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1.
Lipase-catalyzed interesterification was used to prepare different structured lipids (SL) from rice bran oil (RBO) by replacing
some of the fatty acids with α-linolenic acid (ALA) from linseed oil (LSO) and n-3 long chain polyunsaturated fatty acids
(PUFA) from cod liver oil (CLO). In one SL, the ALA content was 20% whereas in another the long chain n-3 PUFA content was
10%. Most of the n-3 PUFA were incorporated into the sn-1 and sn-3 positions of triacylglycerol. The influence of SL with RBO rich in ALA and EPA + DHA was studied on various lipid parameters
in experimental animals. Rats fed RBO showed a decrease in total serum cholesterol by 10% when compared to groundnut oil (GNO).
Similarly structured lipids with CLO and LSO significantly decreased total serum cholesterol by 19 and 22% respectively compared
to rice bran oil. The serum TAGs level of rats fed SLs and blended oils were also significantly decreased by 14 and 17% respectively
compared to RBO. Feeding of an n-3 PUFA rich diet resulted in the accumulation of long chain n-3 PUFA in various tissues and
a reduction in the long chain n-6 PUFA. These studies indicate that the incorporation of ALA and EPA + DHA into RBO can offer
health benefits. 相似文献
2.
Enzymatic extraction of mustard seed and rice bran 总被引:15,自引:0,他引:15
Aqueous enzymatic extraction was investigated for recovery of oil from mustard seed and rice bran. The extraction process
was reproducible based on statistical analysis of extraction data under different extraction conditions. The most significant
factors for extraction were the time of digestion with enzymes, seed or bran concentration in water, volume of hexane added
before recovery, and amount of enzyme(s) used. The pretreatment steps of each material before enzyme digestion influenced
oil yield.
Quality of enzyme-extracted mustard oil was better with respect to color and odor than commercial expeller-extracted and Soxhlet-extracted
oils. Most of the characteristics of rice bran oil were identical to those of commercial solvent-extracted oils, but rice
bran oil had a lower content of colored substances and higher acidity (free fatty acid). Enzymatic extraction led to recovery
of a protein concentrate with increased protein and reduced fiber and ash contents in the mustard and rice bran meals. 相似文献
3.
Fatty Acid Composition,Oxidative Stability,and Radical Scavenging Activity of Vegetable Oil Blends with Coconut Oil 总被引:1,自引:1,他引:0
A. S. Bhatnagar P. K. Prasanth Kumar J. Hemavathy A. G. Gopala Krishna 《Journal of the American Oil Chemists' Society》2009,86(10):991-999
Coconut (Cocos nucifera) contains 55–65% oil, having C12:0 as the major fatty acid. Coconut oil has >90% saturates and is deficient in monounsaturates
(6%), polyunsaturates (1%), and total tocopherols (29 mg/kg). However, coconut oil contains medium chain fatty acids (58%),
which are easily absorbed into the body. Therefore, blends of coconut oil (20–80% incorporation of coconut oil) with other
vegetable oils (i.e. palm, rice bran, sesame, mustard, sunflower, groundnut, safflower, and soybean) were prepared. Consequently,
seven blends prepared for coconut oil consumers contained improved amounts of monounsaturates (8–36%, p < 0.03), polyunsaturates (4–35%, p < 0.03), total tocopherols (111–582 mg/kg, p < 0.02), and 5–33% (p < 0.02) of DPPH (2,2-diphenyl-1-picrylhydrazyl free radicals) scavenging activity. In addition, seven blends prepared for
non-coconut oil consumers contained 11–13% of medium chain fatty acids. Coconut oil + sunflower oil and coconut oil + rice
bran oil blends also exhibited 36.7–89.7% (p < 0.0005) and 66.4–80.5% (p < 0.0313) reductions in peroxide formation in comparison to the individual sunflower oil and rice bran oil, respectively.
It was concluded that blending coconut oil with other vegetable oils provides medium chain fatty acids and oxidative stability
to the blends, while coconut oil will be enriched with polyunsaturates, monounsaturates, natural antioxidants, and a greater
radical scavenging activity. 相似文献
4.
A. L. Amrutha Kala 《Journal of the American Oil Chemists' Society》2012,89(10):1813-1821
The fatty acid composition of 27 samples of commercial hydrogenated vegetable oils and 23 samples of refined oils such as sunflower oil, rice bran oil, soybean oil and RBD palmolein marketed in India were analyzed. Total cis, trans unsaturated fatty acids (TFA) and saturated fatty acids (SFA) were determined. Out of the 27 hydrogenated fats, 11 % had TFA about 1 % where as 11 % had more than 5 % TFA with an average value of about 13.1 %. The 18:1 trans isomers, elaidic acid was the major trans contributor found to have an average value of about 10.8 % among the fats. The unsaturated fatty acids like cis-oleic acid, linoleic acid and α-linolenic acid were in the range of 21.8–40.2, 1.9–12.2, 0.0–0.7 % respectively. Out of the samples, eight fats had fatty acid profiles of low TFA (less than 10 %) and high polyunsaturated fatty acids (PUFA) such as linoleic and α-linolenic acid. They had a maximum TFA content of 7.3 % and PUFA of 11.7 %. Among the samples of refined oils, rice bran oil (5.8 %) and sunflower oil (4.4 %) had the maximum TFA content. RBD palmolein and rice bran oils had maximum saturated fatty acids content of 45.1 and 24.4 % respectively. RBD palmolein had a high monounsaturated fatty acids (MUFA) content of about 43.4 %, sunflower oil had a high linoleic acid content of about 56.1 % and soybean oil had a high α-linolenic acid content of about 5.3 %. 相似文献
5.
Chao‐Chin Lai Siti Zullaikah Shaik Ramjan Vali Yi‐Hsu Ju 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(3):331-337
Biodiesel has attracted considerable attention as an alternative fuel during the past decades. The main hurdle to the commercialization of biodiesel is the cost of the raw material. Use of an inexpensive raw material such as rice bran oil is an attractive option to lower the cost of biodiesel. Two commercially available immobilized lipases, Novozym 435 and IM 60, were employed as catalyst for the reaction of rice bran oil and methanol. Novozym 435 was found to be more effective in catalyzing the methanolysis of rice bran oil. Methanolysis of refined rice bran oil and fatty acids (derived from rice bran oil) catalyzed by Novozym 435 (5% based on oil weight) can reach a conversion of over 98% in 6 h and 1 h, respectively. Methanolysis of rice bran oil with a free fatty acid content higher than 18% resulted in lower conversions (<68%). A two‐step lipase‐catalyzed methanolysis of rice bran oil was developed for the efficient conversion of both free fatty acid and acylglycerides into fatty acid methyl ester. More than 98% conversion can be obtained in 4–6 h depending on the relative proportion of free fatty acid and acylglycerides in the rice bran oil. Inactivation of lipase by phospholipids and other minor components was observed during the methanolysis of crude rice bran oil. Simultaneous dewaxing/degumming proved to be efficient in removing phospholipids and other minor components that inhibit lipase activity from crude rice bran oil. Copyright © 2005 Society of Chemical Industry 相似文献
6.
Yasushi Endo Chieko Hayashi Takashi Yamanaka Koichi Takayose Miki Yamaoka Takuo Tsuno Shigeo Nakajima 《Journal of the American Oil Chemists' Society》2013,90(7):959-964
Acrolein, which is an irritating and off-flavor compound formed during heating of vegetable oils, was estimated by the gas–liquid chromatography (GLC). Several vegetable oils such as high-oleic sunflower, perilla, rapeseed, rice bran, and soybean oils were heated at 180 °C for 480 min and then the concentration of acrolein in the head space gas was determined by GLC. The formation of acrolein was greatest in perilla oil among the tested oils, while it was much lower in rice bran oil and high-oleic sunflower oil. There was a good correlation between the level of acrolein and linolenate (18:3n-3) in the vegetable oils. To investigate the formation of acrolein from linolenate, methyl oleate, methyl linoleate, and methyl linolenate were also heated at 180 °C, and the amounts of acrolein formed from them were determined by GLC. The level of acrolein was the greatest in methyl linolenate. Acrolein was also formed from methyl linoleate, but not from methyl oleate. Acrolein in vegetable oils may be formed from polyunsaturated fatty acids, especially linolenic acid but not from glycerol backbone in triacylglycerols. 相似文献
7.
Fatty acid distillates (FADs) produced during physical refining of vegetable oil contains large amount of free fatty acid. A mutant of Candida tropicalis (M20) obtained after several stages of UV mutation are utilized to produce dicarboxylic acids (DCAs) from the fatty acid distillates of rice bran, soybean, coconut, palm kernel and palm oil. Initially, fermentation study was carried out in shake flasks for 144 h. Products were isolated and identified by GLC analysis. Finally, fermentation was carried out in a 2 L jar fermenter, which yielded 62 g/L and 48 g/L of total dibasic acids from rice bran oil fatty acid distillate and coconut oil fatty acid distillate respectively. FADs can be effectively utilized to produce DCAs of various chain lengths by biooxidation process. 相似文献
8.
B. Sreenivasan 《Journal of the American Oil Chemists' Society》1968,45(4):259-265
Nineteen different samples of oils and fats have been examined for their component acids and composition by gas-liquid chromatography.
Under programmed-temperature operations, the temperatures at which different components start to elute bear a straight-line
relationship with their respective carbon numbers. Chromatograms, under programmed-temperature conditions, of methyl esters
from such oils as coconut, groundnut, mustard, etc., are used for identifying the components of an unknown oil by comparing
its chromatogram taken under nearly identical conditions. For confirmatory identifications, such plots as logarithm of retention
times versus carbon numbers for saturated acids (14:0 to 24:0), monoenoic acids (14:1 to 24:1), and dienoic acids (18:2 to
24:2), under isothermal conditions, have also been used. Some new fatty acids, noted for the first time in traditional oils,
are 15:0 in cottonseed oil, 20:1 in sesame oil, 22:0 in soybean oil, and 24:2 in mustard oil. Odd-carbon chain acids from
11∶0 to 23:0 have been observed in such vegetable oils as peanut germ, rice bran, andMesua ferrea. Fatty acid composition by GLC for new samples like peanut lecithin, peanut germ oil,Myristica attenuata, Myristica kanarica, Myristica magnifica, Mesua ferrea, Vateria indica, Schleichera trijuga, and shark-liver stearine are presented. Industrial utilization of these new oils and fats is discussed. 相似文献
9.
Production of structured lipids by lipase-catalyzed interesterification in a flat membrane reactor 总被引:2,自引:0,他引:2
X. Xu S. Balchen G. Jonsson J. Adler-Nissen 《Journal of the American Oil Chemists' Society》2000,77(10):1035-1041
The application of membrane technology to the enzymatic production of specific structured lipids has been investigated in
this work. Membrane screening was carried out in a membrane diffusion cell. Twenty-six flat membranes of different materials
were tested using rapeseed oil and capric acid. The suitable membranes were selected in terms of higher fatty acid and lower
rapeseed oil permeation rates. The stability of membranes and the effect of fatly acid chain length on effluent fluxes were
also investigated. Reaction experiments were carried out in a membrane reactor between medium-chain triacylglycerols and n−3
polyunsaturated fatty acids (PUFA) from fish oil. Lipozyme IM was used as the biocatalyst. The incorporation of PUFA into
medium-chain triacylglycerols was increased by about 15% in a PUFA 90-h reaction by simultaneous separation of the released
medium-chain fatty acids, compared to no separation under the same reaction conditions. It has thus clearly been demonstrated
that membrane-assisted separation improved the incorporation of acyl donors into oils beyond the reaction equilibrium defined
by the original substrate concentration. 相似文献
10.
Hiromi Yoshida Mikiko Tatsumi Goro Kajimoto 《Journal of the American Oil Chemists' Society》1992,69(2):119-125
Effects of 0, 0.05, 0.25, 0.50 and 1.0% levels of fatty acids (caproic, caprylic, capric and lauric) or hydrocarbons (decane
and dodecane) on tocopherol stability in vegetable oils during microwave heating were determined by measuring tocopherol losses
and carbonyl and anisidine values. The fatty acids showed similar prooxidant activities toward tocopherols in purified vegetable,
oils when heated in a microwave oven. However, decane or dodecane, which had the same number of carbons as capric or lauric
acid but no carboxylic group, did not show prooxidant activity. The shorter the chainlength and the higher the level of fatty
acids, the greater was the reduction of tocopherols in the oils. The addition of low-molecular weight fatty acids resulted
in greater acceleration in the oxidation of to pay attention to these free fatty acids produced in the oils when heated in
a microwave oven. 相似文献
11.
Comprehensive Two‐Dimensional Gas Chromatography–Mass Spectrometry Analysis of Different Types of Vegetable Oils
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Olga Vyviurska Nikoleta Jánošková Tibor Jakubík Ivan Špánik 《Journal of the American Oil Chemists' Society》2015,92(6):783-790
Comprehensive two‐dimensional gas chromatography coupled with time‐of‐flight mass spectrometry (GC×GC‐TOFMS) was applied for detailed characterization of fatty acid profile of 8 vegetable oils. Due to enhanced selectivity and sensitivity characteristics, the GC×GC method yielded more reliable quantification results compared to one dimensional gas chromatography, especially for medium‐chain fatty acids and odd‐carbon number fatty acids, which are present only at trace level. All problematic positional counterparts of unsaturated fatty acids (e.g. C21:0–C20:3 ω6, C20:3ω3–C20:4 ω6 and C20:5 ω3–C22:0), which commonly coeluted in the case of 1D gas chromatography, were baseline resolved. The specific compounds were found for particular vegetable oils, such as γ‐linolenic acid for hempseed oil, heneicosylic acid and tricosylic acid for olive pomace oil, and nervonic acid for mustard oil. 相似文献
12.
Preparation of Infant Formula Fat Analog Containing Capric Acid and Enriched with DHA and ARA at the sn-2 Position
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An infant formula fat analog with capric acid mostly esterified at the sn‐1,3 positions, and substantial amounts of palmitic, docosahexaenoic (DHA), and arachidonic (ARA) acids at the sn‐2 position, was prepared by physically blending enzymatically synthesized structured lipids (SL) with vegetable oils. The components of the blend included high sn‐2 palmitic acid SL enriched with capric acid (SLCA), canola oil (CAO), corn oil (CO), high sn‐2 DHA (DHAOm), and high sn‐2 ARA (ARAOm) enzymatically modified oils. Each component was proportionally blended to match the fatty acid profile of commercial fat blends used for infant formula. The infant formula fat analog (IFFA1) was characterized for total and positional fatty acids (FA), triacylglycerol (TAG) molecular species, thermal behavior, and tocopherol content. IFFA1 contained 17.37 mol% total palmitic acid of which nearly 35 % was located at the sn‐2 position. The total capric acid content was 13.93 mol%. The content of DHA and ARA were 0.49 mol% (48.18 % at sn‐2) and 0.57 mol% (35.80 % at sn‐2), respectively. The predominant TAG were OPO (24.09 %), POP (15.70 %), OOO (11.53 %), and CLC (7.79 %). The melting completion and crystallization onset temperatures were 18.65 and ?2.19 °C, respectively. The total tocopherol content was 566.45 μg/g. This product might be suitable for commercial production of infant formulas. 相似文献
13.
Lutein and zeaxanthin are selectively accumulated in the macula of the retina, yet their bioavailability is influenced by
various dietary factors. Insights regarding the effects of dietary lipids on lutein micellization that is available for absorption
are limited. This study investigated the influence of vegetable oils on the relative efficiency of lutein micellization using
in vitro digestion procedure. Lutein dispersed in either olive oil (OO), corn oil (CO), soybean oil (SBO), sunflower oil (SFO),
groundnut oil (GNO), rice bran oil (RBO) or palm oil (PO) was subjected to simulated gastric and small intestinal digestion.
Results showed that the efficiency of micellization of lutein dispersed in olive oil exceeds the other vegetable oils. The
percent lutein micellization was in the order of OO > GNO > RBO > SFO > CO > SBO > PO. In comparison, the values for OO were
higher than GNO (11%), RBO (18.3%), SFO (19%), CO (21.7%), SBO (30.5%) and PO (35.2%), respectively. These results suggest
that OO rich in oleic acid may favor the incorporation of lutein into micelles at the intestinal level. To conclude, the type
of vegetable oil in which carotenoids are dispersed is important to achieve an enhanced bioavailable lutein. The correlation
between the micellizable lutein and fatty acid composition of vegetable oils are discussed. 相似文献
14.
Neel Chandrasekara Fereidoon Shahidi 《Journal of the American Oil Chemists' Society》2011,88(8):1197-1202
Cashew nut oils, extracted from raw and roasted whole cashew nuts, were examined for their fatty acid composition, color change
and oxidative stability. Fatty acids were analyzed using gas chromatography, and a spectrophotometric method was used to determine
the color changes of the resultant oils. Oxidative stability was determined under accelerated oxidation conditions by employing
conjugated diene (CD) and thiobarbituric acid reactive substances (TBARS) assays. The contents of monounsaturated (MUFA),
polyunsaturated (PUFA) and saturated (SAFA) fatty acids were 61, 17 and 21%, respectively. Oleic acid was the major MUFA whereas
linoleic acid was the main PUFA present in cashew nut oils. Oxidative stability of the oil as determined by CD values after
72 h of storage under Schall oven condition at 60 °C was 1.08 and 0.65 for the raw and high temperature roasted cashew nut,
respectively. The TBARS values, expressed as malondialdehyde equivalents decreased with increasing roasting temperature. Thus
roasting of whole cashew nuts improved the oxidative stability of the resultant nut oils. 相似文献
15.
Microbial lipase-catalyzed hydrolysis, esterification, and alcoholysis reactions were carried out on acid oils of commerce
such as coconut, soybean, mustard, sunflower, and rice bran for the purpose of making fatty acids and various monohydric alcohol
esters of fatty acids of the acid oils. Neutral glycerides of the acid oils were hydrolyzed byCanadida cylindracea lipase almost completely within 48 h. Acid oils were converted into fatty acid esters of short- and long-chain alcohols like
C4, C8, C10, C12, C16, and C18 in high yields by simultaneous esterification and alcoholysis reactions withMucor miehei lipase as catalyst. Acid oils of commerce can be utilized as raw materials in making fatty acids and fatty acid esters using
lipase-catalyzed methodologies. 相似文献
16.
Rajni Chopra Sunki Reddy Yella Reddy Kari Sambaiah 《European Journal of Lipid Science and Technology》2008,110(1):32-39
The major objective of the present study was to prepare structured lipids rich in stearic acid from rice bran oil (RBO) using immobilized lipase (IM 60) from Rhizomucor miehei. The effects of incubation time and temperature, substrate molar ratio, and enzyme load on incorporation of stearic acid were studied. Acidolysis reactions were performed in hexane. Pancreatic lipase‐catalyzed sn‐2 positional analysis and tocopherol analyses were performed before and after enzymatic modification. The kinetics of the reaction was studied and maximum incorporation of stearic acid was observed at 6 h, at 37 °C, when the triacylglycerol and stearic acid molar ratio was maintained at 1 : 6 and the enzyme concentration was 10% of total substrates weight. Stearic acid in RBO after acidolysis was increased from 2.28 to 48.5%, with a simultaneous decrease in palmitic, oleic and linoleic acids. HPLC analysis of tocopherols and tocotrienols was carried out and their content in modified RBO was not significantly affected compared to that of native RBO. The oryzanol content of the modified RBO was reduced from 1.02 to 0.68%. Melting and crystallizing characteristics of the modified fat were studied using differential scanning calorimetry. The total solid fat content at 25 °C increased from 26.12 to 34.8% with an increase in stearic acid incorporation into RBO from 38 to 48%, but it was comparatively less than for cocoa butter and vanaspati. However, the modified RBO completely melted at 37 °C and was useful as plastic fat for various culinary purposes, bakery and confectionary applications. The results of the present study indicated that structured lipids prepared from RBO rich in stearic acid retained their beneficial nutraceuticals; in addition, they do not contain any trans fatty acids. 相似文献
17.
Refined, bleached, and deodorized soybean oil and vanaspati (partially hydrogenated vegetable oil blend consisting of peanut,
cottonseed, nigerseed, palm, rapeseed, mustard, rice bran, soybean, sunflower, corn, safflower, sesame oil, etc., in varying
proportions) were used for deep-fat frying potato chips at 170, 180, and 190°C. Refractive index, specific gravity, color,
viscosity, saponification value, and free fatty acids of soybean oil increased with frying temperature, whereas the iodine
value decreased. The same trend was observed in vanaspati, but less markedly than in soybean oil, indicating a lesser degree
of deterioration. Iodine values of soybean oil and vanaspati decreased from their initial values of 129.8 and 74.7 to 96.2
and 59.6, respectively, after 70 h of frying. Polyunsaturated fatty acids decreased in direct proportion to frying time and
temperature. Losses were highest in soybean oil with a 79% decrease in trienoic acids and a 60% decrease in dienoic acids.
Levels of nonurea adduct-forming esters were proportional to the losses of unsaturated fatty acids. Butylated hydroxyanisole
and tertiary butylhydroquinone did not affect deterioration of soybean oil at frying temperatures. 相似文献
18.
Application of principal-component analysis on near-infrared spectroscopic data of vegetable oils for their classification 总被引:3,自引:0,他引:3
Tetsuo Sato 《Journal of the American Oil Chemists' Society》1994,71(3):293-298
In the near-infrared (NIR) spectra of oil, information about fatty acid composition is concentrated in the range of 1600–2200
nm. Principal-component analysis (PCA) was applied on the standardized full NIR spectral data of this region for vegetable
oils to totally capture the NIR spectral pattern. Nine varieties of vegetable oils (soybean, corn, cottonseed, olive, rice
bran, peanut, rapeseed, sesame and coconut oil) could be successfully classified from their PCA scores. Examining the contribution
of wavelengths to PCA scores showed that wavelengths with a high loading weight were assigned to characteristic absorption
regions that correspond to specific fatty acid moieties. This classification is related to the fatty acid composition of an
oil, and it can be carried out rapidly and easily after eigenvectors were obtained. 相似文献
19.
Crude rice bran oil was dewaxed by chilling to 17°C, followed by centrifuging. The wax sludge obtained was 68% free fatty
acids and 32% waxes, whereas the oil phase was 65.65% fatty acids and 34.35% glycerides. The dewaxed oil was evaluated as
an antifoaming agent for aqueous media and compared to commercial oleic acid. It was thought that dewaxed rice bran oil has
an antifoaming power greater than oleic acid, especially when used in small proportions.
Dewaxed rice bran oil was also applied to break and control the foam formation in a phosphoric acid production unit. 相似文献
20.
Chandhapuram Mounika Sunki Yella Reddy 《Journal of the American Oil Chemists' Society》2012,89(9):1691-1697
Structured lipids containing behenic and medium chain (MC) fatty acids were prepared from palm stearin using 1,3-specific lipase-catalyzed acidolysis. Incorporation of MC and behenic acids was affected by proportion of substrate, type of fatty acids, reaction time, addition of water and quantity of lipase. It was found that incorporation of caproic acid was less compared to other longer chain fatty acids. Caprylic, capric and behenic acids shared similar incorporation (up to 32 %), which increased with the amount of fatty acids added and the time of reaction. The incorporation of these acids increased with addition of 1 % moisture and the increasing amount of enzyme from 5 to 10 % at the beginning of the reaction. Incorporating behenic and MC fatty acids, reduced palmitic and oleic acids considerably from palm stearin, the extent being the same as those incorporated. However, the reduction of linoleic acid was marginal. The solid fats content of the modified palm stearin containing MC and behenic acids were reduced at all temperatures due to a reduction in higher molecular weight triglycerides and an increasing proportion of lower chain triglycerides. The modified products of palm stearin with added capric and behenic acids were similar to commercial bakery shortenings and those with added capric acid were like salad or cooking oils or butter in melting characteristics. 相似文献