Correlation of flip chip underfill process parameters and materialproperties with in-process stress generation

Electronic packaging designs are moving toward fewer levels of packaging to enable miniaturization and to increase performance of electronic products. One such package design is flip chip on board (FCOB). In this method, the chip is attached face down directly to a printed wiring board (PWB). Since the package is comprised of dissimilar materials, the mechanical integrity of the flip chip during assembly and operation becomes an issue due to the coefficient of thermal expansion (CTE) mismatch between the chip, PWB, and interconnect materials. To overcome this problem, a rigid encapsulant (underfill) is introduced between the chip and the substrate. This reduces the effective CTE mismatch and reduces the effective stresses experienced by the solder interconnects. The presence of the underfill significantly improves long term reliability. The underfill material, however, does introduce a high level of mechanical stress in the silicon die. The stress in the assembly is a function of the assembly process, the underfill material, and the underfill cure process. Therefore, selection and processing of underfill material is critical to achieving the desired performance and reliability. The effect of underfill material on the mechanical stress induced in a flip chip assembly during cure was presented in previous publications. This paper studies the effect of the cure parameters on a selected commercial underfill and correlates these properties with the stress induced in flip chip assemblies during processing     

Effect of Hygrothermal Aging on Interfacial Reliability of Silicon/Underfill/FR-4 Assembly

The reliability issues have been converted to the underfill adjacent interfaces since the introduction of the underfill to flip chip package in 1990's. Both thermal cycling and hygrothermal conditioning severely attack the interfaces to de- laminate. The moisture migrating into the underfill decreases the adhesion strength, swells to deform the assembly, and weakens the mechanical and thermal properties of the material. In this study, interfacial reliability of a silicon/underfill/FR-4 assembly exposed at 85degC/85%RH was studied using moire interferometry and micro-digital image speckle correlation (mu-DiSC) techniques. A thermal aging study was simultaneously performed to understand the long-term reliability of the assembly. The results showed that the thermal aging relieved the stresses induced by hygrothermal swelling mismatch between dissimilar materials involved, whereas increased the strains induced by hygrothermal swelling. It indicated the time effect is not negligible when the assembly is subjected to the moisture conditioning, otherwise, the deformation induced by the swelling could be overestimated. The mu-DiSC technique was applied to measure the critical interfacial fracture toughness of the silicon/underfill interface. The results showed that the moisture could significantly reduce the interfacial strength due to the break of hydrogen bonding. By combining the moire and mu-DiSC results, it was concluded that the hygrothermal loading could increase the possibility of interfacial delamination in a flip chip package. Finally, the morphologies of the fractured surface were studied with the aid of scanning electron microscope. Remarkable changes of the failure mode were observed.     

Highly reliable non-conductive adhesives for flip chip CSP applications

Non-conductive adhesives (NCA), widely used in display packaging and fine pitch flip chip packaging technology, have been recommended as one of the most suitable interconnection materials for flip-chip chip size packages (CSPs) due to the advantages such as easier processing, good electrical performance, lower cost, and low temperature processing. Flip chip assembly using modified NCA materials with material property optimization such as CTEs and modulus by loading optimized content of nonconductive fillers for the good electrical, mechanical and reliability characteristics, can enable wide application of NCA materials for fine pitch first level interconnection in the flip chip CSP applications. In this paper, we have developed film type NCA materials for flip chip assembly on organic substrates. NCAs are generally mixture of epoxy polymer resin without any fillers, and have high CTE values un-like conventional underfill materials used to enhance thermal cycling reliability of solder flip chip assembly on organic boards. In order to reduce thermal and mechanical stress and strain induced by CTE mismatch between a chip and organic substrate, the CTE of NCAs was optimized by filler content. The flip chip CSP assembly using modified NCA showed high reliability in various environmental tests, such as thermal cycling test (-55/spl deg/C/+160/spl deg/C, 1000 cycle), high temperature humidity test (85/spl deg/C/85%RH, 1000 h) and high temperature storage test (125/spl deg/C, dry condition). The material properties of NCA such as the curing profile, the thermal expansion, the storage modulus and adhesion were also investigated as a function of filler content.     

Do chip size limits exist for DCA?

Solder joints, the most widely used flip chip on board (FCOB) interconnects, have a relatively low structural compliance due to the large thermal expansion mismatch between silicon die and the organic substrate. The coefficient of thermal expansion (CTE) of the printed wiring board (PWB) is almost an order of magnitude greater than that of the integrated circuit (IC). Under operating and testing conditions, this mismatch subjects the solder joints to large creep strains and leads to early failure of the solder connections. The reliability of such flip chip structures can be enhanced by applying an epoxy-based underfill between the chip and the substrate, encapsulating the solder joints. This material, once cured, mechanically couples the IC and substrate together to locally constrain the CTE mismatch. However, the effects of CTE mismatch are assumed to become more severe with increasing chip size. Even with the addition of an underfill material, it has been supposed that there are limits on the chip size used in flip chip applications     

Effects of underfill material properties on the reliability ofsolder bumped flip chip on board with imperfect underfill encapsulants

Three different types of underfill imperfections were considered; i.e., (1) interfacial delamination between the underfill encapsulant and the solder mask on the PCB (crack initiated at the tip of underfill fillet), (2) interfacial delamination between the chip and the underfill encapsulant (crack initiated at the chip corner), and (3) the same as (2) but without the underfill fillet. Five different combinations of coefficient of thermal expansion (CTE) and Young's modulus with the aforementioned delaminations were investigated. A fracture mechanics approach was employed for computational analysis. The strain energy release rate at the crack tip and the maximum accumulated equivalent plastic strain in the solder bumps of all cases were evaluated as indices of reliability. Besides, mechanical shear tests were performed to characterize the shear strength at the underfill-solder mask interface and the underfill-chip passivation interface. The main objective of the present study is to achieve a better understanding in the thermo-mechanical behavior of flip chip on board (FCOB) assemblies with imperfect underfill encapsulants     

Determination of Fracture Toughness of Underfill/Chip Interface With Digital Image Speckle Correlation Technique

The layered packages are prone to multimode damages and failures when they are subjected to complicated and coupling environmental loading. As a result, fracture toughness is usually used as a fracture criterion to evaluate the reliability of polymer/inorganic interface. In this study, an in-situ/real-time micro-digital image speckle correlation (mu-DiSC) system was established and employed to determine the fracture toughness of underfill/chip interface involved in flip chip assembly. The tests were carried out over a wide range of temperatures and at various loading angles. In order to verify the finding of the mu-DiSC technique, an interface fracture mechanics based finite element model is implemented into ANSYS to calculate the values of crack-tip opening displacement of underfill/chip joint under different loading configurations. The results obtained from the simulation are found to be in good agreement with those measured by the mu-DiSC system, indicating that the system can be used as an accurate and effective experimental tool for the electronic packages. The fractographs, with respect to different temperatures and loading angles, are further discussed     

Parametric reliability analysis of no-underfill flip chip package

This research proposes a parametric analysis for a flip chip package with a constraint-layer structure. Previous research has shown that flip-chip type packages with organic substrates require underfill for achieving adequate reliability life. Although underfill encapsulant is needed to improve the reliability of flip chip solder joint interconnects, it will also increase the difficulty of reworkability, increase the packaging cost and decrease the manufacturing throughput. This research is based on the fact that if the thermal mismatch between the silicon die and the organic substrate could be minimized, then the reliability of the solder joint could be accordingly enhanced. This research proposes a structure using a ceramic-like material with CTE close to silicon, mounted on the backside of the substrate to constrain the thermal expansion of the organic substrate. The ceramic-like material could reduce the thermal mismatch between silicon die and substrate, thereby enhancing the reliability life of the solder joint. Furthermore, in order to achieve better reliability design of this flip chip package, a parametric analysis using finite element analysis is performed for package design. The design parameters of the flip chip package include die size, substrate size/material, and constraint-layer size/material, etc. The results show that this constraint-layer structure could make the solder joints of the package achieve the same range of reliability as the conventional underfill material. More importantly, the flip chip package without underfill material could easily solve the reworkability problem, enhance the thermal dissipation capability and also improve the manufacturing throughput     

Measurement of underfill interfacial and bulk fracture toughness in flip-chip packages

Flip-chip package reliability is greatly improved by encapsulating the solder interconnections between a polymeric encapsulant or underfill. However, thermo-mechanical stresses within such packages often lead to failures initiating in the vicinity of chip and underfill interface. In this study, we present experimental results geared towards measuring and understanding such failure mechanisms. We provide the bulk fracture toughness of the underfill material and interfacial fracture toughness between the underfill material and the silicon die. The bulk and interfacial fracture toughness measurements are performed as a function of temperature. We use the single edge notch bending test to calculate the bulk fracture toughness of the underfill and to measure the interfacial fracture toughness, we use a novel technique referred to as the wedge delamination method. The wedge delamination method provides substantial advantage in measuring the interfacial fracture toughness for brittle materials over traditional methods. Using the wedge delamination method we compare the fracture strength between the underfill and silicon at the front-face and side-wall interfaces. Additionally, the influence of dicing technique on fracture toughness is also investigated.     

Experimental study on the thermo-mechanical effects of underfill and low-CTE substrate in a flip-chip device

Moiré interferometry was used to analyze the thermal deformation of four flip-chip devices mounted on FR-4 substrate and a new multi-layer substrate, with and without underfill. Thermal loading was applied by cooling the devices from 100 °C to room temperature (25 °C). The effects of underfill and the low-CTE (coefficient of thermal expansion) substrate on thermal deformation were investigated. The experimental results showed that the underfill curved in a manner similar to the silicon chip. For the flip-chip devices mounted on the multi-layer substrate, the CTE mismatch between the silicon chip and substrate was reduced, and bending deformation decreased. Of the four flip-chip devices studied, the underfilled flip-chip device mounted on the multi-layer substrate had the least deformed solder balls.     

Mechanical loading of flip chip joints before underfill: the impact on yield and reliability

The underfill-facilitated migration from ceramic to lower cost laminate substrates has become a powerful enabler of direct chip attach by offering lower cost, greater electrical functionality, and a smaller system footprint over comparable packaging technologies. Once underfilled, flip chip on laminate has proven extremely reliable even in severe automotive environments. However, between the process steps of reflow and underfill cure, unprotected flip chip solder joints assembled to laminate boards are susceptible to damage and breakage if mishandled. Here, the survivability and long-term reliability of flip chip joints was studied over a range of applied strains. Mechanical loading of joints was applied via beam deflections of populated, but nonunderfilled, laminate boards. Electrical continuity was monitored before and after testing to determine when the load applied to the flip chip exceeded the joint fracture strength. The propensity for solder joint fracture was then calculated as a function of solder bump size and also as a function of strain rate. Analysis of the mechanical properties of solder revealed assembly strategies which reduce bump damage and eliminate yield loss during the process steps leading up to underfill cure. Both strained and unstrained units were then underfilled and cycled between −50 and +150 °C. While mechanical damage was evident in bump cross-sections of strained flip chip assemblies, the fatigue lives of underfilled solder joints were found to be independent of the size of mechanical loads applied before underfill.     

Material properties of anisotropic conductive films (ACFs) and their flip chip assembly reliability in NAND flash memory applications

In this paper, the material properties of anisotropic conductive films (ACFs) and ACF flip chip assembly reliability for a NAND flash memory application were investigated. Measurements were taken on the curing behaviors, the coefficient of thermal expansion (CTE), the modulus, the glass transition temperature (T_g), and the die adhesion strength of six types of ACF. Furthermore, the bonding processes of the ACFs were optimized. After the ACF flip chip assemblies were fabricated with optimized bonding processes, reliability tests were then carried out. In the pressure cooker test, the ACF with the highest adhesion strength showed the best reliability and the ACF flip chip assembly revealed no delamination at the chip-ACF interface, even after 96 h. In the high temperature storage test and the thermal cycling test, the reliability of the ACF flip chip assembly strongly depends on the T_g value of the ACF. In the thermal cycling test, in particular, which gives ACF flip chip assemblies repetitive shear stress, high value of CTE above T_g accelerates the failure rate of the ACF flip chip assembly. From the reliability test results, ACFs with a high T_g and a low CTE are preferable for enhancing the thermal and thermo-mechanical reliability. In addition, a new double-sided chip package with a thickness of 570 μm was demonstrated for NAND flash memory application. In conclusion, this study verifies the ACF feasibility, and recommends the optimum ACF material properties, for NAND flash memory application.     

Procedure for design optimization of a T-cap flip chip package

In this study, a 1/4 three-dimensional finite element model of a T-cap flip chip package containing the substrate, underfill, solder bump, silicon die, metal cap and cap attachment was established to conduct thermo-mechanical reliability study during the flip chip fabrication processes. The applied thermal load was cooled from 183 °C to ambience 25 °C to determine the thermal stress and warpage during the curing period of solder ball mounting process. Under fixed geometry, two levels of underfill, metal caps and cap attachments were used to conduct the 2³ factorial design for determining reliable material combinations. The statistical tests revealed that the significant effects affecting the thermal stress were the underfill, metal cap, cap attachment and the interaction between the underfill and cap attachment. The metal cap, cap attachment and their interaction significantly affected the warpage. The proposed regression models were used to perform the surface response simulations and were useful in selecting suitable materials for constructing the package. This study provides a powerful strategy to help the designer to easily determine reliable packaging structures under various reliability considerations.     

Adhesion and toughening mechanisms at underfill interfaces forflip-chip-on-organic-substrate packaging

The flip chip-on-organic-substrate packaging technology utilizes a particulate reinforced epoxy as the underfill (UF) to adhere the chip to the package or board, Although the use of underfill encapsulation leads to improved reliability of flip-chip solder interconnections, delamination at various interfaces becomes a major concern for assembly yield loss and package reliability. In spite of their importance, the adhesion and fracture behaviors of the underfill interfaces have not been investigated until recently. Considerable controversy exists over the effects of underfill formulation and the adhesion and toughening mechanisms of the interfaces. The present work focuses on investigating the effects of several key variables on the interface adhesion strengths for UF/chip and UF/organic substrate systems. These variables are underfill organosilane content, filler particle content, rubber particle content, surface morphology and chemistry of the chip and organic substrates. The approach of this study is to measure the effect of these variables on the interfacial fracture energy using the double-cantilever-beam (DCB) techniques. The results demonstrate that the underfill interfacial adhesion and fracture characteristics are controlled by several distinct but competing mechanisms, such as formation of primary bonds, crack-pinning by glass fillers, debonding of glass filler from epoxy matrix (defect formation), and cavitation and shearing induced by rubber particles. Fundamental understanding of the interfacial adhesion and toughening mechanisms can provide guidance for developing new processes and materials to enhance interfacial adhesion and reliability     

Numerical Investigation of Underfill Failure Due to Phase Change of Pb-Free Flip Chip Solders During Board-Level Reflow

In this paper, the effects of phase change of Pb-free flip chip solders during board-level interconnect reflow are investigated using numerical technique. Most of the current Pb-free solder candidates are based on Sn and their melting temperatures are in the range of 220 $^{circ}$ C–240 $^{circ}$ C. Thus, Pb-free flip chip solders melt again during subsequent board-level interconnect (BGA) reflow cycle. Since solder volume expands as much as 4% during the phase change from solid to liquid, the volumetric expansion of solder in a predefined volume by chip, substrate, and underfill creates serious reliability issues. One issue is the shorting between neighboring flip chip interconnects by the interjected solder through underfill crack or delaminated interfaces. The authors have observed the interjection of molten solder and the interfacial failure of underfill during solder reflow process. In this paper, a flip chip package is modeled to quantify the effect of the volumetric expansion of Pb-free solder. Three possible cases are investigated. One is without existence of micro crack and the other two are with the interfacial crack between chip and underfill and the crack through the underfill. The strain energy release rate around the crack tip calculated by the modified crack closure integral method is compared with interfacial fracture toughness. Parametric studies are carried out by changing material properties of underfill and interconnect pitch. Also, the effects of solder interconnect geometry and crack length are explored. For the case with interfacial crack, the configuration of a large bulge with small pitch is preferred for the board-level interconnect, whereas a large pitch is preferred for cracks in the mid plane of the underfill.      

Adhesion issues in flip-chip on organic modules

Flip chip attach on organic carriers is a novel electronic packaging assembly method which provides advantages of high input/output (I/O) counts, electrical performance and thermal dissipation. In this structure, the flip chip device is attached to organic laminate with predeposited eutectic solder. Mechanical coupling of the chip and the laminate is done via underfill encapsulant materials. As the chip size increases, the thermal mismatch between silicon and its organic carrier becomes greater. Adhesion becomes an important factor since the C4 joints fail quickly if delamination of the underfill from either chip or the solder mask interface occurs. Newly developed underfills have been studied to examine their properties, including interfacial adhesion strength, flow characteristics, void formation and cure kinetics. This paper will describe basic investigations into the properties of these underfills and also how these properties related to the overall development process. In addition, experiments were performed to determine the effects on adhesion degradation of flip chip assembly processes and materials such as IR reflow profile, flux quantity and residues. Surface treatment of both the chip and the laminate prior to encapsulation were studied to enhance underfill adhesion. Accelerated thermal cycling and highly accelerated stress testing (HAST) were conducted to compare various underfill properties and reliability responses     

Underfill selection methodology for fine pitch Cu/low-k FCBGA packages

A systematic underfill selection approach has been presented to characterize and identify suitable underfill encapsulants for large size flip chip ball grid array (FCBGA) packages. In the selection scheme, a total of six evaluation factors such as fracture toughness, coefficient of moisture expansion, flowability, delamination performance and filler settlement were considered. Driving stresses for package failure were also included as a factor of consideration, which clearly depends on the package size and geometry. Based on the approach adopted, underfill material that is suitable for 35 × 35 mm² packages with 15 mm die size and 45 × 45 mm² packages with 21 mm die size was selected. Target value for underfill properties has also been revised.     

Influence of underfill materials on the reliability of coreless flip chip package

A flip chip package was assembled by using 6-layer laminated polyimide coreless substrate, eutectic Sn37Pb solder bump, two kinds of underfill materials and Sn_3.0Ag_0.5Cu solder balls. Regarding to the yield, the peripheral solder joints were often found not to connect with the substrate due to the warpage at high temperature, modification of reflow profile was benefit to improve this issue. All the samples passed the moisture sensitive level test with a peak temperature of 260 °C and no delamination at the interface of underfill and substrate was found. In order to know the reliability of coreless flip chip package, five test items including temperature cycle test (TCT), thermal shock test (TST), highly accelerated stress test (HAST), high temperature storage test (HTST) and thermal humidity storage test (THST) were done. Both of the two underfill materials could make the samples pass the HTST and THST, however, in the case of TCT, TST and HAST, the reliability of coreless flip chip package was dominated by underfill material. A higher Young’s modules of underfill, the more die crack failures were found. Choosing a correct underfill material was the key factor for volume production of coreless flip chip package.     

倒装芯片下填充工艺的新进展(一)

为了增加在有机基板上倒装芯片安装的可靠性,在芯片安装后,通常都要进行下填充。下填充的目的是为了重新分配由于硅芯片和有机衬底间热膨胀系数失配产生的热应力。然而,仅仅依靠填充树脂毛细管流动的传统下填充工艺存在一些缺点。为了克服这些缺点,人们研究出了一些新的材料和开发出了一些新的工艺。     

倒装芯片下填充工艺的新进展(二)

为了增加在有机基板上倒装芯片安装的可靠性,在芯片安装后,通常都要进行下填充。下填充的目的是为了重新分配由于硅芯片和有机衬底间热膨胀系数失配产生的热应力。然而,仅仅依靠填充树脂毛细管流动的传统下填充工艺存在一些缺点。为了克服这些缺点,人们研究出了一些新的材料和开发出了一些新的工艺。     

Filler size and content effects on the composite properties of anisotropic conductive films (ACFs) and reliability of flip chip assembly using ACFs

Flip chip assembly on organic board using anisotropic conductive films (ACFs) is gained more attention because of its many advantages. But to obtain more reliable flip chip assembly, it is necessary to have low coefficient of thermal expansion (CTE) value of ACFs. To control the CTE of ACF materials, non-conductive silica fillers were incorporated into ACFs. The effect of non-conductive silica filler content and size on cure kinetics and thermo-mechanical properties of ACFs was studied. Furthermore, filler content and size effects on reliability of flip chip assembly using ACFs were also investigated. In accordance with increasing filler content, curing peak temperature and storage modulus (E′) increased. But CTE decreased as the filler content increased. The effect of filler size on composite properties and assembly reliability showed similar tendency with the filler content effect. The smaller filler size was applied, the better composite properties and reliability were obtained. Conclusively, incorporation of non-conductive fillers, particularly in case of smaller size and higher content, in ACFs improves the material properties significantly, and as a result, flip chip assembly using ACFs is resulted in better reliability.