A Genetic‐Algorithm‐Based Optimized Clustering for Energy‐Efficient Routing in MWSN

With the increasing demands for mobile wireless sensor networks in recent years, designing an energy‐efficient clustering and routing protocol has become very important. This paper provides an analytical model to evaluate the power consumption of a mobile sensor node. Based on this, a clustering algorithm is designed to optimize the energy efficiency during cluster head formation. A genetic algorithm technique is employed to find the near‐optimal threshold for residual energy below which a node has to give up its role of being the cluster head. This clustering algorithm along with a hybrid routing concept is applied as the near‐optimal energy‐efficient routing technique to increase the overall efficiency of the network. Compared to the mobile low energy adaptive clustering hierarchy protocol, the simulation studies reveal that the energy‐efficient routing technique produces a longer network lifetime and achieves better energy efficiency.     

Toward On‐and‐Off Magnetism: Reversible Electrochemistry to Control Magnetic Phase Transitions in Spinel Ferrites

The magnetoelectric effect, i.e., electric‐field control of magnetism in artificial heterostructures is usually limited to surface/interface atoms of the magnetic materials. In order to attain electrical control of magnetism in bulk ferromagnets, this study proposes to extend the definition of magnetoelectric phenomena to include reversible, chemistry‐controlled magnetization switching. A large and reversible change in the room temperature magnetization in strong ferromagnets is reported, with electrochemistry‐driven Li‐ion exchange; carefully chosen spinel ferrites demonstrate a reversible magnetization variation up to 50% for CuFe₂O₄ and 70% for ZnFe₂O₄. In case of CuFe₂O₄, the magnetization variation is predominantly associated with the preferential reduction of Cu²⁺ to Cu⁺ ions, and, hence, abides a nearly one‐to‐one relationship with the amount of injected Li‐ions. In addition, the reduction of Cu²⁺ also annihilates the Fe³⁺? O? Cu²⁺ magnetic interaction, resulting in a marked decrease in the Neél temperature of CuFe₂O₄. In contrast, the electrical tuning of superexchange interactions is found to play the decisive role in ZnFe₂O₄, where the simple electrochemical reduction model of magnetic cations can only explain a nominal fraction of the total magnetization variation, and indeed an electrochemically controlled reversible change in transition temperature is found necessary to account for the large magnetization variation observed.     

ECaD: Energy‐efficient routing in flying ad hoc networks

Much progress can be expected in the domain of unmanned aerial vehicle (UAV) communication by the next decade. The cooperation between multiple UAVs in the air exchanging data among themselves can naturally form a flying ad hoc network (FANET). Such networks can be the key support to accomplish several kinds of missions while providing the required assistance to terrestrial networks. However, they are confronted with many challenges and difficulties, which are due to the high mobility of UAVs, the frequent packet losses, and the weak links between UAVs, all affecting the reliability of the data delivery. Furthermore, the unbalanced energy consumption may result in earlier UAV failure and consequently accelerate the decrease of the network lifetime, thus disrupting the overall network. This paper supports the use of the movement information and the residual energy level of each UAV to guarantee a high level of communication stability while predicting a sudden link breakage prior to its occurrence. A robust route discovery process is used to explore routing paths where the balanced energy consumption, the link breakage prediction, and the connectivity degree of the discovered paths are all considered. The performance of the scheme is evaluated through a series of simulations. The outcomes demonstrate the benefits of the proposed scheme in terms of increasing the lifetime of the network, minimizing the number of path failures, and decreasing the packet losses.     

Energy‐efficient partner selection in cooperative wireless networks: a matching‐theoretic approach

In this paper, the problem of stable energy‐efficient partner selection in cooperative wireless networks is studied. Each node aims to be paired with another node so as to minimize the total energy consumption required to meet a target end‐to‐end signal‐to‐noise ratio requirement and thus maintain quality of service. Specifically, each node ranks every other node in the network according to their energy saving achievable through cooperation. Two polynomial time complexity algorithms based on the stable roommates matching problem are proposed through which nodes are paired according to their preference lists. The first algorithm, denoted Irving's stable matching, may not always have a stable solution. Therefore, the second algorithm—which is a modified version of Irving's algorithm and denoted maximum stable matching—is proposed to find the maximum number of stable disjoint pairs. Simulation results are provided to validate the efficiency of the proposed algorithms in comparison with centralized energy‐efficient partner selection as well as other matching algorithms, yielding a trade‐off between stability and total energy consumption, but comparable symbol error rate performance and network sum rate. Copyright © 2016 John Wiley & Sons, Ltd.     

Magnetic Field‐Induced Phase Transformation in NiMnCoIn Magnetic Shape‐Memory Alloys—A New Actuation Mechanism with Large Work Output

Magnetic shape memory alloys (MSMAs) have recently been developed into a new class of functional materials that are capable of magnetic‐field‐induced actuation, mechanical sensing, magnetic refrigeration, and energy harvesting. In the present work, the magnetic &!hyphen;field‐induced martensitic phase transformation (FIPT) in Ni₄₅Mn_36.5Co₅In_13.5 MSMA single crystals is characterized as a new actuation mechanism with potential to result in ultra‐high actuation work outputs. The effects of the applied magnetic field on the transformation temperatures, magnetization, and superelastic response are investigated. The magnetic work output of NiMnCoIn alloys is determined to be more than 1 MJ m^?3 per Tesla, which is one order of magnitude higher than that of the most well‐known MSMAs, i.e., NiMnGa alloys. In addition, the work output of NiMnCoIn alloys is orientation independent, potentially surpassing the need for single crystals, and not limited by a saturation magnetic field, as opposed to NiMnGa MSMAs. Experimental and theoretical transformation strains and magnetostress levels are determined as a function of crystal orientation. It is found that [111]‐oriented crystals can demonstrate a magnetostress level of 140 MPa T^?1 with 1.2% axial strain under compression. These field‐induced stress and strain levels are significantly higher than those from existing piezoelectric and magnetostrictive actuators. A thermodynamical framework is introduced to comprehend the magnetic energy contributions during FIPT. The present work reveals that the magnetic FIPT mechanism is promising for magnetic actuation applications and provides new opportunities for applications requiring high actuation work‐outputs with relatively large actuation frequencies. One potential issue is the requirement for relatively high critical magnetic fields and field intervals (1.5–3 T) for the onset of FIPT and for reversible FIPT, respectively.     

MHP: Master‐Handoff Protocol for Fast and Energy‐Efficient Data Transfer over SPI in Wireless Sensing Systems

Serial peripheral interface (SPI) has been identified as a bottleneck in many wireless sensing systems today. SPI is used almost universally as the physical connection between the microcontroller unit (MCU) and radios, storage devices, and many types of sensors. Virtually all wireless sensor nodes today perform up to twice as many bus transactions as necessary to transfer a given piece of data, as an MCU must serve as the bus master in all transactions. To eliminate this bottleneck, we propose the master‐handoff protocol. After the MCU initiates reading from the source slave device and writing to the sink slave device, the MCU as a master becomes a slave, and either the source or the sink slave becomes the temporary master. Experiment results show that this master‐handoff technique not only cuts the data transfer time in half, but, more importantly, also enables a superlinear energy reduction.     

Atmosphere‐Induced Reversible Resistivity Changes in Ca/Y‐Doped Bismuth Iron Garnet Thin Films

Bismuth iron garnet Bi₃Fe₅O₁₂ (BIG) is a multifunctional insulating oxide exhibiting remarkably the largest known Faraday rotation and linear magnetoelectric coupling. Enhancing the electrical conductivity in BIG while preserving its magnetic properties would further widen its range of potential applications in oxitronic devices. Here, a site‐selective codoping strategy in which Ca²⁺ and Y³⁺ substitute for Bi³⁺ is applied. The resulting p‐ and n‐type doped BIG films combine state‐of‐the‐art magneto‐optical properties and semiconducting behaviors above room temperature with rather low resistivity: 40 Ω cm at 450 K is achieved in an n‐type Y‐doped BIG; this is ten orders of magnitude lower than that of Y₃Fe₅O₁₂. High‐resolution electron spectromicroscopy unveils the complete dopant solubility and the charge compensation mechanisms at the local scale in p‐ and n‐type systems. Oxygen vacancies as intrinsic donors play a key role in the conduction mechanisms of these doped BIG films. On the other hand, a self‐compensation of Ca²⁺ with oxygen vacancies tends to limit the conduction in p‐type Ca/Y‐doped BIG. These results highlight the possibility of integrating n‐type and p‐type doped BIG films in spintronic structures as well as their potential use in gas sensing applications.     

Energy‐efficient design of 3D UWSNs leveraging compressive sensing and principal component analysis: A communication techniques perspective

The design of energy‐efficient underwater wireless sensor networks (UWSNs) poses many challenges due to the intrinsic properties of propagation medium and limited battery power of sensor nodes. This paper proposes the concept of optimal clustering for three‐dimensional (3D) UWSNs leveraging compressive sensing (CS) and principal component analysis (PCA) technique of data compression. Optimal clustering reduces the energy consumption by selecting the optimal number of clusters whereas CS and PCA compression techniques reduce the energy consumption by considering a lesser number of samples and reduce the data redundancy at cluster heads (CHs) level, respectively. Moreover, three communication techniques like acoustic, electromagnetic (EM), and free‐space optical (FSO) wave are considered for communication in 3D UWSNs. We compared the energy efficiency for all three communication techniques by examining the three base station (BS) positions at the center, at the corner, and at the lateral midpoint of the 3D sensing area. Moreover, performance parameters (network lifetime, throughput, packet drop rate, and latency) are also evaluated for 3D UWSNs. It is observed that PCA outperforms the CS technique. The proposed technique is suitable for long‐term and densely deployed 3D UWSNs, in which saving energy is of crucial importance.     

Anodic Electrochromism for Energy‐Efficient Windows: Cation/Anion‐Based Surface Processes and Effects of Crystal Facets in Nickel Oxide Thin Films

Anodic electrochromic (EC) oxides are of major interest as counter electrodes for smart window applications owing to their unique optical properties upon charge insertion and extraction. However, performance optimization of such oxides has been hampered by limited understanding of their EC mechanism, particularly in Li⁺‐conducting electrolytes. This paper reports on NiO_x films with 1.16 ≤ x ≤ 1.32, prepared by sputter deposition. These films are immersed in an electrolyte of lithium perchlorate in propylene carbonate, and EC properties are studied by cyclic voltammetry and in situ optical transmittance measurements. The electrochromism is significantly enhanced at large values of x. It has been found that charge exchange in Ni oxide is mainly due to surface processes and involves both cations and anions from the electrolyte, which is different from the case of cathodic EC materials such as WO₃. Whereas previous studies of Ni oxide have focused on cation intercalation, the cation/anion‐based mechanism presented here offers a new paradigm for designing and developing EC devices such as smart windows for energy efficient buildings.     

A Hollow‐Core,Magnetic, and Mesoporous Double‐Shell Nanostructure: In Situ Decomposition/Reduction Synthesis,Bioimaging, and Drug‐Delivery Properties

A novel in situ decomposition/reduction approach is developed to manu­facture hollow core, magnetic, and mesoporous double‐shell nanostructures (HMMNSs) via in situ decomposition and reduction of a β‐FeOOH nanorod core and organosilicate‐incorporated silica‐shell precursor. The formed HMMNSs are then aminated by silanization for further covalent conjugation to rhodamine B isothiocyanate (RBITC) and poly(ethylene glycol) (PEG) chains. The resultant RBITC‐grafted and PEGylated nanocomposites (HMMNS–R/Ps) have excellent blood compatibility and very low cytotoxicity towards HeLa and MCF‐7 cells, and can be taken up by cancer cells effectively in a dose‐dependent manner, as confirmed by in vitro flow cytometry, confocal luminescence imaging, and magnetic resonance imaging (MRI) studies. In vivo MRI studies coupled with Prussian blue staining of slides from different organs show that the nanocomposites preferentially accumulate in liver and spleen after intravenous injection, which suggests a potential application of the nanocomposites as MRI contrast agents. Importantly, the HMMNS–R/P nanocomposites show high loading capacity for water‐insoluble anticancer drugs (docetaxel or camptothecin) owing to the presence of a large inner cavity and enhanced surface area and pore volume. Furthermore, the drug‐loaded nanocomposites exhibit greater cytotoxicity than the corresponding free drugs. These results confirm that the HMMNS–R/P nanocomposites are promising candidates for simultaneous bioimaging and drug delivery.     

Eutectic Gallium‐Indium (EGaIn): A Liquid Metal Alloy for the Formation of Stable Structures in Microchannels at Room Temperature

This paper describes the rheological behavior of the liquid metal eutectic gallium‐indium (EGaIn) as it is injected into microfluidic channels to form stable microstructures of liquid metal. EGaIn is well‐ ;suited for this application because of its rheological properties at room temperature: it behaves like an elastic material until it experiences a critical surface stress, at which point it yields and flows readily. These properties allow EGaIn to fill microchannels rapidly when sufficient pressure is applied to the inlet of the channels, yet maintain structural stability within the channels once ambient pressure is restored. Experiments conducted in microfluidic channels, and in a parallel‐plate rheometer, suggest that EGaIn's behavior is dictated by the properties of its surface (predominantly gallium oxide, as determined by Auger measurement s); these two experiments both yield approximately the same number for the critical surface stress required to induce EGaIn to flow (～0 .5 N/m). This analysis–which shows that the pressure that must be exceeded for EGaIn to flow through a microchannel is inversely proportional to the critical (i.e., smallest) dimension of the channel–is useful to guide future fabrication of microfluidic channels to mold EGaIn into functional microstructures.     

Stretching‐Induced Growth of PEDOT‐Rich Cores: A New Mechanism for Strain‐Dependent Resistivity Change in PEDOT:PSS Films

It remains a fundamental challenge in the development of stretchable electronics to understand how mechanical strain changes the electrical properties of materials. Although the piezoresistive behavior of poly(3,4‐ethylene‐ dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been observed, its intrinsic origin is not yet fully understood because there are many extrinsic contributing factors and an experimental platform with which to assess such behavior has not been established. Here, systematic analysis shows that the matching Poisson's ratio and elastic modulus between PEDOT:PSS films and their underlying substrates is important in decoupling the factors that affect the material's piezoresistivity, allowing for tunable resistivity. Based on such a fundamental understanding, the conductivity of PEDOT:PSS can be controlled to be invariant and decrease as a function of applied tensile stress. Furthermore, a linear response of the resistivity with respect to mechanical strains of up to 60%, which has never before been realized, is shown. The irreversible conductivity enhancement is primarily caused by the coalescence‐induced growth of conductive PEDOT‐rich cores.     

Optimization‐based workload distribution in geographically distributed data centers: A survey

Energy efficiency is a contemporary and challenging issue in geographically distributed data centers. These data centers consume significantly high energy and cast a negative impact on the energy resources and environment. To minimize the energy cost and the environmental impacts, Internet service providers use different approaches such as geographical load balancing (GLB). GLB refers to the placement of data centers in diverse geolocations to exploit variations in electricity prices with the objective to minimize the total energy cost. GLB helps to minimize the overall energy cost, achieve quality of service, and maximize resource utilization in geo‐distributed data centers by employing optimal workload distribution and resource utilization in the real time. In this paper, we summarize various optimization‐based workload distribution strategies and optimization techniques proposed in recent research works based on commonly used optimization factors such as workload type, load balancer, availability of renewable energy, energy storage, and data center server specification in geographically distributed data centers. The survey presents a systemized and a novel taxonomy of workload distribution in data centers. Moreover, we also debate various challenges and open research issues along with their possible solutions.     

Reduction of Tungsten Oxide: A Path Towards Dual Functionality Utilization for Efficient Anode and Cathode Interfacial Layers in Organic Light‐Emitting Diodes

Here, we report on the dual functionality of tungsten oxide for application as an efficient electron and hole injection/transport layer in organic light‐emitting diodes (OLEDs). We demonstrate hybrid polymer light‐emitting diodes (Hy‐PLEDs), based on a polyfluorene copolymer, by inserting a very thin layer of a partially reduced tungsten oxide, WO_2.5, at the polymer/Al cathode interface to serve as an electron injection and transport layer. Significantly improved current densities, luminances, and luminous efficiencies were achieved, primarily as a result of improved electron injection at the interface with Al and transport to the lowest unoccupied molecular orbital (LUMO) of the polymer, with a corresponding lowering of the device driving voltage. Using a combination of optical absorption, ultraviolet spectoscopy, X‐ray photoelectron spectroscopy, and photovoltaic open circuit voltage measurements, we demonstrate that partial reduction of the WO₃ to WO_2.5 results in the appearance of new gap states just below the conduction band edge in the previously forbidden gap. The new gap states are proposed to act as a reservoir of donor electrons for enhanced injection and transport to the polymer LUMO and decrease the effective cathode workfunction. Moreover, when a thin tungsten oxide film in its fully oxidized state (WO₃) is inserted at the ITO anode/polymer interface, further improvement in device characteristics was achieved. Since both fully oxidized and partially reduced tungsten oxide layers can be deposited in the same chamber with well controlled morphology, this work paves the way for the facile fabrication of efficient and stable Hy‐OLEDs with excellent reproducibility.