａｌ合金的微观组织、室温拉伸及高周疲劳性能，Ｎｉ３Ａｌ（０．６ａｔ．－％Ｂ）合金为单相组织，Ｎｉ３Ａｌ（１．０ａｔ．－％Ｂ）合金中除γ相外，还有微量共晶体，虽然Ｎｉ３Ａｌ（１．０Ｂ）的拉伸强度较Ｎｉ３Ａｌ（０．６Ｂ）的高，但在相同的循环应力水平下，后者的疲劳寿命显著高于前者的，疲劳断口观察表明两种合金的疲劳裂纹萌生和扩展行为各不相同。     

平衡相对8090Al—Li合金力学性能的影响

研究了一种８０９０Ａｌ－Ｌｉ合金中平衡相Ｔ２（Ａｌ６ＣｕＬｉ３）和δ（ＡｌＬｉ）数量变化对合金室温力学性能的影响。结果表明，合金经过双级时效（２１０－３００℃，４ｈ＋回复处理＋１６０℃，１００ｈ）后，Ｔ２相的大量析出会使合金的强度有所降低，塑性有一定程度升高，而δ相的大量析出迅速降低合金的强度，大幅度提高塑性。     

平衡相对8090Al－Li合金力学性能的影响

研究了一种８０９０Ａｌ－Ｌｉ合金中平衡相Ｔ２（Ａｌ６ＣｕＬｉ３）和δ（ＡｌＬｉ）数量变化对合金室温力学性能的影响。结果表明，合金经过双级时效（２１０－３００℃，４ｈ＋回复处理＋１６０℃，１００ｈ）后，Ｔ２相的大量析出会使合金的强度有所降低，塑性有一定程度升高，而δ相的大量析出迅速降低合金的强度，大幅度提高塑性。     

渗铝NiAl－20％Fe金属间合金的高温热腐蚀

本文研究了在９５０℃空气中，表面涂Ｎａ_２ＳＯ_４盐膜的条件下，ＮｉＡｌ，ＮｉＡｌ－２０％Ｆｅ及渗铝后的高温热腐蚀行为。在热腐蚀过程中，ＮｉＡｌ合金表面能形成Ａｌ_２Ｏ_３膜，显示出一定的耐蚀性能。但Ａｌ_２Ｏ_３膜易开裂，Ａｌ_２Ｏ_３膜的溶解及开裂会引发合金发生快速热腐蚀；２０％Ｆｅ的加入则使ＮｉＡｌ合金的耐蚀性能显著变差，合金表面不能形成单一的Ａｌ_２Ｏ_３膜；渗铝处理可以明显提高ＮｉＡｌ－２０％Ｆｅ合金的耐蚀性能，且渗铝涂层的耐蚀性能优于ＮｉＡｌ合金，这与铝化物涂层中的Ａｌ含量较高，Ａｌ_２Ｏ_３膜的开裂倾向较小有关。     

Sc对Al—Li—Cu—Mg—Zr合金组织与性能的影响

研究了Ｓｃ对Ａｌ－Ｌｉ－Ｃｕ－Ｍｇ－Ｚｒ合金的显微组织与拉伸性能的影响，结果表明，δ＇（Ａｌ３Ｌｉ）和Ｓ＇（Ａｌ２ＣｕＭｇ）仍为含Ｓｃ合金中的主要强化相，Ｓｃ细化了合金的晶粒，降低了δ＇颗粒的长大速度。促进了Ｓ＇相的析出和均匀弥散分布，还使合金析出Ａｌ３Ｓｃ颗粒和Ａｌ３Ｌｉ／Ａｌ３Ｓｃ复合析出相颗粒，这两种颗粒都有益于合金的性能，因此，加入Ｓｃ后合金表现出良好的强塑性配合。     

Sc对Al－Li－Cu－Mg－Zr合金组织与性能的影响

研究了Ｓｃ对Ａｌ—Ｌｉ—Ｃｕ—Ｍｇ—Ｚｒ合金的显微组织与拉伸性能的影响。结果表明，δ′（Ａｌ３Ｌｉ）和Ｓ′（Ａｌ２ＣｕＭｇ）仍为含Ｓｃ合金中的主要强化相，Ｓｃ细化了合金的晶粒，降低了δ′颗粒的长大速度，促进Ｓ′相的析出和均匀弥散分布，还使合金析出Ａｌ３Ｓｃ颗粒和Ａｌ３Ｌｉ／Ａｌ３Ｓｃ复合析出相颗粒，这两种颗粒都有益于合金的性能。因此，加入Ｓｃ后合金表现出良好的强塑性配合。     

不同结构及成分的Al3Ti合金成键特征的分析

利用Ｘ射线光电子能谱法分析了Ａｌ３Ｔｉ系合金的成键性质。Ｄ０２２型Ａｌ３Ｔｉ成键性质的各向异性有利于稳定Ｄ０２２结构，Ｌｌ２型Ａｌ３Ｔｉ成键方式呈各向同性。Ａｌ６７Ｔｉ２５Ｍｎ８合金中Ａｌ－Ｔｉ键与Ａｌ６７Ｔｉ２５Ｎｉ８合金相比具有球化程度高，方向性小的特点，有利于提高塑性。     

EFFECT OF Ce ON OXIDATION BEHAVIOUR OF Ni_3Al ALLOYS

1.IntroductionIntermetallicc0mp0undNi3Alhasthespecificpropertythattheyieldstrengthim-proveswiththeincrease0ftemperature.Thefundamentalresearchonhigh-temperaturestructuralmaterialshaJsmademuchprogress,andther0omtemperaturetensilepr0pertiesofNisAlalloysareimproveddramaticallywiththeaddition0falittleB[1'2].Beingasurfaceactiveelement,Cecanpurifyandmodifysteels,andimprovetheirductility,t0ughness,oxidationresistanceandc0rrosionresistance[3].Theeffect0fCe0nthefabricabilityandroomtemperaturetensil…     

Effect of Current Intensity on Microstructure of Ni3Al Intermetallics Prepared by Directional Solidification Electromagnetic Cold Crucible TechniqueEI北大核心CSCD

Due to their excellent high-temperature strength, and good oxidation resistance, Ni(3)Albased alloys have long attracted considerable interest as a class of high-temperature structural material. These properties, combined with their unique high thermal conductivity, make them ideal for special applications, such as blades in gas turbines and jet engines. However, polycrystalline Ni3Al alloys show almost no ductility and extremely low fracture resistance at ambient temperatures. Ni3Al alloys with the high ductility at room-temperature can be adjusted by the microstructure through directional solidification (DS) and matching. It has been shown that the electric field can refine the solidification structure, reduce the dendrite spacing, promote the diffusion and change the solute redistribution in the solidification process. In order to improve the room temperature ductility of Ni3Al alloy, the effect of current intensity on microstructure of DS Ni-25Al alloy is investigated. In this work, the effects of constant current intensity and NiAl phase on the microstructure are researched. The results show that in the DC electric field, as the result of the aggregation of current along dendrite tip and the Joule heat at the tip of dendrite, the primary dendritic spacing (lambda) decreases with the increasing of current intensity. And the solid-liquid interface tends to be straight resulting from the Joule heat and Peltier effect caused by the segregation of current and the difference in conductivity between solid and liquid interface. When no direct current is applied the DS samples contain the L12 structure of Ni3Al matrix and B2 structure of NiAl precipitate phase. The microstructure is a duplex structure which consist of gray Ni3Al matrix and black NiAl precipitates. NiAl precipitates with regular shape and has obvious orientation along with the growth direction. When the DC current is applied, NiAl precipitates is irregular and dispersion and has no obvious directionality, due to Joule heat effect generated by the current effect, the undercooling increased and the precipitated NiAl phase transformed into thin martensite NiAl phase with twin crystal symmetry from the NiAl-B2 type structure.     

Corrosion of aluminum alloys containing lithium

Aluminum alloys containing lithium exhibit high strength, high elastic modulus, and low density. These alloys contain a metastable, coherent δ′ (Al₃Li) phase which forms by homogeneous decomposition of the solid solution. Efforts are made to improve the ductility by alloying and heat treatment. In this work the corrosion behavior of AlLi, AlLiMn, AlLiZr, AlLiMg, and AlLiCu alloys was investigated as a function of composition and aging and correlated with the microstructure. The tests were made in a 3.5% NaCl solution, and included potential, potentiodynamic and potentiostatic measurements, and weight loss determinations. The results show that aging to peak hardness had little effect on the corrosion resistance. Overaging of the AlLi, AlLiMn, and AlLiZr alloys generally increased the susceptibility to corrosion, which has been attributed to the formation of the stable (AlLi) phase. Mg-containing alloys showed less severe effect of overaging because of the formation of the Al₃MgLi phase which tied up some of the lithium. In the Cu-containing alloy the supersaturation with lithium was low and overaging did not affect the corrosion resistance.     

Room Temperature Mechanical Properties of Fe3Al Intermetallic Alloys with Li and Ni Additions

This work analyzes the effect of very small additions of Li and Ni on the mechanical properties of the Fe₇₂Al₂₈ intermetallic alloy, close to the Fe₃Al ratio. Hardness and tensile strength at room temperature were analyzed for the cast Fe₃Al intermetallic alloys as a function of Li and Ni additions. For this purpose, high-purity raw materials were melted in an open induction furnace into a SiC crucible and the liquid alloys were poured into sand moulds to directly get tensile test-shaped specimens to minimize machining. Mechanical tests were carried out in the as-cast condition as well as after a homogenization heat treatment at 400 °C for 120 h. The obtained microstructure was characterized by XRD and SEM. Results show an increase in ductility, particularly when Li was added.     

EFFECTS OF Cu and Mg ON MICROSTRUCTURE AND PROPERTIES OF -Al(3－4 Wt%)Li AL

ＥＦＦＥＣＴＳＯＦＣｕａｎｄＭｇＯＮＭＩＣＲＯＳＴＲＵＣＴＵＲＥＡＮＤＰＲＯＰＥＲＴＩＥＳＯＦ－Ａｌ（３－４Ｗｔ％）ＬｉＡＬＬＯＹＳＣ．Ｇ．Ｊｉａｏ;Ｇ．Ｆ．ＹｕａｎｄＭ．Ｇ．Ｙａｎ（ＩｎｓｔｉｔｕｔｅｏｆＡｅｒｏｎａｕｔｉｃａｌＭａｔｅｒｉａｌｓ,...     

SURFACE REACTION OF Ni_3Al WITH WATER VAPOR OR OXYGEN

1.IntroductionManyresearcheshavedem0nstratedthatthebrittlefractureandpoorductilityatambienttemperature0fsomeintermetallicc0mp0undsarecausedbytheatmosphereofen.ir0n.entIl-4].Forexample,theel0ngationofFe3Alanditsalloystestedinairwasmuchlowerthanthatinvacuum0roxygenl516].Ni3Al-basedall0yswith0utbor0nandwitha1owcontent0fboronweresh0wnt0bequiteductilewithel0ngati0nof15-25%wl1entestedinvacuum0rpllreoxygen,whi1etheyexhibitedp0orductilityof4-10%inai,[7'8].Thisphenomen0nisbelievedtobeahydrogenembritt…     

EFFECT OF Zr ON DUCTILITY OF CAST Ni_3 Al-BASE ALLOYS

Many compressive and tensile tests showed that the room temperature ductility of boron-freeNi_3Al alloy may be markedly improved by a moderate addition of Zr.The ductility of thestoichiometric Ni_3Al and even slightly enriched with Al,may be improved fairly between 400—600℃,which behaves much better if Zr is added together with B.However,the high tem-perature ductility of Ni_3Al alloys containing Cr may be significantly increased by Zr whichsegregates slightly along grain boundaries.Thus,the toughening mechanism of Zr alloyingseems to be different from that of B addition.     

用正电子湮没技术研究Zr对Ni_3Al缺陷态的影响

本文用正电子湮没技术（ＰＴＡ）研究了含不同ｚｒ量多晶Ｎｉ３Ａｌ的ｅ＋寿命谱。结果表明：在Ｎｉ３Ａｌ中加入Ｚｒ，一部分Ｚｒ原子进行原子替位，使晶格发生畸变，导致基体中正电子寿命（τ_１）增长；另一部分在晶界偏聚的Ｚｒ调整了晶界结构，使平均寿命（τ）下降。当Ｚｒ量为１．２ａｔ．－％时，缺陷态的寿命τ２显著增长，表明有自由体积较大的缺陷组态生成．     

STUDY OF THE EFFECT OF BORON CONTENT ON THE ORDERED EXTENT OF THE Ni_3Al INTERMETALLICS COMPOUND BY AP-FIM

1. IntroductionPolycrystalline Ni3AI materials, an intermetallic compound with the L12 ordered structure, have been studied extensively in the past few years becallse of their potential application at high temperature structural applications. The brittle intergranular fractures andthe dramatic ductilizing effect of small amounts boron in polycrystalline Ni3AI led on tostudy the structure and chemistry of grain boundary[1--3]. The intergranular fragility ofNisAI alloys has been explained by…     

First-principles study of the influence of lattice misfit on the segregation behaviors of hydrogen and boron in the Ni–Ni3Al system

A first-principles method is employed to investigate the segregation behaviors of hydrogen and boron in Ni-based and Ni₃Al-based alloys using two models. Chemical binding energy analysis shows that both boron and hydrogen are able to segregate to the interstices in the Ni phase, Ni₃Al phase and Ni/Ni₃Al interface. Boron, however, is bound to its neighbor atoms more tightly than hydrogen in both models and its stable state exists over a broader lattice misfit range compared with hydrogen. The bond order analysis we have proposed reveals the origin of the boron-induced ductility and hydrogen-induced embrittlment at the Ni/Ni₃Al interface with different lattice misfit. The calculations indicate that hydrogen causes more severe embrittlement at the Ni/Ni₃Al interface in Ni₃Al-based than in Ni-based alloys. Furthermore, it is found that the boron-induced ductility and hydrogen-induced embrittlement are changed, and thus controllable, by the lattice misfit. Our results provide a quantitative explanation of many experimental phenomena caused by the addition of boron and hydrogen to Ni-based and Ni₃Al-based alloys.