Improving the Property–Function Tuning Range of Thiophene Materials via Facile Synthesis of Oligo/Polythiophene‐S‐Oxides and Mixed Oligo/Polythiophene‐S‐Oxides/Oligo/Polythiophene‐S,S‐Dioxides

A platform is described for the first time for the facile synthesis of oligo‐ and polythiophene‐S‐oxides and the corresponding ‐S,S‐dioxides in short times, mild conditions, high yields. Employing ultrasound assistance, brominated thiophenes are selectively mono‐ or dioxygenated at room temperature. These building blocks are then combined with metalated thiophenes via microwave‐assisted cross‐coupling reactions through a “Lego‐like” strategy to afford unprecedented oligo/polythiophene‐S‐oxides and mixed ‐S‐oxides/‐S,S‐dioxides. It is demonstrated that depending on the number, type, and sequence alternation of nonoxygenated, monooxygenated, and dioxygenated thiophene units a very wide property–function tuning can be achieved spanning from frontier orbital energies and energy gaps, to charge transport characteristics and supramolecular H‐bonding interactions with specific proteins inside live cells.     

10‐Bit 200‐MS/s Current‐Steering DAC Using Data‐Dependant Current‐Cell Clock‐Gating

This letter proposes a low‐power current‐steering digital‐to‐analog converter (DAC). The proposed DAC reduces the clock power by cutting the clock signal to the current‐source cells in which the data will not be changed. The 10‐bit DAC is implemented using a 0.13‐μm CMOS process with V_DD=1.2 V. Its area is 0.21 mm². It consumes 4.46 mW at a 1‐MHz signal frequency and 200‐MHz sampling rate. The clock power is reduced to 30.9% and 36.2% of a conventional DAC at 1.25‐MHz and 10‐MHz signal frequencies, respectively. The measured spurious free dynamic ranges are 72.8 dB and 56.1 dB at 1‐MHz and 50‐MHz signal frequencies, respectively.