Nitrogen management in reservoir catchments through constructed wetland systems.

In this study, nitrogen removal was investigated in pilot-scale subsurface flow (SSF) and in free water surface flow (FWS) constructed wetlands installed in the campus of TUBITAK-Marmara Research Center, Gebze, near Istanbul, Turkey. The main purposes of this study are to apply constructed wetlands for the protection of water reservoirs and to reuse wastewater. Experiments were carried out at continuous flow reactors. The effects of the type of plants on the removal were investigated by using emergent (Canna, Cyperus, Typhia spp., Phragmites spp., Juncus, Poaceae, Paspalum and Iris.), submerged (Elodea, Egeria) and floating (Pistia, Salvina and Lemna) marsh plants at different conditions. During the study period HLRs were 30, 50, 70, 80 and 120 L m(2)d(-1) respectively. The average annual NH4-N, NO(3)-N, organic N and TN treatment efficiencies in SSF and FWS wetlands are 81% and 68%, 37% and 49%, 75% and 68%, 47% and 53%, respectively. Nitrification, denitrification and ammonification rate constant (k20) values in SSF and FNS systems have been found as 0.898 d(-1) and 0.541 d(-1), 0.488 d(-1) and 0.502 d(-1), 0.986 d(-1) and 0.908 respectively. Two types of the models (first-order plug flow and multiple regression) were tried to estimate the system performances.     

Treatments of oil-refinery and steel-mill wastewaters by mesocosm constructed wetland systems.

In this study, two types of industrial wastewater, oil-refining and steel-milling, were selected for investigating their feasibility of treatment by mesocosm constructed wetland systems. The secondly treated effluents from the wastewater treatment plants were directly discharged into the systems controlled at different flow rates. Three wetland mesocosms were installed in the two industries: mesocosms A and B were in the oil refinery, and mesocosm C was in the steel mill. The substratum media used in wetland systems were sand (mesocosm A) and gravel (mesocosms B and C), while the vegetation types selected were reeds (mesocosms A and B) and mixed species of reeds and cattails (mesocosm C). The flow regimes were controlled as free water surface (FWS) and subsurface flow (SSF) for the sand- and gravel-beds, respectively. According to the experimental results, we found that the system treating oil-refining wastewater performed better than that treating steel-milling wastewater learned by comparing the removal efficiencies of COD, total N and total P. In addition, it was found that for oil-refining wastewater treatments, the SSF wetland system (mesocosm B) performed better than FWS (mesocosm A) wetland system when comparing both of their removal of pollutants and growth of vegetation. Besides, the effluents from these two industrial wetland treatment systems might be reclaimed and reused for boiler water, cooling, cleaning and miscellaneous purposes in industries. Further treatments are required if the constructed wetland effluents are thought about being reused for processing in industries.     

Danish guidelines for small-scale constructed wetland systems for onsite treatment of domestic sewage.

The Danish Ministry of Environment and Energy has passed new legislation that requires the wastewater from single houses and dwellings in rural areas to be treated adequately before discharge into the aquatic environment. Therefore official guidelines for a number of onsite treatment solutions have been produced. These include guidelines for soakaways, biological sand filters, technical systems as well as different types of constructed wetland systems. This paper summarises briefly the guidelines for horizontal flow constructed wetlands, vertical flow constructed wetlands, and willow systems with no outflow and with soil infiltration. There is still a lack of a compact onsite solution that will fulfil the treatment classes demanding 90% removal of phosphorus. Therefore work is presently being carried out to identify simpler and robust P-removal solutions.     

Integrated constructed wetland systems: design, operation, and performance of low-cost decentralized wastewater treatment systems.

Several different types of constructed wetland systems are being used as decentralized treatment systems including surface-flow, subsurface-flow, vertical-flow, and hybrid systems. Archetypical wetland systems have design strengths and weaknesses, and therefore it should be possible to design combined (integrated) systems to optimize a number of important treatment processes. This study provides comparative efficacy data for two integrated wetland treatment systems (IWTS) designed to enhance treatment of medium strength wastewater generated from a pilot-scale intensive fish farm. Results from the twenty eight months study included consistently high removal of COD (84% +) and ammonia nitrogen (93%) in both systems. Initially, phosphorus removal was also high (>90%) in both systems, but removal efficacy declined significantly over time. Nitrate removal was significantly better in the system that provided sequential aerobic and anoxic environments. Short hydraulic retention times coupled with sustained removal of COD and ammonia indicate that the ReCip components could be a least-cost wastewater treatment technology in the decentralized market sector.     

Vertical flow constructed wetland for textile effluent treatment.

A pulse feed vertical flow constructed wetland (VFCW) proved to be efficient in the treatment of a textile effluent being able to buffer, dilute and treat an Acid Orange (AO7) accidental discharge. The influence of the flooding level (FL) and pulse feed (PF) duration on the removal efficiencies of a VFCW was examined. Average AO7 removal efficiencies of 70% were achieved for an AO7 Inlet concentration of 700 mgl(-1) applied during 15 min cycle(-1) (every three hours) at a hydraulic load of 13 lm(-2) cycle(-1) and an FL of 21%. The VFCW was modelled by analogy with a combination of ideal reactors. The simplest combination that best reproduced the experimental results was an association of 2 reactors in series plus 1 reactor accounting the dead volumes. The model parameters helped to understand the hydrological and kinetic processes occurring in VFCW. Through the model simulation it was shown that 3 VFCW in series were enough to efficiently treat an organic mass load of 76 gAO7 m(-2) day(-1) in 9 hours and fulfil the discharge legislation. In this work it was possible to establish that the overall degradation kinetics was of first order.     

人工湿地技术在污水处理中的应用

人工湿地技术是建立在生态学原理基础上的一项新型污水处理技术,因其具有净化效果好、工艺设备简单、运行费用低、美观等特点,从而受到人们的广泛关注。现主要从人工湿地的基本构型、人工湿地分类和国内外应用现状3个方面进行了阐述,并提出了人工湿地在实际应用中的问题和未来发展方向。     

Performance of constructed wetland treating wastewater from seafood industry.

Wastewater from seafood industry contains high concentrations of organic matter, nitrogen compounds, and solid matter. Constructed wetland can be used as tertiary treatment and for nutrient recycling. This research studied the performance of nitrogen and suspended solids removal efficiency of a constructed wetland treating wastewater from a seafood-processing factory located at Songkhla, southern Thailand. The existing constructed wetland has dimensions of 85 m, 352 m and 1.5 m in width, length and depth respectively, with an area of about 29,920 m2. The water depth of 0.30 m is maintained in operation with plantation of cattails (Typha augustifolia). Flow rate of influent ranged between 500-4,660 m3/d. Average hydraulic retention time in the constructed wetland was about 4.8 days. Influent and effluent from the constructed wetland were collected once a week and analyzed for pH, temperature, dissolved oxygen (DO), biochemical oxygen demand (BOD5), Suspended solid (SS), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), organic nitrogen (Org-N), nitrate (NO3-N), and nitrite (NO2-N). The average removal efficiencies of BOD5, SS, TKN, NH3-N, and Org-N were 84%, 94%, 49%, 52% and 82%, respectively. It was found that the constructed wetland acting as a tertiary treatment process provided additional removal of BOD5, SS and TKN from wastewater from the seafood industry.     

Twenty years experience with constructed wetland systems in Denmark--what did we learn?

Full scale constructed wetland systems for wastewater treatment have been in operation in Denmark since 1983, mainly for the treatment of domestic sewage from small villages. The systems are constructed as soil-based horizontal subsurface flow systems but, because of low soil hydraulic conductivity, surface runoff is evident in most of the systems. Two decades of experience show that soil-based systems are generally efficient in removing suspended solids and BOD, but the removal of nitrogen and phosphorus is lower (typically 30-50%) and the systems do not nitrify ammonium. Contrary to earlier claims, the reeds do not increase the hydraulic conductivity of cohesive soils as much as necessary to secure sub-surface flow. Operation needs of soil-based reed beds are low and normally restricted to emptying of the sedimentation tank, cleaning of the distribution system and mowing of the grass around the system. The dead plant material and accumulated litter on the surface of the systems improve performance after the initial years. A significant number of systems have been shut down or extended with other technologies in order to meet new effluent standards, particularly demands for nitrification. New constructed wetland systems are either compact vertical flow systems which provide good nitrification, willow systems with no discharge or restored wetland systems for nitrate removal. If efficient removal of phosphorus is required, this is achieved by chemical precipitation in the sedimentation tank.     

The performance of vertical flow constructed wetland systems with special reference to the significance of oxygen transfer and hydraulic loading rates.

The paper reviews the development of the vertical flow (VF) reed beds/constructed wetlands over the past 20 years. The performance of VF systems (and their use within hybrid systems) is analysed by reference to a number of brief case studies. The oxygen transfer rate (OTR) achieved is absolutely critical to the sizing of the systems. The author reviews the reported OTRs and comments on the existing design equations proposed for calculation of the area of beds. The 1st generation of VF systems used a set of parallel beds that were dosed one at a time in rotation and then rested for a period of days because there was considerable concern (based on early experience) that they would become clogged. In the past 10 years a number of new designs of 2nd generation VF beds have been built which make use of a single bed and hence operate without any resting periods. The hydraulic loading rate and the selection of the bed media, which are critical to the design and hence successful operation of these 2nd generation compact VF beds, are described. It is now possible to produce a very high quality of effluent from VF beds alone sized at 2 m2/pe when treating domestic sewage.     

Biodegradation of chlorobenzene in a constructed wetland treating contaminated groundwater.

Monochlorobenzene (MCB) is an important groundwater contaminant world-wide. In this study, a horizontal subsurface flow constructed wetland with an integrated water compartment was fed with MCB contaminated groundwater originating from the local aquifer. Analysis of spatial concentration dynamics of MCB and oxygen was combined with isotope composition analysis of MCB for assessing in situ biodegradation. Removal of MCB was most effective in the upper layer of the soil filter, reaching up to 77.1%. Trace oxygen concentrations below 0.16 mg L(-1) were observed throughout the wetland transect, suggesting a considerable limitation of aerobic microbial MCB degradation. Enrichment of 13C in the residual MCB fraction at increasing distance from the inflow point indicated microbial MCB degradation in the wetland. The observed isotope shift was higher than expected for aerobic MCB degradation and thus pointed out a significant contribution of an anaerobic degradation pathway to the overall biodegradation.     

潜流人工湿地水力设计浅议

人工湿地水处理技术人为创建拟自然条件,利用自然界微生物学、生物学、物理和化学过程来处理污水,在发达国家应用非常广泛,目前我国对人工湿地的设计还没有形成规范化的标准和导则,系统地论述了EPA人工湿地手册中潜流人工湿地的水力设计理论、步骤等,并针对其局限性提出了改进措施,以期为国内的人工湿地工程设计提供技术参考。     

The effect of a vertical flow filter bed on a hybrid constructed wetland system.

Data from 18 sampling wells in Kodij?rve horizontal subsurface flow (HSSF) constructed wetland (CW) (South Estonia) is presented and differences in purification efficiencies inside the HSSF CW are calculated. Temporarily anaerobic conditions in the Kodij?rve HSSF system did not allow efficient removal of BOD7, NH4-N, Ntot and Ptot. In 2002 a vertical subsurface flow filter was constructed to enhance aeration. The design of the system was based simply on the oxygen demand of the wastewater and on the aeration potential of vertical flow wetlands. The vertical flow system has shown satisfactory results. The purification efficiency of BOD7 in the Kodij?rve CW has improved significantly and there has been a slight increase in purification efficiencies of NH4-N and Ntot. On the ohther hand, the removal efficiency of Ptot has decreased significantly. Although, the mass loading rates have increased, mass removal rates of all four parameters have improved significantly. Nevertheless, optimization of the constructed wetland system is essential in order to meet effluent standards during wintertime.     

Nitrogen dynamics in a constructed wetland system treating landfill leachate.

A pilot scale treatment system was established in 2002 at the Laflèche Landfill in Eastern Ontario, Canada. The system consists of a series of treatment steps: a stabilisation basin (10,000 m3), a woodland peat trickling filter (5,200 m2), a subsurface flow constructed wetland planted in Phragmites sp. (2,600 m2), a surface flow constructed wetland planted in Typha sp. (3,600 m2) and a polishing pond (3,600 m2). The system operates from May to December with leachate being recycled within the landfill during the winter months. Hydraulic loading was increased three-fold over four operating seasons with nitrogen and organic mass loading increasing six-fold. Excellent removal efficiencies were observed with 93% BOD5, 90% TKN and 97% NH4-N removed under the highest loading conditions. Almost complete denitrification was observed throughout the treatment system with NO3-N concentrations never exceeding 5mg L(-1). The peat filter reached treatment capacity at a hydraulic loading of 4cm d(-1) and organic loading rate of 42 kg BOD ha(-1) d(-1), which is consistent with design criteria for vertical flow wetland systems and intermittent sand filters, The first order plug flow kinetic model was effective at describing TKN and ammonium removal in the SSF and FWS wetlands when background concentrations were taken into account. Ammonium removal k-values were consistent with the literature at 52.6 and 57.7 yr(-1) for the SSF and FWS wetlands, respectively, while TKN k-values at 6.9 and 7.7 yr(-1) were almost an order of magnitude lower than literature values, suggesting that leachate TKN could contain refractory organics not found in domestic wastewater.     

Slag columns for upgrading phosphorus removal from constructed wetland effluents.

The current best option to upgrade constructed wetlands (CWs) for phosphorus (P) retention, in terms of efficiency, cost and simplicity, consists in using media having a strong P affinity. The media can be used either in the planted beds or in a filtration system downstream of the beds. The use of slag filters was shown to be efficient for removing P from wastewater as it represented a slow release source of calcium and hydroxide, favouring the formation of hydroxyapatite. Our study aimed at maximising the P retention capacity of slag filters located at the outlet of CWs since electric arc furnace slag has been shown to inhibit the growth of macrophytes when used in the filtration matrix. Bench-scale columns (Vtot = 6.2 L) filled with various combinations of filter media (slag, granite, limestone) of different sizes (2-5, 5-10, 10-20 mm) were fed on-site during four months with a CW effluent (in mg/L: 30 COD, 30 TSS, 10 Pt). Results showed that the best media combination enabling the maximum o-PO4 retention (more than 80% removal without clogging) consisted in a series of a ternary mix column (slag 5-10 mm, granite 2-5 mm, limestone 5-10 mm) followed by a slag column (slag 5-10 mm). Pilot scale columns (Vtot = 300 L), filled with the best media combination, were installed at the outlet of a 28 m2 CW. These columns showed more than 75% removal efficiency during one year and were designed to be easily replaced each year.     

Diversity of ammonia oxidising bacteria in a vertical flow constructed wetland.

Vertical flow constructed wetlands (VFCWs) with intermittent loading are very suitable for nitrification. Ammonia oxidising bacteria (AOB) are the limiting step of nitration. Therefore the AOB community of a full-scale VFCW, receiving municipal wastewater, was investigated within this study. The diversity of the functional gene encoding the alpha-subunit of the ammonia monooxygenase (amoA), present only in AOB, was assessed by denaturing gradient gel electrophoresis (DGGE). Only very few amoA sequence types dominated the wetland filter substrate; nevertheless a stable nitrification performance could be observed. During the cold season the nitrification was slightly reduced, but it has been shown that the same AOB could be identified. No spatial AOB pattern could be observed within the filter body of the VFCW. The most prominent bands were excised from DGGE gels and sequenced. Sequence analyses revealed two dominant AOB lineages: Nitrosomonas europaea/"Nitrosococcus mobilis" and Nitrosospira. Species of the Nitrosomonas lineage are commonly found in conventional wastewater treatment plants (WWTPs). In contrast, members of the Nitrosospira lineage are rarely present in WWTPs. Our observations indicate that the AOB community in this VFCW is similar to that found in horizontal flow constructed wetlands, but differs from common WWTPs regarding the presence of Nitrosospira.     

Simulation of a subsurface vertical flow constructed wetland for CSO treatment.

Constructed wetlands (CWs) have proved to be a highly effective measure to reduce the ecological impact of combined sewer overflows (CSOs) on receiving waters. Due to the stochastic nature of the loading regime and the multitude of environmental influences, assessment of the performance of such plants requires detailed mathematical modelling. A multi-component reactive transport module (CW2D) was applied to simulate the flow, transport and degradation processes occurring in a CW for CSO treatment. CW2D was originally developed to simulate the treatment of municipal wastewater in subsurface flow CWs. Loading and operational conditions in CSO treatment differ fundamentally from the conditions occurring for wastewater treatment. Despite these differences, first results from the simulation of lab-scale experiments show, that the model is generally applicable to this type of plant. Modelling of adsorption, degradation processes, and influent fractionation, however, require further research.     

Treatment of high strength wastewater with vertical flow constructed wetland filters.

The aim of the present study was to evaluate the behaviour of vertical flow constructed wetlands to treat high strength wastewater. Influents were obtained mixing tap water with different percentages of MSW landfill leachate (5%, 10% and 20%). Phragmites australis seedlings were used as macrophytes. The reeds were nurtured during three spring months, before the start of the experimental period. Three and four days of detention time were adopted. Influent concentrations of 510-2,050 mg L(-1), 180-740 mg L(-1) and 65-260 mg L(-1) were obtained for COD, N-NH4(+) and N-NO3(-), respectively. The environmental temperature averaged around 31.0 +/- 1.4 degrees C. During the experimental period, all parameters showed an increasing removal efficiency trend. Best results in terms of COD removal were obtained for mixtures at lowest rate of landfill leachate; while, denitrification process showed an opposite behaviour; finally, the removal of ammonia nitrogen appeared to be independent upon influent concentrations. Analysis carried out on the reed tissues showed a theoretic maximum storage of TKN in the leaves of about 55 mg/g dry weight. A leachate percentage of about 35% was derived to be able to fully inhibit the growth of macrophytes.     

不同类型复合湿地对处理滏阳河水的影响

以河北邯郸滏阳河水为例,构建两组不同类型的人工湿地来处理城市污水,探究适合华北地区处理城市污水的人工湿地类型。经由实验测定结果显示,复合型人工湿地对污水处理效果较好,两组人工湿地对TN、TP、浊度、CODMn的去除率分别为41%、96%、92%、57%和27%、89%、88%、44%。基质填料限制了湿地对污染物的去除,建议采用沸石、煤渣或者组合基质,以增加湿地污染物去除效果。此外,植物的选择也影响着湿地对污染物的去除效果。     

The effect of the redox-potential on the retention of phosphorus in a small constructed wetland.

Building wetlands in small arable streams is a popular supplement to best management practice on arable fields. Particle bound phosphorus settles in the small constructed wetlands (CWs), receiving agricultural diffuse pollution. The sorption behavior of phosphorus is, however, redox-sensitive, and bound phosphorus may be remobilized in periods with low redox potential. This paper investigates changes in the redox potential in the free water of wetland Berg (Norway) during a three-year period, and how these redox changes affect the total phosphorus (TP) and total reactive phosphorus (TRP) retention. Despite eutrophic conditions in the wetland, the redox potential was never negative, and usually higher than 400 mV, indicating aerobic conditions. The relative retention was 440% and 43% for TP and TRP, respectively. The specific retention was 100 g TP and 43 g TRPm(-2) yr(-1). Loss of phosphorus was only observed during less than 19% of the total period of time. The net loss was less than 5% of the specific retention. The high positive redox potential probably conserves the redox-sensitive phosphorus in the wetland sediment as long as water fows through the CW.     

人工湿地处理污水机理及效率比较

介绍国内外人工湿地处理技术的研究现状及人工湿地对有机物、氮、磷等的去除机理及效率,分析了人工湿地处理技术存在的不足.提出人工湿地污水处理系统作为一种高效、节能、低投资、运行费用低、操作简单的污水处理技术在我国尤其是中小城镇及广大农村具有应用前景.