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超低碳钢钢中夹杂物的研究 总被引:1,自引:0,他引:1
为控制超低碳钢中的簇状夹杂物,对超低碳钢中的夹杂物和与全氧含量的关系进行了研究.钢中的夹杂物主要是Al2O3夹杂和Al2O3-TiN复合夹杂,独立夹杂物尺寸大部分小于10 μm.铸坯中w(TO)小于0.003 0%时,钢中仍存在簇状Al2O3夹杂;Al2O3簇状夹杂物与铸坯中全氧含量没有直接关系,所以钢中的全氧含量不能完全代表钢中夹杂物的水平.钢中的簇状Al2O3夹杂物与RH脱碳结束活度氧有关,要控制超低碳钢中簇状Al2O3夹杂物必须稳定生产工艺,减少RH加铝升温,使RH脱碳结束活度氧保持在一定范围. 相似文献
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超低碳钢夹杂物控制技术探讨 总被引:2,自引:0,他引:2
本文综述了超低碳钢的夹杂物起源,并以日本等先进钢厂的实践经验为基础,对Al2O3夹杂物的产生的工艺过程、影响因素重点进行了讨论,包括渣钢间二次氧化行为、RH处理中夹杂物行为、夹杂物的上浮行为以及铸坯的皮下气泡等.钢包渣改质是控制二次氧化的重要手段,RH加铝前自由氧含量尽可能降低,将浇铸时的氩气量降低均为控制超低碳钢的Al2O3类夹杂物的有效措施. 相似文献
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对某厂BOF-RH-CC生产的超低碳钢头坯夹杂物变化规律进行研究,结果表明:头坯中T[O]和氮含量均随着浇铸长度的增加呈明显的下降趋势;头坯中显微夹杂物数量和大型夹杂物数量随着浇铸长度的增加大体都呈减少趋势;头坯中显微夹杂物主要为:Al2O3、TiN和A12O3-TiN复合夹杂物;大型夹杂物的来源主要为:TiN、SiO2、Al2O3、含K的铝硅酸盐和Na的钙铝硅酸盐复合夹杂物;与正常坯相比较,头坯夹杂物数量在浇铸长度为3.5m以后与正常坯水平相一致. 相似文献
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硼对低碳钢晶粒尺寸的影响 总被引:3,自引:0,他引:3
研究了硼对低碳钢晶粒尺寸的影响,结果表明:低碳钢中酸溶硼([B]s)的质量分数大于0.005%时,随酸溶硼的质量分数增加,铁素体晶粒尺寸明显变大.主要原因为硼的加入使钢的奥氏体晶粒增大,从而使铁素体晶粒尺寸变大;硼的加入抑制铁素体形核并降低相变开始的实际温度,孕育期变长,从而使铁素体晶粒尺寸变大.冷却速度为0.5~5℃/s,随冷却速度加快,晶粒尺寸明显减小;冷却速度为5~15℃/s,晶粒尺寸的变化不大.冷却速度大于5℃/s时,含硼低碳钢明显出现贝氏体,因此热轧后盘条的冷却速度最好控制在5℃/s以下. 相似文献
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对某厂BOF-RH-CC生产的超低碳钢头坯夹杂物变化规律进行研究,结果表明:头坯中T[O]和氮含量均随着浇铸长度的增加呈明显的下降趋势;头坯中显微夹杂物数量和大型夹杂物数量随着浇铸长度的增加大体都呈减少趋势;头坯中显微夹杂物主要为:Al2O3、TiN和Al2O3-TiN复合夹杂物;大型夹杂物的来源主要为:TiN、SiO2、Al2O3、含K的铝硅酸盐和Na的钙铝硅酸盐复合夹杂物;与正常坯相比较,头坯夹杂物数量在浇铸长度为3.5 m以后与正常坯水平相一致。 相似文献
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针对高拉速板坯连铸生产的低碳铝镇静钢铸坯,采用Aspex自动扫描电镜对铸坯表层夹杂物进行大面积的扫描分析,得到不同拉速下夹杂物的变化规律,并探究流场和S含量对夹杂物分布的影响.结果表明:随着拉速增大,钩状坯壳的深度和长度逐渐减小.对拉速大于2 m·min-1的铸坯,由于钩状坯壳不是很发达,铸坯表层没有发现大于200μm的夹杂物.铸坯表层尺寸介于50~200μm的夹杂物主要是由凝固坯壳所捕获,而夹杂物在凝固前沿的受力决定了夹杂物的捕获行为.随着拉速提高,凝固前沿的钢液流速增加,随着冲刷力的增加、捕获力的减少,夹杂物被捕获的数量减少.在高拉速连铸下,如果钢液中S含量较大,夹杂物受到明显的温度Marangoni力,会更容易被凝固坯壳捕获. 相似文献
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B2O3 was added to tire cord steel during refining in a carbon tube furnace.The influence of boron on the deformability of oxide inclusions was studied by metallographic and scanning electron microscope(SEM) observations.The melting points of boron-bearing compound oxide inclusions were calculated using Factsage software.The results showed that the main inclusion was a boron-bearing compound oxide and the deformation properties of the inclusions were clearly improved by adding B2O3.As the boron content was increased from 0.0046% to 0.039%,the proportion of long strip type inclusions changed slightly and the number of inclusions decreased.The low-melting point areas of the MnO-SiO2-Al2O3 and CaO-SiO2-Al2O3 ternary system increased with the addition of B2O3.Moreover,the area increased with the increase of B2O3 content.Clear improvements in the deformation ability of the inclusions occurred when the B2O3 mass percent rose to 5% in the CaO-SiO2-Al2O3 inclusion system and to 10% in the MnO-SiO2-Al2O3 inclusion system 相似文献
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Effect of Mg Addition on Nucleation of Intra-granular Acicular Ferrite in Al-killed Low Carbon Steel
《钢铁研究学报(英文版)》2016,(5):415-421
To verify the formation behaviors and mechanisms of intra-granular acicular ferrite( IAF) grains nucleated by Mg-Al-O in low carbon steel,the steels containing different Mg contents were refined in a vacuum induction furnace. The effect of Mg addition on the formation of IAF structure in Al-killed low carbon steel was investigated by optical microscope( OM) and scanning electron microscope with energy dispersive X-ray spectroscope( SEM-EDX). It reveals that the IAFs are only detected in Mg-added steels,and the volume fraction of IAF increases with the Mg concentration from 8 × 10~(-6) to 26 × 10~(-6). It shows that not only the MgO-Al_2O_3-MnS and MgO-Al_2O_3-P_2O_5 particles are the effective nucleation sites for IAF,but also the pure MgO·Al_2O_3 phase can promote the ferrite nucleation. A Mn-depletion zone( MDZ) is characterized adjacent to the MgO-Al_2O_3-MnS,which is believed to be one of the possible mechanisms to explain the IAF nucleation. The MDZ around the MgO-Al_2O_3-MnS inclusion would be induced by the Mn S precipitation on the inclusion. It seems that the ability of Mg-containing inclusions to induce the nucleation of ferrite might be attributed to a new mechanism,i. e.,the Prich zone formed on a few Mg-Al-O inclusions might be another factor for promoting the IAF formation. 相似文献